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    Novel polymer composition
    1.
    发明授权
    Novel polymer composition 失效
    新型聚合物组成

    公开(公告)号：US4510024A

    公开(公告)日：1985-04-09

    申请号：US542950

    申请日：1983-10-18

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai ,  Hajime Asai

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai ,  Hajime Asai

    IPC分类号： C08F2/58 ,  C09D5/44 ,  C25B3/00

    CPC分类号： C08F2/58 ,  C09D5/4476

    摘要： A polymer composition in which an organic polymer and carbon fiber are strongly combined and a process for producing the polymer composition by the electrolytic polymerization of a reactive monomer using the carbon fiber as an electrode, which process is characterized in that the polymerization is carried out by adding an aliphatic epoxy compound, alicyclic epoxy compound, organic titanate compound, or vinylsilane compound, as part or all of the reactive monomer.

    摘要翻译： 其中有机聚合物和碳纤维被强力组合的聚合物组合物和通过使用碳纤维作为电极的反应性单体的电解聚合制备聚合物组合物的方法，该方法的特征在于聚合由 添加脂族环氧化合物，脂环族环氧化合物，有机钛酸酯化合物或乙烯基硅烷化合物作为反应性单体的一部分或全部。

    Novel polymer composition
    2.
    发明授权
    Novel polymer composition 失效
    新型聚合物组成

    公开(公告)号：US4435540A

    公开(公告)日：1984-03-06

    申请号：US336460

    申请日：1981-12-31

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai

    IPC分类号： C08F2/44 ,  C08K3/04 ,  C08K3/00 ,  C08K3/08 ,  C08K3/26

    CPC分类号： C08F2/44

    摘要： A polymer composition wherein an inorganic substance and an organic polymer are firmly consolidated, which is characterized by being produced by polymerizing a vinyl monomer susceptible to radical polymerization in a polymerization system containing a dispersed inorganic substance in the presence of at least one monomer selected from sulfonic acid monomers, sulfonate monomers, or carboxylic acid monomers represented by the general formula [I] ##STR1## wherein R.sub.1 is a hydrogen atom, alkyl group having 1 to 20 carbon atoms, phenyl group, derivative of phenyl group, or halogen atom, X is CONH, ##STR2## COO(CH.sub.2).sub.m or (CH.sub.2).sub.n (wherein R.sub.2 and R.sub.3 are each a hydrogen atom or alkyl group having 1 to 15 carbon atoms, R.sub.4 is an alkylene group having 1 to 15 carbon atoms, m is an integer of 1 to 20, and n is an integer of 0 to 20), and Y is a hydrogen atom, ammonium radical, or an alkali metal atom, or by the general formula [II] ##STR3## wherein R.sub.5 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.6 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.7 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group, and Z is a hydrogen atom, ammonium radical, or alkali metal atom, or by the general formula [III] ##STR4## wherein R.sub.8 and R.sub.9 are each a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group.

    摘要翻译： 一种聚合物组合物，其中无机物质和有机聚合物被牢固地固化，其特征在于通过在含有分散的无机物质的聚合体系中聚合具有自由基聚合的乙烯基单体在至少一种选自以下的单体 由通式[I]表示的酸单体，磺酸酯单体或羧酸单体其中R1是氢原子，具有1-20个碳原子的烷基，苯基，苯基衍生物或卤素 原子，X为CONH，COO（CH 2）m或（CH 2）n（其中R 2和R 3各自为氢原子或具有1至15个碳原子的烷基，R 4为具有1至15个碳原子的亚烷基 m为1〜20的整数，n为0〜20的整数，Y为氢原子，铵基或碱金属原子，通式[II]表示。[II] ]其中R5是氢原子，具有1至1的烷基 5个碳原子，COOZ，卤素原子，苯基或苯基的衍生物，R6是氢原子，具有1至15个碳原子的烷基，COOZ，卤素原子，苯基或苯基的衍生物，R7是 氢原子，碳原子数1〜15的烷基，卤素原子，苯基或苯基的衍生物，Z为氢原子，铵基或碱金属原子，或通式[III] [III]其中R8和R9各自为氢原子，具有1至15个碳原子的烷基，卤素原子，苯基或苯基的衍生物。

