公开(公告)号：US09266080B2

公开(公告)日：2016-02-23

申请号：US13823326

申请日：2011-07-19

申请人： Kyoung Su Ha ,  Du Eil Kim ,  Gyu In Jung ,  Jong Wook Bae ,  Ki Won Jun

发明人： Kyoung Su Ha ,  Du Eil Kim ,  Gyu In Jung ,  Jong Wook Bae ,  Ki Won Jun

IPC分类号： B01J8/22 ,  C10G2/00 ,  B01J8/00

CPC分类号： B01J8/0085 ,  B01J8/006 ,  B01J8/22 ,  B01J8/226 ,  B01J8/228 ,  B01J2208/00902 ,  B01J2208/00929 ,  B01J2208/00938 ,  C10G2/32 ,  C10G2/342 ,  C10G2300/1022

摘要： Disclosed is a reaction device for producing hydrocarbons from synthesis gas, in which hydrocarbons, olefins, oxygenates, etc., are produced over a Fischer-Tropsch catalyst by using synthesis gas, so that the catalyst particles can easily be from a slurry which is discharged to the outside. That is, the present invention provides a reaction device for producing hydrocarbons from synthesis gas, in which an internal filter system for separating particles enlarged due to agglomeration phenomenon of a catalyst is installed inside the reactor, and a separating device is separately disposed outside, such that it is possible to recirculate only particles having a size appropriate for performing F-T synthesis in the slurry phase, and additionally, it is possible to effectively discharge and process a catalyst aggregated due to a combination of fine catalyst particles, the catalyst chipped off during the operation, etc., liquid hydrocarbon, resulting water, etc., in the slurry phase reactor.

摘要翻译： 公开了一种通过合成气从费 - 托催化剂上生产碳氢化合物，烯烃，含氧化合物等的合成气生产烃的反应装置，使得催化剂颗粒可以容易地从排出的浆料中 到外面 也就是说，本发明提供了一种用于从合成气生产烃的反应装置，其中用于分离由于催化剂的聚集现象而扩大的颗粒的内部过滤系统安装在反应器内部，并且分离装置分开设置在外部， 可以仅在浆料相中仅再循环具有适合于进行FT合成的尺寸的颗粒，另外，可以有效地排出和处理由于催化剂颗粒的组合而聚集的催化剂，催化剂颗粒在 操作等，液态烃，产生的水等，在浆相反应器中。

公开(公告)号：US20130171040A1

公开(公告)日：2013-07-04

申请号：US13823326

申请日：2011-07-19

申请人： Kyoung Su Ha ,  Du Eil Kim ,  Gyu In Jung ,  Jong Wook Bae ,  Ki Won Jun

发明人： Kyoung Su Ha ,  Du Eil Kim ,  Gyu In Jung ,  Jong Wook Bae ,  Ki Won Jun

IPC分类号： B01J8/00

CPC分类号： B01J8/0085 ,  B01J8/006 ,  B01J8/22 ,  B01J8/226 ,  B01J8/228 ,  B01J2208/00902 ,  B01J2208/00929 ,  B01J2208/00938 ,  C10G2/32 ,  C10G2/342 ,  C10G2300/1022

摘要： Disclosed is a reaction device for producing hydrocarbons from synthesis gas, in which hydrocarbons, olefins, oxygenates, etc., are produced over a Fischer-Tropsch catalyst by using synthesis gas, so that catalyst particles can easily be from a slurry which is discharged to the outside. That is, the present invention provides a reaction device for producing hydrocarbons from synthesis gas, in which an internal filter system for separating particles enlarged due to a agglomeration phenomenon of a catalyst is installed inside the reactor, and an separating device is separately disposed outside, such that it is possible to recirculate only particles having a size appropriate for performing F-T synthesis in the slurry phase, and additionally, it is possible to effectively discharge and process a catalyst aggregated due to a combination of fine catalyst particles, the catalyst chipped off during the operation, etc., liquid hydrocarbon, resulting water, etc., in the slurry phase reactor.

