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23 条记录 (耗时 0.017 秒)

    Cycloaminals and a process for their preparation
    1.
    发明授权
    Cycloaminals and a process for their preparation 失效
    环状物及其制备方法

    公开(公告)号：US4404379A

    公开(公告)日：1983-09-13

    申请号：US935439

    申请日：1978-08-21

    申请人： Manfred Hajek ,  Kuno Wagner ,  Walter Uerdingen ,  Wolfgang Wellner

    发明人： Manfred Hajek ,  Kuno Wagner ,  Walter Uerdingen ,  Wolfgang Wellner

    IPC分类号： C07D233/02 ,  C07D239/04 ,  C08G18/80

    CPC分类号： C07D239/04 ,  C07D233/02 ,  C08G18/808

    摘要： The present invention is concerned with a new class of compounds prepared by reacting cyclic aminals of the formula ##STR1## with polyisocyanates of the formula R.sub.5 (NCO).sub.m+n to yield ##STR2## and with this process for obtaining said compounds, as well as the use of such compounds in polyurethane chemistry. If such compounds are free of isocyanates (n=0) they are useful as latent cross-linkers or hardeners activatable by heat or moisture. If such compounds carry free isocyanate groups (n=1 or 2) there are useful as synthetic resin precursors. In the above formulaem represents an integer of from 1 to 3, andn represents 0, 1 or 2, and the sum of m+n is 2 or 3,R.sub.1 represents an aliphatic hydrocarbon group which is optionally cyano-substituted and which has from 1 to 6 carbon atoms, a cycloaliphatic hydrocarbon group having from 5-10 carbon atoms or an araliphatic hydrocarbon group having from 7-10 carbon atoms;R.sub.2 represents a divalent aliphatic hydrocarbon group having from 2 to 6 carbon atoms, at least two carbon atoms being situated between the two nitrogen atoms;R.sub.3 and R.sub.4 are identical or different and represent hydrogen, aliphatic hydrocarbon groups having from 1 to 18 carbon atoms, cycloaliphatic hydrocarbon groups having from 5 to 10 carbon atoms or aromatic hydrocarbon groups having from 6 to 10 carbon atoms, or the two groups R.sub.3 and R.sub.4 together with the carbon atom of the heterocyclic ring may also form a 5-membered or 6-membered cycloaliphatic ring; andR.sub.5 represents an (m+n)-valent group such as that which can be obtained by the removal of m+n isocyanate groups from an (m+n)-valent polyisocyanate.

    摘要翻译： 本发明涉及通过使式“IMAGE”的环状胺与式R 5（NCO）m + n的多异氰酸酯反应得到新一类化合物，得到所述化合物的方法 作为这种化合物在聚氨酯化学中的应用。 如果这些化合物不含异氰酸酯（n = 0），它们可用作潜热的交联剂或通过热或湿气活化的硬化剂。 如果这些化合物带有游离异氰酸酯基团（n = 1或2），则可用作合成树脂前体。 在上式中，m表示1〜3的整数，n表示0,1或2，m + n的和为2或3，R1表示任意氰基取代的脂肪族烃基， 1至6个碳原子，具有5-10个碳原子的脂环族烃基或具有7-10个碳原子的芳脂族烃基; R2表示具有2至6个碳原子的二价脂族烃基，至少两个碳原子位于两个氮原子之间; R3和R4相同或不同，表示氢，具有1至18个碳原子的脂族烃基，具有5至10个碳原子的脂环族烃基或具有6至10个碳原子的芳族烃基，或两个基团R3和 R4与杂环的碳原子一起也可以形成5元或6元脂环族环; 并且R 5表示可以通过从（m + n）价多异氰酸酯除去m + n个异氰酸酯基团而得到的（m + n）价基团。

    Urea or carbonamide containing diisocyanate polyaddition products with phosphoric ester substituents
    2.
    发明授权
    Urea or carbonamide containing diisocyanate polyaddition products with phosphoric ester substituents 失效
    含有含磷酸酯取代基的二异氰酸酯加成产物的尿素或碳酰胺

