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公开(公告)号：US09051501B2
公开(公告)日：2015-06-09
申请号：US12514417
申请日：2007-11-22
IPC分类号： C08K3/26 , C09D17/00 , C09K3/10 , C08K3/16 , C08K3/36 , C08K5/16 , C08L83/00 , C08L83/04 , C08G77/08 , C08L21/00 , C08L101/10
CPC分类号： C09K3/10 , C08G77/08 , C08K3/16 , C08K3/26 , C08K3/36 , C08K5/16 , C08L21/00 , C08L101/10 , C08L71/02
摘要： An object of the present invention is to provide a curable composition made mainly of an organic polymer having a reactive silicon group, exhibits a good curability without using any organic tin compound substantially, and gives a cured product having a sufficient strength; and to provide a catalyst composition. The object is solved by a curable composition, comprising a polymer (A) having a silicon-containing group which can be crosslinked by forming a siloxane bond, and a fluoride salt compound (B).
摘要翻译： 本发明的目的是提供一种主要由具有反应性硅基团的有机聚合物制成的可固化组合物，其基本上不使用任何有机锡化合物，显示出良好的固化性，并且得到具有足够强度的固化产物; 并提供催化剂组合物。 该目的是通过可固化组合物来解决的，该组合物包含具有可通过形成硅氧烷键而交联的含硅基团的聚合物（A）和氟化物盐化合物（B）。
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公开(公告)号：US20100041810A1
公开(公告)日：2010-02-18
申请号：US12514417
申请日：2007-11-22
CPC分类号： C09K3/10 , C08G77/08 , C08K3/16 , C08K3/26 , C08K3/36 , C08K5/16 , C08L21/00 , C08L101/10 , C08L71/02
摘要： An object of the present invention is to provide a curable composition made mainly of an organic polymer having a reactive silicon group, exhibits a good curability without using any organic tin compound substantially, and gives a cured product having a sufficient strength; and to provide a catalyst composition. The object is solved by a curable composition, comprising a polymer (A) having a silicon-containing group which can be crosslinked by forming a siloxane bond, and a fluoride salt compound (B).
摘要翻译： 本发明的目的是提供一种主要由具有反应性硅基团的有机聚合物制成的可固化组合物，而基本上不使用任何有机锡化合物显示出良好的固化性，并且得到具有足够强度的固化产物; 并提供催化剂组合物。 该目的是通过可固化组合物来解决的，该组合物包含具有可通过形成硅氧烷键而交联的含硅基团的聚合物（A）和氟化物盐化合物（B）。
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公开(公告)号：US08815985B2
公开(公告)日：2014-08-26
申请号：US12526751
申请日：2008-02-13
申请人： Katsuyu Wakabayashi , Katsuya Ouchi
发明人： Katsuyu Wakabayashi , Katsuya Ouchi
CPC分类号： C08L83/04 , C08G65/2609 , C08G65/2663 , C08G65/336 , C08G65/337 , C08K5/16 , C08K5/31 , C08K5/5419 , C08K5/5425 , C08L101/10 , C08L2312/08 , C09D133/08 , C09J171/02 , C09K3/10 , C09K2200/0239 , C09K2200/0657
摘要： An object of the present invention is to provide a curable composition which is made mainly of a polymer having one or more reactive silicon groups, has good curability even when filler is used while a non-organotin catalyst is used, and is further high in industrial practicability. The object is solved by a curable composition, comprising, as constituents, a polymer (A) having one or more reactive silicon groups on average per molecule thereof, the reactive silicon group(s) being (each) a group which can be crosslinked by forming a siloxane bond, a Lewis acid and/or derivative thereof (B), an amine compound (C), a compound (D) having a reactive silicon group, and filler (E), and obtained by mixing the constituents with each other.
