公开(公告)号：US20110087059A1

公开(公告)日：2011-04-14

申请号：US12903690

申请日：2010-10-13

Applicant: Laurent SIMON ,  Antoine DAUDIN

Inventor： Laurent SIMON ,  Antoine DAUDIN

IPC: C10G1/00

CPC classification number: B01J29/166 ,  B01J23/883 ,  B01J29/084 ,  B01J29/72 ,  B01J29/7261 ,  B01J29/78 ,  B01J29/7861 ,  B01J37/20 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/42 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G3/54 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/06 ,  C10G2400/08 ,  Y02P30/20

Abstract: This invention describes a process for treatment of feedstocks obtained from a renewable source implementing a catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one zeolite that has at least one series of channels whose opening is defined by a ring with 8 oxygen atoms modified by a) at least one stage for introducing at least one alkaline cation that belongs to group IA or IIA of the periodic table, b) a stage for treating said zeolite in the presence of at least one molecular compound that contains at least one silicon atom, c) at least one stage of partial exchange of said alkaline cations by NH4+ cations, and d) at least one heat treatment stage.

Abstract translation: 本发明描述了一种处理从可再生原料获得的原料的方法，该方法包括至少一种选自由元素周期表第ⅥB族和Ⅷ族金属形成的基团的至少一种氢化脱氢金属的催化剂，以及 底物，其包含至少一种沸石，其具有至少一个通道系列，其开口由具有8个氧原子的环限定，所述环具有由a）至少一个阶段修饰，用于引入至少一种碱性阳离子，所述碱性阳离子属于 周期表，b）在至少一种含有至少一个硅原子的分子化合物存在下处理所述沸石的阶段，c）至少一个阶段由NH 4 +阳离子部分交换所述碱性阳离子，和d）至少 一个热处理阶段。

公开(公告)号：US20110155633A1

公开(公告)日：2011-06-30

申请号：US12903587

申请日：2010-10-13

Applicant: Laurent SIMON ,  Christophe Bouchy

Inventor： Laurent SIMON ,  Christophe Bouchy

IPC: C10G65/12 ,  C10G47/20 ,  C10G49/08

CPC classification number: C10G47/18 ,  C10G2/30 ,  C10G45/62 ,  C10G45/64 ,  C10G47/20 ,  C10G65/12

Abstract: The invention relates to a process for the production of middle distillates from a paraffinic feedstock that is produced by Fischer-Tropsch synthesis, implementing a hydrocracking/hydroisomerization catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one zeolite that has at least one series of channels of which the opening is defined by a ring with 12 oxygen atoms modified by a) a stage for introducing at least one alkaline cation that belongs to group IA or IIA of the periodic table, b) a stage for treatment of said zeolite in the presence of at least one molecular compound that contains at least one silicon atom, c) at least one stage for partial exchange of said alkaline cations by NH4+ cations such that the remaining content of alkaline cations in the modified zeolite at the end of stage c) is such that the alkaline cation/aluminum molar ratio is between 0.2:1 and 0.01:1, and d) at least one heat treatment stage.

Abstract translation: 本发明涉及一种由费 - 托合成生产的石蜡原料生产中间馏分的方法，其实施加氢裂化/加氢异构化催化剂，该加氢裂化/加氢异构化催化剂包含至少一种加氢脱氢金属，其选自由 元素周期表VIB族和VIII族的金属和至少一种具有至少一个通道系列的沸石的基质，该沸石的开口由具有12个氧原子的环所限定，该氧原子被a） 至少一种属于周期表的IA或IIA族的碱性阳离子，b）在至少一种含有至少一个硅原子的分子化合物的存在下，用于处理所述沸石的阶段，c）至少一个用于 通过NH 4 +阳离子部分交换所述碱性阳离子，使得在阶段c）结束时改性沸石中碱性阳离子的剩余含量使得碱性阴离子 铝/铝摩尔比为0.2:1至0.01:1，和d）至少一个热处理阶段。

