公开(公告)号：US06780811B2

公开(公告)日：2004-08-24

申请号：US10100989

申请日：2002-03-20

申请人： Kuo-Chen Shih ,  Li-Jiun Chen ,  Yu-Shan Chao

发明人： Kuo-Chen Shih ,  Li-Jiun Chen ,  Yu-Shan Chao

IPC分类号： B01J3100

CPC分类号： C08F20/12 ,  C08F4/00 ,  C08F36/04

摘要： A catalyst composition for living free radical polymerization. The catalyst composition includes a transition metal complex MXp and a ligand, wherein M is a transition metal; X is halogen, —NO2, —NCS, —NCO, —SCN, —CN, —N3, —SO4, carboxylate group, or —PF6; p is the valence of the transition metal, the ligand is represented by formula (I): wherein R1 can be the same or different and is C1-20 alkyl, C6-20 aryl, C7-20 alkylaryl, C7-20 arylalkyl, or heterocyclic groups; R2 can be the same or different and is H, C1-20 alkyl, C6-20 aryl, C7-20 alkylaryl, C7-20 arylalkyl, heterocyclic groups, alkyl sulfide groups, nitrile groups, alkylsilyl, or ester groups; n is an integer of 0 to 6; and A is deleted or an S or O atom, wherein the molar ratio of the transition metal complex MXp and the ligand is 1 to 4. The catalyst composition of the present invention can be used to polymerize (meth)acrylic, vinyl, vinylidene, and diene monomers, and the polymer obtained has narrow polydispersity.

摘要翻译： 用于活性自由基聚合的催化剂组合物。 催化剂组合物包括过渡金属络合物MXp和配体，其中M是过渡金属; X是卤素，-NO 2，-NCS，-NCO，-SCN，-CN，-N 3，-SO 4，羧酸酯基或-PF 6; p是过渡金属的化合价，配体由式（I）表示：其中R 1可以相同或不同，并且是C 1-20烷基，C 6-20芳基，C 7-20烷基芳基，C 7-20 芳烷基或杂环基; R 2可以相同或不同，为H，C 1-20烷基，C 6-20芳基，C 7-20烷基芳基，C 7-20芳基烷基，杂环基，烷基硫基，腈基，烷基甲硅烷基或酯基; n为0〜6的整数。 并且A被除去或S或O原子，其中过渡金属络合物MXp和配体的摩尔比为1〜4。本发明的催化剂组合物可用于聚合（甲基）丙烯酸，乙烯基，亚乙烯基， 和二烯单体，并且所得聚合物具有窄的多分散性。

公开(公告)号：US20110160466A1

公开(公告)日：2011-06-30

申请号：US12981813

申请日：2010-12-30

申请人： Hsi-Yen Hsu ,  Yu-Shan Chao

发明人： Hsi-Yen Hsu ,  Yu-Shan Chao

IPC分类号： C07D307/36

CPC分类号： C07D307/60

摘要： The disclosure provides a method for preparing the citraconic anhydride and a method for isomerizing/dehydrating itaconic acid. The method for preparing the citraconic anhydride includes the following steps: providing itaconic acid as a starting material; and subjecting the itaconic acid to an isomerization/dehydration reaction in the presence of a catalyst to obtain the citraconic anhydride, wherein the catalyst includes a heteropolyacid or heteropolyacid salt.

摘要翻译： 本公开内容提供了制备柠康酸酐的方法和使衣康酸异构化/脱水的方法。 制备柠康酸酐的方法包括以下步骤：提供衣康酸作为原料; 并在催化剂存在下使衣康酸进行异构化/脱水反应，得到柠康酸酐，其中催化剂包括杂多酸或杂多酸盐。

公开(公告)号：US06207773B1

公开(公告)日：2001-03-27

申请号：US09362024

申请日：1999-07-28

申请人： Ching Ting ,  Jing-Cherng Tsai ,  Yi-Chun Chen ,  Sung-Song Hua ,  Tsai-Tien Su ,  Yu-Shan Chao

