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公开(公告)号：US07288616B2
公开(公告)日：2007-10-30
申请号：US10338275
申请日：2003-01-08
CPC分类号： C08F220/28 , C08F220/04 , C08F220/36 , C08F290/062
摘要： Disclosed are multi-purpose alkali-swellable and alkali soluble associative polymers, which are the polymerization product of a monomer mixture comprising: (a) at least one acidic vinyl monomer; (b) at least one nonionic vinyl monomer; (c) a first associative monomer having a first hydrophobic end group; (d) a monomer selected from the group consisting of a second associative monomer having a second hydrophobic end, a semihydrophobic monomer and a combination thereof; and, optionally, (e) one or more crosslinking monomers or chain transfer agents. When monomer (d) is an associative monomer, the first and second hydrophobic end groups of monomers (c) and (d) have significantly different hydrophobic and/or steric character from one another. The multi-purpose associative polymers surprisingly provide desirable Theological and aesthetic properties in aqueous media.
摘要翻译： 公开了多用途碱溶胀性和碱溶性缔合聚合物，它们是单体混合物的聚合产物，其包含：（a）至少一种酸性乙烯基单体; （b）至少一种非离子型乙烯基单体; （c）具有第一疏水性端基的第一缔合单体; （d）选自具有第二疏水末端的第二缔合单体，半疏水单体及其组合的单体; 和（e）一种或多种交联单体或链转移剂。 当单体（d）是缔合单体时，单体（c）和（d）的第一和第二疏水端基彼此之间具有显着不同的疏水和/或空间特性。 多用途缔合聚合物令人惊讶地在水介质中提供理想的神学和美学特性。
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公开(公告)号：US07649047B2
公开(公告)日：2010-01-19
申请号：US11876296
申请日：2007-10-22
CPC分类号： C08F220/28 , C08F220/04 , C08F220/36 , C08F290/062
摘要： Disclosed are multi-purpose alkali-swellable and alkali soluble associative polymers, which are the polymerization product of a monomer mixture comprising: (a) at least one acidic vinyl monomer; (b) at least one nonionic vinyl monomer; (c) a first associative monomer having a first hydrophobic end group; (d) a monomer selected from the group consisting of a second associative monomer having a second hydrophobic end, a semihydrophobic monomer and a combination thereof; and, optionally, (e) one or more crosslinking monomers or chain transfer agents. When monomer (d) is an associative monomer, the first and second hydrophobic end groups of monomers (c) and (d) have significantly different hydrophobic and/or steric character from one another. The multi-purpose associative polymers surprisingly provide desirable rheological and aesthetic properties in aqueous media.
摘要翻译： 公开了多用途碱溶胀性和碱溶性缔合聚合物，它们是单体混合物的聚合产物，其包含：（a）至少一种酸性乙烯基单体; （b）至少一种非离子型乙烯基单体; （c）具有第一疏水性端基的第一缔合单体; （d）选自具有第二疏水末端的第二缔合单体，半疏水单体及其组合的单体; 和（e）一种或多种交联单体或链转移剂。 当单体（d）是缔合单体时，单体（c）和（d）的第一和第二疏水端基彼此之间具有显着不同的疏水和/或空间特性。 多用途缔合聚合物令人惊奇地在含水介质中提供了所需的流变学和美学性质。
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公开(公告)号：US07153496B2
公开(公告)日：2006-12-26
申请号：US10338510
申请日：2003-01-08
IPC分类号： A61Q5/06
CPC分类号： A61K8/8147 , A61K8/8152 , A61K2800/54 , A61Q5/06
摘要： Disclosed are aqueous hair setting compositions comprising, as the sole hair fixative component, rheology modifying, hair setting, associative polymers (RMHS), which are the polymerization product of a monomer mixture comprising an acidic vinyl monomer; and an associative monomer. The hair setting compositions provide surprisingly good to excellent hair setting efficacy, based on high humidity curl retention. A wide range of rheological characteristics was achieved together with good clarity and aesthetic product properties. Particularly preferred rheology modifying hair setting associative polymers are certain hydrophobically modified alkali-swellable and alkali-soluble associative polymers (ASAP) and HASE polymers disclosed herein. Also disclosed are methods of setting hair using RMHS polymer-containing compositions.
