公开(公告)号：US20130209667A1

公开(公告)日：2013-08-15

申请号：US13880659

申请日：2011-10-25

申请人： Kohei Yamada ,  Yasushi Horiuchi ,  Yukiko Hachiya ,  Masashi Uzawa ,  Takahiro Sakai ,  Tamae Takagi

发明人： Kohei Yamada ,  Yasushi Horiuchi ,  Yukiko Hachiya ,  Masashi Uzawa ,  Takahiro Sakai ,  Tamae Takagi

IPC分类号： C09D5/24

CPC分类号： H01B1/128 ,  B05D5/12 ,  C08G73/0266 ,  C08L79/02 ,  C09D5/24 ,  C09D179/02 ,  H01B13/30

摘要： When measuring the molecular mass distribution of conductive aniline polymer of formula (1) by GPC and converting its retention time into molecular mass (M) in terms of sodium polystyrene sulfonate, for the molecular mass (M), the area ratio (X/Y) of the area (X) of a region of 15,000 Da or more to the area (Y) of a region of less than 15,000 Da is 1.20 or more. A method for producing such a polymer includes: polymerization step (Z1) where specific aniline derivative (A) is polymerized in a solution containing basic compound (B), solvent (C), and oxidizing agent (D) at a liquid temperature lower than 25° C.; or polymerization step (Z2) where specific aniline derivative (A) and oxidizing agent (D) are added to and polymerized in a solution of a conductive aniline polymer (P-1) with a unit of formula (1) dissolved or dispersed in a solvent (C).

公开(公告)号：US20140043731A1

公开(公告)日：2014-02-13

申请号：US14111847

申请日：2012-04-20

申请人： Kohei Yamada ,  Takahiro Sakai ,  Masashi Uzawa ,  Youko Sasata ,  Akira Yamazaki

发明人： Kohei Yamada ,  Takahiro Sakai ,  Masashi Uzawa ,  Youko Sasata ,  Akira Yamazaki

IPC分类号： H01G9/15

CPC分类号： H01B1/128 ,  C08G73/0266 ,  C08K3/22 ,  H01B1/124 ,  H01G9/042 ,  H01G9/151 ,  C08L79/02

摘要： A conductive composition according to the present invention contains a conductive polymer (A) having a sulfonic acid group and/or a carboxyl group; and an alkali metal hydroxide and/or an alkaline earth metal hydroxide (B). In such a conductive composition, the amount of the hydroxide (B) is set at 0.2˜0.65 mol per 1 mol of a repeating unit that contains a sulfonic acid group and/or a carboxyl group in the conductive polymer (A).

摘要翻译： 本发明的导电性组合物含有具有磺酸基和/或羧基的导电性聚合物（A） 和碱金属氢氧化物和/或碱土金属氢氧化物（B）。 在这种导电性组合物中，氢氧化物（B）的量相对于导电性聚合物（A）中每1摩尔含有磺酸基和/或羧基的重复单元为0.2〜0.65摩尔。

公开(公告)号：US5932144A

公开(公告)日：1999-08-03

申请号：US916333

申请日：1997-08-22

申请人： Shigeru Shimizu ,  Takashi Saitoh ,  Masashi Uzawa ,  Yasuyuki Takayanagi

发明人： Shigeru Shimizu ,  Takashi Saitoh ,  Masashi Uzawa ,  Yasuyuki Takayanagi

IPC分类号： C08G73/02 ,  H01B1/12 ,  C08G65/38

CPC分类号： H01B1/128 ,  C08G73/0266 ,  Y10T428/2933

摘要： A soluble aniline conducting polymer characterized in that said conductive polymer comprises as a repeating unit an alkoxyl group-substituted aminobenzenesulfonic acid, its alkali metal salts, ammonium salts and/or substituted ammonium salts, and is a solid having a weight average molecular weight of about 1900 or more at room temperature, a conductive composition and electric conductor comprising the same, and a method for producing a soluble aniline conducting polymer having a weight average molecular weight of 10,000 t 3,240,000 characterized by polymerizing at least one compound (1) selected from the group consisting of an acidic group-substituted aniline, its alkali metal salts, ammonium salts and substituted ammonium salts in a solution containing a basic compound (2) using an oxidizing agent.