    Polymer composition
    3.
    发明授权
    Polymer composition 失效
    聚合物组成

    公开(公告)号：US4546145A

    公开(公告)日：1985-10-08

    申请号：US640252

    申请日：1984-08-14

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai

    IPC分类号： C08F2/44 ,  C08K3/04 ,  C08K3/00 ,  C08K3/08 ,  C08K3/26

    CPC分类号： C08F2/44

    摘要： A polymer composition wherein an inorganic substance and an organic polymer are firmly consolidated, which is characterized by being produced by polymerizing a vinyl monomer susceptible to radical polymerization in a polymerization system containing a dispersed inorganic substance in the presence of at least one monomer selected from sulfonic acid monomers, sulfonate monomers, or carboxylic acid monomers represented by the general formula [I] ##STR1## wherein R.sub.1 is a hydrogen atom, alkyl group having 1 to 20 carbon atoms, phenyl group, derivative of phenyl group, or halogen atom, X is CONH, ##STR2## COO(CH.sub.2).sub.m or (CH.sub.2).sub.n (wherein R.sub.2 and R.sub.3 are each a hydrogen atom or alkyl group having 1 to 15 carbon atoms, R.sub.4 is an alkylene group having 1 to 15 carbon atoms, m is an integer of 1 to 20, and n is an integer of 0 to 20), and Y is a hydrogen atom, ammonium radical, or an alkali metal atom, or by the general formula [II] ##STR3## wherein R.sub.5 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.6 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.7 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group, and Z is a hydrogen atom, ammonium radical, or alkali metal atom, or by the general formula [III] ##STR4## wherein R.sub.8 and R.sub.9 are each a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group.

    摘要翻译： 一种聚合物组合物，其中无机物质和有机聚合物被牢固地固化，其特征在于通过在含有分散的无机物质的聚合体系中聚合具有自由基聚合的乙烯基单体在至少一种选自以下的单体 由通式[I]表示的酸单体，磺酸酯单体或羧酸单体其中R1是氢原子，具有1-20个碳原子的烷基，苯基，苯基衍生物或卤素 原子，X为CONH，COO（CH 2）m或（CH 2）n（其中R 2和R 3各自为氢原子或具有1至15个碳原子的烷基，R 4为具有1至15个碳原子的亚烷基 m为1〜20的整数，n为0〜20的整数，Y为氢原子，铵基或碱金属原子，通式[II]表示。[II] ]其中R5是氢原子，具有1至1的烷基 5个碳原子，COOZ，卤素原子，苯基或苯基的衍生物，R6是氢原子，具有1至15个碳原子的烷基，COOZ，卤素原子，苯基或苯基的衍生物，R7是 氢原子，碳原子数1〜15的烷基，卤素原子，苯基或苯基的衍生物，Z为氢原子，铵基或碱金属原子，或通式[III] [III]其中R8和R9各自为氢原子，具有1至15个碳原子的烷基，卤素原子，苯基或苯基的衍生物。

    Delustering coating composition excellent in abrasion resistance
    5.
    发明授权
    Delustering coating composition excellent in abrasion resistance 失效
    具有优异耐磨性的清漆涂料组合物

    公开(公告)号：US4518472A

    公开(公告)日：1985-05-21

    申请号：US525895

    申请日：1983-08-24

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Masahiro Sugimori

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Masahiro Sugimori

    IPC分类号： C08F2/48 ,  C08F285/00 ,  C08J7/04 ,  C09D4/06 ,  C08F220/00 ,  C09D3/00

    CPC分类号： C08J7/047 ,  C08F285/00 ,  C09D4/06 ,  C08J2333/06 ,  C08J2433/00

    摘要： A coating composition curable by an activation energy ray, which comprises (a) 100 parts by weight of a monomer mixture (A) comprising at least 30% by weight of a compound having at least 3 acryloyloxy and/or methacryloyloxy groups in the molecule and up to 70% by weight of a compound having 1 to 2 .alpha.,.beta.-ethylenically unsaturated bonds in the molecule, (b) 0.01 to 6.0 parts by weight of at least one photosensitizer and (c) 0.5 to 30 parts by weight of an emulsion type crosslinked polymer or copolymer of a reactive monomer having one .alpha.,.beta.-ethylenically unsaturated bond in the molecule and a reactive monomer having at least two .alpha.,.beta.-ethylenically unsaturated bonds in the molecule.