摘要翻译： 本发明的目的是提供一种主要由具有一个或多个反应性硅基团的聚合物制成的可固化组合物，即使使用非有机锡催化剂，即使使用填料也具有良好的固化性，并且工业上更高 实用性。 该目的通过一种可固化组合物来解决，该组合物包含平均每分子具有一个或多个反应性硅基团的聚合物（A），反应性硅基团为（各自）可以被 形成硅氧烷键，路易斯酸和/或其衍生物（B），胺化合物（C），具有反应性硅基团的化合物（D）和填料（E），并且通过将组分彼此混合 。
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公开(公告)号：US20100152373A1
公开(公告)日：2010-06-17
申请号：US12526751
申请日：2008-02-13
申请人： Katsuyu Wakabayashi , Katsuya Ouchi
发明人： Katsuyu Wakabayashi , Katsuya Ouchi
CPC分类号： C08L83/04 , C08G65/2609 , C08G65/2663 , C08G65/336 , C08G65/337 , C08K5/16 , C08K5/31 , C08K5/5419 , C08K5/5425 , C08L101/10 , C08L2312/08 , C09D133/08 , C09J171/02 , C09K3/10 , C09K2200/0239 , C09K2200/0657
摘要： An object of the present invention is to provide a curable composition which is made mainly of a polymer having one or more reactive silicon groups, has good curability even when filler is used while a non-organotin catalyst is used, and is further high in industrial practicability. The object is solved by a curable composition, comprising, as constituents, a polymer (A) having one or more reactive silicon groups on average per molecule thereof, the reactive silicon group(s) being (each) a group which can be crosslinked by forming a siloxane bond, a Lewis acid and/or derivative thereof (B), an amine compound (C), a compound (D) having a reactive silicon group, and filler (E), and obtained by mixing the constituents with each other.
摘要翻译： 本发明的目的是提供一种主要由具有一个或多个反应性硅基团的聚合物制成的可固化组合物，即使使用非有机锡催化剂，即使使用填料也具有良好的固化性，并且工业上更高 实用性。 该目的通过一种可固化组合物来解决，该组合物包含平均每分子具有一个或多个反应性硅基团的聚合物（A），反应性硅基团为（各自）可以被 形成硅氧烷键，路易斯酸和/或其衍生物（B），胺化合物（C），具有反应性硅基团的化合物（D）和填料（E），并且通过将组分彼此混合 。
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公开(公告)号：US20090171025A1
公开(公告)日：2009-07-02
申请号：US12088799
申请日：2006-10-02
IPC分类号： C08F283/12
CPC分类号： C09K3/1018 , C08G65/336 , C08K5/3462 , C08L71/02 , C08L101/10
摘要： The present invention has its object to provide, by using a non-organotin curing catalyst, a curable composition having a practical level of curability. Furthermore, the present invention has its object to provide a curable composition excellent in adhesiveness while it secures a practical level of curability.The present invention relates to a curable composition which comprises:(A) an organic polymer containing a silicon-containing group capable of crosslinking by siloxane bond formation and (B) a silanol condensation catalyst: and that the silanol condensation catalyst is an amine compound and that an aqueous solution prepared by adding 5 millimoles of the amine compound to 100 g of a mixed solvent composed of isopropyl alcohol and water in a weight ratio of 10:3 has a pH value of not lower than 13.4 as measured at 23° C. according to JIS Z 8802.
摘要翻译： 本发明的目的是通过使用非有机锡固化催化剂来提供具有实用的固化性水平的可固化组合物。 此外，本发明的目的是提供一种固化性优异的固化性组合物，同时确保了固化性的实用性。 本发明涉及一种可固化组合物，其包含：（A）含有能够通过硅氧烷键形成交联的含硅基团的有机聚合物和（B）硅烷醇缩合催化剂;所述硅烷醇缩合催化剂是胺化合物， 通过向100g由异丙醇和水组成的混合溶剂中加入5毫摩尔胺化合物而制备的水溶液，其重量比为10:3，在23℃下测得的pH值不低于13.4。 根据JIS Z 8802。
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公开(公告)号：US08013080B2
公开(公告)日：2011-09-06
申请号：US12088799
申请日：2006-10-02
IPC分类号： C08F283/00
CPC分类号： C09K3/1018 , C08G65/336 , C08K5/3462 , C08L71/02 , C08L101/10
摘要： The present invention has its object to provide, by using a non-organotin curing catalyst, a curable composition having a practical level of curability. Furthermore, the present invention has its object to provide a curable composition excellent in adhesiveness while it secures a practical level of curability. The present invention relates to a curable composition which comprises:(A) an organic polymer containing a silicon-containing group capable of crosslinking by siloxane bond formation and(B) a silanol condensation catalyst:and that the silanol condensation catalyst is an amine compound and that an aqueous solution prepared by adding 5 millimoles of the amine compound to 100 g of a mixed solvent composed of isopropyl alcohol and water in a weight ratio of 10:3 has a pH value of not lower than 13.4 as measured at 23° C. according to JIS Z 8802.
