Abstract:
A fuel cell includes an anode including an anode catalyst, a cathode, a channel that is contiguous with the anode, and a liquid electrolyte in the channel. The cathode includes a gas diffusion electrode, a cathode catalyst on the gas diffusion electrode, and a hydrogel on the cathode catalyst. The hydrogel is between the anode and the cathode, and includes an aqueous liquid and a polymer. The polymer has an acid capacity less than 0.8 meq/g and/or has no sulfonic acid groups covalently bound to the polymer. A method of generating electricity includes flowing a liquid electrolyte through the channel, oxidizing a fuel at the anode, and reducing a gaseous oxidant at the cathode.
Abstract:
A fuel cell includes an anode, a cathode, a microfluidic channel contiguous with at least one of the anode and the cathode, and a single flowing electrolyte. The flowing electrolyte passes through the microfluidic channel. A method of generating electricity includes flowing the single electrolyte through the microfluidic channel, where a fuel is oxidized at the anode, an oxidant is reduced at the cathode, and the electrolyte comprises the fuel or the oxidant. The flowing electrolyte may pass through the microfluidic channel in a laminar flow.
Abstract:
Novel difucntionalized cyclobutabenzene monomers of the general formula: ##STR1## wherein Z can be hydrogens or a cyclobutane ring; and X and Y are carboxyl, amino, alcohol, isocyanate, acid halide, or bis-acyl fluoride groups. In a particularly preferred embodiment, the cyclobutabenzene derivative is 1,2-dihydrocyclobutabenzene-3,6-carboxylic acid. The difunctionalized cyclobutabenzene monomer can form part of a polymer backbone chain, but has an additional functionality, the butane ring, which can be easily opened to produce strong, covalent bond crosslinking between polymer chains. The crosslinking can be induced simply by heating the polymer to a temperature in excess of 300.degree. C.
Abstract:
Novel difunctionalized cyclobutabenzene monomers of the general formula: ##STR1## wherein Z can be hydrogens or a cyclobutane ting; and X and Y are carbox amino, alcohol, isocyanate, acid halide, or bis-acyl fluoride groups. In a particularly preferred embodiment, the cyclobutabenzene derivative is 1,2-dihydrocyclobutabenzene-3,6-carboxylic acid. The difunctionalized cyclobutabenzene monomer can form part of a polymer backbone chain, but has an additional functionality, the butane ring, which can be easily opened to produce strong, covalent bond crosslinking between polymer chains. The crosslinking can be induced simply by heating the polymer to a temperature in excess of 300.degree. C.
Abstract:
A generator system includes (i) an internal combustion engine, (ii) an exhaust gas outlet, connected to the internal combustion engine, for venting exhaust gasses, and (iii) a condenser, connected to the exhaust gas outlet, for condensing water from exhaust gasses.
Abstract:
A generator system includes (i) an internal combustion engine, (ii) an exhaust gas outlet, connected to the internal combustion engine, for venting exhaust gasses, and (iii) a condenser, connected to the exhaust gas outlet, for condensing water from exhaust gasses.
Abstract:
A fuel cell is described. The fuel cell includes current collectors, each of which includes a substrate of lightweight material, such as Kapton material. Micro channels are formed via laser machining or chemical etching into the substrate. The current collectors further include conductive layers sputtered on the substrate, and protective coating on the conductive layers. A variety of materials are available for the conductive layers. The fuel cell so developed is particularly well suited to mobile applications, such as electronic devices.
Abstract:
A fuel cell comprises an anode comprising an anode catalyst, a cathode comprising a gas diffusion electrode and a cathode catalyst on the gas diffusion electrode, a microfluidic channel contiguous with the anode, and a liquid comprising fuel in the channel. The concentration of the fuel in the liquid is 0.05-0.5 M.
Abstract:
A fuel cell includes a direct liquid fuel cell and a humidifier. The direct liquid fuel cell includes an air intake channel for providing oxidant to the fuel cell and an exhaust channel for exhausting depleted oxidant. The humidifier forms a fluid connection between the air intake channel and the exhaust channel.
Abstract:
An electrochemical cell is described that includes (a) a first electrode; (b) a second electrode; and (c) a channel contiguous with at least a portion of the first and the second electrodes. When a first liquid is contacted with the first electrode, a second liquid is contacted with the second electrode, and the first and the second liquids flow through the channel, a parallel laminar flow is established between the first and the second liquids. Electronic devices containing such electrochemical cells and methods for their use are also described.