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公开(公告)号：US20080233069A1
公开(公告)日：2008-09-25
申请号：US12125288
申请日：2008-05-22
申请人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
发明人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
CPC分类号： C08L53/00 , A61K8/8158 , A61K2800/5426 , A61Q5/06 , A61Q5/12 , C08F220/28 , C08F220/34 , C08F220/60 , C08F290/06 , C08F290/062 , C08F293/005 , C09D153/00 , C08L2666/02
摘要： Disclosed are multi-purpose polymers that are the polymerization product of a monomer mixture comprising at least one amino-substituted vinyl monomer; at least one nonionic vinyl monomer; at least one associative vinyl monomer; at least one semihydrophobic vinyl surfactant monomer; and, optionally, comprising one or more hydroxy-substituted nonionic vinyl monomer, crosslinking monomer, chain transfer agent or polymeric stabilizer. These vinyl addition polymers have a combination of substituents, including amino substituents that provide cationic properties at low pH, hydrophobic substituents, hydrophobically modified polyoxyalkylene substituents, and hydrophilic polyoxyalkylene substituents. The polymers provide surprisingly beneficial rheological properties in acidic aqueous compositions, and are compatible with cationic materials. The multi-purpose polymers are useful in a variety of products for personal care, health care, household care, institutional and industrial care, and industrial applications.
摘要翻译： 公开了作为包含至少一个氨基取代的乙烯基单体的单体混合物的聚合产物的多用途聚合物; 至少一种非离子型乙烯基单体; 至少一种缔合乙烯基单体; 至少一种半疏水乙烯基表面活性剂单体; 和任选地包含一种或多种羟基取代的非离子乙烯基单体，交联单体，链转移剂或聚合物稳定剂。 这些乙烯基加成聚合物具有取代基的组合，包括在低pH下提供阳离子性质的氨基取代基，疏水取代基，疏水改性聚氧化烯取代基和亲水性聚氧化烯取代基。 聚合物在酸性含水组合物中提供令人惊讶的有利的流变性能，并与阳离子材料相容。 多用途聚合物可用于个人护理，保健，家庭护理，机构和工业保健以及工业应用的各种产品。
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公开(公告)号：US08044156B2
公开(公告)日：2011-10-25
申请号：US12125288
申请日：2008-05-22
申请人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
发明人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
IPC分类号： C08F122/38
CPC分类号： C08L53/00 , A61K8/8158 , A61K2800/5426 , A61Q5/06 , A61Q5/12 , C08F220/28 , C08F220/34 , C08F220/60 , C08F290/06 , C08F290/062 , C08F293/005 , C09D153/00 , C08L2666/02
摘要： Disclosed are multi-purpose polymers that are the polymerization product of a monomer mixture comprising at least one amino-substituted vinyl monomer; at least one nonionic vinyl monomer; at least one associative vinyl monomer; at least one semihydrophobic vinyl surfactant monomer; and, optionally, comprising one or more hydroxy-substituted nonionic vinyl monomer, crosslinking monomer, chain transfer agent or polymeric stabilizer. These vinyl addition polymers have a combination of substituents, including amino substituents that provide cationic properties at low pH, hydrophobic substituents, hydrophobically modified polyoxyalkylene substituents, and hydrophilic polyoxyalkylene substituents. The polymers provide surprisingly beneficial rheological properties in acidic aqueous compositions, and are compatible with cationic materials. The multi-purpose polymers are useful in a variety of products for personal care, health care, household care, institutional and industrial care, and industrial applications.