    公开(公告)号：US4028306A

    公开(公告)日：1977-06-07

    申请号：US583133

    申请日：1975-06-02

    申请人： Kuno Wagner ,  Manfred Hajek

    发明人： Kuno Wagner ,  Manfred Hajek

    IPC分类号： C08G18/00 ,  C07F9/40 ,  C08G18/10 ,  C08G18/38 ,  C08G18/65 ,  C08G18/78 ,  C08G18/80 ,  C08G18/73

    CPC分类号： C08G18/8054 ,  C07F9/4006 ,  C08G18/10 ,  C08G18/3889

    摘要： The present invention relates to linear, film-forming diisocyanate polyaddition products soluble in lacquer solvents which contain 10 to 69 wt. % of structural units of the formula: ##STR1## and processes for producing such diisocyanate polyaddition products. The polymer produced may be polyureas, polyhydrazocarbonamide, a polyurethane polyurea, polyurethane polyhydrazocarbonamides, polyurea polyhydrazocarbonamides or polyurethane polyurea polyhydrazocarbonamides. These diisocyanate polyaddition products are useful for the production of surface coatings, lacquer coatings and impregnations.

    摘要翻译： 本发明涉及可溶于漆溶剂的线性成膜二异氰酸酯加聚产物，其含有10至69wt。 ％的下式结构单元：＆lt; IMAGE＆gt;和制备这种二异氰酸酯加聚产物的方法。 所生产的聚合物可以是聚脲，聚酰肼，聚氨酯聚脲，聚氨酯聚酰肼，聚脲聚酰肼或聚氨酯聚脲聚酰肼。 这些二异氰酸酯加成产物可用于生产表面涂料，漆涂料和浸渍。

    Urethane oxazolidines
    3.
    发明授权
    Urethane oxazolidines 失效
    聚氨酯恶唑烷

    公开(公告)号：US4002601A

    公开(公告)日：1977-01-11

    申请号：US614470

    申请日：1975-09-18

    申请人： Manfred Hajek ,  Kuno Wagner

    发明人： Manfred Hajek ,  Kuno Wagner

    IPC分类号： C07D263/04 ,  C08G18/78 ,  C08G18/80 ,  C08G18/06 ,  C07D265/04

    CPC分类号： C07D263/04 ,  C08G18/7881 ,  C08G18/8064

    摘要： This invention relates to compounds corresponding to the following general formula: ##STR1## wherein M REPRESENTS AN INTEGER OF FROM 1 TO 6;N represents an integer of from 0 to 4;R.sub.1 represents an aliphatic hydrocarbon group containing from 2 to 6 carbon atoms;R.sub.2 and R.sub.3 which may be the same or different, each represents hydrogen, an aliphatic hydrocarbon group containing from 1 to 4 carbon atoms, a cycloaliphatic hydrocarbon group containing from 5 to 7 carbon atoms, or an aromatic hydrocarbon group containing from 6 to 10 carbon atoms, or when taken together with the ring carbon atom they may form a 5- or 6-membered cycloaliphatic hydrocarbon ring;R.sub.4 represents an aliphatic hydrocarbon group containing from 2 to 6 carbon atoms; andR.sub.5 represents a residue of the type which may be obtained by removing the isocyanate groups from an organic (n + m)-valent polyisocyanate.The invention also relates to a process for preparing urethanes which contain oxazolidine groups and optionally isocyanate groups, characterized in that N-hydroxyalkyl-oxazolidines are reacted with organic polyisocyanates at an OH/NCO ratio of from 1:1 to 1:6.

    摘要翻译： 本发明涉及对应于以下通式的化合物：其中M代表1至6的整数; N表示从0到4的整数; R1表示含有2至6个碳原子的脂族烃基; R 2和R 3可以相同或不同，各自表示氢，含有1至4个碳原子的脂族烃基，含有5至7个碳原子的脂环族烃基或含有6至10个碳原子的芳族烃基 或者当与环碳原子一起时，它们可以形成5-或6-元环脂族烃环; R4表示含有2至6个碳原子的脂族烃基; R 5表示通过从有机（n + m）价多异氰酸酯中除去异氰酸酯基而得到的残基。

