Preparation of soft and hard resins, and their use
    5.
    发明授权
    Preparation of soft and hard resins, and their use 失效
    软和硬树脂的制备及其用途

    公开(公告)号:US4220751A

    公开(公告)日:1980-09-02

    申请号:US969664

    申请日:1978-12-15

    CPC分类号: C08G12/12 C09D161/24

    摘要: A process for the preparation of soft and hard resins, and their use in surface-coating binders.According to the invention, soft and hard resins are prepared from a urea and a CH-acidic aldehyde by reacting a urea of the general formula (I) ##STR1## where X is oxygen or sulfur and R.sup.1 and R.sup.2 are hydrogen or identical or different alkyl, aryl or aralkyl, or may be an alkyleneurea radical, with at least 2 moles of a CH-acidic aldehyde of the general formula (II) ##STR2## where R.sup.3 is hydrogen and R.sup.4 is alkyl, aryl or aralkyl, or R.sup.3 and R.sup.4 are identical or different alkyl, aryl or aralkyl, in the presence of a strong acid, to give a condensation product, and then treating the latter with a base in an anhydrous medium.These soft and hard resins are used, in combination with other film-forming agents, as surface-coating binders.

    摘要翻译: 用于制备软和硬树脂的方法及其在表面涂层粘合剂中的应用。 根据本发明,通过使通式(I)的脲(I)其中X是氧或硫,R 1和R 2是氢或通式 具有至少2摩尔的通式(II)的II型的酸式醛,其中R 3是氢和R 4是烷基,芳基,芳基或芳烷基,或可以是亚烷基脲基, 或芳烷基,或者R3和R4是相同或不同的烷基,芳基或芳烷基,在强酸存在下,得到缩合产物,然后用无水介质中的碱处理后者。 这些软和硬树脂与其它成膜剂一起用作表面涂层粘合剂。

    Process for the manufacture of soft and hard resins of urea,
formaldehyde and a CH-acidic aldehyde, and their use
    8.
    发明授权
    Process for the manufacture of soft and hard resins of urea, formaldehyde and a CH-acidic aldehyde, and their use 失效
    用于制造尿素,甲醛和CH-酸性醛的软和硬树脂的方法及其用途

    公开(公告)号:US4243797A

    公开(公告)日:1981-01-06

    申请号:US971187

    申请日:1978-12-20

    CPC分类号: C08G12/12 C09D161/24

    摘要: A process for the preparation of soft and hard resins, and their use in surface-coating binders are disclosed. According to the invention, soft and hard resins are prepared from a urea, formaldehyde and a CH-acidic aldehyde by reacting a urea of the general formula (I) or (II) ##STR1## where R.sup.1 and R.sup.2 are hydrogen or identical or different alkyl, A is alkylene and X is oxygen or sulfur, with formaldehyde and a CH-acidic aldehyde of the general formula (III) ##STR2## where R.sup.3 and R.sup.4 are identical or different alkyl, aryl or alkylaryl wherein the urea, formaldehyde and CH-acidic aldehyde are employed in a mole ratio of from 1:2:2 to 1:4:4, at from 60.degree. to 150.degree. C., in the presence of an acid and in the presence or absence of a solvent and/or diluent, and then treating the product with a base in an anhydrousmedium.

    摘要翻译: 公开了一种用于制备软和硬树脂的方法及其在表面涂层粘合剂中的用途。 根据本发明,通过使通式(I)或(II)的脲与(II)的脲反应,由尿素,甲醛和CH-酸性醛制备软和硬的树脂,其中 R 1和R 2是氢或相同或不同的烷基,A是亚烷基,X是氧或硫,与通式(III)的甲醛和CH-酸醛形成,其中R 3和R 4是相同或不同的烷基,芳基 或烷基芳基,其中使用的脲,甲醛和CH-酸性醛的摩尔比为1:2:2至1:4:4,在60-150℃,在酸的存在下, 溶剂和/或稀释剂的存在或不存在,然后用无水介质中的碱处理产物。

    Dyeing and printing of textiles with disperse dyes
    10.
    发明授权
    Dyeing and printing of textiles with disperse dyes 失效
    用分散染料染色和印花纺织品

    公开(公告)号:US4239491A

    公开(公告)日:1980-12-16

    申请号:US103074

    申请日:1979-12-12

    摘要: An improved process for dyeing or printing water-swellable cellulosic fibers and mixtures of said cellulosic fibers with synthetic fibers by contacting the fibers throughout with a dye liquor or print paste which contains, as essential ingredients, water in an amount sufficient to swell the cellulosic fibers, a water-insoluble disperse dye and a water-soluble solvent which maintains swelling of the cellulose if water is removed and which is a solvent for the disperse dye, and heating the contacted fibers to effect fixation of the dye, the improvement comprising using as water-soluble solvent a mixture of(a) polyethylene oxide, a block copolymer of ethylene oxide and propylene oxide or an ether, ester or carbamate derivative thereof and(b) a polyoxyethylated amine.

    摘要翻译: 一种改进的染色或印刷水溶胀纤维素纤维的方法,以及所述纤维素纤维与合成纤维的混合物,通过将纤维与整个含有作为必需成分的染料液或印刷糊剂接触,其量足以溶胀纤维素纤维 ,水不溶性分散染料和水溶性溶剂,如果去除水,则保持纤维素的溶胀,并且其是用于分散染料的溶剂,并且加热接触的纤维以实现染料的固定,改进包括使用 水溶性溶剂是(a)聚环氧乙烷,环氧乙烷和环氧丙烷的嵌段共聚物或其醚,酯或氨基甲酸酯衍生物和(b)聚氧乙基化胺的混合物。