公开(公告)号：US4600655A

公开(公告)日：1986-07-15

申请号：US732732

申请日：1985-05-10

申请人： Hans D. Hermann ,  Kurt Fock ,  Klaus Fabian ,  Joachim Ebigt

发明人： Hans D. Hermann ,  Kurt Fock ,  Klaus Fabian ,  Joachim Ebigt

IPC分类号： C08K5/14 ,  B32B17/10 ,  C03C27/12 ,  C08J5/18 ,  C08K3/30 ,  C08K5/41 ,  C08K5/42 ,  C08L29/00 ,  C08L29/14 ,  C09J129/14 ,  B32B17/06 ,  C08J3/20

CPC分类号： C08K5/41 ,  B32B17/10688 ,  C08K5/42 ,  Y10T428/3163

摘要： Reduction in the adhesion to glass of thermoplastic, plasticized polyvinylbutyral molding compositions, in particular sheeting, by adding the magnesium salt of sulfonic acids or sulfuric acid half-esters or mixtures of these compounds as an non-stick agent, preferably in amounts of 0.003 to 0.3% by weight, relative to the plasticized polyvinylbutyral. The non-stick agent is preferably employed in the form of a solution in the plasticizer. The use of the sheeting having an adhesion to glass reduced in accordance with the invention as the laminating layer for the production of glass laminates.

摘要翻译： 通过加入磺酸或硫酸半酯的镁盐或这些化合物的混合物作为不粘剂，降低与玻璃的热塑性塑化聚乙烯醇缩丁醛成型组合物的粘合性，特别是片材的量，优选为0.003〜 相对于增塑聚乙烯醇缩丁醛为0.3重量％。 不粘剂优选以增塑剂溶液的形式使用。 根据本发明，使用具有与玻璃的粘合性的片材作为用于生产玻璃层压材料的层压层。

公开(公告)号：US4663235A

公开(公告)日：1987-05-05

申请号：US732734

申请日：1985-05-10

申请人： Kurt Fock ,  Hans D. Hermann ,  Klaus Fabian ,  Joachim Ebigt

发明人： Kurt Fock ,  Hans D. Hermann ,  Klaus Fabian ,  Joachim Ebigt

IPC分类号： B32B17/10 ,  C03C27/12 ,  C08J5/18 ,  C08K5/00 ,  C08K5/07 ,  C08L29/00 ,  C08L29/04 ,  C08L29/14

CPC分类号： C08K5/0091 ,  B32B17/10605 ,  B32B17/10688 ,  B32B17/10761 ,  C08K5/07 ,  Y10T428/315 ,  Y10T428/3163

摘要： Reduction in the adhesion to glass of thermoplastic, plasticized polyvinylbutyral molding compositions, in particular sheeting, by the addition of a metal salt and/or metal chelate of an enolizable .beta.-diketone, or mixtures of these compounds, as an non-stick agent, preferably in amounts of 0.003 to 0.3% by weight, relative to the plasticized polyvinylbutyral. It is preferable to employ the non-stick agent in the form of a solution in the plasticizer. The use of the sheeting having an adhesion to glass reduced in accordance with the invention as a laminating layer for the production of glass laminates.

摘要翻译： 通过加入可烯化的β-二酮的金属盐和/或金属螯合物或这些化合物的混合物作为不粘剂，降低与玻璃的热塑性塑化聚乙烯醇缩丁醛成型组合物的粘合力，特别是片材， 优选相对于增塑聚乙烯醇缩丁醛为0.003〜0.3重量％。 优选在增塑剂中使用溶液形式的不粘剂。 根据本发明，使用具有对玻璃的粘合性的片材作为用于生产玻璃层压板的层压层。

公开(公告)号：US4533601A

公开(公告)日：1985-08-06

申请号：US575712

申请日：1984-01-31

申请人： Hans D. Hermann ,  Klaus Fabian ,  Joachim Ebigt

发明人： Hans D. Hermann ,  Klaus Fabian ,  Joachim Ebigt

IPC分类号： C08L29/00 ,  B32B17/10 ,  C03C27/12 ,  C08J5/18 ,  C08K5/00 ,  C08K5/098 ,  C08K5/16 ,  C08K5/19 ,  C08K5/42 ,  C08L29/14 ,  C08K3/22 ,  C08K5/17 ,  C08L29/04

CPC分类号： C08J5/18 ,  B32B17/10688 ,  B32B17/10761 ,  C08K5/0008 ,  C08K5/098 ,  C08K5/19 ,  C08J2329/14 ,  Y10T428/3163

摘要： The reduction of the adhesion to glass of thermoplastic polyvinylbutyral molding compositions, in particular films, which contain plasticizer and in which the polyvinylbutyral component has an increased content of vinyl alcohol units, by addition of a combination of potassium hydroxide, potassium formate or potassium acetate and a compound having a betaine structure, as the anti-adhesive agent. Use of the films with reduced adhesion to glass as the bonding layer for the production of glass laminates.