摘要翻译： 公开了一种用于从合成气中生产烃的反应装置，其中通过使用合成气在费 - 托催化剂上生产烃，烯烃，含氧化合物等，使得催化剂颗粒可以容易地从排出到 外。 也就是说，本发明提供了一种用于从合成气中生产烃的反应装置，其中用于分离由于催化剂的聚集现象而扩大的颗粒的内部过滤系统安装在反应器内部，并且分离装置分开设置在外部， 使得可以仅在浆料相中仅再循环具有适合于进行FT合成的尺寸的颗粒，此外，可以有效地排出和处理由于催化剂颗粒的组合而聚集的催化剂，催化剂在 操作等，液态烃，得到的水等在浆相反应器中。

公开(公告)号：US20110237689A1

公开(公告)日：2011-09-29

申请号：US13132471

申请日：2009-09-09

申请人： Jong Wook Bae ,  Jong Hyeok Oh ,  Ki Won Jun ,  Yun Jo Lee ,  Jun-ho Ko ,  Seok-Lyong Song ,  Keh-Sik Min

发明人： Jong Wook Bae ,  Jong Hyeok Oh ,  Ki Won Jun ,  Yun Jo Lee ,  Jun-ho Ko ,  Seok-Lyong Song ,  Keh-Sik Min

IPC分类号： C07C27/00

CPC分类号： C07C29/154 ,  Y02P20/582 ,  C07C31/04

摘要： Disclosed is a method for methanol synthesis using synthesis gas obtained from reforming of natural gas with carbon dioxide. First, synthesis gas is obtained from steam carbon dioxide reforming of methane, in which steam reforming of natural gas is carried out simultaneously with carbon dioxide reforming of methane, by using a catalyst (Ni/Ce/MgAlOx, or Ni/Ce—Zr/MgAlOx) and processing condition capable of maintaining a predetermined ratio of carbon monoxide, carbon dioxide, and hydrogen [H2/(2CO+3CO2)=0.85-1.15] Next, methanol synthesis is carried out by using the obtained synthesis as and a catalyst system suitable for methanol synthesis with minimum byproduct formation (a catalyst system including a Cu—Zn—Al oxide containing CuO, ZnO, and Al2O3 at a predetermined ratio in combination with a cerium-zirconium oxide obtained by a sol-gel process). In addition, unreacted synthesis gas remaining after the operation of methanol synthesis is recycled efficiently to improve the carbon availability (methane and CO2 availability) and energy efficiency in the overall process.

摘要翻译： 公开了使用由二氧化碳重整天然气得到的合成气进行甲醇合成的方法。 首先，通过使用催化剂（Ni / Ce / MgAlO x或Ni / Ce-Zr / Ni）与甲烷的二氧化碳重整与甲烷的二氧化碳重整同时进行天然气的蒸汽重整，从蒸汽二氧化碳重整获得合成气， MgAlOx）和能够保持一氧化碳，二氧化碳和氢的预定比例的加工条件[H 2 /（2CO + 3CO 2）= 0.85-1.15]接下来，通过使用所得到的合成和催化剂体系进行甲醇合成 适合于最小副产物形成的甲醇合成（包括以规定比例含有CuO，ZnO和Al 2 O 3的Cu-Zn-Al氧化物与通过溶胶 - 凝胶法得到的铈 - 锆氧化物组合的催化剂体系）。 此外，在甲醇合成操作之后残留的未反应的合成气被有效地再循环以提高整个过程中的碳利用率（甲烷和二氧化碳可用性）和能量效率。

公开(公告)号：US08729141B2

公开(公告)日：2014-05-20

申请号：US13132471

申请日：2009-09-14

申请人： Jong Wook Bae ,  Jong Hyeok Oh ,  Ki Won Jun ,  Yun Jo Lee ,  Jun-ho Ko ,  Seok-Lyong Song ,  Keh-Sik Min

