摘要:
The invention relates to a method for removing a process solvent (P-sol) from a polymer extrudate, especially in connection with a process for producing a microporous membrane. The method involves contacting the extrudate with chlorinated hydrocarbon (CHC) and hydrofluoroether (HFE) in a first stage; contacting the extrudate from the first stage with HFE in a second stage; combining the first and second waste streams and then separating the P-sol from the combined streams to make an HFE-CHC stream; cooling the HFE-CHC stream to make an HFE-rich phase and a CHC-rich phase; and conducting the CHC-rich phase and/or the HFE-rich phase to step (A).
摘要:
The invention relates to a method for removing diluent from a polymer extrudate, especially in connection with a process for producing a microporous membrane. The method involves contacting the extrudate with a second solvent in a first stage; contacting the extrudate from the first stage with a third solvent in a second stage; conducting a first stream away from the first stage and/or conducting a second stream away from the second stage; and cooling at least a portion of the first and/or second stream and separating therefrom at least one of a first phase rich in the second solvent or a second phase rich in the third solvent.
摘要:
A microporous composite membrane comprising a microporous polyolefin membrane and a polypropylene-based coating layer formed on at least one surface of the microporous polyolefin membrane, the polypropylene having a mass-average molecular weight within a range of 5,000-500,000, and solubility of 0.5 g or more in 100 g of toluene at a temperature of 25° C., and the microporous composite membrane having air permeability (converted to the value at 25-μm thickness) of 50-10,000 seconds/100 cc.
摘要:
The invention relates to a method for removing diluent from a polymer extrudate, especially in connection with a process for producing a microporous membrane. The method involves contacting the extrudate with a second solvent in a first stage; contacting the extrudate from the first stage with a third solvent in a second stage; conducting a first stream away from the first stage and/or conducting a second stream away from the second stage; and cooling at least a portion of the first and/or second stream and separating therefrom at least one of a first phase rich in the second solvent or a second phase rich in the third solvent.
摘要:
A method for producing a microporous thermoplastic resin membrane comprising the steps of extruding a solution obtained by melt-blending a thermoplastic resin and a membrane-forming solvent through a die, cooling an extrudate to form a gel-like molding, removing the membrane-forming solvent from the gel-like molding by a washing solvent, and removing the washing solvent, the washing solvent having (a) a surface tension of 24 mN/m or less at a temperature of 25° C., (b) a boiling point of 100° C. or lower at the atmospheric pressure, and (c) a solubility of 600 ppm (on a mass basis) or less in water at a temperature of 16° C.; and the washing solvent remaining in the washed molding being removed by using warm water.
摘要:
A method for removing a process solvent (P-sol) from a polymer extrudate, especially in connection with a process for producing a microporous membrane. The method involves contacting the extrudate with chlorinated hydrocarbon (CHC) and hydrofluoroether (HFE) in a first stage; contacting the extrudate from the first stage with HFE in a second stage; combining the first and second waste streams and then separating the P-sol from the combined streams to make an HFE-CHC stream; cooling the HFE-CHC stream to make an HFE-rich phase and a CHC-rich phase; and conducting the CHC-rich phase and/or the HFE-rich phase to step (A).
摘要:
A microporous composite membrane comprising a microporous polyolefin membrane and a polypropylene-based coating layer formed on at least one surface of the microporous polyolefin membrane, the polypropylene having a mass-average molecular weight within a range of 5,000-500,000, and solubility of 0.5 g or more in 100 g of toluene at a temperature of 25° C., and the microporous composite membrane having air permeability (converted to the value at 25-μm thickness) of 50-10,000 seconds/100 cc.
摘要:
The invention generally relates to an extruder for preparing a mixture of polymer and diluent. The extruder includes multiple extruder stages, the multiple extruder stages comprising an inlet stage, a dispersion stage, and at least one mixing stage comprising a reverse mixing screw segment having a helical flight that traverses and forms an outer periphery thereof, the helical flight having a plurality of notches positioned therealong. A process for extruding the polymer-diluent mixture is also provided.
摘要:
An emulsion composition of a modified polypropylene. It can have exceedingly improved emulsion stability because the modified polypropylene used has extremely high solubility in solvents and is easily emulsifiable. The modified-polypropylene emulsion composition comprises water and a modified polypropylene dispersed and emulsified therein, and is characterized in that the modified polypropylene has a racemic diad content [r] of 0.12 to 0.88 and has hydrophilic functional groups in a number of 0.5 or larger on the average per molecular chain of the polypropylene.
摘要:
A method for producing a modified polyolefin solution, which can reduce polymer loss, solvent loss and further number of steps, and thus has excellent productivity and economic efficiency in a series of steps, wherein an α-olefin is polymerized to obtain a polyolefin, followed by modification with a modifying agent to produce a modified polyolefin solution, characterized by comprising a step wherein an α-olefin is polymerized in the presence of polymerization catalyst in liquid phase to obtain a polyolefin as a polymer solution or slurry state and a step wherein thus obtained polymer is reacted with a modifying agent to modify a polyolefin, and in that the polymer is not isolated, not recovered, nor substantially dried, in a method for producing a modified polyolefin solution by modification, using a modification agent, of a polyolefin obtained by polymerization of an α-olefin.