公开(公告)号：US4510024A

公开(公告)日：1985-04-09

申请号：US542950

申请日：1983-10-18

申请人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai ,  Hajime Asai

发明人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai ,  Hajime Asai

IPC分类号： C08F2/58 ,  C09D5/44 ,  C25B3/00

CPC分类号： C08F2/58 ,  C09D5/4476

摘要： A polymer composition in which an organic polymer and carbon fiber are strongly combined and a process for producing the polymer composition by the electrolytic polymerization of a reactive monomer using the carbon fiber as an electrode, which process is characterized in that the polymerization is carried out by adding an aliphatic epoxy compound, alicyclic epoxy compound, organic titanate compound, or vinylsilane compound, as part or all of the reactive monomer.

摘要翻译： 其中有机聚合物和碳纤维被强力组合的聚合物组合物和通过使用碳纤维作为电极的反应性单体的电解聚合制备聚合物组合物的方法，该方法的特征在于聚合由 添加脂族环氧化合物，脂环族环氧化合物，有机钛酸酯化合物或乙烯基硅烷化合物作为反应性单体的一部分或全部。

公开(公告)号：US4435540A

公开(公告)日：1984-03-06

申请号：US336460

申请日：1981-12-31

申请人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai

发明人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai

IPC分类号： C08F2/44 ,  C08K3/04 ,  C08K3/00 ,  C08K3/08 ,  C08K3/26

CPC分类号： C08F2/44

摘要： A polymer composition wherein an inorganic substance and an organic polymer are firmly consolidated, which is characterized by being produced by polymerizing a vinyl monomer susceptible to radical polymerization in a polymerization system containing a dispersed inorganic substance in the presence of at least one monomer selected from sulfonic acid monomers, sulfonate monomers, or carboxylic acid monomers represented by the general formula [I] ##STR1## wherein R.sub.1 is a hydrogen atom, alkyl group having 1 to 20 carbon atoms, phenyl group, derivative of phenyl group, or halogen atom, X is CONH, ##STR2## COO(CH.sub.2).sub.m or (CH.sub.2).sub.n (wherein R.sub.2 and R.sub.3 are each a hydrogen atom or alkyl group having 1 to 15 carbon atoms, R.sub.4 is an alkylene group having 1 to 15 carbon atoms, m is an integer of 1 to 20, and n is an integer of 0 to 20), and Y is a hydrogen atom, ammonium radical, or an alkali metal atom, or by the general formula [II] ##STR3## wherein R.sub.5 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.6 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.7 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group, and Z is a hydrogen atom, ammonium radical, or alkali metal atom, or by the general formula [III] ##STR4## wherein R.sub.8 and R.sub.9 are each a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group.

摘要翻译： 一种聚合物组合物，其中无机物质和有机聚合物被牢固地固化，其特征在于通过在含有分散的无机物质的聚合体系中聚合具有自由基聚合的乙烯基单体在至少一种选自以下的单体 由通式[I]表示的酸单体，磺酸酯单体或羧酸单体其中R1是氢原子，具有1-20个碳原子的烷基，苯基，苯基衍生物或卤素 原子，X为CONH，COO（CH 2）m或（CH 2）n（其中R 2和R 3各自为氢原子或具有1至15个碳原子的烷基，R 4为具有1至15个碳原子的亚烷基 m为1〜20的整数，n为0〜20的整数，Y为氢原子，铵基或碱金属原子，通式[II]表示。[II] ]其中R5是氢原子，具有1至1的烷基 5个碳原子，COOZ，卤素原子，苯基或苯基的衍生物，R6是氢原子，具有1至15个碳原子的烷基，COOZ，卤素原子，苯基或苯基的衍生物，R7是 氢原子，碳原子数1〜15的烷基，卤素原子，苯基或苯基的衍生物，Z为氢原子，铵基或碱金属原子，或通式[III] [III]其中R8和R9各自为氢原子，具有1至15个碳原子的烷基，卤素原子，苯基或苯基的衍生物。