    Process for the preparation of 3-hydrazino-1,2-benz-isothiazole 1,1-dioxides
    7.
    发明授权
    Process for the preparation of 3-hydrazino-1,2-benz-isothiazole 1,1-dioxides 失效
    3-肼基-1,2-苯并异噻唑1,1-二氧化物的制备方法

    公开(公告)号：US4667041A

    公开(公告)日：1987-05-19

    申请号：US706577

    申请日：1985-02-28

    申请人： Herbert Salzburg ,  Manfred Hajek ,  Gerd Hanssler

    发明人： Herbert Salzburg ,  Manfred Hajek ,  Gerd Hanssler

    IPC分类号： A01N43/80 ,  C07D275/06

    CPC分类号： C07D275/06 ,  A01N43/80

    摘要： A process for the preparation of a 3-hydrazino-1, 2-benzisothiazole 1,1-dioxide of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is hydrogen, alkyl, halogen, amino, hydroxyl or carboxyl, andR.sup.3 and R.sup.4 each independently is hydrogen, alkyl, cycloalkyl or aryl,comprising reacting a 3-keto-2H,3H-1,2-benzisothiazole 1,1-dioxide of the formula ##STR2## with a hydrazine of the formula ##STR3## in a molar ratio of 1:1 to 1:50, in an inert solvent, at a temperature between 75.degree. C. and 200.degree. C. and for a reaction time of 15 to 40 hours. The products, some of which are known, are fungicidally active and can also be used as intermediates.

    摘要翻译： 制备式“IMAGE”的3-肼基-1,2-苯并异噻唑1,1-二氧化物的方法，其中R 1和R 2各自独立地为氢，烷基，卤素，氨基，羟基或羧基，以及R 3和 R 4各自独立地是氢，烷基，环烷基或芳基，包括使式IMAGE的3-酮基-2H，3H-1,2-苯并异噻唑1,1-二氧化物与式IMAMA的肼反应 摩尔比为1:1至1:50，在惰性溶剂中，在75℃至200℃之间，反应时间为15至40小时。 其中一些已知的产品是杀真菌活性的并且也可以用作中间体。

    Process for the production of microcapsules
    8.
    发明授权
    Process for the production of microcapsules 失效
    微胶囊生产工艺

    公开(公告)号：US4428983A

    公开(公告)日：1984-01-31

    申请号：US310923

    申请日：1981-10-13

    申请人： Ulrich Nehen ,  Manfred Hajek ,  Norbert Weimann ,  Manfred Dahm

    发明人： Ulrich Nehen ,  Manfred Hajek ,  Norbert Weimann ,  Manfred Dahm

    IPC分类号： A61K9/50 ,  B01J13/14 ,  B01J13/16 ,  C09J5/00 ,  B01J13/02 ,  B05D7/00

    CPC分类号： B01J13/16 ,  Y10T428/2985 ,  Y10T428/2989

    摘要： A process for encapsulating products in a polymer by interfacial polymerization, in which a stabilized dispersion of droplets of a first liquid which is to be encapsulated or a stabilized dispersion of solid particles which are to be encapsulated is formed in a continuous phase of a second liquid, and wherein one of the two capsule wall-forming reaction components is present in free form while the other of the two capsule wall-forming reaction components is present in reversibly blocked form, both reaction components are present in the first or second liquid without reacting with one another and the reaction component which is present in reversibly blocked form is deblocked by means of water present in the second or first liquid and then reacts with the reaction component present in free form to form a polymeric capsule wall, the droplets of the first liquid or the solid particles being encapsulated in small capsules consisting of polymeric material.

    摘要翻译： 通过界面聚合将产物包封在聚合物中的方法，其中待包封的第一液体的液滴的稳定分散体或待被包封的固体颗粒的稳定化分散体形成在第二液体的连续相中 ，并且其中两个胶囊壁形成反应组分中的一个以游离形式存在，而两个胶囊壁形成反应组分中的另一个以可逆阻挡的形式存在，两个反应组分都存在于第一或第二液体中而没有反应 彼此之间并且以可逆阻挡形式存在的反应组分通过存在于第二或第一液体中的水解封，然后与游离形式存在的反应组分反应形成聚合物胶囊壁，第一 液体或固体颗粒被包封在由聚合物材料组成的小胶囊中。