摘要翻译： 通过加入氢氧化钾，甲酸钾或乙酸钾的组合，通过加入氢氧化钾，甲酸钾或乙酸钾的组合，减少与含有增塑剂的热塑性聚乙烯醇缩丁醛成型组合物的玻璃，特别是其中聚乙烯醇缩丁醛成分具有增加的乙烯醇单元含量的粘合剂 具有甜菜碱结构的化合物作为抗粘合剂。 使用具有降低与玻璃粘合的膜作为生产玻璃层压板的粘合层。

公开(公告)号：US4205146A

公开(公告)日：1980-05-27

申请号：US925873

申请日：1978-07-18

申请人： Hans D. Hermann ,  Joachim Ebigt ,  Ulrich M. Hutten

发明人： Hans D. Hermann ,  Joachim Ebigt ,  Ulrich M. Hutten

IPC分类号： C08F8/00 ,  C08F8/28

CPC分类号： B32B17/10761 ,  C08F8/48 ,  Y10T428/3163

摘要： The preparation of polyvinylbutyral is commonly effected by the acetalization of polyvinyl alcohol with n-butyraldehyde, either in an organic solvent or in water. By varying the reaction conditions it is possible to obtain the polyvinylbutyral in a coarse-grain or fine-grained form. The production of polyvinylbutyral having improved properties is possible by using a polyvinylbutyral having a content of from 17 to 24% by weight of vinyl alcohol units as starting material for an after-treatment in the presence of an organic sulfonic acid having an emulsifying effect. The polyvinylbutyral obtained is particularly suitable for the manufacture of compound sheets.

摘要翻译： 聚乙烯醇缩丁醛的制备通常通过聚乙烯醇与正丁醛在有机溶剂或水中的缩醛化来实现。 通过改变反应条件，可以获得粗粒或细粒形式的聚乙烯醇缩丁醛。 具有改进性能的聚乙烯醇缩丁醛的生产可以通过使用含有17-24％（重量）乙烯醇单元的聚乙烯醇缩丁醛作为在具有乳化作用的有机磺酸存在下进行后处理的原料。 所得聚乙烯醇缩丁醛特别适用于复合片材的制造。

公开(公告)号：US4161565A

公开(公告)日：1979-07-17

申请号：US841394

申请日：1977-10-12

申请人： Hans D. Hermann ,  Joachim Ebigt

发明人： Hans D. Hermann ,  Joachim Ebigt

IPC分类号： C03C27/12 ,  B32B17/10 ,  C09D129/14 ,  C08K5/17

CPC分类号： B32B17/10761 ,  B32B17/10688 ,  C09D129/14 ,  Y10T428/3163

摘要： Plasticizer containing polyvinylbutyral sheets are known intermediate layers for glass laminates. Generally, the polyvinylbutyral used for this application contains certain amounts of vinyl alcohol units and vinyl acetate units. In order to adjust an optimum adhesion to glass, certain additives are mixed with the polyvinylbutyral, which additives must not cause discoloration of the laminate and deterioration of the transparency. Betains are especially suitable anti-adhesives, and efficient in very small amounts.

摘要翻译： 含有聚乙烯醇缩丁醛片的增塑剂是玻璃层压材料的已知中间层。 通常，用于该应用的聚乙烯醇缩丁醛含有一定量的乙烯醇单元和乙酸乙烯酯单元。 为了调节对玻璃的最佳粘合性，某些添加剂与聚乙烯醇缩丁醛混合，这些添加剂不会引起层压板的变色和透明度的劣化。 甜菜是特别合适的抗粘合剂，并且非常少量的高效。

公开(公告)号：US4751266A

公开(公告)日：1988-06-14

申请号：US762826

申请日：1985-08-06

申请人： Hans D. Hermann ,  Ulrich M. Hutten ,  Klaus Fabian

发明人： Hans D. Hermann ,  Ulrich M. Hutten ,  Klaus Fabian

IPC分类号： C08F8/00 ,  C08F8/28 ,  C08F16/00 ,  C08F16/38

CPC分类号： C08F8/28

摘要： Polyvinylbutyral of reduced tackiness and improved tensile strength is prepared by acetalization of polyvinyl alcohol, which is capable of association, in the associated state with n-butyraldehyde in aqueous phase in the presence of an acid catalyst. In the process for its preparation from more highly saponified, associated polyvinyl alcohol having a vinyl acetate unit content of less than 1% by weight, the acetalization is started preferably at temperatures below 20.degree. C. and the temperature is raised to above 40.degree. C. in the course of the reaction. Use for the production of plasticized thermoplastic polyvinylbutyral films and use of the latter as the joining layer in laminated glass.