    摘要翻译： 一种由活化能射线固化的涂料组合物，其包含（a）100重量份的包含至少30重量％的分子中具有至少3个丙烯酰氧基和/或甲基丙烯酰氧基的化合物的单体混合物（A），和 至多70重量％的分子中具有1至2个α，β-烯属不饱和键的化合物，（b）0.01至6.0重量份的至少一种光敏剂和（c）0.5至30重量份的 分子中具有一个α，β-烯属不饱和键的反应性单体的乳液型交联聚合物或共聚物，以及在分子中具有至少两个α，β-烯属不饱和键的反应性单体。

    Flame retardant polyester resin compositions
    6.
    发明授权
    Flame retardant polyester resin compositions 失效
    阻燃聚酯树脂组合物

    公开(公告)号：US4504608A

    公开(公告)日：1985-03-12

    申请号：US461228

    申请日：1983-01-26

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    IPC分类号： C08L67/00 ,  C08G59/00 ,  C08K3/00 ,  C08K3/22 ,  C08K5/3492 ,  C08K5/3495 ,  C08L63/00 ,  C08L67/02 ,  C08L63/02

    CPC分类号： C08K5/34924

    摘要： Flame retardant reinforced with polyester resin compositions are disclosed glass fiber and a system of flame retardants represented by the following general formulas (I) and (II), together with antimony trioxide. The flame retardant system is a blend of 1-20 parts by weight of component (I), and 2-30 parts by weight of component (II), provided the weight ratio (I)/(II) of the flame retardant component (I) to (II) is in the range of 0.2

    摘要翻译： 公开了用聚酯树脂组合物增强的阻燃剂，由下列通式（I）和（II）表示的玻璃纤维和阻燃剂体系以及三氧化锑。 阻燃剂体系是1-20重量份组分（I）和2-30重量份组分（II）的混合物，只要阻燃组分的重量比（I）/（II） I）至（II）在0.2 <（I）/（II）<4的范围内，阻燃剂（I）+（II）的总量在3-40重量份的范围内。 存在2至30重量份的三氧化锑，并且还存在5至60重量％的玻璃纤维，这两个百分比基于总树脂组合物的重量来表示。 树脂组合物除了是阻燃剂外还具有出色的机械，热性能和成型性。 其中X是氢，氯或溴，m的平均值为0至11，n的平均值为0至7，卤素 含量为10重量％以上。 R1和R2的值在附件说明书中给出。

    Coating composition and process for preparing synthetic resin shaped articles by using same
    7.
    发明授权
    Coating composition and process for preparing synthetic resin shaped articles by using same 失效
    涂料组合物及其制备方法

    公开(公告)号：US4367245A

    公开(公告)日：1983-01-04

    申请号：US246942

    申请日：1981-03-24

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    IPC分类号： C08F20/00 ,  B05D3/06 ,  B05D7/02 ,  C08F2/48 ,  C08F20/10 ,  C08F20/26 ,  C08F22/10 ,  C08F220/28 ,  C08F290/00 ,  C08F299/02 ,  C08J7/04 ,  C09D4/00 ,  C09D133/04

    CPC分类号： C08F22/105 ,  C09D4/00

    摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer mixture comprising (i) 25-75 wt. % of at least one polyfunctional monomer of the formula (I): ##STR1## wherein at least three of X.sub.11, X.sub.12, X.sub.13, X.sub.22, X.sub.23 -X.sub.n2, X.sub.n3 and X.sub.14 are CH.sub.2 .dbd.CH.C00-- and the remaining groups are --OH, and n is an integer of 1-5, (ii) 25-75 wt. % of at least one polyfunctional monomer of the formula (II): ##STR2## wherein at least three of the R groups are CH.sub.2 .dbd.CH COO-- and each of the remaining is H or --OH, n.sub.1, n.sub.2, n.sub.3, n.sub.4, m.sub.1, m.sub.2, m.sub.3 and m.sub.4 are integers of 0, 1 or 2, and X is an integer of 1 to 10 and (iii) 0 to 50 wt. % of a monomer containing one acryloyloxy group and having a boiling point of at least 150.degree. C. at normal pressure and a viscosity of not higher than 20 cps/20.degree. C., and (b) 0.01-6.0 wt. parts, based on 100 wt. parts of the polyfunctional monomer mixture, of at least one photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with utraviolet rays in air to form a crosslinked coating film having a thickness of 1-30 microns.

