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公开(公告)号：US07449425B2
公开(公告)日：2008-11-11
申请号：US11230088
申请日：2005-09-19
申请人： Kun Wang , Raymond A. Cook
发明人： Kun Wang , Raymond A. Cook
CPC分类号： B01J23/007 , B01J23/58 , B01J23/6562 , B01J23/78 , C07C29/153 , Y02P20/52 , C07C31/04 , C07C31/08
摘要： The invention relates to a catalyst composition, a method of making the same and its use in a process for converting synthesis gas to alcohols. The catalyst composition comprises an anionic clay hydrotalcite and a catalytically active metal component, such as rhodium, manganese, cobalt, copper, and a mixture thereof.
摘要翻译： 本发明涉及一种催化剂组合物及其制备方法及其在将合成气转化为醇的方法中的用途。 催化剂组合物包含阴离子粘土水滑石和催化活性金属组分，例如铑，锰，钴，铜及其混合物。
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公开(公告)号：US06740718B2
公开(公告)日：2004-05-25
申请号：US10320931
申请日：2002-12-17
IPC分类号： C08F432
CPC分类号： C08G67/02
摘要： The invention relates to a method of forming carbon monoxide-containing polymers from multi-component syngas feeds and at least one vinyl comonomer. Feeds useful in the practice of the invention comprise ethylene in an amount ranging from about 5 to about 40 mole %, carbon monoxide is an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about 10 mole %. The feed may contain at least one free radical-polymerizable vinyl comonomer, or a cofeed containing such a comonomer can be used.
摘要翻译： 本发明涉及从多组分合成气进料和至少一种乙烯基共聚单体形成含一氧化碳的聚合物的方法。 在本发明的实践中有用的进料包含量为约5至约40摩尔％的乙烯，一氧化碳的量为约1至约40摩尔％，氢量为约4至约55摩尔 ％，约3至约10摩尔％的量的二氧化碳和约4至约85摩尔％的量的甲烷。 进料还可以包括高达约10摩尔％的量的乙炔。 饲料可以含有至少一种可自由基聚合的乙烯基共聚单体，或者可以使用含有这种共聚单体的共进料。
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公开(公告)号：US20080153997A1
公开(公告)日：2008-06-26
申请号：US11714546
申请日：2007-03-06
申请人： Gary L. Casty , Raymond A. Cook , Gabor Kiss , Patrick Brant
发明人： Gary L. Casty , Raymond A. Cook , Gabor Kiss , Patrick Brant
CPC分类号： C08F10/06 , C08F110/06 , C08F210/06 , Y02P20/544 , C08F4/64144 , C08F2/06 , C08F2500/20 , C08F2500/17 , C08F2500/09 , C08F2500/03
摘要： This invention relates to a process to polymerize olefins comprising contacting, at a temperature of 60° C. or more and a pressure of at least 15 MPa, one or more olefin monomers having three or more carbon atoms, with: 1) a catalyst system comprising one or more activators and one or more nonmetallocene metal-centered, heteroaryl ligand catalyst compounds, where the metal is chosen from the Group 4, 5, 6, the lanthanide series, or the actinide series of the Periodic Table of the Elements, 2) optionally one or more comonomers, 3) optionally diluent or solvent, and 40 optionally solvent, wherein: a) the olefin monomers and any comonomers are present in the polymerization system at 40 weight % or more, b) the monomer having three or more carbon atoms is present at 80 wt % or more based upon the weight of all monomers and comonomers present in the feed, c) the polymerization occurs at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, in the event the solid-fluid phase transition temperature of the polymerization system cannot be determined then the polymerization occurs at a temperature above the fluid fluid phase transition temperature.
