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1.发明授权
公开(公告)号：US5384040A
公开(公告)日：1995-01-24
申请号：US7682
申请日：1993-01-22
申请人： Larry Mank , Yves Barthel , Charles Cameron , Patrick Sarrazin
发明人： Larry Mank , Yves Barthel , Charles Cameron , Patrick Sarrazin
摘要： A process for the elimination of mercury and possibly of arsenic from hydrocarbons wherein compounds containing mercury are transformed into elemental mercury, the charge is fractioned, and then the fractions rich in mercury are purified through contact with a mercury collecting mass.
摘要翻译： 一种消除汞的可能来自碳氢化合物的砷的方法，其中含有汞的化合物被转化为元素汞，电荷被分馏，然后通过与汞收集物质接触纯化富含汞的馏分。
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公开(公告)号：US5421994A
公开(公告)日：1995-06-06
申请号：US59396
申请日：1993-05-11
CPC分类号： C10G67/06
摘要： A process for the recovery of mercury and arsenic for which elementary mercury and/or mercury mercaptides are recovered prior to the recovery of arsenic and wherein the recovery temperature of the arsenic is higher than the recovery temperature of the mercury.
摘要翻译： 在回收砷之前回收汞和/或汞硫酸汞的汞和砷的回收方法，其中砷的回收温度高于汞的回收温度。
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3.发明授权
公开(公告)号：US5531886A
公开(公告)日：1996-07-02
申请号：US193591
申请日：1994-02-08
IPC分类号： B01J20/02 , B01J27/04 , C10G25/00 , C10G45/02 , C10G45/04 , C10G45/06 , C10G45/08 , C10G45/10
CPC分类号： C10G45/04 , C10G25/003
摘要： A process for the elimination of arsenic from hydrocarbons with a retention mass wherein the retention mass is pretreated before being brought into contact with the feedstock to be purified. The retention mass contains at least one element selected from the group formed by iron, nickel, cobalt, molybdenum, tungsten, palladium and chromium. At least 5% by weight of these element(s) are in the sulfide form. The pretreatment involves impregnation with a sulfur compound carried out simultaneously with reduction. The arsenic elimination process is carried out between 120.degree. C. and 250.degree. C. in the presence of 0-1000 mg of sulfur/kg of feedstock
摘要翻译： 用于从具有保留质量的烃中除去砷的方法，其中保留物质在与待纯化的原料接触之前进行预处理。 保留量包含至少一种选自铁，镍，钴，钼，钨，钯和铬形成的元素。 这些元素的至少5重量％是硫化物形式。 预处理包括用还原反应同时进行的硫化合物浸渍。 在0-1000mg硫/ kg原料存在下，砷消除过程在120℃和250℃之间进行
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公开(公告)号：US5648576A
公开(公告)日：1997-07-15
申请号：US466685
申请日：1995-06-06
IPC分类号： B01J23/44 , B01J23/48 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/00 , B01J35/02 , B01J35/08 , C07B61/00 , C07C5/09 , C07C7/167 , C07C11/04 , C07C11/06 , B01J21/04
CPC分类号： C07C5/09 , B01J23/44 , B01J23/48 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/0006 , C07C7/167 , B01J35/008 , C07C2521/04 , C07C2523/02 , C07C2523/04 , C07C2523/44 , C07C2523/50 , C07C2523/66 , Y02P20/52
摘要： A process for the selective hydrogenation in the gas phase of acetylene compounds containing 2 or 3 carbon atoms to the corresponding ethylene compounds in the presence of a catalyst in the form of spherules or extradates containing an alumina support, 0.01-0.5% by weight palladium, 0.001 to 0.5% by weight of at least one group IB metal, preferably silver, and optionally at least one alkaline or alkaline-earth metal, the weight ratio of the group IB metal to palladium being 0.05:1 to 0.25:1, in which catalyst at least 80% of the palladium and at least 80% of the group IB element are present in a volume at a periphery of the catalyst defined between a spherical or cylindrical surface of radius r.sub.1 corresponding to the average spherule or extradate diameter and a spherical or cylindrical surface of radius r.sub.2 at least equal to 0.8r.sub.1.
摘要翻译： 含有2或3个碳原子的乙炔化合物的气相中的选择性氢化到相应的乙烯化合物在催化剂存在下的催化剂的方法，所述催化剂是包含0.01-0.5重量％钯的氧化铝载体， 0.001至0.5重量％的至少一种IB族金属，优选银，以及任选的至少一种碱金属或碱土金属，IB族金属与钯的重量比为0.05:1至0.25:1，其中 催化剂至少80％的钯和至少80％的IB族元素以体积计存在催化剂的外围，该体积定义在对应于平均球粒或引导体直径的半径r1的球形或圆柱形表面之间， 或半径r2的圆柱形表面至少等于0.8r1。
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5.发明授权Process for the isomerization of external olefins to internal olefins concomitantly with diolefin hydrogenation 失效将外部烯烃异构化为内烯烃同时进行二烯烃氢化的方法
公开(公告)号：US5502269A
公开(公告)日：1996-03-26
申请号：US282474
申请日：1994-07-29
摘要： The present invention concerns a process for the isomerization of external olefins to internal olefins, the feedstock also containing diolefins, using a palladium based catalyst which contains 0.05% to 10% by weight of sulphur, said catalyst being treated before loading into the reactor with at least one organic sulphur-containing compound dissolved in a solvent, then activated in a neutral or reducing atmosphere at a temperature of between 20.degree. C. and 300.degree. C., before being brought into contact with the feedstock.