发明人： Jong Wook Bae ,  Jong Hyeok Oh ,  Ki Won Jun ,  Yun Jo Lee ,  Jun-ho Ko ,  Seok-Lyong Song ,  Keh-Sik Min

IPC分类号： C07C27/00

CPC分类号： C07C29/154 ,  Y02P20/582 ,  C07C31/04

摘要： Disclosed is a method for methanol synthesis using synthesis gas obtained from reforming of natural gas with carbon dioxide. First, synthesis gas is obtained from steam carbon dioxide reforming of methane, in which steam reforming of natural gas is carried out simultaneously with carbon dioxide reforming of methane, by using a catalyst (Ni/Ce/MgAlOx, or Ni/Ce—Zr/MgAlOx) and processing condition capable of maintaining a predetermined ratio of carbon monoxide, carbon dioxide, and hydrogen [H2/(2CO+3CO2)=0.85-1.15]. Next, methanol synthesis is carried out by using the obtained synthesis gas and a catalyst system suitable for methanol synthesis with minimum byproduct formation (a catalyst system including a Cu—Zn—Al oxide containing CuO, ZnO, and Al2O3 at a predetermined ratio in combination with a cerium-zirconium oxide obtained by a sol-gel process). In addition, unreacted synthesis gas remaining after the operation of methanol synthesis is recycled efficiently to improve the carbon availability (methane and CO2 availability) and energy efficiency in the overall process.

摘要翻译： 公开了使用由二氧化碳重整天然气得到的合成气进行甲醇合成的方法。 首先，通过使用催化剂（Ni / Ce / MgAlO x或Ni / Ce-Zr / Ni）与甲烷的二氧化碳重整与甲烷的二氧化碳重整同时进行天然气的蒸汽重整，从蒸汽二氧化碳重整获得合成气， MgAlOx）和能够保持一氧化碳，二氧化碳和氢气的预定比例的加氢条件[H 2 /（2CO + 3CO 2）= 0.85-1.15]。 接下来，通过使用所得到的合成气和适合于具有最小副产物形成的甲醇合成的催化剂体系（包含含有CuO，ZnO和Al 2 O 3的Cu-Zn-Al氧化物以预定比例组合的催化剂体系进行甲醇合成） 与通过溶胶 - 凝胶法获得的铈 - 氧化锆）。 此外，在甲醇合成操作之后残留的未反应的合成气被有效地再循环以提高整个过程中的碳利用率（甲烷和二氧化碳可用性）和能量效率。

公开(公告)号：US20110178186A1

公开(公告)日：2011-07-21

申请号：US13121111

申请日：2009-08-28

申请人： Jong Hyeok Oh ,  Jong Wook Bae ,  Sun Ju Park ,  Yun Jo Lee ,  Ki Won Jun

发明人： Jong Hyeok Oh ,  Jong Wook Bae ,  Sun Ju Park ,  Yun Jo Lee ,  Ki Won Jun

IPC分类号： C07C27/00

CPC分类号： B01J23/75 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  C10G2/32 ,  C10G2/332 ,  C10G2/342 ,  C10G2300/4081

摘要： The present invention relates to a method for preparing liquid hydrocarbons via a slurry phase Fischer-Tropsch (F-T) synthesis. In particular, the present invention relates to a method for preparing liquid hydrocarbons from syngas via slurry phase F-T synthesis using a catalyst, which can prevent the decrease in catalyst activity and filter clogging due to catalyst aggrega-tion, simultaneously with improving selectivity for C5 or higher hydrocarbons by using C7-C12 alcohols having a high boiling point as an additive for a slurry reaction solvent or recycling the same alcohol separated from by-products that are generated during the F-T reaction. Since the method of the present invention is more carbon-effective and shows improved long-term stability of a re-actor, it can be effectively used in the preparation of liquid hydrocarbons.