发明人： Ching Ting ,  Jing-Cherng Tsai ,  Yi-Chun Chen ,  Sung-Song Hua ,  Tsai-Tien Su ,  Yu-Shan Chao

IPC分类号： C08F444

CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F210/16 ,  C08F210/18 ,  Y10S526/905 ,  Y10S526/916 ,  Y10S526/943 ,  C08F4/6592 ,  C08F210/06 ,  C08F2500/03 ,  C08F2500/26 ,  C08F236/20 ,  C08F2500/25

摘要： A metallocene complex in which the cyclopentadienyl group is substituted with an alkanediyl silyl group. The yield of the metallocene complex is high, and it can be used as the catalyst for preparing high molecular weight olefin polymers.

摘要翻译： 茂金属络合物，其中环戊二烯基被烷二基甲硅烷基取代。 茂金属络合物的产率高，可用作制备高分子量烯烃聚合物的催化剂。

公开(公告)号：US5519108A

公开(公告)日：1996-05-21

申请号：US481114

申请日：1995-06-07

申请人： Wu-Bin Yuo ,  Chien-Shiun Liao ,  Wen-Jeng Lin ,  Cheng Yeh ,  Yu-Shan Chao ,  Li-Kuel Lin

发明人： Wu-Bin Yuo ,  Chien-Shiun Liao ,  Wen-Jeng Lin ,  Cheng Yeh ,  Yu-Shan Chao ,  Li-Kuel Lin

IPC分类号： C08G63/82 ,  C08G63/02

CPC分类号： C08G63/82

摘要： A catalyst composition for use in the preparation of poly(butylene terephthalate) from dimethyl terephthalate, comprising: (a) a titanium compound primary catalyst, from about 0.0005 PHR to about 5 PHR; (b) a first co-catalyst containing at least one of Zn, Co, Mn, Mg, Ca, or Pb series compounds, between about 0.0001 PHR and 5 PHR; and (c) a second co-catalyst containing an alkali metal phosphate, an alkali metal phosphite, an alkali hypophosphite, or an alkali metal polyphosphate between about 0.0001 PHR and 5 PHR; wherein PHR represents parts of the primary catalyst or the co-catalyst per one hundred parts, by weight, of dimethyl terephthalate. Preferred titanium compounds include tetrabutyl titanate or tetra(isopropyl)titanate. Preferred metal compounds for use as first co-catalyst are metal acetates. The alkali metal phosphate can be a phosphate salt containing one, two, or three metal groups; and the alkali metal phosphite can be a phosphite salt containing one or two metal groups. The alkali metal hypophosphite can be a hypophosphite salt containing any number of alkali metal groups. The alkali metal polyphosphate can be a polyphosphate salt containing one, two, three, four, or five alkali metal groups. With this catalyst composition, the rate of polycondensation was increased by 40 percent or more. The catalyst composition is also effective in the preparation of poly(butylene terephthalate) from terephthalic acid.

摘要翻译： 一种用于从对苯二甲酸二甲酯制备聚（对苯二甲酸丁二醇酯）的催化剂组合物，包括：（a）钛化合物一次催化剂，约0.0005PHR至约5PHR; （b）含有Zn，Co，Mn，Mg，Ca或Pb系化合物中的至少一种的第一助催化剂，约0.0001PHR和5PHR之间; 和（c）含有约0.0001PHR与5PHR之间的碱金属磷酸盐，碱金属亚磷酸盐，碱性次磷酸盐或碱金属多磷酸盐的第二助催化剂; 其中PHR代表每100重量份对苯二甲酸二甲酯的主要催化剂或助催化剂的部分。 优选的钛化合物包括钛酸四丁酯或钛酸四（异丙基）酯。 用作第一助催化剂的优选金属化合物是金属乙酸盐。 碱金属磷酸盐可以是含有一个，两个或三个金属基团的磷酸盐; 碱金属亚磷酸盐可以是含有一个或两个金属基团的亚磷酸盐。 碱金属次磷酸盐可以是含有任何碱金属基团的次亚磷酸盐。 碱金属多磷酸盐可以是含有一个，两个，三个，四个或五个碱金属基团的多磷酸盐。 使用该催化剂组合物，缩聚率提高了40％以上。 催化剂组合物在从对苯二甲酸制备聚对苯二甲酸丁二醇酯时也是有效的。