摘要翻译： 本发明涉及一种聚合烯烃的方法，包括在60℃或更高的温度和至少15MPa的压力下使一种或多种具有三个或更多个碳原子的烯烃单体与以下物质接触：1）催化剂体系 包含一种或多种活化剂和一种或多种非金属茂金属中心的杂芳基配位体催化剂化合物，其中金属选自第4,5,6族，镧系元素或元素周期表的锕系元素，2 ）任选的一种或多种共聚单体，3）任选的稀释剂或溶剂，以及40任选溶剂，其中：a）烯烃单体和任何共聚单体在40重量％或更多的重量％存在于聚合体系中，b）具有三个或更多个的单体 基于进料中存在的所有单体和共聚单体的重量，碳原子存在于80重量％以上，c）聚合在高于聚合体系的固体 - 流体相转变温度的温度下进行， 肯定不低于聚合体系的浊点压力10MPa以下，并且小于1500MPa，在聚合体系的固体流体相转变温度不能确定的情况下，聚合在高于流体流体相的温度下发生 转变温度。
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公开(公告)号：US5354916A
公开(公告)日：1994-10-11
申请号：US187351
申请日：1994-01-24
IPC分类号： C07C17/10 , C07C29/124 , C07C29/58
CPC分类号： C07C17/10 , C07C29/124
摘要： The invention relates to a process for selectively producing alkyl halides from alkanes, such as methane and ethane at low temperatures and low pressures. Optional hydrolysis to the corresponding alcohols may follow. The process involves adding an alkane and an added halogen source to an aqueous solution in a homogeneous system in the presence of a transition metal halide containing complex, for a time, under conditions and in effective amounts that will permit the formation of alkyl monohalides.
摘要翻译： 本发明涉及一种在低温和低压下从烷烃如甲烷和乙烷中选择性生产烷基卤的方法。 可以按照相应的醇进行任选的水解。 该方法包括在含有过渡金属卤化物的络合物的存在下，在一定时间内，在允许形成单卤代烷烃的条件下和有效量下，在均相体系中将烷烃和加入的卤素源加入到水溶液中。
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公开(公告)号：US08058371B2
公开(公告)日：2011-11-15
申请号：US12098907
申请日：2008-04-07
申请人： Patrick Brant , Gary L. Casty , Gabor Kiss , Raymond A. Cook , James R. Lattner
发明人： Patrick Brant , Gary L. Casty , Gabor Kiss , Raymond A. Cook , James R. Lattner
IPC分类号： C08F4/6592 , C08F2/06 , C08F110/06 , C08F210/06
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08L21/00 , C08F4/65908 , C08F2/06 , C08F2/14 , C08F2500/03 , C08F2500/17 , C08F2500/09 , C08F2500/12 , C08F2500/20
摘要： Processes for polymerizing propylene. About 40 wt % to about 80 wt % propylene monomer, based on total weight of propylene monomer and diluent, and about 20 wt % to about 60 wt % diluent, based on total weight of propylene monomer and diluent, can be fed into a reactor. The propylene monomer can be polymerized in the presence of a metallocene catalyst and an activator within the reactor at a temperature of about 80° C. or more and a pressure of about 13 MPa or more to produce a polymer product in a homogenous system. About 20 wt % to about 76 wt % (preferably About 28 wt % to about 76 wt %) propylene monomer, based on total weight of the propylene monomer, diluent, and polymer product, can be present at the reactor exit at steady state conditions.