摘要翻译： 通过在酸催化剂的存在下，在水相中与正丁醛在相关状态下缩合能够缔合的聚乙烯醇来制备降低粘性和改善拉伸强度的聚乙烯醇缩丁醛。 在由具有小于1重量％的乙酸乙烯酯单元含量的更高皂化的相关聚乙烯醇制备的方法中，优选在低于20℃的温度下开始缩醛化，并将温度升至40℃以上 在反应过程中。 用于生产塑化热塑性聚乙烯醇缩丁醛薄膜，并使用后者作为夹层玻璃中的接合层。

公开(公告)号：US4537830A

公开(公告)日：1985-08-27

申请号：US575711

申请日：1984-01-31

申请人： Hans D. Hermann ,  Klaus Fabian

发明人： Hans D. Hermann ,  Klaus Fabian

IPC分类号： C08L29/00 ,  B32B17/10 ,  C08J5/18 ,  C08K5/103 ,  C08K5/523 ,  C08L29/14 ,  C08K5/10 ,  C08K5/52

CPC分类号： C08J5/18 ,  B32B17/10605 ,  B32B17/10688 ,  B32B17/10761 ,  C08K5/103 ,  C08K5/523 ,  C08J2329/14 ,  Y10T428/3163

摘要： Thermoplastic molding compositions comprising 65-80% by weight (based on the molding composition) of a polyvinylbutyral which preferably contains 19-28% by weight (based on the polyvinylbutyral) of vinyl alcohol units, and 35-20% by weight (based on the molding composition) of a plasticizer mixture of 50-99% by weight (based on the plasticizer mixture) of a di-, tri- or tetra-glycol diester and 50-1% by weight (based on the plasticizer mixture) of a phosphoric acid triester. The preparation of the molding compositions by mixing the constituent components and their use for the production of shaped thermoplastic articles, in particular high-strength films for use as the bonding intermediate layer in the production of laminated glass.

摘要翻译： 包含65-80重量％（基于成型组合物）的聚乙烯醇缩丁醛的热塑性成型组合物，其优选含有19-28重量％（基于聚乙烯醇缩丁醛）乙烯醇单元，和35-20重量％（基于 50至99重量％（基于增塑剂混合物）的二元，三元或四元二醇二酯和50-1重量％（基于增塑剂混合物）的增塑剂混合物的成型组合物 磷酸三酯。 通过混合构成成分及其制造成型热塑性制品的用途，特别是用作夹层玻璃的生产中的接合中间层的高强度薄膜来制备成型组合物。

公开(公告)号：US4287107A

公开(公告)日：1981-09-01

申请号：US87976

申请日：1979-10-25

申请人： Hans D. Hermann ,  Albrecht Harreus

发明人： Hans D. Hermann ,  Albrecht Harreus

IPC分类号： C08L29/00 ,  C08K5/10 ,  C08K5/101 ,  C08K5/103 ,  C08L29/14 ,  C08L91/06 ,  B32B17/10 ,  B32B27/42

CPC分类号： B32B17/10761 ,  B32B17/10577 ,  C08K5/101 ,  C08K5/103 ,  Y10T428/3163

摘要： The tendency to blocking of polymer sheets can be reduced by means of anti-blocking agents. Suitable anti-blocking agents in transparent polyvinyl butyral sheets are especially montanic acid esters, which do not adversely affect the adhesion of the sheet to glass. The polyvinyl butyral sheets are used as interlayers of laminated glass (safety glass).

摘要翻译： 可以通过防粘连剂降低聚合物片材的阻塞倾向。 在透明聚乙烯醇缩丁醛片中的合适的防粘连剂特别是褐煤酸酯，其不会对片材与玻璃的粘合性产生不利影响。 聚乙烯醇缩丁醛片用作夹层玻璃（安全玻璃）的夹层。

公开(公告)号：US4968473A

公开(公告)日：1990-11-06

申请号：US281200

申请日：1988-12-07

申请人： Hans D. Hermann ,  Dieter Grote ,  Karl Waldmann

发明人： Hans D. Hermann ,  Dieter Grote ,  Karl Waldmann

IPC分类号： B01F17/00 ,  B01F17/46 ,  C04B35/634

CPC分类号： C04B35/6342 ,  B01F17/0042 ,  C04B35/634 ,  C04B35/63488

摘要： Ceramic green films having advantageous isotropic distribution of the inorganic pigment can be obtained by casting and drying a slip containing finely divided inorganic pigment, organic solvents, polyvinylbutyral, plasticizer and dispersing agent if compounds which contain in their molecules at least one structural unit of the formula Z ##STR1## in which A and B, which must be different, stand for either the oxyalkylene unit --C.sub.3-4 H.sub.6-8 O-- or the oxyalkylene unit --C.sub.2 H.sub.4 O-- and x and y, which can be identical or different, each denote a number from 1 to 200, are used as dispersing agents.Ceramic green films produced according to the invention can be converted to isotropic ceramic substrates by subsequent heat treatment and sintering.

