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公开(公告)号：US09604888B2
公开(公告)日：2017-03-28
申请号：US14124757
申请日：2012-06-26
CPC分类号： C07C2/06 , C07C1/24 , C07C4/04 , C10G9/26 , C10G2300/807 , C10G2400/20 , Y02P30/10
摘要： Method of producing ethylene and, optionally, propylene by subjecting a feedstock to steam cracking to produce a first olefin containing stream; heating an ethanol containing stream with heat from a steam cracker; passing the heated ethanol containing stream over a dehydration catalyst at a temperature between 200 C to 500 C preferably 250 C to 450 C to produce a second olefin containing stream; and combining the first and second olefin containing streams to give an initial product stream containing ethylene and optionally propylene. The initial product stream is subjected to purification including at least i) water content reduction ii) hydrogen content reduction iii) reduction of content of molecules containing 4 or more carbon atoms and iv) ethane content reduction.
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2.发明申请PROCESS AND APPARATUS FOR PRODUCING OLEFINS WITH HEAT TRANSFER FROM STEAM CRACKING TO ALCOHOL DEHYDRATION PROCESS 有权用于从蒸汽破碎转移到酒精脱水过程中生产烯烃的方法和装置公开(公告)号：US20140114104A1
公开(公告)日：2014-04-24
申请号：US14124757
申请日：2012-06-26
CPC分类号： C07C2/06 , C07C1/24 , C07C4/04 , C10G9/26 , C10G2300/807 , C10G2400/20 , Y02P30/10
摘要： A method of producing ethylene and, optionally, propylene comprising: a) subjecting a feedstock to steam cracking to produce a first olefin containing stream; b) heating an ethanol containing stream with heat from a steam cracker; c) passing the heated ethanol containing stream over a dehydration catalyst at a temperature between 200 C to 500 C preferably 250 C to 450 C to produce a second olefin containing stream; d) combining the first and second olefin containing streams to give an initial product stream comprising ethylene and optionally propylene; and e) subjecting the initial product stream to purification comprising at least i) water content reduction ii) hydrogen content reduction iii) reduction of content of molecules containing 4 or more carbon atoms and iv) ethane content reduction.
摘要翻译： 一种生产乙烯和任选的丙烯的方法，包括：a）使原料进行蒸汽裂化以产生含第一烯烃的料流; b）用来自蒸汽裂解器的热量加热含乙醇的流; c）在200℃至500℃，优选250℃至450℃的温度下将经过加热的含乙醇的料流通过脱水催化剂，以产生第二烯烃流; d）将第一和第二烯烃流合并，得到包含乙烯和任选的丙烯的初始产物流; 和e）对初始产物流进行纯化，包括至少i）含水量降低ii）氢含量降低iii）减少含有4个或更多个碳原子的分子的含量和iv）乙烷含量降低。
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公开(公告)号：US5763883A
公开(公告)日：1998-06-09
申请号：US467179
申请日：1995-06-06
CPC分类号： G01N33/2829 , G01N21/359
摘要： A method of determining or predicting a value P.sub.x of a property of a material X, which is a feed to a process or a property of a product of a process from said material or yield of said process, which method comprises measuring the absorption D.sub.i x of said material at more than one wavelength in the region 600-2600 nm, comparing the said absorptions or a derivative thereof with absorptions D.sub.i m or derivatives thereof at the same wavelength for a number of standards S in a bank for which the said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the absorption D.sub.i x (or derivative thereof) for the material and the absorption D.sub.i m (or derivative thereof) for the standards S.sub.m to obtain P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen, and wherein said process is at least one of polymerization, an oligomerization or an organic reaction in which at least one of the reactant and a product is a functionalized compound.