公开(公告)号：US5623047A

公开(公告)日：1997-04-22

申请号：US412784

申请日：1995-03-28

申请人： Wu-Bin Yuo ,  Jong-Wu Chen ,  Yu-Shan Chao

发明人： Wu-Bin Yuo ,  Jong-Wu Chen ,  Yu-Shan Chao

IPC分类号： C08G63/78 ,  C08G63/82 ,  C08G63/00 ,  C08G63/02

CPC分类号： C08G63/82 ,  C08G63/78

摘要： A catalyst composition for use in a polycondensation reaction for making poly(ethylene terephthalate) from terephthalic acid comprising: (a) an antimony salt catalyst present in a range from about 10 to about 1,000 ppm; (b) a metal salt catalyst of at least one of cobalt, magnesium, zinc, manganese, calcium, and lead, present in a range from about 10 to about 500 ppm; and (c) an alkali metal acetate, present in a range from about 10 to about 500 ppm; all amounts are based on the metallic elements relative to the theoretical yield of the poly(ethylene terephthalate), by weight, to be made from the terephthalic acid. The catalyst composition was found to have increased the reaction rate in the production of poly(ethylene terephthalate), as well as improved the color of the produced product, by reducing the degree of yellowness in the final poly(ethylene terephthalate) product. Attenuation of the yellowish color indicates a reduction in the amount of undesired side reaction product.

摘要翻译： 一种用于由对苯二甲酸制造聚（对苯二甲酸乙二醇酯）的缩聚反应中使用的催化剂组合物，其包含：（a）约10至约1,000ppm范围内的锑盐催化剂; （b）钴，镁，锌，锰，钙和铅中的至少一种的金属盐催化剂，其存在范围为约10至约500ppm; 和（c）碱金属乙酸盐，其存在量为约10至约500ppm; 相对于由对苯二甲酸制成的聚对苯二甲酸乙二醇酯的理论产率，所有量都是基于金属元素。 发现催化剂组合物通过降低最终的聚（对苯二甲酸乙二醇酯）产品的黄度而增加聚（对苯二甲酸乙二醇酯）的生产中的反应速率，以及改进所生产的产品的颜色。 淡黄色的衰减表示不期望的副反应产物的量的减少。

公开(公告)号：US5608032A

公开(公告)日：1997-03-04

申请号：US413027

申请日：1995-03-28

申请人： Wu-Bin Yuo ,  Jong-Wu Chen ,  Yu-Shan Chao

发明人： Wu-Bin Yuo ,  Jong-Wu Chen ,  Yu-Shan Chao

IPC分类号： C08G63/82 ,  C08G63/86 ,  C08G63/00 ,  C08G63/02 ,  C08G63/78

CPC分类号： C08G63/82 ,  C08G63/866

摘要： A catalyst composition for use in a polycondensation reaction for making poly(ethylene terephthalate) from terephthalic acid comprising: (a) an antimony salt catalyst present in a range from about 10 to about 1,000 ppm; (b) a metal salt catalyst of at least one of cobalt, magnesium, zinc, manganese, calcium, and lead, present in a range from about 10 to about 500 ppm; and (c) a phosphorus salt co-catalyst selected from the group consisting of alkali metal phosphates, alkali metal phosphites, alkali metal hypophosphites and alkali metal polyphosphates, present in a range from about 10 to about 500 ppm; all amounts are based on the metallic or phosphorus element relative to the theoretical yield of the poly(ethylene terephthalate), by weight, to be made from the terephthalic acid. The catalyst composition was found to have increased the reaction rate in the production of poly(ethylene terephthalate), as well as improved the color of the produced product, by reducing the degree of yellowness in the final poly(ethylene terephthalate) product. Attenuation of the yellowish color indicates a reduction in the amount of undesired side reaction product.