公开(公告)号：US20110108460A1

公开(公告)日：2011-05-12

申请号：US12942487

申请日：2010-11-09

Applicant: Laurent SIMON ,  Emmanuelle Guillon ,  Antoine Daudin

Inventor： Laurent SIMON ,  Emmanuelle Guillon ,  Antoine Daudin

IPC: C10G65/02

CPC classification number: C10G3/45 ,  B01J23/883 ,  B01J29/084 ,  B01J29/146 ,  B01J29/166 ,  B01J37/10 ,  B01J2229/16 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/38 ,  B01J2229/42 ,  C10G3/46 ,  C10G3/49 ,  C10G3/50 ,  C10G3/54 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

Abstract: This invention describes a process for treatment of feedstocks obtained from a renewable source implementing—in one hydroisomerization stage—a catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one dealuminified Y zeolite that has an initial overall atomic ratio of silicon to aluminum of between 2.5 and 20, a fraction by weight of an initial extra-network aluminum atom that is greater than 10%, relative to the total mass of aluminum that is present in the zeolite, an initial mesopore volume that is measured by nitrogen porosimetry that is greater than 0.07 ml·g−1, and an initial crystalline parameter ao of the unit cell mesh of between 24.38 Å and 24.30 Å, whereby said zeolite is modified by a) a basic treatment stage that consists of the mixing of said dealuminified Y zeolite with a basic aqueous solution, and at least one heat treatment stage c).

Abstract translation: 本发明描述了一种处理从可再生来源获得的原料的方法，该可再生来源实施了一个加氢异构化阶段 - 催化剂，该催化剂包含至少一种选自由VIB族金属和VIII族金属形成的基团的加氢脱氢金属 和包含至少一种脱铝Y沸石的底物，所述脱铝Y沸石的硅与铝的初始总原子比为2.5至20，初始超网络铝原子的重量百分比大于10％ ，相对于存在于沸石中的铝的总质量，通过氮气孔率法测量的初始中孔体积大于0.07ml·g-1，并且单元孔网的初始结晶参数ao在24.38 所述沸石通过以下步骤进行改性：a）碱性处理阶段，其由所述脱铝Y沸石与碱性水溶液的混合组成， 至少一个热处理阶段c）。

公开(公告)号：US20110108459A1

公开(公告)日：2011-05-12

申请号：US12942351

申请日：2010-11-09

Applicant: Laurent SIMON ,  Emmanuelle Guillon

Inventor： Laurent SIMON ,  Emmanuelle Guillon

IPC: C10G65/12 ,  C10G47/20 ,  C01B39/00 ,  B01J29/04

CPC classification number: C01B39/00 ,  B01J29/084 ,  B01J29/146 ,  B01J29/166 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/16 ,  B01J2229/22 ,  B01J2229/36 ,  B01J2229/38 ,  B01J2229/40 ,  C10G45/08 ,  C10G45/12 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/1007 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018 ,  C10G2400/02 ,  C10G2400/04

Abstract: The present invention describes a hydrocracking and/or hydrotreatment process using a catalyst comprising an active phase containing at least one hydrogenating/dehydrogenating component selected from the group VIB elements and the non-precious elements of group VIII of the periodic table, used alone or in a mixture, and a support comprising at least one dealuminated zeolite Y having an overall initial atomic ratio of silicon to aluminium between 2.5 and 20, an initial weight fraction of extra-lattice aluminium atoms greater than 10%, relative to the total weight of aluminium present in the zeolite, an initial mesopore volume measured by nitrogen porosimetry greater than 0.07 ml·g−1 and an initial crystal lattice parameter a0 between 24.38 Å and 24.30 Å, said zeolite being modified by a) a stage of basic treatment comprising mixing said dealuminated zeolite Y with a basic aqueous solution, and at least one stage c) of thermal treatment.

Abstract translation: 本发明描述了使用催化剂的加氢裂化和/或加氢处理方法，所述催化剂包含活性相，所述活性相含有至少一种选自元素周期表中VIB族元素和VIII族非贵金属的氢化/脱氢组分， 混合物和包含至少一种脱铝沸石Y的载体，其具有2.5至20的硅与铝的总初始原子比，超晶格铝原子的初始重量分数相对于铝的总重量大于10％ 存在于沸石中，通过氮气孔隙度法测量的初始中孔体积大于0.07ml·g -1，初始晶格参数a0在24.38埃至24.30埃之间，所述沸石通过以下步骤进行修饰：a）碱性处理阶段，包括将所述 用碱性水溶液脱铝沸石Y和至少一个热处理阶段c）。