公开(公告)号：US4546145A

公开(公告)日：1985-10-08

申请号：US640252

申请日：1984-08-14

申请人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai

发明人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai

IPC分类号： C08F2/44 ,  C08K3/04 ,  C08K3/00 ,  C08K3/08 ,  C08K3/26

CPC分类号： C08F2/44

摘要： A polymer composition wherein an inorganic substance and an organic polymer are firmly consolidated, which is characterized by being produced by polymerizing a vinyl monomer susceptible to radical polymerization in a polymerization system containing a dispersed inorganic substance in the presence of at least one monomer selected from sulfonic acid monomers, sulfonate monomers, or carboxylic acid monomers represented by the general formula [I] ##STR1## wherein R.sub.1 is a hydrogen atom, alkyl group having 1 to 20 carbon atoms, phenyl group, derivative of phenyl group, or halogen atom, X is CONH, ##STR2## COO(CH.sub.2).sub.m or (CH.sub.2).sub.n (wherein R.sub.2 and R.sub.3 are each a hydrogen atom or alkyl group having 1 to 15 carbon atoms, R.sub.4 is an alkylene group having 1 to 15 carbon atoms, m is an integer of 1 to 20, and n is an integer of 0 to 20), and Y is a hydrogen atom, ammonium radical, or an alkali metal atom, or by the general formula [II] ##STR3## wherein R.sub.5 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.6 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.7 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group, and Z is a hydrogen atom, ammonium radical, or alkali metal atom, or by the general formula [III] ##STR4## wherein R.sub.8 and R.sub.9 are each a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group.

摘要翻译： 一种聚合物组合物，其中无机物质和有机聚合物被牢固地固化，其特征在于通过在含有分散的无机物质的聚合体系中聚合具有自由基聚合的乙烯基单体在至少一种选自以下的单体 由通式[I]表示的酸单体，磺酸酯单体或羧酸单体其中R1是氢原子，具有1-20个碳原子的烷基，苯基，苯基衍生物或卤素 原子，X为CONH，COO（CH 2）m或（CH 2）n（其中R 2和R 3各自为氢原子或具有1至15个碳原子的烷基，R 4为具有1至15个碳原子的亚烷基 m为1〜20的整数，n为0〜20的整数，Y为氢原子，铵基或碱金属原子，通式[II]表示。[II] ]其中R5是氢原子，具有1至1的烷基 5个碳原子，COOZ，卤素原子，苯基或苯基的衍生物，R6是氢原子，具有1至15个碳原子的烷基，COOZ，卤素原子，苯基或苯基的衍生物，R7是 氢原子，碳原子数1〜15的烷基，卤素原子，苯基或苯基的衍生物，Z为氢原子，铵基或碱金属原子，或通式[III] [III]其中R8和R9各自为氢原子，具有1至15个碳原子的烷基，卤素原子，苯基或苯基的衍生物。

公开(公告)号：US5047442A

公开(公告)日：1991-09-10

申请号：US227606

申请日：1988-08-02

申请人： Isao Sasaki ,  Nobuhiro Mukai

发明人： Isao Sasaki ,  Nobuhiro Mukai

IPC分类号： C08F2/50 ,  C08F4/40 ,  G03F7/031

CPC分类号： C08F2/50 ,  G03F7/031

摘要： A photopolymerizable composition comprising a vinylic compound, a sulfur-containing compound and an .alpha.-diketone is disclosed. The sulfur-containing compound may be a mercaptobenzoic acid or a polysulfide.

