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公开(公告)号：US5421994A
公开(公告)日：1995-06-06
申请号：US59396
申请日：1993-05-11
CPC分类号： C10G67/06
摘要： A process for the recovery of mercury and arsenic for which elementary mercury and/or mercury mercaptides are recovered prior to the recovery of arsenic and wherein the recovery temperature of the arsenic is higher than the recovery temperature of the mercury.
摘要翻译： 在回收砷之前回收汞和/或汞硫酸汞的汞和砷的回收方法，其中砷的回收温度高于汞的回收温度。
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2.发明授权
公开(公告)号：US5601701A
公开(公告)日：1997-02-11
申请号：US193590
申请日：1994-02-08
IPC分类号： B01J20/02 , B01J23/24 , B01J23/44 , B01J23/74 , B01J27/04 , B01J37/20 , C10G45/04 , C10G45/10 , C10G67/06
摘要： The invention concerns a process for the elimination of mercury from hydrocarbons by passage of the feedstock with hydrogen over a catalyst then bringing the product obtained into contact with a mercury retention bed, the catalyst comprising at least one element selected from the group constituted by iron, nickel, cobalt, molybdenum, tungsten, palladium, wherein at least 5% is in the sulphide state. Any arsenic present in the feedstock is also eliminated.In accordance with the invention, the catalyst is simultaneously presulphurated and reduced.The invention results in a considerable reduction in operation period and high retention efficiency at temperatures between 120.degree. C. and 250.degree. C. and in the presence of 0-1000 mg of sulphur/kg of feed.
摘要翻译： 本发明涉及一种通过使原料通过原料与氢气在催化剂上消除汞的方法，然后将所得产物与汞保留床接触，所述催化剂包含至少一种选自铁， 镍，钴，钼，钨，钯，其中至少5％处于硫化物状态。 原料中存在的任何砷也被消除。 根据本发明，催化剂同时被预硫化并还原。 本发明导致在120℃至250℃的温度和0-1000mg硫/ kg进料存在下的操作周期和高保留效率的显着降低。
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3.发明授权Process for the isomerization of external olefins to internal olefins concomitantly with diolefin hydrogenation 失效将外部烯烃异构化为内烯烃同时进行二烯烃氢化的方法
公开(公告)号：US5502269A
公开(公告)日：1996-03-26
申请号：US282474
申请日：1994-07-29
摘要： The present invention concerns a process for the isomerization of external olefins to internal olefins, the feedstock also containing diolefins, using a palladium based catalyst which contains 0.05% to 10% by weight of sulphur, said catalyst being treated before loading into the reactor with at least one organic sulphur-containing compound dissolved in a solvent, then activated in a neutral or reducing atmosphere at a temperature of between 20.degree. C. and 300.degree. C., before being brought into contact with the feedstock.
摘要翻译： 本发明涉及使用含有0.05重量％至10重量％硫的钯基催化剂将外部烯烃异构化成内部烯烃的方法，所述原料还含有二烯烃，所述催化剂在装载到反应器中之前被处理 将至少一种有机含硫化合物溶解在溶剂中，然后在中性或还原性气氛中在20℃至300℃的温度下活化，然后与原料接触。
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4.发明授权Process for selective hydrogenation, in particular of diolefins in steam cracking volatiles, with a catalyst in the form of beds which are used successively 失效用于选择性氢化的方法，特别是蒸汽裂解挥发物中的二烯烃与催化剂以床形式连续使用的方法
公开(公告)号：US5306852A
公开(公告)日：1994-04-26
申请号：US10386
申请日：1993-01-28
摘要： The invention concerns a hydrogenation process, in particular for the selective hydrogenation of diolefins in volatiles produced by steam cracking or other cracking processes, in which the catalyst is distributed in a plurality of beds. It is characterized in that the different catalyst beds are not used at the same time, but successively and in accordance with a given order.
摘要翻译： 本发明涉及氢化方法，特别是用于通过蒸汽裂化或其它裂化方法制备的挥发物中二烯烃的选择性氢化，其中催化剂分布在多个床中。 其特征在于不同的催化剂床不是同时使用，而是依次按照给定的顺序使用。
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5.发明授权
公开(公告)号：US5531886A
公开(公告)日：1996-07-02
申请号：US193591
申请日：1994-02-08
IPC分类号： B01J20/02 , B01J27/04 , C10G25/00 , C10G45/02 , C10G45/04 , C10G45/06 , C10G45/08 , C10G45/10
CPC分类号： C10G45/04 , C10G25/003
摘要： A process for the elimination of arsenic from hydrocarbons with a retention mass wherein the retention mass is pretreated before being brought into contact with the feedstock to be purified. The retention mass contains at least one element selected from the group formed by iron, nickel, cobalt, molybdenum, tungsten, palladium and chromium. At least 5% by weight of these element(s) are in the sulfide form. The pretreatment involves impregnation with a sulfur compound carried out simultaneously with reduction. The arsenic elimination process is carried out between 120.degree. C. and 250.degree. C. in the presence of 0-1000 mg of sulfur/kg of feedstock
摘要翻译： 用于从具有保留质量的烃中除去砷的方法，其中保留物质在与待纯化的原料接触之前进行预处理。 保留量包含至少一种选自铁，镍，钴，钼，钨，钯和铬形成的元素。 这些元素的至少5重量％是硫化物形式。 预处理包括用还原反应同时进行的硫化合物浸渍。 在0-1000mg硫/ kg原料存在下，砷消除过程在120℃和250℃之间进行
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6.发明授权
公开(公告)号：US5384040A
公开(公告)日：1995-01-24
申请号：US7682
申请日：1993-01-22
申请人： Larry Mank , Yves Barthel , Charles Cameron , Patrick Sarrazin
发明人： Larry Mank , Yves Barthel , Charles Cameron , Patrick Sarrazin
摘要： A process for the elimination of mercury and possibly of arsenic from hydrocarbons wherein compounds containing mercury are transformed into elemental mercury, the charge is fractioned, and then the fractions rich in mercury are purified through contact with a mercury collecting mass.