摘要翻译： 一种可溶性苯胺导电聚合物，其特征在于所述导电聚合物包含烷氧基取代的氨基苯磺酸，其碱金属盐，铵盐和/或取代的铵盐作为重复单元，并且是重均分子量约为 1900以上，导电性组合物和含有该导电性组合物的电导体，以及制造重均分子量为10000t 3,240,000的可溶性苯胺导电聚合物的方法，其特征在于，聚合至少一种选自以下的化合物（1）： 在使用氧化剂的碱性化合物（2）的溶液中由酸性基团取代的苯胺，其碱金属盐，铵盐和取代的铵盐组成的组。

公开(公告)号：US5589108A

公开(公告)日：1996-12-31

申请号：US361577

申请日：1994-12-22

申请人： Shigeru Shimizu ,  Takashi Saitoh ,  Masashi Uzawa ,  Yasuyuki Takayanagi

发明人： Shigeru Shimizu ,  Takashi Saitoh ,  Masashi Uzawa ,  Yasuyuki Takayanagi

IPC分类号： C08G73/02 ,  H01B1/12 ,  H01B1/00

CPC分类号： H01B1/128 ,  C08G73/0266 ,  Y10T428/2933

摘要： A soluble aniline conducting polymer characterized in that said conductive polymer comprises as a repeating unit an alkoxyl group-substituted aminobenzenesulfonic acid, its alkali metal salts, ammonium salts and/or substituted ammonium salts, and is a solid having a weight average molecular weight of about 1900 or more at room temperature, a conductive composition and electric conductor comprising the same, and a method for producing a soluble aniline conducting polymer having a weight average molecular weight of 10,000 t 3,240,000 characterized by polymerizing at least one compound (1) selected from the group consisting of an acidic group-substituted aniline, its alkali metal salts, ammonium salts and substituted ammonium salts in a solution containing a basic compound (2) using an oxidizing agent.

摘要翻译： 一种可溶性苯胺导电聚合物，其特征在于所述导电聚合物包含烷氧基取代的氨基苯磺酸，其碱金属盐，铵盐和/或取代的铵盐作为重复单元，并且是重均分子量约为 1900以上，导电性组合物和含有该导电性组合物的电导体，以及制造重均分子量为10000t 3,240,000的可溶性苯胺导电聚合物的方法，其特征在于，聚合至少一种选自以下的化合物（1）： 在使用氧化剂的碱性化合物（2）的溶液中由酸性基团取代的苯胺，其碱金属盐，铵盐和取代的铵盐组成的组。

公开(公告)号：US20100090170A1

公开(公告)日：2010-04-15

申请号：US12446643

申请日：2007-10-24

申请人： Masashi Uzawa

发明人： Masashi Uzawa

IPC分类号： H01B1/12

CPC分类号： H01B1/127 ,  C08G2261/1426 ,  C08G2261/1452 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08L65/00 ,  D06M15/356 ,  D06M15/61 ,  D06M15/63 ,  D06M2200/00 ,  H01B1/14

摘要： Disclosed is a method for giving electric conductivity to a material, by which a conductive material having excellent water resistance and sufficient antistatic properties even at a low temperature and a low humidity can be easily obtained at low cost. In the method, electric conductivity is given to a base material (A) having a nitrogen-containing functional group by soaking the base material (A) in a liquid containing a conductive polymer (B) having at least one kind of sulfonic group and carboxyl group while holding the liquid at a temperature in the range of from 30 to 130° C. A conductive material to be obtained by such a method is also disclosed.

摘要翻译： 公开了一种赋予材料导电性的方法，即使在低温和低湿度下也能够容易地获得具有优异的耐水性和足够的抗静电性能的导电材料。 在该方法中，通过将基材（A）浸渍在含有具有至少一种磺酸基和羧基的导电性聚合物（B）的液体中，赋予具有含氮官能团的基材（A）的导电性 同时将液体保持在30至130℃的温度范围内。还公开了通过这种方法获得的导电材料。

公开(公告)号：US6024895A

公开(公告)日：2000-02-15

申请号：US950791

申请日：1997-10-15

申请人： Shigeru Shimizu ,  Masashi Uzawa ,  Takashi Saitoh ,  Masami Yuasa ,  Yasuyuki Takayanagi ,  Naoki Sugama

发明人： Shigeru Shimizu ,  Masashi Uzawa ,  Takashi Saitoh ,  Masami Yuasa ,  Yasuyuki Takayanagi ,  Naoki Sugama

IPC分类号： C08G61/02 ,  C08G61/12 ,  C08L75/04 ,  C08L79/00 ,  C08L79/02 ,  C08L79/04 ,  C08L81/00 ,  C08L101/00 ,  C08L101/06 ,  C09D5/08 ,  C09D5/24 ,  C09D133/06 ,  H01B1/12 ,  H01B1/20

CPC分类号： H01B1/128 ,  C08G61/02 ,  C08G61/124 ,  C08G61/126 ,  C08L101/00 ,  C08L101/06 ,  C08L75/04 ,  C08L79/02 ,  C08L79/04 ,  C09D133/06 ,  C09D5/08 ,  C09D5/24 ,  H01B1/127 ,  C08L2201/04 ,  C08L79/00 ,  C08L81/00

摘要： A cross-linkable, electrically conductive composition comprising (a) a soluble, electrically conducting polymer having a sulfonic acid group and/or a carboxyl group and (b) a thermally cross-linkable or ultraviolet- or electron beam-cross-linkable resin or paint.