    摘要翻译： 描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。 该组合物包含（a）多官能单体混合物，其包含（i）25-75wt。 ％的至少一种式（I）的多官能单体：其中X11，X12，X13，X22，X23-Xn2，Xn3和X14中的至少三个是CH2 = CH。 C00-，其余基团为-OH，n为1-5的整数，（ii）25-75wt。 ％的至少一种式（II）的多官能单体：其中至少三个R基团是CH 2 = CH COO-，并且其中每一个是H或-OH， n1，n2，n3，n4，m1，m2，m3和m4为0,1或2的整数，X为1〜10的整数，（iii）0〜50重量％ ％的含有1个丙烯酰氧基的单体，沸点在常压下为至少150℃，粘度不高于20cps / 20℃，（b）0.01-6.0wt。 基于100wt。 部分多官能单体混合物，至少一种光敏剂。 将涂料组合物涂布在合成树脂成型制品上，然后在空气中用紫外线照射，形成厚度为1-30微米的交联涂膜。

    Flame retardant polyester resin compositions
    8.
    发明授权
    Flame retardant polyester resin compositions 失效
    阻燃聚酯树脂组合物

    公开(公告)号：US4562216A

    公开(公告)日：1985-12-31

    申请号：US568531

    申请日：1984-01-05

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    IPC分类号： C08L67/00 ,  C08K5/06 ,  C08K5/1515 ,  C08L67/02

    CPC分类号： C08K5/06 ,  C08K5/1515 ,  C08L67/02

    摘要： Flame retardant reinforced with thermoplastic polyester resin compositions are disclosed glass fiber and a system of flame retardants represented by the following general formulas (I) and (II), together with antimony trioxide. The flame retardant system is a blend of 1-20 parts by weight of component (I), and 2-40 parts by weight of component (II), provided the weight ratio (I)/(II) of the flame retardant components (I) to (II) is in the range of 0

    摘要翻译： 公开了用热塑性聚酯树脂组合物增强的阻燃剂，由下列通式（I）和（II）表示的玻璃纤维和阻燃剂体系以及三氧化锑。 阻燃剂体系是1-20重量份组分（I）和2-40重量份组分（II）的混合物，只要阻燃组分的重量比（I）/（II） I）至（II）的范围在0 <（I）/（II）≤5的范围内，阻燃剂（I）+（II）的总量在3-40份的范围内， 重量。 存在2至3重量份的三氧化锑，并且还存在5至60重量％的玻璃纤维，这两个百分比基于总树脂组合物的重量来表示。 树脂组合物除了具有阻燃性外，还具有突出的机械，热，成型和机加工性能。 其中X是氢，氯或溴，其中1和m的平均值分别为0〜11，卤素含量为10％以上， 重量。 R1和R2的值在附件说明书中给出。

    Glass fiber reinforced polyethylene terephthalate resin composition
    9.
    发明授权
    Glass fiber reinforced polyethylene terephthalate resin composition 失效
    玻璃纤维增​​强聚对苯二甲酸乙二醇酯树脂组合物

    公开(公告)号：US4351751A

    公开(公告)日：1982-09-28

    申请号：US217095

    申请日：1980-12-16

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    IPC分类号： C08K5/098 ,  C08K7/14 ,  C08L67/02 ,  C08L91/08

    CPC分类号： C08K5/098 ,  C08K7/14 ,  C08L67/02

    摘要： Polyethylene terephthalate type resin-containing molding compositions reinforced with glass fibers also containing from 0.03 to 5 weight percent of an organic caboxylic acid metal salt such as sodium stearate and an ether compound such as polyoxyethylene monononylphenyl ether present in an amount of from 0.1 up to 20 weight percent in which the average number of recurring alkylene oxide units is from 5 to 200 are disclosed. Also a solid or liquid paraffin or polyethylene wax may be included in an amount of from 0.3 to 5 weight percent. Moldings made from the disclosed compositions have a uniform appearance and exhibit improved heat resistance.

    摘要翻译： 还含有0.03〜5重量％的有机羧酸金属盐如硬脂酸钠和乙醚化合物如聚氧乙烯单壬基苯基醚的玻璃纤维增​​强聚对苯二甲酸乙二醇酯型树脂成型组合物，其量为0.1至20 公开了其中平均循环氧化烯单元数为5至200的重量百分数。 固体或液体石蜡或聚乙烯蜡的含量也可以为0.3〜5重量％。 由所公开的组合物制成的模制品具有均匀的外观并且显示出改进的耐热性。