摘要翻译： 本发明涉及一种通过浆料相费 - 托（F-T）合成制备液体烃的方法。 特别地，本发明涉及一种通过使用催化剂的浆料相FT合成从合成气制备液体烃的方法，其可以防止催化剂活性降低和由于催化剂聚集而过滤堵塞，同时提高对C5的选择性或 通过使用具有高沸点的C7-C12醇作为浆料反应溶剂的添加剂或循环与在FT反应期间产生的副产物分离的相同的醇，来获得高级烃。 由于本发明的方法更具碳有效性并且显示改善反应剂的长期稳定性，因此可有效地用于制备液体烃。

公开(公告)号：US20110114892A1

公开(公告)日：2011-05-19

申请号：US13055853

申请日：2009-07-30

申请人： Ki Won Jun ,  Seung-Chan Baek ,  Jong Wook Bae ,  Keh-Sik Min ,  Seok-Lyong Song ,  Tae-Young Oh

发明人： Ki Won Jun ,  Seung-Chan Baek ,  Jong Wook Bae ,  Keh-Sik Min ,  Seok-Lyong Song ,  Tae-Young Oh

IPC分类号： C01B3/38 ,  B01J21/02 ,  B01J37/08 ,  B01J37/02

CPC分类号： B01J23/83 ,  B01J21/10 ,  B01J23/002 ,  B01J23/22 ,  B01J23/31 ,  B01J35/002 ,  B01J35/006 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0207 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0283 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  C07C29/1518 ,  Y02P20/52 ,  C07C31/04

摘要： Disclosed are a catalyst for preparing synthesis gas from natural gas and carbon dioxide, and a method for preparing the same. More particularly, a combined reforming process is performed as an economical way of using carbon dioxide, wherein steam reforming of natural gas is carried out simultaneously with carbon dioxide reforming of methane in such a manner that a predetermined ratio of carbon monoxide/carbon dioxide/hydrogen (H2/(2CO+3CO2)=0.85-1.15) is maintained. In this manner, the catalyst is used to prepare synthesis gas suitable for methanol synthesis and Fischer-Tropsch synthesis. Disclosed also is a method for preparing synthesis gas on a specific catalyst consisting of Ni/Ce/MgAlOx or Ni/Ce—Zr/MgAlOx. The catalyst is inhibited from deactivation caused by generation of cokes during the reaction as well as deactivation caused by reoxidation of nickel with water added during the reaction. Therefore, the catalyst shows excellent activity as compared to other catalysts for use in combined reforming.

摘要翻译： 公开了从天然气和二氧化碳制备合成气的催化剂及其制备方法。 更具体地，作为使用二氧化碳的经济方法进行组合重整方法，其中天然气的蒸汽重整与甲烷的二氧化碳重整同时进行，使得一氧化碳/二氧化碳/氢气的预定比例 （H2 /（2CO + 3CO2）= 0.85-1.15）。 以这种方式，催化剂用于制备适用于甲醇合成和费 - 托合成的合成气。 还公开了在由Ni / Ce / MgAlO x或Ni / Ce-Zr / MgAlO x组成的特定催化剂上制备合成气的方法。 催化剂被抑制在反应期间由焦炭产生引起的失活以及由反应期间加入的水的镍再氧化引起的失活。 因此，与用于组合重整的其它催化剂相比，催化剂显示出优异的活性。

公开(公告)号：US08183301B2

公开(公告)日：2012-05-22

申请号：US13121111

申请日：2009-08-28

申请人： Jong Hyeok Oh ,  Jong Wook Bae ,  Sun Ju Park ,  Yun Jo Lee ,  Ki won Jun

发明人： Jong Hyeok Oh ,  Jong Wook Bae ,  Sun Ju Park ,  Yun Jo Lee ,  Ki won Jun

IPC分类号： C07C27/00

CPC分类号： B01J23/75 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  C10G2/32 ,  C10G2/332 ,  C10G2/342 ,  C10G2300/4081

摘要： The present invention relates to a method for preparing liquid hydrocarbons via a slurry phase Fischer-Tropsch (F-T) synthesis. In particular, the present invention relates to a method for preparing liquid hydrocarbons from syngas via slurry phase F-T synthesis using a catalyst, which can prevent the decrease in catalyst activity and filter clogging due to catalyst aggregation, simultaneously with improving selectivity for C5 or higher hydrocarbons by using C7-C12 alcohols having a high boiling point as an additive for a slurry reaction solvent or recycling the same alcohol separated from by-products that are generated during the F-T reaction. Since the method of the present invention is more carbon-effective and shows improved long-term stability of a reactor, it can be effectively used in the preparation of liquid hydrocarbons.

