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1.发明授权Extruded thermoplastic, liquid crystalline polymers and blends thereof having a planar morphology 失效具有平面形态的挤压热塑性，液晶聚合物及其共混物
公开(公告)号：US5981007A
公开(公告)日：1999-11-09
申请号：US595135
申请日：1996-02-01
CPC分类号： C08J5/18 , C08L79/08 , Y10T428/1345 , Y10T428/249921
摘要： The present invention relates to articles of manfacture, such as films, tubes, and coatings, comprising a multiaxially oriented film having a planar morphology, wherein the article of manfacture comprises at least one thermoplastic flexible polymer, at least one thermotropic liquid crystalline polymer, or a blend thereof. Recyclable articles of manufacture having improved barrier properties are also provided.
摘要翻译： 本发明涉及制造物品，例如膜，管和涂层，其包括具有平面形态的多轴取向膜，其中所述制品包含至少一种热塑性柔性聚合物，至少一种热致变液晶聚合物，或 它们的混合物。 还提供了具有改进的阻隔性能的可回收制品。
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公开(公告)号：US5589236A
公开(公告)日：1996-12-31
申请号：US217236
申请日：1994-03-24
CPC分类号： B29D7/01 , B29C47/0023 , B29C47/0026 , B29C47/009 , B29C47/065 , B29C47/24 , B29C47/268 , B29C47/28 , B29C55/00 , C09K19/38 , H05K1/0313 , B29C2791/007 , B29C47/0019 , B29C47/0021 , B29K2105/0079 , B29L2031/7158 , Y10T428/31786
摘要： A flat and nearly mechanically isotropic polymer film or sheet, or a tube, can be formed by laminating two or more films, preferably by coextrusion of a liquid crystal polymer film and a thermoplastic polymer film. A liquid crystal polymer layer may be combined with one or more thermoplastic polymer layer in various arrangements. The liquid crystal, and possibly the thermoplastic as well, may have a controlled molecular orientation. The film may be formed by passing a polymer through a set of two or three tubular rotors which are concentric and have facing surfaces which define inner and outer annular polymer flow channels.
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3.发明授权
公开(公告)号：US5882741A
公开(公告)日：1999-03-16
申请号：US590565
申请日：1996-01-26
CPC分类号： C03C25/106 , B29C47/0014 , B29C47/0023 , B29C47/021 , B29C47/025 , B29C47/24 , B29C67/0003 , G02B6/02395 , B29L2011/0075 , Y10T428/105 , Y10T428/24058 , Y10T428/29 , Y10T428/2913 , Y10T428/2933 , Y10T428/2936 , Y10T428/294 , Y10T428/31786
摘要： Coatings of multiaxially oriented Thermotropic Liquid Crystalline Polymer (TLCP) are provided to elongated members. Suitable members include glass rods, glass fibers, pipes, beams, and other oval or polygonal members having an essentially regular cross-section. Members of ceramic, plastic, or metal can also be coated. This extrusion is performed using a die having inner and outer mandrels capable of rotating in opposite directions. Concentricity between inner and outer mandrels of the die is maintained to assure uniform coating thickness. In order to produce a high level of multiaxial orientation at lower die rotational speeds, the die design may include spiraling feed zones on one or both facing surfaces of the inner and outer mandrels. The application of the multiaxially oriented coating provides superior impermeability to water vapor and oxygen, and increased strength to the elongated member in the axial direction.
摘要翻译： 多轴取向热致液晶聚合物（TLCP）的涂层被提供给细长部件。 合适的构件包括玻璃棒，玻璃纤维，管，梁和具有基本上规则横截面的其它椭圆形或多边形构件。 陶瓷，塑料或金属的成员也可以涂覆。 使用具有能够沿相反方向旋转的内心轴和外心轴的模具进行该挤出。 维持模具的内心轴和外心轴之间的同心度，以确保均匀的涂层厚度。 为了在较低的模具转速下产生高水平的多轴取向，模具设计可以包括在内心轴和外心轴的一个或两个相对表面上的螺旋进给区。 多轴取向涂层的应用提供了对水蒸气和氧的优异的不渗透性，并且在轴向方向上提高了细长构件的强度。
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公开(公告)号：US6045737A
公开(公告)日：2000-04-04
申请号：US136491
申请日：1998-08-19
CPC分类号： B29C47/28 , B29C47/0023 , B29C47/065 , B29C47/24 , B29C47/268 , B29C55/00 , B29C47/0026 , B29C47/26 , B29K2105/0079 , Y10T428/10
摘要： A flat and nearly mechanically isotropic polymer film or sheet, or a tube, can be formed by laminating two or more films, preferably by coextrusion of a liquid crystal polymer film and a thermoplastic polymer film. A liquid crystal polymer layer may be combined with one or more thermoplastic polymer layer in various arrangements. The liquid crystal, and possibly the thermoplastic as well, may have a controlled molecular orientation. The film may be formed by passing a polymer through a set of two or three tubular rotors which are concentric and have facing surfaces which define inner and outer annular polymer flow channels.
