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1.发明授权Cellulose microfibrils with modified surface, preparation method and use thereof 失效具有改性表面的纤维素微原纤维，其制备方法和用途公开(公告)号：US06703497B1
公开(公告)日：2004-03-09
申请号：US09787272
申请日：2001-06-25
申请人： Laurence Ladouce , Etienne Fleury , Cécile Gousse , Robert Cantiani , Henri Chanzy , Gérard Excoffier
发明人： Laurence Ladouce , Etienne Fleury , Cécile Gousse , Robert Cantiani , Henri Chanzy , Gérard Excoffier
IPC分类号： C08B1100
摘要： The invention concerns cellulose microfibrils with modified surface, characterised in that the hydroxyl functions present at the surface of the microfibrils are etherified with at least an organic compound comprising at least a function capable of reacting with said hydroxyl functions, and the degree of surface substitution (DSs) is at least 0.05. The invention also concerns a method for obtaining said microfibrils and their use as agent for modifying viscosity, texture and/or as reinforcing filler.
摘要翻译： 本发明涉及具有改性表面的纤维素微原纤维，其特征在于，存在于微原纤维表面的羟基官能团与至少一种至少包含能够与所述羟基官能团反应的功能的有机化合物和表面取代度 DS）至少为0.05。 本发明还涉及获得所述微原纤维的方法及其用作改性粘度，质地和/或作为增强填料的试剂的用途。
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公开(公告)号：US5969068A
公开(公告)日：1999-10-19
申请号：US492276
申请日：1995-06-19
IPC分类号： C10M159/12 , C08F20/10 , C08F220/12 , C08F220/18 , C08F265/00 , C08F265/06 , C10M149/04 , C10M149/06 , C10M149/08 , C10M149/10 , C10N30/02 , C10N30/04 , C08F126/06
CPC分类号： C10M149/10 , C08F220/12 , C10M149/04 , C10M149/06 , C10M149/08 , C10M2209/084 , C10M2215/04 , C10M2215/26 , C10M2217/022 , C10M2217/023 , C10M2217/024 , C10M2217/028 , C10M2217/046 , C10M2217/06 , C10M2219/02 , C10M2219/046 , C10M2223/045 , C10N2210/02 , C10N2270/02
摘要： A polyacrylate ester, and more particularly a polymethacrylate ester based dispersant-viscosity improver for lubricating oil compositions. Specifically, the dispersant viscosity improvers of this invention are nitrogen-containing copolymers comprising units derived from(A) from about 5% to about 75% by weight of alkyl acrylate ester monomers containing from 1 to 11 carbon atoms in the alkyl group;(B) from about 25% to about 95% by weight of alkyl acrylate ester monomers containing from 12 to about 24 carbon atoms in the alkyl group; and(C) From about 0.1% to about 20% by weight of at least one nitrogen containing monomer selected from the group consisting of vinyl substituted nitrogen heterocyclic monomers, N,N-dialkylaminoalkyl acrylate monomers, N,N-dialkylaminoalkyl acrylamide monomers and tertiary-alkyl acrylamides, provided that the total equals 100%. Processes for preparing the compositions, additive concentrates and lubricating oil compositions are described.
摘要翻译： 聚丙烯酸酯，特别是用于润滑油组合物的聚甲基丙烯酸酯类分散剂 - 粘度改进剂。 具体地说，本发明的分散剂粘度改进剂是包含衍生自（A）约5％至约75％重量的在烷基中含有1至11个碳原子的丙烯酸烷基酯单体的单元的含氮共聚物; （B）约25％至约95％重量的在烷基中含有12至约24个碳原子的丙烯酸烷基酯单体; 和（C）约0.1％至约20％重量的至少一种选自乙烯基取代的氮杂环基单体，N，N-二烷基氨基烷基丙烯酸酯单体，N，N-二烷基氨基烷基丙烯酰胺单体和三级 烷基丙烯酰胺，条件是总量等于100％。 描述了制备组合物，添加剂浓缩物和润滑油组合物的方法。
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公开(公告)号：US07078198B1
公开(公告)日：2006-07-18
申请号：US09958673
申请日：2000-04-10
摘要： The present invention relates to a heteropolysaccharide (HP) characterized in that it can be obtained by fermentation of a medium comprising at least one strain of Pseudomonas sp I-2054 (or DSM 12295), one of the recombinants thereof or the mutants thereof and a source of carbon which can be assimilated by said strain, one of the recombinants thereof or one of the mutants thereof. The invention also relates to a method for the production and use of said heteropolysaccharide as a thickening agent and/or gelling agent.