公开(公告)号：US4762863A

公开(公告)日：1988-08-09

申请号：US84096

申请日：1987-08-11

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： A61K6/083 ,  A61K6/09 ,  A61K6/08

CPC分类号： A61K6/09 ,  A61K6/083

摘要： Disclosed is a photopolymerizable dental composition consisting essentially of (A) a composite filler obtained by non-catalytically polymerizing a carboxylic acid monomer with a vinyl monomer in a polymerization system having an inorganic compound dispersed therein; (B) a monomer mixture composed of 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, at least one hexafunctional urethane methacrylate having an isocyanuric acid skeleton, and an ethylenic vinyl monomer diluent; and (C) a photopolymerization initiator. The composite resin obtained by curing this dental composition has high mechanical strength and good water resistance.

公开(公告)号：US4910251A

公开(公告)日：1990-03-20

申请号：US246737

申请日：1988-09-20

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： C08F2/44 ,  C08F292/00

CPC分类号： C08F292/00

摘要： A method for preparing a polymeric composition in which an inorganic compound is firmly consolidated in an organic polymer, which comprises polymerizing at least one radical polymerizable vinyl monomer in an aqueous medium polymerization system comprising an inorganic compound dispersed in the presence of an organic acid monomer or organic acid salt monomer, by using a radical polymerization initiator.

公开(公告)号：US4678819A

公开(公告)日：1987-07-07

申请号：US767433

申请日：1985-08-20

申请人： Isao Sasaki ,  Nobuhiro Mukai

发明人： Isao Sasaki ,  Nobuhiro Mukai

IPC分类号： C04B26/04 ,  C08K7/14 ,  C08K3/00 ,  C08K9/00 ,  C08K9/04

CPC分类号： C04B26/04 ,  C04B2111/545

摘要： A composition for artificial marble which comprises a polymer composition in which an inorganic substance and an organic polymer are firmly bound in one body and a vinyl compound, said polymer composition being obtained by polymerizing a polymerizable vinyl monomer, in the presence of at least one monomer selected from the group consisting of carboxylic acid monomer, sulfonic acid monomer, and sulfonate monomer, in an aqueous polymerization system containing an inorganic substance dispersed therein; and a processs for producing artificial marble from said composition by cast polymerization with the addition of a polymerization initiator.

摘要翻译： 一种人造大理石用组合物，其特征在于，包含无机物和有机聚合物在一体中牢固地结合的聚合物组合物和乙烯基化合物，所述聚合物组合物是通过使聚合性乙烯基单体在至少一种单体 选自由羧酸单体，磺酸单体和磺酸酯单体组成的组，其含有分散在其中的无机物质的水性聚合体系; 以及通过加入聚合引发剂通过浇铸聚合从所述组合物生产人造大理石的方法。

公开(公告)号：US4783501A

公开(公告)日：1988-11-08

申请号：US898496

申请日：1986-08-21

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： C08F2/44 ,  C08F292/00 ,  C08K3/02

CPC分类号： C08F292/00

摘要： A method for preparing a polymeric composition in which an inorganic compound is firmly consolidated in an organic polymer, which comprises polymerizing at least one radical polymerizable vinyl monomer in an aqueous medium polymerization system comprising an inorganic compound dispersed in the presence of an organic acid monomer or organic acid salt monomer, by using a radical polymerization initiator.

摘要翻译： 一种制备聚合物组合物的方法，其中无机化合物牢固地固结在有机聚合物中，其包括在包含在有机酸单体存在下分散的无机化合物的水性介质聚合体系中聚合至少一种可自由基聚合的乙烯基单体，或 有机酸盐单体，通过使用自由基聚合引发剂。

公开(公告)号：US4977197A

公开(公告)日：1990-12-11

申请号：US192931

申请日：1988-05-12

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： A61K6/08 ,  A61K6/083 ,  A61K6/09

