摘要:
A multi-layer, microporous polyethylene membrane having at least three layers comprising (a) a first microporous layer amount of a polyethylene resin and constituting at least both surface layers, and (b) at least one second microporous layer made of a polyethylene resin, a heat-resistant resin having a melting point or glass transition temperature of 150° C. or higher and a filler, and sandwiched by both surface layers.
摘要:
A microporous polyethylene membrane made of a polyethylene resin having a ratio (mass-average molecular weight/number-average molecular weight) of 5 to 300 and comprising 1% or more by mass of ultra-high-molecular-weight polyethylene having a mass-average molecular weight of 7×105 or more, the microporous polyethylene membrane comprising (a) a coarse-structure layer having an average pore diameter of more than 0.04 μm, which is formed on at least one surface, and (b) a dense-structure layer having an average pore diameter of 0.04 μm or less, an area ratio of the coarse-structure layer to the dense-structure layer in a membrane cross section being 0.1 to 0.8.
摘要:
A microporous polyethylene membrane made of a polyethylene resin having a ratio (mass-average molecular weight/number-average molecular weight) of 5 to 300 and comprising 1% or more by mass of ultra-high-molecular-weight polyethylene having a mass-average molecular weight of 7×105 or more, the microporous polyethylene membrane comprising (a) a coarse-structure layer having an average pore diameter of more than 0.04 μm, which is formed on at least one surface, and (b) a dense-structure layer having an average pore diameter of 0.04 μm or less, an area ratio of the coarse-structure layer to the dense-structure layer in a membrane cross section being 0.1 to 0.8.
摘要:
A microporous polyethylene membrane made of a polyethylene resin comprising 15% or less by mass of ultra-high-molecular-weight polyethylene having a mass-average molecular weight of 1×106 or more, which is constituted by a dense-structure layer having an average pore diameter of 0.01 to 0.05 μm, and a coarse-structure layer formed on at least one surface and having an average pore diameter 1.2-fold to 5.0-fold of that of the dense-structure layer, has a high electrolytic solution absorption speed with thickness and air permeability little changing when compressed. Such a microporous polyethylene membrane is produced by extruding a melt blend of the above polyethylene resin and a membrane-forming solvent through a die, cooling the resultant extrudate with a temperature distribution in a thickness direction to provide a gel-like sheet, stretching the gel-like sheet at a temperature from the crystal dispersion temperature of the polyethylene resin +10° C. to the crystal dispersion temperature +30° C., removing the membrane-forming solvent, and stretching the membrane again to 1.05-fold to 1.45-fold.
摘要:
A method for producing a microporous polyolefin membrane by extruding a melt blend comprising a polyethylene resin, polypropylene having a mass-average molecular weight of 1×105 or more and an ethylene content of 5% by mass or less, and a membrane-forming solvent through a die, slowly cooling the resultant extrudate to form a gel-like sheet, stretching the gel-like sheet, and removing the above membrane-forming solvent, the slow-cooling speed of the extrudate being 30° C./second or less.
摘要:
A microporous polyolefin membrane having excellent compression resistance is obtained by stretching a gel molding comprising a polyolefin and a membrane-forming solvent, removing the membrane-forming solvent, and stretching the resultant membrane again at least uniaxially at a speed of 3%/second or more at a temperature equal to or lower than the crystal dispersion temperature +20° C.
摘要:
The microporous polyolefin membrane obtained by stretching a gel molding comprising a polyolefin and a membrane-forming solvent at least uniaxially, heat-setting it, removing the membrane-forming solvent, and re-stretching it at least uniaxially has a large pore diameter and excellent air permeability, mechanical strength and compression resistance.
摘要:
A multi-layer, microporous polyolefin membrane having at least three layers, which comprises first microporous layers made of a polyethylene resin for constituting at least both surface layers, and at least one second microporous layer comprising a polyethylene resin and polypropylene and disposed between both surface layers, the heat of fusion (ΔHm) of the polypropylene measured by differential scanning calorimetry being 90 J/g or more, and the polypropylene content in the second microporous layer being 50% or less by mass based on 100% by mass of the total of the polyethylene resin and the polypropylene.
摘要:
A coextrusion die for producing a multilayer film or sheet of thermoplastic materials. The coextrusion die includes a die outlet through which a layered melt stream of the thermoplastic materials is extruded as a multilayer film or sheet, a first die section for producing a core layer, the first die section having a flat manifold, the flat manifold having a feed entrance and a pressure manifold in communication with the slotted die outlet, a second die section for producing a first skin layer, the second die section having a cross flow manifold, the cross flow manifold having a flow path wherein a portion of a melt stream of the thermoplastic material traverses the second die section's length more than once, the cross flow manifold having a feed entrance and a pressure manifold in communication with the slotted die outlet, and a third die section for producing a second skin layer, the third die section having a cross flow manifold, the cross flow manifold having a flow path wherein a portion of a melt stream of the thermoplastic material traverses the third die section's length more than once, the cross flow manifold having a feed entrance and a pressure manifold in communication with the slotted die outlet. A process for making a multilayer extrudate of thermoplastic materials is also provided.
摘要:
A multi-layer, microporous polyolefin membrane having at least three layers, which comprises first microporous layers made of a polyethylene resin for constituting at least both surface layers, and at least one second microporous layer comprising a polyethylene resin and polypropylene and disposed between both surface layers, the heat of fusion (ΔHm) of the polypropylene measured by differential scanning calorimetry being 90 J/g or more, and the polypropylene content in the second microporous layer being 50% or less by mass based on 100% by mass of the total of the polyethylene resin and the polypropylene.