公开(公告)号：US20110083999A1

公开(公告)日：2011-04-14

申请号：US12903573

申请日：2010-10-13

Applicant: Laurent SIMON

Inventor： Laurent SIMON

IPC: C10G45/00 ,  C10G47/20

CPC classification number: C10G45/12 ,  B01J29/064 ,  B01J29/072 ,  B01J29/076 ,  B01J29/084 ,  B01J29/166 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/12 ,  B01J2229/32 ,  B01J2229/37 ,  B01J2229/42 ,  C10G45/08 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

Abstract: The present invention describes a method for hydrocracking and/or hydrotreating hydrocarbon-containing feeds using a catalyst comprising at least one hydro-dehydrogenizing metal selected from the group made up of group VIB and non-noble group VIII metals of the periodic table and a support comprising at least one zeolite having at least pore openings containing 12 oxygen atoms, modified by a) at least a stage of introducing at least one alkaline cation belonging to groups IA or IIA of the periodic table, b) a stage of treating said zeolite in the presence of at least one molecular compound containing at least one silicon atom, c) at least one stage of partial exchange of said alkaline cations by NH4+ cations in such a way that the proportion of alkaline cations remaining in the modified zeolite at the end of stage c) is such that the alkaline cation/aluminium molar ratio ranges between 0.2:1 and 0.01:1, and d) at least one thermal treatment stage.

Abstract translation: 本发明描述了一种使用包含至少一种选自元素周期表VIB族和非贵族VIII族金属的加氢脱氢金属的催化剂加氢裂化和/或加氢处理含烃原料的方法， 包括至少一种沸石，其至少具有含有12个氧原子的孔隙，通过a）至少引入至少一种属于周期表的IA或IIA族的碱性阳离子的阶段，b）将所述沸石处理的阶段 存在至少一种含有至少一个硅原子的分子化合物，c）至少一个阶段通过NH 4 +阳离子部分交换所述碱性阳离子，使得残留在改性沸石中末端的碱性阳离子的比例 阶段c）使得碱性阳离子/铝的摩尔比在0.2:1和0.01:1之间，d）至少一个热处理阶段。

公开(公告)号：US20100179361A1

公开(公告)日：2010-07-15

申请号：US12541540

申请日：2009-08-14

Applicant: Simone GOERGEN ,  Loic ROULEAU ,  Emmanuelle GUILLON ,  Florent GUILLOU ,  Laurent SIMON ,  Christophe BOUCHY ,  Joël PATARIN

Inventor： Simone GOERGEN ,  Loic ROULEAU ,  Emmanuelle GUILLON ,  Florent GUILLOU ,  Laurent SIMON ,  Christophe BOUCHY ,  Joël PATARIN

IPC: C07C5/22 ,  B01J29/06 ,  B01J29/40 ,  B01J29/064 ,  C10G47/04

CPC classification number: B01J29/06 ,  B01J29/084 ,  B01J29/166 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7023 ,  B01J29/7446 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1038 ,  B01J35/1066 ,  B01J2229/186 ,  B01J2229/64 ,  C10G47/16 ,  C10G49/08

Abstract: The invention describes a porous composite material that comprises a porous substrate based on a refractory inorganic oxide in which said substrate has a zeolite crystal content that is less than 25% by mass, whereby said crystals are dispersed homogeneously in the pores of said substrate, and the distribution coefficient that is measured by Castaing microprobe is between 0.75 and 1.25, and in which the total pore volume of said substrate represents at least 40% of the initial total pore volume of the substrate, and the mean diameter of the pores represents at least 50% of the mean diameter of the pores of the initial substrate, its process for preparation and its use as catalyst in the hydrocarbon feedstock conversion reactions.

Abstract translation: 本发明描述了一种多孔复合材料，其包括基于难熔无机氧化物的多孔基材，其中所述基材的沸石晶体含量小于25质量％，由此所述晶体均匀地分散在所述基材的孔中，以及 由Castaing微探针测量的分布系数在0.75和1.25之间，其中所述基材的总孔体积占基材初始总孔体积的至少40％，孔的平均直径至少表示 初始底物孔的平均直径的50％，其制备方法及其作为烃原料转化反应中的催化剂。