摘要翻译： 一种用于由对苯二甲酸制造聚（对苯二甲酸乙二醇酯）的缩聚反应中使用的催化剂组合物，其包含：（a）约10至约1,000ppm范围内的锑盐催化剂; （b）钴，镁，锌，锰，钙和铅中的至少一种的金属盐催化剂，其存在范围为约10至约500ppm; 和（c）选自碱金属磷酸盐，碱金属亚磷酸盐，碱金属次磷酸盐和碱金属多磷酸盐的磷盐助催化剂，其存在范围为约10至约500ppm; 相对于由对苯二甲酸制成的聚对苯二甲酸乙二醇酯的理论产率，所有量都基于金属或磷元素。 发现催化剂组合物通过降低最终的聚（对苯二甲酸乙二醇酯）产品的黄度而增加聚（对苯二甲酸乙二醇酯）的生产中的反应速率，以及改进所生产的产品的颜色。 淡黄色的衰减表示不期望的副反应产物的量的减少。

公开(公告)号：US08273903B2

公开(公告)日：2012-09-25

申请号：US12981813

申请日：2010-12-30

申请人： Hsi-Yen Hsu ,  Yu-Shan Chao

发明人： Hsi-Yen Hsu ,  Yu-Shan Chao

IPC分类号： C07D307/60

CPC分类号： C07D307/60

摘要： The disclosure provides a method for preparing the citraconic anhydride and a method for isomerizing/dehydrating itaconic acid. The method for preparing the citraconic anhydride includes the following steps: providing itaconic acid as a starting material; and subjecting the itaconic acid to an isomerization/dehydration reaction in the presence of a catalyst to obtain the citraconic anhydride, wherein the catalyst includes a heteropolyacid or heteropolyacid salt.

摘要翻译： 本公开内容提供了制备柠康酸酐的方法和使衣康酸异构化/脱水的方法。 制备柠康酸酐的方法包括以下步骤：提供衣康酸作为原料; 并在催化剂存在下使衣康酸进行异构化/脱水反应，得到柠康酸酐，其中催化剂包括杂多酸或杂多酸盐。

公开(公告)号：US06313230B1

公开(公告)日：2001-11-06

申请号：US09400544

申请日：1999-09-21

申请人： Jing-Cherng Tsai ,  Wen-Sheng Chang ,  Yu-Shan Chao ,  Chih-Nan Chu ,  Chen-Pao Huang ,  Hung-Yang Hsiao

发明人： Jing-Cherng Tsai ,  Wen-Sheng Chang ,  Yu-Shan Chao ,  Chih-Nan Chu ,  Chen-Pao Huang ,  Hung-Yang Hsiao

IPC分类号： C08F804

CPC分类号： C08F8/04 ,  C08C19/02

摘要： A process for hydrogenation of conjugated diene polymers comprises hydrogenating said polymer in the presence of hydrogen and a hydrogenation catalyst composition comprising: (a) at least one titanium compound represented by the following formula (a): wherein R1 and R2, which may be the same or different, represent a halogen atom, an alkyl group, an aryl group, an arakyl group, a cycloalkyl group, an aryloxy group, an alkoxy group or a carbonyl group, and Cp* represents a cyclopentadienyl group or a derivative having the formula of C5R5, and R5, which may be the same or different, represents a hydrogen atom, an alkyl group an aralkyl group and an aryl group; and (b) at least one silyl hydride.

摘要翻译： 共轭二烯聚合物的氢化方法包括在氢气和氢化催化剂组合物的存在下氢化所述聚合物，所述氢化催化剂组合物包含：（a）至少一种由下式（a）表示的钛化合物：其中R1和R2可以是 代表卤素原子，烷基，芳基，芳基，环烷基，芳氧基，烷氧基或羰基，Cp *表示环戊二烯基或具有式 的C5R5和R5可以相同或不同，表示氢原子，烷基，芳烷基和芳基; 和（b）至少一种甲硅烷基氢化物。