摘要翻译： 杂多糖（HP）本发明涉及杂多糖（HP），其特征在于其可以通过发酵包含至少一种假单胞菌属I-2054（或DSM 12295）菌株，其重组体或其突变体和 可以由所述菌株吸收的碳源，其重组体之一或其突变体之一。 本发明还涉及用于生产和使用所述杂多糖作为增稠剂和/或胶凝剂的方法。
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4.发明授权Buccodental formulation comprising essentially amorphous cellulose nanofibrils 有权Buccodental制剂包含基本上无定形纤维素纳米原纤维公开(公告)号：US06312669B1
公开(公告)日：2001-11-06
申请号：US09508228
申请日：2000-05-16
申请人： Robert Cantiani , Claudie Willemin
发明人： Robert Cantiani , Claudie Willemin
IPC分类号： A61K716
CPC分类号： A61K8/027 , A61K8/731 , A61K2800/5424 , A61Q11/00
摘要： The invention concerns buccodental formulation characterized in that it comprises at least a thickening agent comprising cellulose nanofibrils, said cellulose nanofibrils being substantially amorphous, having a crystallinity index not more than 50%. The invention also concerns said cellulose nanofibrils as thickening agent and/or flavour enhancer in buccodental formulations.
摘要翻译： 本发明涉及蜂王浆制剂，其特征在于它包含至少一种包含纤维素纳米原纤维的增稠剂，所述纤维素纳米纤维基本上是无定形的，其结晶度指数不超过50％。 本发明还涉及所述纤维素纳米原纤维作为增稠剂和/或香料增强剂。
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5.发明授权Supplementation of essentially amorphous cellulose nanofibrils with carboxycellulose which has a high degree of substitution 有权用具有高取代度的羧甲基纤维素补充基本无定形纤维素纳米原纤维公开(公告)号：US06306207B2
公开(公告)日：2001-10-23
申请号：US09782802
申请日：2001-02-14
IPC分类号： C08L102
CPC分类号： B82Y5/00 , A23L29/262 , A23L29/27 , A61K8/02 , A61K8/027 , A61K8/731 , A61K2800/413 , A61Q19/00 , C04B18/24 , C04B40/0039 , C04B2103/44 , C08L1/00 , C08L1/02 , C08L2205/02 , C09K8/10 , C09K8/206 , C11D3/222 , Y02W30/97 , C08L2666/02 , C04B24/383 , C04B24/38 , C04B24/02 , C04B20/008 , C04B20/006
摘要： The present invention relates to compositions comprising essentially amorphous cellulose nanofibrils, at least one additive chosen from carboxycellulose with a degree of substitution of more than 0.95, a natural polysaccharide, a polyol, and optionally at least one co-additive, the content of additive and of optional co-additive being less than or equal to 30% by weight relative to the weight of nanofibrils and of additive and of optional co-additive. Similarly, a subject of the invention is a process for preparing such compositions, which consists in adding the additive and the optional co-additive to a suspension of essentially amorphous nanofibrils, and then in drying the suspension thus supplemented. The compositions obtained are readily redispersable and conserve their initial rheological properties.
摘要翻译： 本发明涉及包含基本上无定形纤维素纳米原纤维的组合物，至少一种选自取代度高于0.95的羧甲基纤维素的添加剂，天然多糖，多元醇和任选的至少一种共添加剂，添加剂和 任选的共添加剂相对于纳米原纤维和添加剂和任选的共添加剂的重量小于或等于30重量％。 类似地，本发明的主题是制备这种组合物的方法，其包括将添加剂和任选的辅助添加剂添加到基本上无定形的纳米原纤维的悬浮液中，然后干燥由此补充的悬浮液。 获得的组合物容易再分散，并保持其初始流变性能。
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公开(公告)号：US06348436B1
公开(公告)日：2002-02-19
申请号：US09214769
申请日：1999-05-14
申请人： Bruno Langlois , Joël Benchimol , Gilles Guerin , Isabelle Vincent , Alain Senechal , Robert Cantiani
发明人： Bruno Langlois , Joël Benchimol , Gilles Guerin , Isabelle Vincent , Alain Senechal , Robert Cantiani
IPC分类号： C09K700
CPC分类号： C09K8/206 , A23L29/262 , A23L29/27 , B82Y5/00 , C04B18/24 , C04B40/0039 , C08L1/00 , C09K8/10 , Y02W30/97 , C08L2666/02
摘要： The present invention relates to a drilling fluid comprising cellulose nanofibrils comprising at least 80% of cells with primary walls and charged with carboxylic acids and with acidic polysaccharides, alone or as a mixture. This additive, alone, gives the drilling fluid shear-thinning properties and is stable up to temperatures of about 180° C.