摘要翻译： 一种可交联的导电组合物，其包含（a）具有磺酸基和/或羧基的可溶性导电聚合物和（b）可热交联或紫外或电子束可交联树脂或 涂料。

公开(公告)号：US5776659A

公开(公告)日：1998-07-07

申请号：US762877

申请日：1996-12-12

申请人： Keiji Watanabe ,  Ei Yano ,  Takahisa Namiki ,  Keiko Yano ,  Takashi Maruyama ,  Tomio Nakamura ,  Shigeru Shimizu ,  Takashi Saitoh ,  Masashi Uzawa ,  Masami Ishikawa

发明人： Keiji Watanabe ,  Ei Yano ,  Takahisa Namiki ,  Keiko Yano ,  Takashi Maruyama ,  Tomio Nakamura ,  Shigeru Shimizu ,  Takashi Saitoh ,  Masashi Uzawa ,  Masami Ishikawa

IPC分类号： G03F7/004 ,  C08G73/00 ,  C08G73/02 ,  C08L79/00 ,  C08L79/08 ,  C09D5/00 ,  C09D179/00 ,  C09D179/08 ,  G03F7/09 ,  G03F7/11 ,  G03F7/20 ,  G03F7/26 ,  H01L21/027 ,  H01L21/265 ,  H01L21/266 ,  H01L21/66 ,  G03F7/30

CPC分类号： C08G73/0266 ,  G03F7/093 ,  Y10S430/143

摘要： A composition for irradiation with an ionizing radiation, characterized by comprising: (a) 0.01 to 30 parts by weight of a soluble aniline polymer which comprises one or both of the repeating units represented by the following general formulae (1) and (2), said repeating units being included at least 80% of the total repeating units, possesses a weight average molecular weight of not less than 10,000, and is solid at room temperature; and (b) 100 parts by weight of a solvent, ##STR1## wherein R.sup.1 to R.sup.4 represent an electron-donating group, Y.sup.1 to Y.sup.4 represent --SO.sub.3 -- or --COO--, and M.sup.1 to M.sup.4 represent a hydrogen ion, an ammonium ion, an a1kyl ammonium ion with 1 to 8 carbon atoms, an aromatic ammonium ion, or a quaternary ion of an aromatic heterocyclic ring.

摘要翻译： 一种用于照射电离辐射的组合物，其特征在于包括：（a）0.01至30重量份的可溶性苯胺聚合物，其包含由以下通式（1）和（2）表示的一个或两个重复单元， 所述重复单元包括总重复单元的至少80％，重均分子量不小于10,000，在室温下为固体; （b）100重量份溶剂，其中R1至R4表示给电子基团，Y1至Y4表示-SO3-或-COO-，M1至 M4表示氢离子，铵离子，碳原子数1〜8的烷基铵离子，芳香族铵离子或芳香族杂环的四价离子。

公开(公告)号：US20140198428A1

公开(公告)日：2014-07-17

申请号：US14238703

申请日：2011-08-17

申请人： Akira Yamazaki ,  Takeo Sando ,  Masashi Uzawa ,  Hiroaki Iriyama

发明人： Akira Yamazaki ,  Takeo Sando ,  Masashi Uzawa ,  Hiroaki Iriyama

IPC分类号： H01G9/028 ,  H01G9/00

CPC分类号： H01G9/028 ,  H01G9/0036 ,  H01G9/15

摘要： A solid electrolytic capacitor in which a solid electrolytic layer is formed by applying and drying a conductive-polymer solution which contains a conductive polymer that satisfies following condition (A) and which meets following condition (B) to a dielectric layer formed by oxidizing the surface of an anode metal.Condition (A): Out of one or more peaks that appear when particle size distributions are measured by a dynamic light-scattering method using a conductive-polymer solution containing 1 mass % conductive polymer, the volume average particle size in the distribution that includes the peak of the smallest particle size is smaller than 26 nm.Condition (B): A conductive-polymer solution containing the conductive polymer is applied and dried to provide a solid electrolytic layer on the dielectric layer formed by oxidizing a surface of aluminum with an electrical capacitance of 95 μF/cm2, and when a stacked aluminum electrolytic capacitor is formed using the solid electrolytic layer, the rate of exhibited capacitance of the stacked aluminum electrolytic capacitor is no less than 70%.