摘要翻译： 本发明的目的是通过使用非有机锡固化催化剂来提供具有实用的固化性水平的可固化组合物。 此外，本发明的目的是提供一种固化性优异的固化性组合物，同时确保了固化性的实用性。 本发明涉及一种可固化组合物，其包含：（A）含有能够通过硅氧烷键形成交联的含硅基团的有机聚合物和（B）硅烷醇缩合催化剂;所述硅烷醇缩合催化剂是胺化合物， 通过向100g由异丙醇和水组成的混合溶剂中加入5毫摩尔胺化合物而制备的水溶液，其重量比为10:3，在23℃下测得的pH值不低于13.4。 根据JIS Z 8802。
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公开(公告)号：US07807756B2
公开(公告)日：2010-10-05
申请号：US11667340
申请日：2005-11-09
IPC分类号： C08F8/30
CPC分类号： C08L101/10 , C08K5/16 , C08K5/57 , C08L75/08 , C09J175/08 , C09J201/10 , C09K3/1018 , C08L71/02
摘要： A problem of the present invention is to provide a curable composition which gives good curability, adhesiveness and storage stability by use of a catalyst other than organic tin catalysts. The above problem is solved by a curable composition, comprising: (A) one or more organic polymers having a reactive-silicon-containing group, and (B) a silanol condensation catalyst consisting of one or more compound(s) selected from organic tin compounds, carboxylic acids, and amine compounds, wherein at least one part of the reactive-silicon-containing group(s) of the organic polymer(s) (A) is represented by the following general formula (1): —(CR22)2—(SiR12-aXaO)m—SiX3 (1), and the silanol condensation catalyst (B) consists of amine compound(s) (B1) or consists of amine compound(s) (B1) and a carboxylic acid (B2), and when the mol number of the amine compound(s) is regarded as 1, the ratio by mol of the total amount of the carboxylic acid(s) to the amount of the amine compound(s) is 0.1 or less.
摘要翻译： 本发明的问题是提供一种通过使用有机锡催化剂以外的催化剂而具有良好的固化性，粘合性和保存稳定性的固化性组合物。 上述问题由可固化组合物解决，其包括：（A）一种或多种具有反应性含硅基团的有机聚合物，和（B）由一种或多种选自有机锡的化合物组成的硅烷醇缩合催化剂 化合物，羧酸和胺化合物，其中有机聚合物（A）的至少一部分反应性含硅基团由以下通式（1）表示： - （CR 22） 2-（SiR12-aXaO）m-SiX3（1）和硅烷醇缩合催化剂（B）由胺化合物（B1）或胺化合物（B1）和羧酸（B2）组成， ，当胺化合物的摩尔数为1时，羧酸的总量与胺化合物的量的摩尔比为0.1以下。
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公开(公告)号：US20070299214A1
公开(公告)日：2007-12-27
申请号：US11667340
申请日：2005-11-09
IPC分类号： C08L101/10 , C08K5/09 , C08K5/17 , C09K3/10 , C09J201/10 , C08K5/57
CPC分类号： C08L101/10 , C08K5/16 , C08K5/57 , C08L75/08 , C09J175/08 , C09J201/10 , C09K3/1018 , C08L71/02
摘要： A problem of the present invention is to provide a curable composition which gives good curability, adhesiveness and storage stability by use of a catalyst other than organic tin catalysts. The above problem is solved by a curable composition, comprising: (A) one or more organic polymers having a reactive-silicon-containing group, and (B) a silanol condensation catalyst consisting of one or more compound(s) selected from organic tin compounds, carboxylic acids, and amine compounds, wherein at least one part of the reactive-silicon-containing group(s) of the organic polymer(s) (A) is represented by the following general formula (1): —(CR22)2—(SiR12-aXaO)m—SiX3 (1), and the silanol condensation catalyst (B) consists of amine compound(s) (B1) or consists of amine compound(s) (B1) and a carboxylic acid (B2), and when the mol number of the amine compound(s) is regarded as 1, the ratio by mol of the total amount of the carboxylic acid(s) to the amount of the amine compound(s) is 0.1 or less.