摘要翻译： 丙烯聚合方法 基于丙烯单体和稀释剂的总重量计，约40重量％至约80重量％的丙烯单体和约20重量％至约60重量％的稀释剂（基于丙烯单体和稀释剂的总重量）可以进料到反应器 。 丙烯单体可在茂金属催化剂和活化剂存在下在约80℃以上的温度和约13MPa或更高的压力下在反应器内聚合，以在均匀体系中生产聚合物产物。 基于丙烯单体，稀释剂和聚合物产物的总重量，约20重量％至约76重量％（优选约28重量％至约76重量％）的丙烯单体可以在稳态条件下在反应器出口处存在 。
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公开(公告)号：US20080188635A1
公开(公告)日：2008-08-07
申请号：US12098907
申请日：2008-04-07
申请人： Patrick Brant , Gary L. Casty , Gabor kiss , Raymond A. Cook , James R. Lattner
发明人： Patrick Brant , Gary L. Casty , Gabor kiss , Raymond A. Cook , James R. Lattner
IPC分类号： C08F110/06
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08L21/00 , C08F4/65908 , C08F2/06 , C08F2/14 , C08F2500/03 , C08F2500/17 , C08F2500/09 , C08F2500/12 , C08F2500/20
摘要： Processes for polymerizing propylene. About 40 wt % to about 80 wt % propylene monomer, based on total weight of propylene monomer and diluent, and about 20 wt % to about 60 wt % diluent, based on total weight of propylene monomer and diluent, can be fed into a reactor. The propylene monomer can be polymerized in the presence of a metallocene catalyst and an activator within the reactor at a temperature of about 80° C. or more and a pressure of about 13 MPa or more to produce a polymer product in a homogenous system. About 20 wt % to about 76 wt % (preferably About 28 wt % to about 76 wt %) propylene monomer, based on total weight of the propylene monomer, diluent, and polymer product, can be present at the reactor exit at steady state conditions.
摘要翻译： 丙烯聚合方法 基于丙烯单体和稀释剂的总重量计，约40重量％至约80重量％的丙烯单体和约20重量％至约60重量％的稀释剂（基于丙烯单体和稀释剂的总重量）可以进料到反应器 。 丙烯单体可在茂金属催化剂和活化剂存在下在约80℃以上的温度和约13MPa或更高的压力下在反应器内聚合，以在均匀体系中生产聚合物产物。 基于丙烯单体，稀释剂和聚合物产物的总重量，约20重量％至约76重量％（优选约28重量％至约76重量％）的丙烯单体可以在稳态条件下在反应器出口处存在 。
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7.发明授权Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide hydrogen ethylene and acetylene-(LAW072) 失效含有一氧化碳氢乙烯和乙炔的多组分合成气的直接加氢甲酰化（LAW072）
公开(公告)号：US5600017A
公开(公告)日：1997-02-04
申请号：US563838
申请日：1995-11-28
申请人： Gabor Kiss , Michael G. Matturro , Harry W. Deckman , Istvan T. Horvath , Anthony M. Dean , Frank Hershkowitz , Raymond A. Cook
发明人： Gabor Kiss , Michael G. Matturro , Harry W. Deckman , Istvan T. Horvath , Anthony M. Dean , Frank Hershkowitz , Raymond A. Cook
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , Y02P20/582
摘要： The invention is a process for hydroformylating multicomponent syngas feed streams containing CO, H.sub.2, C.sub.2 to C.sub.5 olefins and mixtures thereof and C.sub.2 to C.sub.5 alkynes and mixtures thereof by contacting the multicomponent syngas feed stream with a solution of an oil soluble rhodium complex catalyst produced by complexing in solution a low valence Rh and an oil soluble triorganophoshorous compound wherein the catalyst has a P/Rh ratio of at least 30, a concentration of Rh in solution from about 1 to about 1000 ppm by weight, a total concentration of coordinatively active P of at least about 0.01 mol/l, and a ratio of [P]/p.sub.co of at least 0.1 mmol/l/kPa, wherein [P] is the total concentration of coordinatively active phosphorous in the solution, and p.sub.co is the partial pressure of CO, to produce the corresponding C.sub.3 to C.sub.6 aldehydes. The process has utility for the hydroformylation of streams that contain olefins and alkynes.