摘要翻译： 一种确定或预测材料X的性质的值Px的方法，该材料X是来自所述材料的过程的产物的过程的产物的进料或所述方法的产率的性质或所述方法的产率的特性，所述方法包括测量所述材料的吸收Dix 所述材料在600-2600nm区域中的多于一个波长处，将所述吸收或其衍生物与相同波长的吸收Dim或其衍生物进行比较，对于所述性质或产率P 已知，并且从银行中选择具有性质Pm的至少一个标准Sm表示具有在材料的吸收Dix（或其衍生物）和吸收Dim（或衍生物）之间的每个波长i处的绝对差的最小平均值的标准 ），以获得Px，当选择多于一个标准Sm时，具有所述性质的平均值或产生Pm，并且其中所述方法是聚合中的至少一种，寡聚体 或其中至少一种反应物和产物是官能化化合物的有机反应。
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公开(公告)号：US09028571B2
公开(公告)日：2015-05-12
申请号：US13324299
申请日：2011-12-13
IPC分类号： C01B3/24 , B01J7/00 , C10J3/72 , C10J3/84 , C10J3/86 , C10K3/00 , C10K1/04 , F22B1/18 , C10K1/02
CPC分类号： C10J3/84 , C01B2203/0877 , C01B2203/0894 , C01B2203/142 , C01B2203/143 , C10J3/72 , C10J3/721 , C10J3/723 , C10J3/726 , C10J3/86 , C10J2200/09 , C10J2200/15 , C10J2300/0956 , C10J2300/0959 , C10J2300/1606 , C10J2300/1846 , C10J2300/1884 , C10K1/02 , C10K1/04 , C10K3/003 , C10K3/005 , C10K3/008 , F22B1/1838 , Y02E50/17 , Y02E50/32 , Y02E50/343 , Y02E60/324 , Y02P20/124 , Y02P20/129 , Y02T10/16
摘要： A process and system for cooling syngas provides effective syngas cooling and results in reduced levels of fouling in syngas cooling equipment. A process for cooling syngas includes blending syngas with cooled recycled syngas in an amount effective for providing a blended syngas with a temperature at an inlet of a syngas cooler of about 600° F. to about 1400° F. The blended syngas changes direction of flow at least once prior to the inlet of the syngas cooler.
摘要翻译： 用于冷却合成气的方法和系统提供有效的合成气冷却，并导致合成气冷却设备中的结垢水平降低。 用于冷却合成气的方法包括将合成气与冷却的再循环合成气混合，其量有效地提供合成气合成气在约600°F至约1400°F的合成气冷却器的入口处的温度。共混合成气改变流动方向 在合成气冷却器的入口之前至少一次。
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公开(公告)号：US20120256128A1
公开(公告)日：2012-10-11
申请号：US13324299
申请日：2011-12-13
CPC分类号： C10J3/84 , C01B2203/0877 , C01B2203/0894 , C01B2203/142 , C01B2203/143 , C10J3/72 , C10J3/721 , C10J3/723 , C10J3/726 , C10J3/86 , C10J2200/09 , C10J2200/15 , C10J2300/0956 , C10J2300/0959 , C10J2300/1606 , C10J2300/1846 , C10J2300/1884 , C10K1/02 , C10K1/04 , C10K3/003 , C10K3/005 , C10K3/008 , F22B1/1838 , Y02E50/17 , Y02E50/32 , Y02E50/343 , Y02E60/324 , Y02P20/124 , Y02P20/129 , Y02T10/16
摘要： A process and system for cooling syngas provides effective syngas cooling and results in reduced levels of fouling in syngas cooling equipment. A process for cooling syngas includes blending syngas with cooled recycled syngas in an amount effective for providing a blended syngas with a temperature at an inlet of a syngas cooler of about 600° F. to about 1400° F. The blended syngas changes direction of flow at least once prior to the inlet of the syngas cooler.
摘要翻译： 用于冷却合成气的方法和系统提供有效的合成气冷却，并导致合成气冷却设备中的结垢水平降低。 用于冷却合成气的方法包括将合成气与冷却的再循环合成气混合，其量有效地提供合成气合成气在约600°F至约1400°F的合成气冷却器的入口处的温度。共混合成气改变流动方向 在合成气冷却器的入口之前至少一次。
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公开(公告)号：US5935863A
公开(公告)日：1999-08-10
申请号：US838706
申请日：1997-04-09
CPC分类号： C10G9/00 , G01N21/3563 , G01N21/359 , G01N33/2829 , Y10T436/115831 , Y10T436/117497 , Y10T436/12 , Y10T436/21 , Y10T436/212 , Y10T436/214 , Y10T436/216
摘要： A method of determining or predicting a value P.sub.x of a property of a feed X to a steam cracking process or yield of said process, which method comprises measuring the absorption D.sub.ix of said material at more than one wavelength in the region 600-2600 nm, comparing signals indicative of said adsorptions or a mathematical function thereof with signals indicative of absorptions D.sub.im or mathematical function thereof at the same wavelength for a number of standards S in a bank for which the said property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m said standard having the smallest average value of the absolute difference at each wavelength i between the signal for the material and the signal for the standard S.sub.m to obtain P.sub.x, with averaging of said properties or yields P.sub.m when more than one standard S.sub.m is chosen. If desired the method can be used as such to control the steam cracking process by comparison of P.sub.m with the desired value and adjustment of the process to minimize deviations from P.sub.m ; in an alternative process the signal (or function thereof) of the standard(s) with the smallest average value of the absolute difference may be used directly to control the process.