摘要翻译： 本发明的问题是提供一种通过使用有机锡催化剂以外的催化剂而具有良好的固化性，粘合性和保存稳定性的固化性组合物。 上述问题由可固化组合物解决，其包括：（A）一种或多种具有反应性含硅基团的有机聚合物，和（B）由一种或多种选自有机锡的化合物组成的硅烷醇缩合催化剂 化合物，羧酸和胺化合物，其中有机聚合物（A）的至少一部分反应性含硅基团由以下通式（1）表示： - （CR < 2 2 2 2 2 （1），硅烷醇缩合催化剂（B）由胺化合物（B1）组成或由胺组成的胺 化合物（B1）和羧酸（B2），当胺化合物的摩尔数被认为是1时，羧酸的总量的摩尔数相对于羧酸的总量 的胺化合物为0.1以下。
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9.发明授权Moisture curable polymer having SiF group, and curable composition containing the same 有权具有SiF基的水分固化性聚合物和含有它们的固化性组合物公开(公告)号：US08124690B2
公开(公告)日：2012-02-28
申请号：US12441270
申请日：2007-08-23
IPC分类号： C08L83/12
CPC分类号： C08G65/33306 , C08G65/2609 , C08G65/2663 , C08G65/30 , C08G65/323 , C08G65/33317 , C08G65/336 , C08G65/337 , C08G2650/48 , C08L71/02 , C08L2666/22 , C09J143/04 , C09J171/02
摘要： A moisture curable polymer and a curable composition having superior curability are provided. A polymer having a silicon group represented by the general formula: —SiFaR1bZc (wherein, R1 represents any one of a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, or an organosiloxy group represented by R23SiO— (R2 is each independently, a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms). Z is a hydroxyl group or a hydrolyzable group other than fluorine. a is any one of 1, 2, or 3; b is any one of 0, 1, or 2; c is any one of 0, 1, or 2; and a+b+c is 3. When b or c is 2, two R1 or two Z may be each the same or different) and a curable composition including this polymer, and a sealant and an adhesive in which the curable composition is used.
摘要翻译： 提供了一种可湿固化聚合物和具有优异固化性的可固化组合物。 具有由以下通式表示的硅基的聚合物：-SiFaR1bZc（其中，R1表示取代或未取代的碳原子数1〜20的烃基或由R23SiO-表示的有机甲硅烷氧基（R2各自独立地为 取代或未取代的碳原子数1〜20的烃基）Z是除氟以外的羟基或水解性基团，a为1,2或3中任一个，b为0,1或2中任一个， c是0，1或2中的任一个; a + b + c为3.当b或c为2时，两个R 1或两个Z可以相同或不同）和包含该聚合物的可固化组合物和 使用可固化组合物的密封剂和粘合剂。
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10.发明申请Method for Producing a-hereto-Substituted Alkylhalohydrosilane and Use Thereof 审中-公开制备α-取代的烷基卤代氢硅烷的方法及其用途公开(公告)号：US20110207886A1
公开(公告)日：2011-08-25
申请号：US13003300
申请日：2011-01-09
IPC分类号： C08G65/336 , C08F8/42
CPC分类号： C07F7/126 , C08F8/42 , C08G65/336 , C08L63/00
摘要： Method for efficiently producing α-hetero-substituted alkylhalohydrosilane, and use thereof. A method for producing (A) a halohydrosilane compound represented by the general formula (1): H—SiR2c(CR13-bYb)aX3-a-c (1) (wherein, R1 represents a hydrogen atom or a substituted or unsubstituted hydrocarbon group; R2 represents a substituted or unsubstituted hydrocarbon group; X represents a halogen atom; Y represents a hetero substituent; a is 1 or 2; b is any one of 1, 2 and 3; c is 1 or 0), by allowing (B) a halosilane compound represented by the general formula (2): SiR2c(CR13-bYb)aX4-a-c (2) (wherein, R1, R2, X, Y, a, b and c are as defined above) to react with (C) a hydrosilane compound. A method for producing a reactive silicon group-containing polymer using the halohydrosilane compound (A).
摘要翻译： 有效生产α-取代烷基卤代氢硅烷的方法及其应用。 （A）由通式（1）表示的卤代氢硅烷化合物的制备方法：H-SiR2c（CR13-bYb）aX3-ac（1）（其中，R1表示氢原子或取代或未取代的烃基; R2 表示取代或未取代的烃基; X表示卤素原子; Y表示杂取代基; a表示1或2; b表示1,2或3中的任一个，c表示1或0） 由式（2）表示的卤代硅烷化合物：（C））与SiRcc（CR13-bYb）aX4-ac（2）（其中R1，R2，X，Y，a，b和c如上定义） 氢硅烷化合物。 使用卤代氢硅烷化合物（A）制造含反应性含硅基团的聚合物的方法。
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