摘要翻译： 本发明涉及包含纤维素纳米原纤维的钻井液，所述纤维素纳米原纤维包含至少80％的具有原壁的细胞和带有羧酸的酸性多糖，单独或作为混合物。 这种添加剂单独给出了钻井液剪切稀化性能，并且在约180℃的温度下是稳定的。
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7.发明授权Supplementation of cellulose nanofibrils with carboxycellulose with low degree of substitution 有权用低度取代的羧基纤维素补充纤维素纳米纤维公开(公告)号：US06231657B1
公开(公告)日：2001-05-15
申请号：US09214765
申请日：1999-05-07
IPC分类号： C08L102
CPC分类号： B82Y5/00 , A61K8/027 , A61K8/731 , A61K2800/413 , A61Q19/00 , C08L1/02 , C08L2205/02 , C09K8/10 , C09K8/206 , C08L1/286
摘要： The invention concerns compositions containing essentially amorphous cellulose nanofibrils, carboxyl cellulose with a degree of substitution not more than o.95 as additive, and optionally at least one co-additive, the content in additive and optional co-additive being less than 30 wt. % relative to the weight of nanofibrils and additive and optional co-additive. The invention also concerns a method for preparing such compositions, consisting in adding to a substantially amorphous nanofibril suspension, the additive and optionally the co-additive(s), then in drying the suspension thus additivated. The resulting compositions are easily redispersable and preserve all their rheological properties.
摘要翻译： 本发明涉及包含基本上无定形纤维素纳米原纤维，具有不超过o.95的添加剂的羧基纤维素和任选的至少一种共添加剂的组合物，添加剂和任选的共添加剂中的含量小于30wt。 ％相对于纳米原纤维和添加剂和任选的共添加剂的重量。 本发明还涉及一种制备这种组合物的方法，该方法包括将基本上无定形的纳米原纤维悬浮液，添加剂和任选的共添加剂加入，然后干燥由此添加的悬浮液。 所得组合物容易再分散，并保持其所有的流变性质。
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8.发明授权Additivation of essentially amorphous cellulose nanofibrils with carboxyl cellulose with a high degree of substitution 有权用高度取代的羧基纤维素添加基本无定形的纤维素纳米纤维公开(公告)号：US06224663B1
公开(公告)日：2001-05-01
申请号：US09214774
申请日：1999-09-08
IPC分类号： C08L102
CPC分类号： B82Y5/00 , A23L29/262 , A23L29/27 , A61K8/02 , A61K8/027 , A61K8/731 , A61K2800/413 , A61Q19/00 , C04B18/24 , C04B40/0039 , C04B2103/44 , C08L1/00 , C08L1/02 , C08L2205/02 , C09K8/10 , C09K8/206 , C11D3/222 , Y02W30/97 , C08L2666/02 , C04B24/383 , C04B24/38 , C04B24/02 , C04B20/008 , C04B20/006
摘要： The present invention relates to compositions comprising essentially amorphous cellulose nanofibrils, at least one additive chosen from carboxycellulose with a degree of substitution of more than 0.95, a natural polysaccharide, a polyol, and optionally at least one co-additive, the content of additive and of optional co-additive being less than or equal to 30% by weight relative to the weight of nanofibrils and of additive and of optional co-additive. Similarly, a subject of the invention is a process for preparing such compositions, which consists in adding the additive and the optional co-additive to a suspension of essentially amorphous nanofibrils, and then in drying the suspension thus supplemented. The compositions obtained are redily redispersable and conserve their initial rheological properties.