摘要翻译： 本发明涉及一种通过浆料相费 - 托（F-T）合成制备液体烃的方法。 特别地，本发明涉及一种通过使用催化剂的淤浆相FT合成从合成气制备液体烃的方法，其可以防止催化剂活性降低和由于催化剂聚集而过滤堵塞，同时提高对C5或更高级烃的选择性 通过使用具有高沸点的C7-C12醇作为淤浆反应溶剂的添加剂或循环与在FT反应期间产生的副产物分离的相同的醇。 由于本发明的方法更有效且反应器的长期稳定性提高，因此可有效地用于制备液体烃。

公开(公告)号：US20110118367A1

公开(公告)日：2011-05-19

申请号：US13055496

申请日：2009-07-24

申请人： Suk-Hwan Kang ,  Jong Wook Bae ,  Ki Won Jun ,  Keh-Sik Min ,  Seok-Lyong Song ,  Sam-Heon Jeong

发明人： Suk-Hwan Kang ,  Jong Wook Bae ,  Ki Won Jun ,  Keh-Sik Min ,  Seok-Lyong Song ,  Sam-Heon Jeong

IPC分类号： C07C27/06 ,  B01J21/06 ,  B01J37/06 ,  B01J37/08 ,  B01J37/03

CPC分类号： B01J23/80 ,  B01J23/002 ,  B01J23/83 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/031 ,  B01J37/036 ,  B01J2523/00 ,  C07C29/154 ,  Y02P20/52 ,  C07C31/04 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48

摘要： Disclosed are a catalyst for synthesis of methanol from synthesis gas and a method for preparing the same. The catalyst includes a Cu—Zn—Al oxide containing CuO, ZnO and Al2O3 in a predetermined ratio or Cu—Zn—Al—Zr oxide containing CuO, ZnO, Al2O3 and ZrO2 in a predetermined ratio, in combination with a cerium-zirconium oxide obtained by a sol-gel process. As compared to the existing Cu—Zn—Al catalysts for synthesizing methanol, the catalyst disclosed herein inhibits formation of byproducts and improves yield of methanol. Therefore, it is possible to improve methanol purification efficiency and carbon conversion efficiency.

摘要翻译： 公开了从合成气合成甲醇的催化剂及其制备方法。 该催化剂包括以规定比例含有CuO，ZnO和Al 2 O 3的Cu-Zn-Al氧化物，或者含有规定比例的CuO，ZnO，Al 2 O 3和ZrO 2的Cu-Zn-Al-Zr氧化物与铈锆氧化物 通过溶胶 - 凝胶法获得。 与用于合成甲醇的现有Cu-Zn-Al催化剂相比，本文公开的催化剂抑制副产物的形成并提高甲醇的产率。 因此，可以提高甲醇净化效率和碳转化效率。

公开(公告)号：US08623927B2

公开(公告)日：2014-01-07

申请号：US13055496

申请日：2009-07-24

申请人： Suk-Hwan Kang ,  Jong Wook Bae ,  Ki Won Jun ,  Keh-Sik Min ,  Seok-Lyong Song ,  Sam-Heon Jeong

发明人： Suk-Hwan Kang ,  Jong Wook Bae ,  Ki Won Jun ,  Keh-Sik Min ,  Seok-Lyong Song ,  Sam-Heon Jeong

IPC分类号： C07C27/00

CPC分类号： B01J23/80 ,  B01J23/002 ,  B01J23/83 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/031 ,  B01J37/036 ,  B01J2523/00 ,  C07C29/154 ,  Y02P20/52 ,  C07C31/04 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48

