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    Supported palladium-gold catalyst, and its manufacture
    6.
    发明授权
    Supported palladium-gold catalyst, and its manufacture 失效
    负载钯 - 金催化剂及其制造

    公开(公告)号：US4490481A

    公开(公告)日：1984-12-25

    申请号：US475651

    申请日：1983-03-15

    申请人： Jean-Paul Boitiaux ,  Jean Cosyns

    发明人： Jean-Paul Boitiaux ,  Jean Cosyns

    IPC分类号： C07C5/05 ,  B01J23/44 ,  B01J23/52 ,  C07B61/00 ,  C07C1/00 ,  C07C5/09 ,  C07C7/167 ,  C07C11/02 ,  C07C67/00 ,  C10G45/50 ,  B01J23/58 ,  B01J27/06 ,  B01J27/24 ,  B01J31/02

    CPC分类号： C10G45/50 ,  B01J23/52 ,  B01J23/44

    摘要： Supported palladium-gold catalyst of high resistance to poisoning by sulfur compounds, not subject to elution by vinylacetylene and not inducing a substantial formation of oligomers, for use in hydrogenation reactions wherein acetylenics and diolefins are selectively hydrogenated, said catalyst being obtained by the steps of: admixing a palladium compound with an inorganic carrier, roasting in the presence of an oxygen-containing gas, treating with a reducing agent, admixing a halogenated gold compound with the resulting composition, treating with a reducing agent, treating with a compound having a basic reaction so as to lower the halogen content of the catalyst below 10 ppm by weight, and roasting, in the presence of an oxygen-containing gas, the palladium and gold compounds being used in convenient proportions so that the catalyst contains 0.03 to 1% palladium and 0.003 to 0.3% gold by weight.

    摘要翻译： 所述催化剂是通过以下步骤获得的，所述钯 - 金催化剂具有高耐硫化合物中毒的乙烯基乙炔中和，不会被乙烯基乙炔洗脱并且不引起大量的低聚物形成，用于氢化反应，其中乙炔基化合物和二烯烃被选择性氢化， ：将钯化合物与无机载体混合，在含氧气体存在下焙烧，用还原剂处理，将卤化金化合物与所得组合物混合，用还原剂处理，用具有碱性的化合物 反应，以使催化剂的卤素含量降低至10重量ppm以下，并且在含氧气体存在下，以适当比例使用钯和金化合物焙烧，使得催化剂含有0.03至1％的钯 和0.003至0.3重量％的金。

    Selectively hydrogenating acetylenic compounds in a high butadiene content C.sub.4 cut
    8.
    发明授权
    Selectively hydrogenating acetylenic compounds in a high butadiene content C.sub.4 cut 失效
    选择性氢化高丁二烯含量C4馏分中的炔属化合物

    公开(公告)号：US4587369A

    公开(公告)日：1986-05-06

    申请号：US664654

    申请日：1984-10-25

    申请人： Jean Cosyns ,  Jean-Paul Boitiaux

    发明人： Jean Cosyns ,  Jean-Paul Boitiaux

    IPC分类号： C07C7/167 ,  B01J23/44 ,  C07C1/00 ,  C07C5/08 ,  C07C11/16 ,  C07C11/167 ,  C07C67/00

    CPC分类号： C07C5/08 ,  C07C2523/44

    摘要： A C.sub.4 cut of high butadiene content is selectively hydrogenated in contact with a supported palladium catalyst, the operation being performed in admixture with a hydrocarbon and an amine.The C.sub.4 cut of high butadiene content (1) and liquid hydrocarbon containing the amine (6) pass through reactor (2). The resultant product is fractionated (13). The C.sub.4 cut is recovered in the vapor phase (15) and the liquid phase recycled (16).

    摘要翻译： 选择性氢化与负载的钯催化剂接触的高丁二烯含量的C4馏分，该操作是与烃和胺混合进行的。 高丁二烯含量（1）的C4馏分和含有胺（6）的液态烃通过反应器（2）。 将所得产物分馏（13）。 在气相（15）和液相循环（16）中回收C4馏分。

    Process for selective catalytic hydrogenation in liquid phase of a normally gaseous feed containing ethylene, acetylene and gasoline
    10.
    发明授权
    Process for selective catalytic hydrogenation in liquid phase of a normally gaseous feed containing ethylene, acetylene and gasoline 失效
    乙烯，乙烯和汽油的正常进料液相中选择性催化氢化方法

    公开(公告)号：US5059732A

    公开(公告)日：1991-10-22

    申请号：US689095

    申请日：1991-04-22

    申请人： Jean Cosyns ,  Jean-Paul Boitiaux

    发明人： Jean Cosyns ,  Jean-Paul Boitiaux

    IPC分类号： C10G45/32 ,  C07C7/167 ,  C07C9/04 ,  C07C11/04 ,  C10G45/34 ,  C10G45/40

    CPC分类号： C10G45/34

    摘要： Disclosed is a process for selective hydrogenation in liquid phase of an effluent originating from an ethane steam cracker in which said effluent is contacted with a catalyst consisting of at least supported palladium characterized in that it is carried out in the presence of a liquid phase containing at least part of the hydrogenated gasoline cut, condensed and recycled, of said effluent.Said effluent (1), said liquid phase (8) and possibly hydrogen (13) pass through the hydrogenation reactor (4). The product obtained is fractionated (5) into a gaseous cut at the top (7) containing ethylene and a liquid gasoline cut at the bottom which is partially recycled (8).The process may be used for production of ethylene and for production of gasoline.

    摘要翻译： 公开了一种在液相中选择性氢化源自乙烷蒸汽裂化器的流出物的方法，其中所述流出物与至少负载的钯组成的催化剂接触，其特征在于其在含有 所述流出物的氢化汽油的最少部分被切割，冷凝和再循环。 所述流出物（1），所述液相（8）和可能的氢气（13）通过氢化反应器（4）。 将得到的产物（5）分馏成含有乙烯的顶部（7）上的气态切口，在底部切割的液体汽油被部分循环（8）。 该方法可用于生产乙烯和生产汽油。