摘要翻译： 一种固体电解质电容器，其中通过将包含满足以下条件（A）并满足以下条件（B）的导电聚合物的导电聚合物溶液施加并干燥以形成氧化表面形成的电介质层，形成固体电解质层 的阳极金属。 条件（A）：当使用含有1质量％导电聚合物的导电聚合物溶液的动态光散射法测量粒度分布时出现的一个或多个峰中，分布中的体积平均粒径包括 最小粒径的峰值小于26nm。 条件（B）：涂布含有导电性高分子的导电性高分子溶液，使其干燥，在电介质层上形成固体电解质层，该电介质层通过以95μF/ cm 2的电容氧化铝的表面而形成， 使用固体电解质层形成电解电容器，叠层铝电解电容器的电容率不小于70％。

公开(公告)号：US5980784A

公开(公告)日：1999-11-09

申请号：US941742

申请日：1997-10-01

申请人： Shigeru Shimizu ,  Masashi Uzawa ,  Takashi Saitoh ,  Shinichi Maeda

发明人： Shigeru Shimizu ,  Masashi Uzawa ,  Takashi Saitoh ,  Shinichi Maeda

IPC分类号： C08G61/12 ,  C08G73/02 ,  C08G75/06 ,  H01B1/12

CPC分类号： C08G61/122 ,  H01B1/127 ,  H01B1/128

摘要： A method for producing a soluble conductive polymer having acidic groups, which comprises subjecting to electrolytic polymerization (a) at least one compound selected from the group consisting of acidic group-substituted anilines, acidic group-substituted pyrroles, acidic group-substituted thiophenes, acidic group-substituted furans, acidic group-substituted selenophenes, acidic group-substituted tellurophenes, acidic group-substituted isothianaphthenes, acidic group-substituted isobenzofurans, acidic group-substituted isoindolines, acidic group-substituted isobenzoselenophenes, acidic group-substituted isobenzotellurophenes, and their metal salts, ammonium salts and substituted ammonium salts in a solution containing (b) a basic compound.

摘要翻译： 一种制备具有酸性基团的可溶性导电聚合物的方法，包括进行电解聚合（a）至少一种选自酸性基团取代的苯胺，酸性取代的吡咯，酸性取代的噻吩，酸性的取代的噻吩， 酸取代的异硫酚，酸性取代的异苯并呋喃，酸性取代的异吲哚啉，酸性取代的异苯并硒吩，酸性取代的异苯并间苯基四氟酚，及其金属 盐，铵盐和取代的铵盐在含有（b）碱性化合物的溶液中。

公开(公告)号：US5700399A

公开(公告)日：1997-12-23

申请号：US700994

申请日：1996-08-21

申请人： Shigeru Shimizu ,  Takashi Saitoh ,  Masashi Uzawa ,  Yasuyuki Takayanagi

发明人： Shigeru Shimizu ,  Takashi Saitoh ,  Masashi Uzawa ,  Yasuyuki Takayanagi

IPC分类号： C08G73/02 ,  H01B1/12 ,  H01B1/00 ,  B05D5/12 ,  D02G3/00

CPC分类号： H01B1/128 ,  C08G73/0266 ,  Y10T428/2933

摘要： A soluble aniline conducting polymer characterized in that said conductive polymer comprises as a repeating unit an alkoxyl group-substituted aminobenzenesulfonic acid, its alkali metal salts, ammonium salts and/or substituted ammonium salts, and is a solid having a weight average molecular weight of about 1900 or more at room temperature, a conductive composition and electric conductor comprising the same, and a method for producing a soluble aniline conducting polymer having a weight average molecular weight of 10,000 t 3,240,000 characterized by polymerizing at least one compound (1) selected from the group consisting of an acidic group-substituted aniline, its alkali metal salts, ammonium salts and substituted ammonium salts in a solution containing a basic compound (2) using an oxidizing agent.

摘要翻译： 一种可溶性苯胺导电聚合物，其特征在于所述导电聚合物包含烷氧基取代的氨基苯磺酸，其碱金属盐，铵盐和/或取代的铵盐作为重复单元，并且是重均分子量约为 1900以上，导电性组合物和含有该导电性组合物的电导体，以及制造重均分子量为10000t 3,240,000的可溶性苯胺导电聚合物的方法，其特征在于，聚合至少一种选自以下的化合物（1）： 在使用氧化剂的碱性化合物（2）的溶液中由酸性基团取代的苯胺，其碱金属盐，铵盐和取代的铵盐组成的组。