摘要： Disclosed are a catalyst for synthesis of methanol from synthesis gas and a method for preparing the same. The catalyst includes a Cu—Zn—Al oxide containing CuO, ZnO and Al2O3 in a predetermined ratio or Cu—Zn—Al—Zr oxide containing CuO, ZnO, Al2O3 and ZrO2 in a predetermined ratio, in combination with a cerium-zirconium oxide obtained by a sol-gel process. As compared to the existing Cu—Zn—Al catalysts for synthesizing methanol, the catalyst disclosed herein inhibits formation of byproducts and improves yield of methanol. Therefore, it is possible to improve methanol purification efficiency and carbon conversion efficiency.

摘要翻译： 公开了从合成气合成甲醇的催化剂及其制备方法。 该催化剂包括以规定比例含有CuO，ZnO和Al 2 O 3的Cu-Zn-Al氧化物，或者含有规定比例的CuO，ZnO，Al 2 O 3和ZrO 2的Cu-Zn-Al-Zr氧化物与铈锆氧化物 通过溶胶 - 凝胶法获得。 与用于合成甲醇的现有Cu-Zn-Al催化剂相比，本文公开的催化剂抑制副产物的形成并提高甲醇的产率。 因此，可以提高甲醇净化效率和碳转化效率。

公开(公告)号：US08524119B2

公开(公告)日：2013-09-03

申请号：US13055853

申请日：2009-07-30

申请人： Ki Won Jun ,  Seung-Chan Baek ,  Jong Wook Bae ,  Keh-Sik Min ,  Seok-Lyong Song ,  Tae-Young Oh

发明人： Ki Won Jun ,  Seung-Chan Baek ,  Jong Wook Bae ,  Keh-Sik Min ,  Seok-Lyong Song ,  Tae-Young Oh

IPC分类号： C01B3/26

CPC分类号： B01J23/83 ,  B01J21/10 ,  B01J23/002 ,  B01J23/22 ,  B01J23/31 ,  B01J35/002 ,  B01J35/006 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0207 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0283 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  C07C29/1518 ,  Y02P20/52 ,  C07C31/04

摘要： Disclosed are a catalyst for preparing synthesis gas from natural gas and carbon dioxide, and a method for preparing the same. More particularly, a combined reforming process is performed as an economical way of using carbon dioxide, wherein steam reforming of natural gas is carried out simultaneously with carbon dioxide reforming of methane in such a manner that a predetermined ratio of carbon monoxide/carbon dioxide/hydrogen (H2/(2CO+3CO2)=0.85-1.15) is maintained. In this manner, the catalyst is used to prepare synthesis gas suitable for methanol synthesis and Fischer-Tropsch synthesis. Disclosed also is a method for preparing synthesis gas on a specific catalyst consisting of Ni/Ce/MgAlOx or Ni/Ce-Zr/MgAlOx. The catalyst is inhibited from deactivation caused by generation of cokes during the reaction as well as deactivation caused by reoxidation of nickel with water added during the reaction. Therefore, the catalyst shows excellent activity as compared to other catalysts for use in combined reforming.

摘要翻译： 公开了从天然气和二氧化碳制备合成气的催化剂及其制备方法。 更具体地，作为使用二氧化碳的经济方法进行组合重整方法，其中天然气的蒸汽重整与甲烷的二氧化碳重整同时进行，使得一氧化碳/二氧化碳/氢气的预定比例 （H2 /（2CO + 3CO2）= 0.85-1.15）。 以这种方式，催化剂用于制备适用于甲醇合成和费 - 托合成的合成气。 还公开了在由Ni / Ce / MgAlO x或Ni / Ce-Zr / MgAlO x组成的特定催化剂上制备合成气的方法。 催化剂被抑制在反应期间由焦炭产生引起的失活以及由反应期间加入的水的镍再氧化引起的失活。 因此，与用于组合重整的其它催化剂相比，催化剂显示出优异的活性。