摘要翻译： 本发明涉及使用含有0.05重量％至10重量％硫的钯基催化剂将外部烯烃异构化成内部烯烃的方法，所述原料还含有二烯烃，所述催化剂在装载到反应器中之前被处理 将至少一种有机含硫化合物溶解在溶剂中，然后在中性或还原性气氛中在20℃至300℃的温度下活化，然后与原料接触。
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6.发明授权Process for selective hydrogenation, in particular of diolefins in steam cracking volatiles, with a catalyst in the form of beds which are used successively 失效用于选择性氢化的方法，特别是蒸汽裂解挥发物中的二烯烃与催化剂以床形式连续使用的方法
公开(公告)号：US5306852A
公开(公告)日：1994-04-26
申请号：US10386
申请日：1993-01-28
摘要： The invention concerns a hydrogenation process, in particular for the selective hydrogenation of diolefins in volatiles produced by steam cracking or other cracking processes, in which the catalyst is distributed in a plurality of beds. It is characterized in that the different catalyst beds are not used at the same time, but successively and in accordance with a given order.
摘要翻译： 本发明涉及氢化方法，特别是用于通过蒸汽裂化或其它裂化方法制备的挥发物中二烯烃的选择性氢化，其中催化剂分布在多个床中。 其特征在于不同的催化剂床不是同时使用，而是依次按照给定的顺序使用。
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公开(公告)号：US6054409A
公开(公告)日：2000-04-25
申请号：US770426
申请日：1996-12-20
CPC分类号： B01J23/44 , B01J23/50 , B01J23/58 , C07C5/09 , B01J35/008 , C07C2521/04 , C07C2523/02 , C07C2523/04 , C07C2523/44 , C07C2523/50
摘要： A catalyst is described for selective gas phase hydrogenation of acetylenic compounds containing 2 or 3 carbon atoms to the corresponding ethylenic compounds. The catalyst, in the form of spherules or extrudates, comprises palladium, at least one metal from group IB, optionally at least one alkali or alkaline-earth metal, and alumina, in which at least 80% of the palladium and at least 80% of the element from group IB are present in a volume at the periphery of the catalyst defined between a spherical or cylindrical surface with radius r.sub.1 corresponding to the average radius of the spherules or extrudates of the catalyst and a spherical or cylindrical surface with radius r.sub.2 at least equal to 0.8 r.sub.1, the catalyst having a group IB metal/palladium ratio of 0.4 to 3 by weight. Further, it is advantageous for this catalyst that at least 30% of the metal particles contain both palladium and silver.
摘要翻译： 描述了一种催化剂，用于将含有2或3个碳原子的炔属化合物选择性气相氢化成相应的烯属化合物。 小球或挤出物形式的催化剂包含钯，至少一种来自IB组分的金属，任选至少一种碱金属或碱土金属和氧化铝，其中至少80％的钯和至少80％ 来自IB组分的元素存在于催化剂周边的体积中，该体积在球形或圆柱形表面之间，其半径r1对应于催化剂的球体或挤出物的平均半径，并且具有半径r 2的球形或圆柱形表面 至少等于0.8r1，IB族金属/钯比例为0.4-3的催化剂。 此外，该催化剂有利的是，至少30％的金属颗粒含有钯和银。
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8.发明授权Olefin isomerisation process using metallic catalysts impregnated with organic sulphur-containing compounds before loading into the reactor 失效在装入反应器之前，使用浸渍有机含硫化合物的金属催化剂进行烯烃异构化处理
公开(公告)号：US5569806A
公开(公告)日：1996-10-29
申请号：US282470
申请日：1994-07-29
IPC分类号： C07B61/00 , B01J37/20 , C07C5/13 , C07C5/22 , C07C5/25 , C07C5/27 , C07C9/15 , C07C11/02 , C07C11/107 , C10G45/60 , C10G45/62 , C07C5/23
摘要： The invention concerns a process for the isomerisation of less substituted olefins to more substituted external olefins and/or internal olefins in the absence of diolefins, in the presence of a palladium based catalyst deposited on a support. Before loading it into the reactor, said catalyst is treated with at least one sulphur-containing compound which is dissolved in a solvent then activated in a neutral or reducing atmosphere between 20.degree. C. and 300.degree. C., 1 and 50 bars and with a VVH of 50 to 600 h.sup.-1. The catalyst, containing 0.05% to 10% by weight of sulphur, is brought into contact with the feedstock and hydrogen between 20.degree. C. and 200.degree. C., 1 and 50 bars, a VVH of 0.5 to 10 h.sup.-1 and a H.sub.2 /olefin molar ratio of 0.01 to 1.