CPC分类号： A61K6/083 ,  A61K6/09

摘要： A photopolymerizable dental composition, which comprises:(A) an organic composite filler obtained by polymerizing at least one carboxylic acid monomer of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOY group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.2 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOZ group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.3 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a halogen atom, or a phenyl group or a derivative thereof; and each of X, Y and Z is a hydrogen atom, NH.sub.4 or an alkali metal atom; or the formula: ##STR2## wherein each of R.sub.4 and R.sub.5 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a halogen atom, or a phenyl group or a derivative thereof; and at least one radical polymerizable vinyl monomer in a polymerization system in which an inorganic compound is dispersed;(B) a monomer mixture comprising 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, at least one hexa-functional urethane (meth)acrylate of the formula: ##STR3## wherein n is an integer of from 1 to 10, and each of R.sub.1 and R.sub.2 which may be the same or different is a hydrogen atom or a methyl group, and a diluting ethylenic vinyl monomer; and(C) a photopolymerization initiator comprising an .alpha.-diketone compound and a reducing agent, wherein the reducing agent is a diaminobenzophenone compound of the formula: ##STR4## wherein each of R.sub.1 to R.sub.4 which may be the same or different is a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group, provided that at least one of them is the alkyl group.

摘要翻译： 一种可光聚合的牙科用组合物，其包含：（A）通过聚合至少一种下式的羧酸单体获得的有机复合填料：其中R 1是氢原子，C 1 -C 15烷基，-COOY基， 卤素原子或苯基或其衍生物; R2是氢原子，C1-C15烷基，-COOZ基，卤原子或苯基或其衍生物; R3是氢原子，C1-C15烷基，卤原子或苯基或其衍生物; X，Y和Z各自为氢原子，NH 4或碱金属原子; 或下式：其中R 4和R 5各自为氢原子，C 1 -C 15烷基，卤原子或苯基或其衍生物; 和在其中分散无机化合物的聚合体系中的至少一种可自由基聚合的乙烯基单体; （B）包含2,2-双[4-（甲基丙烯酰氧基乙氧基）苯基]丙烷，至少一种下式的六官能氨基甲酸酯（甲基）丙烯酸酯的单体混合物：其中n为1至10的整数 R 1和R 2可以相同或不同，为氢原子或甲基，稀释乙烯基乙烯基单体; 和（C）包含α-二酮化合物和还原剂的光聚合引发剂，其中还原剂是下式的二氨基二苯甲酮化合物：其中可以相同或不同的R 1至R 4各自为氢原子 或C 1 -C 5烷基，条件是它们中的至少一个是烷基。 n

公开(公告)号：US4933376A

公开(公告)日：1990-06-12

申请号：US184803

申请日：1988-04-22

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： A61K6/083 ,  A61K6/09

CPC分类号： A61K6/083 ,  A61K6/087 ,  A61K6/09

摘要： A photopolymerizable dental composition, which comprises:(A) an organic composite filler obtained by polymerizing a sulfonic acid or sulfonate monomer of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.20 alkyl group, a phenyl group or a derivative thereof, or a halogen atom; ##STR2## wherein each of R.sub.2 and R.sub.3 is a hydrogen atom or a C.sub.1 -C.sub.15 alkyl group, R.sub.4 is a C.sub.1 -C.sub.15 alkylene group, m is an integer of from 1 to 20 and n is an integer of from 0 to 20; and Y is a hydrogen atom, NH.sub.4 or an alkali metal atom, and at least one radical polymerizable vinyl monomer in a polymerization system in which an inorganic compound is dispersed;(B) a monomer mixture comprising 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, at least one hexa-functional urethane (meth)acrylate of the formula: ##STR3## wherein X is ##STR4## wherein n is an integer of from 1 to 10, and each of R.sub.1 and R.sub.2 which may be the same or different is a hydrogen atom or a methyl group, and a diluting ethylenic vinyl monomer; and(C) a photopolymerization initiator comprising an .alpha.-diketone compound and a reducing agent, wherein the reducing agent is at least one member selected from the group consisting of diaminobenzophenone compounds of the formula: ##STR5## wherein each of R.sub.1 to R.sub.4 which may be the same or different is a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group, provided that at least one of them is the alkyl group, and C.sub.5 -C.sub.10 alkyl esters of 4-(N,N-dimethylamino)benzoic acid.