摘要翻译： 一种消除汞的可能来自碳氢化合物的砷的方法，其中含有汞的化合物被转化为元素汞，电荷被分馏，然后通过与汞收集物质接触纯化富含汞的馏分。
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7.发明授权Catalyst containing a group VIII metal and a group IIIA metal deposited on a support 失效含有VIII族金属和沉积在载体上的IIIA族金属的催化剂
公开(公告)号：US5356851A
公开(公告)日：1994-10-18
申请号：US042191
申请日：1993-04-02
IPC分类号： B01J23/40 , B01J23/62 , B01J23/74 , B01J23/825 , B01J23/835 , B01J37/00 , B01J37/02 , C07B61/00 , C07C5/05 , C07C5/09 , C07C7/163 , C07C11/00 , C07C11/06 , C07C11/08 , C10G45/40 , B01J21/00 , B01J23/82
CPC分类号： C10G45/40 , B01J23/40 , B01J23/62 , B01J23/74 , B01J23/825 , B01J37/0205 , C07C7/163
摘要： The invention relates to a novel catalyst for the selective hydrogenation of unsaturated hydrocarbons. It is characterized in that the catalyst contains a group VIII metal deposited on a support previously modified by an element chosen from within group IIIA constituted by gallium and indium.
摘要翻译： 本发明涉及用于不饱和烃选择性氢化的新型催化剂。 其特征在于催化剂含有沉积在预先由选自由镓和铟构成的IIIA族内的元素修饰的载体上的第Ⅷ族金属。
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公开(公告)号：US5364998A
公开(公告)日：1994-11-15
申请号：US42178
申请日：1993-04-02
IPC分类号： B01J23/40 , B01J23/62 , B01J23/755 , B01J23/825 , B01J23/835 , C07B61/00 , C07C5/05 , C07C5/09 , C07C7/163 , C07C11/00 , C07C11/06 , C07C11/08 , C10G45/40
CPC分类号： C10G45/40 , B01J23/40 , B01J23/62 , B01J23/755 , B01J23/825 , C07C7/163
摘要： A process for the selective hydrogenation of unsaturated hydrocarbons is characterized in that the catalyst contains a group VIII metal and an element chosen from within the group constituted by gallium and indium.
摘要翻译： 用于不饱和烃的选择性氢化的方法的特征在于催化剂含有VIII族金属和选自由镓和铟构成的组中的元素。
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9.发明授权Catalytic reduction of substituted or unsubstituted nitroaromatic compound to corresponding aminoaromatic compounds 失效取代或未经取代的硝基化合物的催化还原相应的氨基化合物
公开(公告)号：US5235106A
公开(公告)日：1993-08-10
申请号：US817559
申请日：1992-01-07
申请人： Blaise Didillon , Fabienne Le Peltier , Jean-Pierre Candy , Patrick Sarrazin , Jean-Paul Boitiaux , Jean-Marie Basset
发明人： Blaise Didillon , Fabienne Le Peltier , Jean-Pierre Candy , Patrick Sarrazin , Jean-Paul Boitiaux , Jean-Marie Basset
IPC分类号： B01J23/62 , C07B61/00 , C07C209/36 , C07C209/38 , C07C211/52 , C07C211/56 , C07C213/02 , C07C215/76 , C07C217/82 , C07C219/34
CPC分类号： B01J23/622 , C07C209/36 , C07C209/365
摘要： The invention concerns the production of a substituted or unsubstituted aniline by selective hydrogenation of the corresponding nitroaromatic compound. It is characterized by the use of a catalyst based on a metal selected from rhodium and ruthenium and based on a metal selected from the group comprising tin, germanium and lead.
摘要翻译： 本发明涉及通过相应的硝基芳族化合物的选择性氢化生产取代或未取代的苯胺。 其特征在于使用基于选自铑和钌的金属和基于选自锡，锗和铅的金属的催化剂。
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公开(公告)号：US06315892B1
公开(公告)日：2001-11-13
申请号：US09688167
申请日：2000-10-16
IPC分类号： C10G35085
CPC分类号： B01J23/622 , B01J23/62 , B01J37/0205 , C10G35/09 , Y10S502/506 , Y10S502/513 , Y10S502/514
摘要： A process of hydroreforming in the presence of a catalyst containing at least one refractory inorganic carrier, platinum, possibly at least one metal from Group VIII (palladium, nickel, and ruthenium), a halogen or compound thereof, and at least one additional metal M selected from among germanium, tin, lead, gallium, indium, and thallium, process in which said metal M, in the form of at least one organic compound, is introduced in situ into the reactor where the hydrocarbon charge will then be treated or into a prereactor that is connected to said reactor.
摘要翻译： 在含有至少一种难熔性无机载体的铂的催化剂存在下进行加氢反应的方法，铂，可能的至少一种来自第VIII族（钯，镍和钌）的金属，卤素或其化合物，以及至少一种另外的金属M 选自锗，锡，铅，镓，铟和铊的方法，其中将至少一种有机化合物形式的所述金属M原位引入反应器中，其中烃装料将被处理或进入 连接到所述反应器的预反应器。
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