摘要翻译： 本发明涉及包含基本上无定形纤维素纳米原纤维的组合物，至少一种选自取代度高于0.95的羧甲基纤维素的添加剂，天然多糖，多元醇和任选的至少一种共添加剂，添加剂和 任选的共添加剂相对于纳米原纤维和添加剂和任选的共添加剂的重量小于或等于30重量％。 类似地，本发明的主题是制备这种组合物的方法，其包括将添加剂和任选的辅助添加剂添加到基本上无定形的纳米原纤维的悬浮液中，然后干燥由此补充的悬浮液。 获得的组合物是可重新分散的并保持其初始流变性质。
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9.发明授权Copolymers of unsaturated fatty esters, their use as viscosity improver and lubricating oil containing said copolymers 失效不饱和脂肪酸酯的共聚物，它们用作粘度改进剂和含有所述共聚物的润滑油
公开(公告)号：US5534175A
公开(公告)日：1996-07-09
申请号：US295696
申请日：1994-11-11
申请人： Robert Cantiani
发明人： Robert Cantiani
IPC分类号： C08F220/18 , C10M145/14
CPC分类号： C10M145/14 , C08F220/18 , C10M2209/084
摘要： Copolymers of unsaturated fatty esters capable of being obtained by copolymerization in a mineral oil of a percentage a) of an ester of a carboxylic acid A.sub.1, of a percentage b) of an ester of a carboxylic acid A.sub.2 and a percentage c) of an ester of a carboxylic acid A.sub.3, wherein a), is between 12 and 20%, c) is between 14 and 30% and b), which is preferably 72 and 45%, is such that a)+b)+c)=100%. The copolymers in accordance with the invention are reemployed as viscosity improver in lubricating oils.
摘要翻译： PCT No.PCT / US93 / 12528 Sec。 371日期：1994年11月11日 102（e）日期1994年11月11日PCT 1993年12月22日PCT公布。 出版物WO94 / 14860 PCT 日期：1994年7月7日。能够通过在矿物油中共聚获得的不饱和脂肪酸酯的酯，其中a）的羧酸A1的酯的百分比，b）的羧酸A2和 c）的羧酸A3的酯，其中a）为12至20％，c）为14至30％，b）优选为72和45％，使得a）+ b）+ c）= 100％。 根据本发明的共聚物在润滑油中作为粘度改进剂被再次使用。
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公开(公告)号：US06881780B2
公开(公告)日：2005-04-19
申请号：US09924033
申请日：2001-08-07
IPC分类号： C10M159/12 , C08F20/10 , C08F220/12 , C08F220/18 , C08F265/00 , C08F265/06 , C10M149/04 , C10M149/06 , C10M149/08 , C10M149/10 , C10N30/02 , C10N30/04 , C08L39/00
CPC分类号： C10M149/10 , C08F220/12 , C10M145/14 , C10M149/04 , C10M149/06 , C10M149/08 , C10M2209/084 , C10M2215/04 , C10M2215/26 , C10M2217/022 , C10M2217/023 , C10M2217/024 , C10M2217/028 , C10M2217/046 , C10M2217/06 , C10M2219/02 , C10M2219/046 , C10M2223/045 , C10N2210/02 , C10N2270/02
摘要： A polyacrylate ester, and more particularly a polymethacrylate ester based dispersant-viscosity improver for lubricating oil compositions. Specifically, the dispersant viscosity improvers of this invention are nitrogen-containing copolymers comprising units derived from (A) from about 5% to about 75% by weight of alkyl acrylate ester monomers containing from 2 to 11 carbon atoms in the alkyl group; (B) from about 25% to about 95% by weight of alkyl acrylate ester monomers containing from 12 to about 24 carbon atoms in the alkyl group; and (C) From about 0.1% to about 20% by weight of at least one nitrogen containing monomer selected from the group consisting of vinyl substituted nitrogen heterocyclic monomers, N,N-dialkylaminoalkyl acrylate monomers, N,N-dialkylaminoalkyl acrylamide monomers and tertiary-alkyl acrylamides, provided that the total equals 100%. Processes for preparing the compositions, additive concentrates and lubricating oil compositions are described.
摘要翻译： 聚丙烯酸酯，特别是用于润滑油组合物的聚甲基丙烯酸酯类分散剂 - 粘度改进剂。 具体地说，本发明的分散剂粘度改进剂是含有来自（A）约5重量％至约75重量％的烷基中含有2至11个碳原子的丙烯酸烷基酯单体的单元的含氮共聚物; （B）约25％至约95％重量的在烷基中含有12至约24个碳原子的丙烯酸烷基酯单体; 和（C）约0.1％至约20％重量的至少一种选自乙烯基取代的氮杂环基单体，N，N-二烷基氨基烷基丙烯酸酯单体，N，N-二烷基氨基烷基丙烯酰胺单体和三级 烷基丙烯酰胺，条件是总量等于100％。 描述了制备组合物，添加剂浓缩物和润滑油组合物的方法。
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