摘要翻译： 一种确定或预测进料X的性质的值Px至蒸汽裂化过程或所述方法的产率的方法，该方法包括在600-2600nm的区域中测量多于一个波长的所述材料的吸收Dix， 将表示所述吸附的信号或其数学函数与指示吸收的信号相同的波长的数学函数或对于所述性质或产率P已知的银行中的多个标准S的数学函数，以及从所述银行中选择 具有性质Pm的至少一个标准Sm表示标准具有在材料的信号与标准Sm的信号之间的每个波长i处的绝对差的最小平均值，以获得Px，具有所述性质的平均或产生更多的Pm 比一个标准Sm选择。 如果需要，可以将该方法用于通过将Pm与期望值进行比较来控制蒸汽裂解过程，并调整过程以最小化与Pm的偏差; 在替代处理中，可以直接使用具有绝对差的最小平均值的标准的信号（或其功能）来控制处理。
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7.发明授权
公开(公告)号：US6070128A
公开(公告)日：2000-05-30
申请号：US838879
申请日：1997-04-09
申请人： Bernard Descales , Didier Lambert , Jean-Richard Llinas , Andre Martens , Sebastien Osta , Michel Sanchez , Sylvie Bages
发明人： Bernard Descales , Didier Lambert , Jean-Richard Llinas , Andre Martens , Sebastien Osta , Michel Sanchez , Sylvie Bages
CPC分类号： B01J19/0006 , G01N21/359
摘要： A method of determining or predicting a value P.sub.x of a property (e.g. octane number) of a material X or a property of a product of a process from the material or yield of the process for example a blending, separation, or chemical (e.g. polymerization) process, which method comprises measuring the absorption D.sub.ix of the material at more than one wavelength in the region 600-2600 nm, comparing the the signals indicative of the absorptions or a derivative thereof with signals indicative of absorptions D.sub.im or derivatives thereof at the same wavelength for a number of standards S in a bank for which the property or yield P is known, and choosing from the bank at least one standard S.sub.m with property P.sub.m the standard having the smallest average value of the absolute difference at each wavelength i between the signal for the material and the signal for the standard S.sub.m to obtain P.sub.x, with averaging of the properties or yields P.sub.m when more than one standard S.sub.m is chosen. If desired the method can be used as such to control the process by comparison of P.sub.m with the desired value and adjustment of the process to minimize deviations from P.sub.m ; in an alternative process the signal (or function thereof) of the standard(s) with the smallest average value of the absolute difference may be used directly to control the process.
摘要翻译： 确定或预测材料X的性质（例如辛烷值）的值P x或方法产物的性质或方法的产率（例如混合，分离或化学品）的方法（例如聚合 ）方法，该方法包括测量600-2600nm区域中多于一个波长的材料的吸收Dix，将表示吸收的信号或其衍生物与指示吸收的信号Dim或其衍生物进行比较 波长，对于其中性质或产量P已知的存储体中的多个标准S，并且从存储体中选择具有属性Pm的至少一个标准Sm，在每个波长i处具有绝对差的最小平均值的标准 信号，并且标准Sm的信号获得Px，当选择多于一个标准Sm时，具有性质的平均或产生Pm。 如果需要，可以使用该方法来通过将Pm与期望值进行比较来控制该过程并且调整该过程以最小化与Pm的偏差; 在替代处理中，可以直接使用具有绝对差的最小平均值的标准的信号（或其功能）来控制处理。
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公开(公告)号：US5861228A
公开(公告)日：1999-01-19
申请号：US466594
申请日：1995-06-06
CPC分类号： G01N33/2829 , C10G9/00 , G01N21/35 , G01N21/359 , Y10T436/115831 , Y10T436/117497 , Y10T436/12 , Y10T436/21 , Y10T436/212 , Y10T436/214 , Y10T436/216 , Y10T436/218
摘要： An apparatus for on-line measuring physical property data of hydrocarbon products such as octane number, cetane number, density, vapour pressure and the like or gasoline/alcohol ratio, comprising means for providing (N)IR radiation in a predetermined spectral range; means for transmitting light at selected wavelengths in the (N)IR spectral region; means for delivering light from said transmitting means to a hydrocarbon product line; means for allowing an optical path length in the hydrocarbon product line; means for detecting the light transmitted through the said optical path; means for providing the obtained signal to be input to processing equipment for spectral analysis and correlating the spectral data to the physical property data of hydrocarbon products such as octane number, cetane number, density, vapour pressure and the like or gasoline/alcohol ratio.