摘要翻译： 本发明是一种通过使多组分合成气进料流与油溶性铑配合物催化剂溶液接触而将含有CO，H 2，C 2至C 5烯烃及其混合物和C 2 -C 5炔烃及其混合物的多组分合成气原料流加氢甲酰化的方法， 在低价Rh和油溶性三有机磷化合物溶液中络合，其中催化剂的P / Rh比为至少30，溶液中Rh的浓度为约1至约1000重量ppm，配位活性P 至少约0.01mol / l，[P] / pco为至少0.1mmol / l / kPa的比例，其中[P]是溶液中配位活性磷的总浓度，pco是分压 的CO，以产生相应的C3至C6醛。 该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。
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公开(公告)号：US20080306215A1
公开(公告)日：2008-12-11
申请号：US11810499
申请日：2007-06-06
申请人： Abhimanyu Onkar Patil , Stephen Zushma , Steven P. Rucker , Christian Peter Mehnert , Raymond A. Cook , Lisa Saunders Baugh , Enock Berluche
发明人： Abhimanyu Onkar Patil , Stephen Zushma , Steven P. Rucker , Christian Peter Mehnert , Raymond A. Cook , Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08C19/34
CPC分类号： C08F8/00 , C08F2800/20 , C08F210/18 , C08F210/02 , C08F210/16 , C08F8/46 , C08F8/06 , C08F8/04 , C08F8/08
摘要： A process is described for functionalizing a copolymer comprising units derived from at least one α-olefin and units derived from at least one diene, which copolymer contains at least one double bond. The process comprises reacting the copolymer with at least one functionalizing agent to introduce polar pendant oxygen-containing functional groups onto the copolymer.
摘要翻译： 描述了一种用于使包含至少一种α-烯烃的单元和源自至少一种二烯的单元的共聚物官能化的方法，该共聚物含有至少一个双键。 该方法包括使共聚物与至少一种官能化试剂反应以将极性侧链含氧官能团引入到共聚物上。
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9.发明授权公开(公告)号：US06541586B2
公开(公告)日：2003-04-01
申请号：US09233353
申请日：1999-01-19
IPC分类号： C08F434
CPC分类号： C08G67/02
摘要： The invention relates to a method of forming carbon monoxide-containing polymers from multi-component syngas feeds and at least one vinyl comonomer. Feeds useful in the practice of the invention comprise ethylene in an amount ranging from about 5 to about 40 mole %, carbon monoxide is an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about 10 mole %. The feed may contain at least one free radical-polymerizable vinyl comonomer, or a cofeed containing such a comonomer can be used.
摘要翻译： 本发明涉及从多组分合成气进料和至少一种乙烯基共聚单体形成含一氧化碳的聚合物的方法。 在本发明的实践中有用的进料包含量为约5至约40摩尔％的乙烯，一氧化碳的量为约1至约40摩尔％，氢量为约4至约55摩尔 ％，约3至约10摩尔％的量的二氧化碳和约4至约85摩尔％的量的甲烷。 进料还可以包括高达约10摩尔％的量的乙炔。 饲料可以含有至少一种可自由基聚合的乙烯基共聚单体，或者可以使用含有这种共聚单体的共进料。
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公开(公告)号：US6156872A
公开(公告)日：2000-12-05
申请号：US233362
申请日：1999-01-19
IPC分类号： C08G67/02 , C08F238/02 , C08G61/00
CPC分类号： C08G67/02
摘要： The invention is related to non-linear, paraffin-soluble olefin/carbon monoxide and olefin/acetylene/carbon monoxide copolymers. The invention is also related to a method for preparing olefin/carbon monoxide copolymers by heating a feed of at least one olefin, carbon monoxide, carbon dioxide, hydrogen, and methane in the presence of a free radical polymerization initiator. More particularly, the feed comprises at least one olefin, the total olefin amount ranging from about 5 to about 40 mole %, carbon monoxide in an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about mole %.
摘要翻译： 本发明涉及非线性，石蜡溶解的烯烃/一氧化碳和烯烃/乙炔/一氧化碳共聚物。 本发明还涉及通过在自由基聚合引发剂的存在下加热至少一种烯烃，一氧化碳，二氧化碳，氢气和甲烷的进料来制备烯烃/一氧化碳共聚物的方法。 更具体地，进料包含至少一种烯烃，总烯烃量为约5至约40摩尔％，量为约1至约40摩尔％的一氧化碳，其量为约4至约40摩尔％ 55摩尔％，量为约3至约10摩尔％的二氧化碳，以及范围为约4至约85摩尔％的甲烷。 进料还可以包括高达约摩尔％的量的乙炔。
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