摘要翻译： 公开了作为包含至少一个氨基取代的乙烯基单体的单体混合物的聚合产物的多用途聚合物; 至少一种非离子型乙烯基单体; 至少一种缔合乙烯基单体; 至少一种半疏水乙烯基表面活性剂单体; 和任选地包含一种或多种羟基取代的非离子乙烯基单体，交联单体，链转移剂或聚合物稳定剂。 这些乙烯基加成聚合物具有取代基的组合，包括在低pH下提供阳离子性质的氨基取代基，疏水取代基，疏水改性聚氧化烯取代基和亲水性聚氧化烯取代基。 聚合物在酸性含水组合物中提供令人惊讶的有利的流变性能，并与阳离子材料相容。 多用途聚合物可用于个人护理，保健，家庭护理，机构和工业保健以及工业应用的各种产品。
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公开(公告)号：US07378479B2
公开(公告)日：2008-05-27
申请号：US10646856
申请日：2003-08-22
申请人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
发明人： Krishnan Tamareselvy , Thomas A. Barker , James E. Mullee , Charles T. Greenslade , Julie F. Schmucker-Castner , Deborah S. Filla
IPC分类号： C08F216/12 , C08F220/10 , C08F20/52
CPC分类号： C08L53/00 , A61K8/8158 , A61K2800/5426 , A61Q5/06 , A61Q5/12 , C08F220/28 , C08F220/34 , C08F220/60 , C08F290/06 , C08F290/062 , C08F293/005 , C09D153/00 , C08L2666/02
摘要： Disclosed are multi-purpose polymers that are the polymerization product of a monomer mixture comprising at least one amino-substituted vinyl monomer; at least one nonionic vinyl monomer; at least one associative vinyl monomer; at least one semihydrophobic vinyl surfactant monomer; and, optionally, comprising one or more hydroxy-substituted nonionic vinyl monomer, crosslinking monomer, chain transfer agent or polymeric stabilizer. These vinyl addition polymers have a combination of substituents, including amino substituents that provide cationic properties at low pH, hydrophobic substituents, hydrophobically modified polyoxyalkylene substituents, and hydrophilic polyoxyalkylene substituents. The polymers provide surprisingly beneficial rheological properties in acidic aqueous compositions, and are compatible with cationic materials. The multi-purpose polymers are useful in a variety of products for personal care, health care, household care, institutional and industrial care, and industrial applications.
摘要翻译： 公开了作为包含至少一个氨基取代的乙烯基单体的单体混合物的聚合产物的多用途聚合物; 至少一种非离子型乙烯基单体; 至少一种缔合乙烯基单体; 至少一种半疏水乙烯基表面活性剂单体; 和任选地包含一种或多种羟基取代的非离子乙烯基单体，交联单体，链转移剂或聚合物稳定剂。 这些乙烯基加成聚合物具有取代基的组合，包括在低pH下提供阳离子性质的氨基取代基，疏水取代基，疏水改性聚氧化烯取代基和亲水性聚氧化烯取代基。 聚合物在酸性含水组合物中提供令人惊讶的有利的流变性能，并与阳离子材料相容。 多用途聚合物可用于个人护理，保健，家庭护理，机构和工业保健以及工业应用的各种产品。
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公开(公告)号：US09187590B2
公开(公告)日：2015-11-17
申请号：US13513306
申请日：2010-12-01
IPC分类号： C08F12/28 , C08F220/44 , C08F2/00 , C08G61/02 , C08G61/04 , C08F297/02 , C08F8/00 , C08G63/48 , C08F220/34 , C08F220/18 , C08F216/14 , C08F220/26 , C08F222/10 , C08F230/08
CPC分类号： C08F220/34 , C08F216/1416 , C08F220/18 , C08F220/26 , C08F222/1006 , C08F230/08
摘要： The present invention relates to hydrolytically stable multi-purpose polymers that are polymerized from a monomer mixture comprising: at least one amino-substituted meth(acrylate) (ASMA) monomer or salt thereof; and at least one nonionic vinyl (NIV) monomer, wherein the monomer mixture optionally comprises one or more of at least one vinyl associative (VA) monomer; at least one vinyl surfactant (VS) monomer; and/or at least one polymerizable silicone macromer (PSM) and wherein the monomer mixture further optionally comprises one or more of at least one crosslinking (XL) monomer; at least one chain transfer agent (CTA); and/or at least one polymeric stabilizer. The multi-purpose polymers of the present invention can also be prepared from monomer mixtures containing chain transfer agents or other functional components commonly utilized in polymerization process.