摘要翻译： 用于在线测量烃产物的物理性质数据的装置，例如辛烷值，十六烷值，密度，蒸气压等或汽油/醇比，包括用于在预定光谱范围内提供（N）IR辐射的装置; 用于在（N）IR光谱区域中发射选定波长的光的装置; 用于将光从所述发送装置传送到烃产品线的装置; 用于允许烃产品线中的光路长度的装置; 用于检测透过所述光路的光的装置; 用于将获得的信号提供给输入到用于光谱分析的处理设备并将光谱数据与烃产物的物理性质数据（例如辛烷值，十六烷值，密度，蒸气压等）或汽油/醇比相关联的装置。
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公开(公告)号：US08894885B2
公开(公告)日：2014-11-25
申请号：US13427193
申请日：2012-03-22
申请人： Peter S. Bell , Ching-Whan Ko , Joseph Golab , Bernard Descales , Julien Eyraud
发明人： Peter S. Bell , Ching-Whan Ko , Joseph Golab , Bernard Descales , Julien Eyraud
CPC分类号： C10J3/84 , C01B2203/0877 , C01B2203/0894 , C01B2203/142 , C01B2203/143 , C10J3/72 , C10J3/721 , C10J3/723 , C10J3/726 , C10J3/86 , C10J2200/09 , C10J2200/15 , C10J2300/0956 , C10J2300/0959 , C10J2300/1606 , C10J2300/1846 , C10J2300/1884 , C10K1/02 , C10K1/04 , C10K3/003 , C10K3/005 , C10K3/008 , F22B1/1838 , Y02E50/17 , Y02E50/32 , Y02E50/343 , Y02E60/324 , Y02P20/124 , Y02P20/129 , Y02T10/16
摘要： A process and apparatus are provided for reducing content of tar in a tar containing syngas. The process includes contacting the tar containing syngas with a molecular oxygen containing gas in a first reaction zone to produce a gas mixture. The gas mixture is passed through a heat treatment zone maintained at a temperature between about 900° C. to about 2000° C. for a contact time of about 0.5 to about 5 seconds. In this aspect, at least a portion of the tar undergoes at least partial oxidation and/or cracking to produce a hot syngas.
摘要翻译： 提供了一种用于降低焦油含焦油含量的合成气含量的方法和装置。 该方法包括在第一反应区中使包含合成气的焦油与含分子氧的气体接触以产生气体混合物。 气体混合物通过保持在约900℃至约2000℃之间的温度的热处理区，接触时间为约0.5至约5秒。 在这方面，至少一部分焦油经历至少部分氧化和/或开裂以产生热合成气。
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公开(公告)号：US20120256130A1
公开(公告)日：2012-10-11
申请号：US13427193
申请日：2012-03-22
申请人： Peter S. Bell , Chin-Whan Ko , Joseph Golab , Bernard Descales , Julien Eyraud
发明人： Peter S. Bell , Chin-Whan Ko , Joseph Golab , Bernard Descales , Julien Eyraud
CPC分类号： C10J3/84 , C01B2203/0877 , C01B2203/0894 , C01B2203/142 , C01B2203/143 , C10J3/72 , C10J3/721 , C10J3/723 , C10J3/726 , C10J3/86 , C10J2200/09 , C10J2200/15 , C10J2300/0956 , C10J2300/0959 , C10J2300/1606 , C10J2300/1846 , C10J2300/1884 , C10K1/02 , C10K1/04 , C10K3/003 , C10K3/005 , C10K3/008 , F22B1/1838 , Y02E50/17 , Y02E50/32 , Y02E50/343 , Y02E60/324 , Y02P20/124 , Y02P20/129 , Y02T10/16
摘要： A process and apparatus are provided for reducing content of tar in a tar containing syngas. The process includes contacting the tar containing syngas with a molecular oxygen containing gas in a first reaction zone to produce a gas mixture. The gas mixture is passed through a heat treatment zone maintained at a temperature between about 900° C. to about 2000° C. for a contact time of about 0.5 to about 5 seconds. In this aspect, at least a portion of the tar undergoes at least partial oxidation and/or cracking to produce a hot syngas.
摘要翻译： 提供了一种用于降低焦油含焦油含量的合成气含量的方法和装置。 该方法包括在第一反应区中使包含合成气的焦油与含分子氧的气体接触以产生气体混合物。 气体混合物通过保持在约900℃至约2000℃之间的温度的热处理区，接触时间为约0.5至约5秒。 在这方面，至少一部分焦油经历至少部分氧化和/或开裂以产生热合成气。
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