Synthesis of nanoparticles comprising metal (III) vanadate
    7.
    发明授权
    Synthesis of nanoparticles comprising metal (III) vanadate 有权
    包含钒酸金属(III)的纳米颗粒的合成

    公开(公告)号:US08337804B2

    公开(公告)日:2012-12-25

    申请号:US10554903

    申请日:2004-04-28

    IPC分类号: C01G31/02

    摘要: The present invention relates to a method for the production of nanoparticulate metal(III) vanadates or vanadate/phosophate mixed crystals, comprising the reaction in a reaction medium of a reactive vanadate source and optionally a phosphate source dissolvable or dispersible in the reaction medium and of a reactive metal(III) salt dissolvable or dispersible in the reaction medium under heating, wherein the reaction medium contains water and a polyol in a volume ratio of 20/80 to 90/10, and the particles thereby obtained. The synthesis provides a high yield of metal(III) vanadate or vanadate/phosphate having a narrow particle size distribution. Doped embodiments thereof are distinguished by excellent luminescence properties.

    摘要翻译: 本发明涉及一种生产纳米颗粒金属(III)钒酸盐或钒酸盐/磷酸盐混合晶体的方法,其包括在反应性钒酸盐源的反应介质中和任选地可溶于或可分散在反应介质中的磷酸盐源的反应,以及 在加热下可溶于或分散在反应介质中的活性金属(III)盐,其中反应介质含有体积比为20/80至90/10的水和多元醇,由此得到的颗粒。 合成提供了高产率的具有窄粒度分布的钒酸盐或钒酸盐/磷酸盐。 其掺杂的实施方案由优异的发光特性来区分。

    Synthesis of nanparticles comprising metal (III) vanadate
    9.
    发明申请
    Synthesis of nanparticles comprising metal (III) vanadate 有权
    包含钒酸金属(III)的纳米颗粒的合成

    公开(公告)号:US20070148082A1

    公开(公告)日:2007-06-28

    申请号:US10554903

    申请日:2004-04-28

    IPC分类号: C01G31/02

    摘要: The present invention relates to a method for the production of nanoparticulate metal(III) vanadates or vanadate/phosophate mixed crystals, comprising the reaction in a reaction medium of a reactive vanadate source and optionally a phosphate source dissolvable or dispersible in the reaction medium and of a reactive metal(III) salt dissolvable or dispersible in the reaction medium under heating, wherein the reaction medium contains water and a polyol in a volume ratio of 20/80 to 90/10, and the particles thereby obtained. The synthesis provides a high yield of metal(III) vanadate or vanadate/phosphate having a narrow particle size distribution. Doped embodiments thereof are distinguished by excellent luminescence properties.

    摘要翻译: 本发明涉及一种生产纳米颗粒金属(III)钒酸盐或钒酸盐/磷酸盐混合晶体的方法,其包括在反应性钒酸盐源的反应介质中和任选地可溶于或可分散在反应介质中的磷酸盐源的反应,以及 在加热下可溶于或分散在反应介质中的活性金属(III)盐,其中反应介质含有体积比为20/80至90/10的水和多元醇,由此得到的颗粒。 合成提供了高产率的具有窄粒度分布的钒酸盐或钒酸盐/磷酸盐。 其掺杂的实施方案由优异的发光特性来区分。

    Method for producing alkaline earth sulphate nanoparticles
    10.
    发明申请
    Method for producing alkaline earth sulphate nanoparticles 有权
    碱土金属硫酸盐纳米粒子的制备方法

    公开(公告)号:US20060133987A1

    公开(公告)日:2006-06-22

    申请号:US10535864

    申请日:2003-11-19

    IPC分类号: C01F11/46

    摘要: The invention relates to synthesis of nanoparticles, in particular to methods for producing nanoparticles with a net-works consisting of Z sulphate (Z=magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba) or the binary mixtures thereof). The inventive method consists in synthesising the nanoparticles by crystal growth from an ion Z source and a sulphate ion source in a synthesis liquid phase mixture. The aim of said invention is to produce in a simple way barium sulphate nanoparticles having a small diameter, said particles being uniformly dispersed in water or other solvents. For this purpose, co-ordinating solvents like glycerine, glycol ethylene and other polyethylene glycols, polyalcohols or dimethylsulphoxide (DMSO) are used for the synthesis mixture. In the preferred embodiment, barium is used in the form of chloride and the sulphate source in the form of tetrabutylammonium hydrogen sulphate. Other metallic dopants can be eventually integrated in the nanoparticles network. When the synthesis is also used in the form of chloride.

    摘要翻译: 本发明涉及纳米颗粒的合成,特别涉及用Z硫酸盐(Z =镁(Mg),钙(Ca),锶(Sr),钡(Ba)或二元混合物 )。 本发明的方法包括通过在合成液相混合物中从离子Z源和硫酸根离子源的晶体生长合成纳米颗粒。 本发明的目的是以简单的方式生产具有小直径的硫酸钡纳米颗粒,所述颗粒均匀分散在水或其它溶剂中。 为此,将合成溶剂如甘油,二醇乙烯和其它聚乙二醇,多元醇或二甲基亚砜(DMSO)用于合成混合物。 在优选的实施方案中,钡以氯化物的形式使用,硫酸盐源以四丁基硫酸氢铵的形式使用。 其他金属掺杂剂可以最终集成在纳米粒子网络中。 当合成也以氯化物的形式使用时。