摘要翻译： 本发明涉及由单体混合物聚合的水解稳定的多用途聚合物，所述单体混合物包含：至少一种氨基取代的（丙烯酸酯）（ASMA）单体或其盐; 和至少一种非离子乙烯基（NIV）单体，其中所述单体混合物任选地包含一种或多种至少一种乙烯基缔合（VA）单体; 至少一种乙烯基表面活性剂（VS）单体; 和/或至少一种可聚合硅氧烷大分子单体（PSM），并且其中所述单体混合物还任选地包含至少一种交联（XL）单体中的一种或多种; 至少一种链转移剂（CTA）; 和/或至少一种聚合物稳定剂。 本发明的多用途聚合物也可以由含有链转移剂或通常用于聚合过程的其它功能组分的单体混合物制备。
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公开(公告)号：US09068148B2
公开(公告)日：2015-06-30
申请号：US13809278
申请日：2011-07-07
IPC分类号： A61K8/72 , C11D3/37 , C08F2/00 , C08L33/02 , C09D133/02 , A61K8/81 , A61Q5/02 , A61Q5/12 , A61Q19/00 , A61Q19/10
CPC分类号： C11D3/3765 , A61K8/8152 , A61K2800/28 , A61Q5/02 , A61Q5/12 , A61Q19/00 , A61Q19/10 , C08F2/00 , C08L33/02 , C08L2312/00 , C09D133/02 , C08L33/08
摘要： Disclosed are blends of acrylic polymers comprising at least one crosslinked acrylic copolymer and at least one linear acrylic copolymer. The acrylic polymer blends surprisingly provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions, particularly at low pH.
摘要翻译： 公开了包含至少一种交联的丙烯酸共聚物和至少一种线性丙烯酸共聚物的丙烯酸聚合物的共混物。 丙烯酸类聚合物混合物令人惊讶地在含水表面活性剂的组合物中提供期望的流变学，透明度和美学性质，特别是在低pH下。
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公开(公告)号：US08840870B2
公开(公告)日：2014-09-23
申请号：US13819875
申请日：2011-09-01
CPC分类号： A61K8/8152 , A61K2800/5424 , A61Q1/10 , A61Q5/06 , A61Q19/00 , C08F20/28 , C08L33/064
摘要： The present invention relates to hair care and personal care compositions which contain an acrylic copolymer which is polymerized in the presence of at least two different classes of crosslinking monomers. The polymer functions both as a fixative/film former and a thickening agent for hair styling and personal care compositions in which it is contained. The copolymer exhibits advantageous fixative, film forming and rheological gel properties.
摘要翻译： 本发明涉及含有在至少两种不同类型的交联单体存在下聚合的丙烯酸共聚物的护发和个人护理组合物。 聚合物既用作固定剂/成膜剂，也用作用于头发造型的增稠剂和其中包含其的个人护理组合物。 共聚物表现出有利的固定剂，成膜和流变凝胶性质。
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公开(公告)号：US20130183361A1
公开(公告)日：2013-07-18
申请号：US13876007
申请日：2011-09-30
IPC分类号： A61K8/02 , D06M15/263 , A61Q19/10 , A61Q5/12 , C11D17/00
CPC分类号： A61K8/0245 , A61K8/8152 , A61K2800/262 , A61K2800/654 , A61Q5/02 , A61Q5/12 , A61Q19/10 , C08F265/06 , C09D133/14 , C11D3/3765 , C11D3/3773 , C11D17/0017 , C11D17/0039 , D06M15/263
摘要： Disclosed are multi-staged acrylic based core-shell polymers comprising a linear core polymer and at least one subsequently polymerized shell polymer. At least one of the subsequently polymerized shell polymers is crosslinked. The core-shell polymers surprisingly provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions, particularly at low pH. The multi-staged acrylic base core-shell polymers can be included in at least one phase of a multi-phase personal care, home care, health care, and institutional and industrial care composition to impart phase stability thereto.
摘要翻译： 公开了包含线性芯聚合物和至少一种随后聚合的壳聚合物的多阶段丙烯酸类核 - 壳聚合物。 至少一种随后聚合的壳聚合物是交联的。 核 - 壳聚合物令人惊讶地在含水表面活性剂组合物中提供所需的流变学，透明度和美学性能，特别是在低pH下。 多阶段丙烯酸类核 - 壳聚合物可以包括在多相个人护理，家庭护理，保健和机构和工业护理组合物的至少一个阶段中，以赋予相位稳定性。
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