摘要翻译： 具有有机无机颜料的各向同性分布的陶瓷绿膜可以通过将含有细碎无机颜料，有机溶剂，聚乙烯醇缩丁醛，增塑剂和分散剂的滑爽液浇铸和干燥来获得，如果化合物在其分子中含有至少一个式 Z （Z）其中A和B必须不同，代表氧化烯单元-C3-4H6-8O-或氧化烯单元-C2H4O-，x和y可以相同或不同， 各自表示1〜200的数，用作分散剂。 通过随后的热处理和烧结，可以将根据本发明生产的陶瓷绿膜转化为各向同性的陶瓷衬底。

公开(公告)号：US4499236A

公开(公告)日：1985-02-12

申请号：US562218

申请日：1983-12-16

申请人： Hans D. Hermann ,  Ulrich M. Hutten

发明人： Hans D. Hermann ,  Ulrich M. Hutten

IPC分类号： C08F8/00 ,  B32B17/10 ,  C08F8/28 ,  C08F16/00 ,  C08F16/38 ,  C08L29/00 ,  C08L29/14 ,  C08L51/00 ,  C08L51/02 ,  C08L77/00 ,  C09D5/03 ,  C09D129/14 ,  D06M13/02 ,  D06M13/137 ,  D06M15/333

CPC分类号： B32B17/10761 ,  C08F8/48

摘要： The invention relates to finely divided polyvinyl acetal which is prepared in the form of an aqueous suspension or, if desired, in powder form, preferably having average particle sizes from 0.5 to 10 .mu.m, from polyvinyl alcohol and at least one aliphatic aldehyde having at least 3 carbon atoms, and which contains 0.1 to 10% by weight, based on polyvinyl acetal, of a completely or partially hydrolyzed vinyl ester copolymer grafted onto polyethylene oxide or polyethylene oxide derivatives and acetalized in the mixture with the polyvinyl alcohol.The invention further relates to a process for preparing finely divided polyvinyl acetals having an average particle size between 0.5 and 10 .mu.m in an aqueous suspension or, if desired, by dewatering the suspension, in powder form, by reacting an aqueous solution of polyvinyl alcohol, in the presence of an acidic catalyst and in the absence or presence of emulsifiers, with at least one aliphatic aldehyde having at least 3 carbon atoms, which comprises performing the acetalization reaction in the presence of 0.1 to 10% by weight, based on the polyvinyl alcohol used, of a completely or partially hydrolyzed graft copolymer of vinyl ester on polyethylene oxide or polyethylene oxide derivatives.A further part of the subject-matter of the invention is the use of the finely divided polyvinyl acetals described above, in particular from a low-electrolyte or electrolyte-free aqueous suspension, preferably having an average particle size between 0.5 and 10 .mu.m, for baked coatings on any coatable substrates, in particular on metals.

摘要翻译： 本发明涉及精细分散的聚乙烯醇缩醛，其以水性悬浮液或如果需要，以粉末形式制备，优选具有0.5至10μm的平均粒度，来自聚乙烯醇和至少一种脂族醛，其具有 至少3个碳原子，并且基于聚乙烯醇缩醛含有0.1至10重量％的全部或部分水解的乙烯基酯共聚物，其接枝到聚环氧乙烷或聚环氧乙烷衍生物上并与聚乙烯醇的混合物缩醛化。 本发明还涉及一种在水性悬浮液中制备平均粒度为0.5-10μm的细分聚乙烯醇缩醛的方法，或者如果需要，通过使粉末形式的悬浮液脱水，通过使聚乙烯醇的水溶液 在酸性催化剂的存在下，在不存在或不存在乳化剂的情况下，与至少一种具有至少3个碳原子的脂肪族醛进行缩合反应，该方法包括在0.1-10重量％的存在下，基于 使用的聚乙烯醇，乙烯基酯在聚环氧乙烷或聚环氧乙烷衍生物上的完全或部分水解的接枝共聚物。 本发明的主题的另一部分是使用上述细碎的聚乙烯醇缩醛，特别是使用低电解质或不含电解质的水性悬浮液，优选具有0.5-10μm的平均粒度， 用于任何可涂覆的基材，特别是金属上的烘烤涂层。