摘要翻译： 本发明涉及在沉积在载体上的钯基催化剂存在下，在不存在二烯烃的情况下将较少取代的烯烃异构化为更多取代的外部烯烃和/或内部烯烃的方法。 在将其装入反应器之前，所述催化剂用至少一种含硫化合物处理，该化合物溶解在溶剂中，然后在中性或还原性气氛中在20℃至300℃，1和50巴之间并在 50至600 h-1的VVH。 将含有0.05重量％至10重量％硫的催化剂与原料接触，在20℃至200℃，1和50巴之间的氢气，0.5至10小时-1的VVH和 H2 /烯烃摩尔比为0.01〜1。
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公开(公告)号：US5889187A
公开(公告)日：1999-03-30
申请号：US808649
申请日：1997-02-28
IPC分类号： B01J23/44 , B01J23/48 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/00 , B01J35/02 , B01J35/08 , C07B61/00 , C07C5/09 , C07C7/167 , C07C11/04 , C07C11/06 , B01J21/04
CPC分类号： C07C5/09 , B01J23/44 , B01J23/48 , B01J23/50 , B01J23/58 , B01J23/66 , B01J35/0006 , C07C7/167 , B01J35/008 , C07C2521/04 , C07C2523/02 , C07C2523/04 , C07C2523/44 , C07C2523/50 , C07C2523/66 , Y02P20/52
摘要： A process for the selective hydrogenation in the gas phase of acetylene compounds containing 2 or 3 carbon atoms to the corresponding ethylene compounds is described. The process uses a catalyst in the form of spherules or extrudates containing palladium, at least one group IB metal, optionally at least one alkaline or alkaline-earth metal and alumina, in which at least 80% of the palladium and at least 80% of the group IB element are present in a volume at the periphery of the catalyst defined between a spherical or cylindrical surface of radius r.sub.1 corresponding to the average spherule or extrudate diameter and a spherical or cylindrical surface of radius r.sub.2 at least equal to 0.8r.sub.1. More particularly, the catalyst comprises an alumina, palladium in a proportion of 0.01% to 0.5% by weight, and group IB metal in a proportion of 0.001 to 0.02% by weight, with a weight ratio of group IB metal/palladium of 0.05 to 0.25.
摘要翻译： 对相应的乙烯化合物的含有2或3个碳原子的乙炔化合物气相的选择氢化的方法进行了描述。 该方法使用包含钯，至少一种IB族金属，任选至少一种碱金属或碱土金属和氧化铝的球形或挤出物形式的催化剂，其中至少80％的钯和至少80％的钯 IB族元素存在于催化剂外围的体积中，所述体积定义在对应于平均球粒或挤出物直径的半径r1的球形或圆柱形表面之间，并且半径r2的球形或圆柱形表面至少等于0.8r1。 更具体地，催化剂包含氧化铝，0.01重量％至0.5重量％的比例的钯，和比例为0.001至0.02重量％的IB族金属，IB金属/钯的重量比为0.05至 0.25。
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10.发明授权
公开(公告)号：US5601701A
公开(公告)日：1997-02-11
申请号：US193590
申请日：1994-02-08
IPC分类号： B01J20/02 , B01J23/24 , B01J23/44 , B01J23/74 , B01J27/04 , B01J37/20 , C10G45/04 , C10G45/10 , C10G67/06
摘要： The invention concerns a process for the elimination of mercury from hydrocarbons by passage of the feedstock with hydrogen over a catalyst then bringing the product obtained into contact with a mercury retention bed, the catalyst comprising at least one element selected from the group constituted by iron, nickel, cobalt, molybdenum, tungsten, palladium, wherein at least 5% is in the sulphide state. Any arsenic present in the feedstock is also eliminated.In accordance with the invention, the catalyst is simultaneously presulphurated and reduced.The invention results in a considerable reduction in operation period and high retention efficiency at temperatures between 120.degree. C. and 250.degree. C. and in the presence of 0-1000 mg of sulphur/kg of feed.
摘要翻译： 本发明涉及一种通过使原料通过原料与氢气在催化剂上消除汞的方法，然后将所得产物与汞保留床接触，所述催化剂包含至少一种选自铁， 镍，钴，钼，钨，钯，其中至少5％处于硫化物状态。 原料中存在的任何砷也被消除。 根据本发明，催化剂同时被预硫化并还原。 本发明导致在120℃至250℃的温度和0-1000mg硫/ kg进料存在下的操作周期和高保留效率的显着降低。
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