摘要翻译： 可以通过层叠两个或更多个膜，优选通过共挤出液晶聚合物膜和热塑性聚合物膜来形成扁平且几乎机械各向同性的聚合物膜或片或管。 液晶聚合物层可以与一种或多种热塑性聚合物层以各种布置组合。 液晶以及可能的热塑性材料也可以具有受控的分子取向。 膜可以通过使聚合物通过一组两个或三个管状转子而形成，这两个或三个管状转子是同心的并且具有限定内部和外部环形聚合物流动通道的相对表面。
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公开(公告)号：US5288529A
公开(公告)日：1994-02-22
申请号：US778812
申请日：1991-12-12
IPC分类号： B29C47/04 , B29C47/06 , B29C47/14 , B29C47/24 , B29C47/28 , B29C47/92 , B29C55/00 , B29C55/02 , B29C55/26 , B29C55/28 , B29D7/01 , B29K79/00 , B29K81/00 , B29K101/12 , B29L7/00 , B29L9/00 , B32B7/02 , B32B7/04 , C08J5/18 , C08L67/00 , C08L79/06 , C08L101/12 , C09K19/38 , H05K1/03 , C09K19/00
CPC分类号： C09K19/38 , B29C47/0023 , B29C47/0026 , B29C47/009 , B29C47/065 , B29C47/24 , B29C47/268 , B29C47/28 , B29C55/00 , B29D7/01 , H05K1/0313 , B29C2791/007 , B29C47/0021 , B29C47/061 , B29K2105/0079 , B29L2031/7158 , Y10T428/1077 , Y10T428/31786
摘要： A flat and nearly mechanically isotropic liquid crystal polymer film (38) can be formed by laminating two continuous biaxially oriented films. A laminate is produced having two thin outer surface portions which are oriented in one direction, and a relatively thick inner portion oriented in a transverse direction. The film may also be formed by passing a polymer through a set of three tubular rotors (30) which are concentric and having surfaces which are concentric and define inner and outer annular polymer flow channels (33, 35) between them. These rotors may rotate in the same or opposite directions. Another way to make the film is with a slit-type die (90) through which a polymer flows in one direction, while a moving band (91) passes continuously in a transverse direction. These ordered-polymer films are useful, for example, in the production of printed circuit boards.
摘要翻译： PCT No.PCT / US90 / 03394 Sec。 371日期1991年12月12日 102（e）日期1991年12月12日PCT Filed 1990年6月18日PCT公布。 出版物WO90 / 15706 日期：1990年12月27日。平面且近似机械各向同性的液晶聚合物膜（38）可以通过层压两个连续的双轴取向薄膜而形成。 制造具有沿一个方向取向的两个薄的外表面部分和沿横向方向定向的相对较厚的内部部分的层压体。 膜也可以通过使聚合物通过一组三个同心的并且具有同心的表面并且在它们之间限定内部和外部环形聚合物流动通道（33,35）的管状转子（30）而形成。 这些转子可以沿相同或相反的方向旋转。 另一种制造薄膜的方法是使一个聚合物沿一个方向流动的狭缝型模头（90），同时移动带（91）在横向上连续地通过。 这些有序聚合物膜可用于例如印刷电路板的生产。
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公开(公告)号：US5443884A
公开(公告)日：1995-08-22
申请号：US834283
申请日：1992-02-14
IPC分类号： B29C49/00 , B29C51/00 , B32B3/12 , B64G1/00 , B64G99/00 , C08J5/18 , C08L63/00 , C08L79/04 , C08L79/06 , C08L79/08 , C08L81/00 , C08L81/06
CPC分类号： B29D99/0089 , B32B3/12 , B64G9/00 , C08L63/00 , C08L79/04 , C08L79/06 , C08L79/08 , C08L81/00 , Y10S428/91 , Y10T156/1003 , Y10T428/236 , Y10T428/24149 , Y10T428/24165
摘要： Film-based composite structures meet the requirements of highly weight-efficient SDI space-based systems. These structures are rigid, lightweight, dimensionally stable, and possess a high degree of structural damping. Thin-walled structures (wall thickness less than 50 .mu.) made from self-reinforced ordered-polymer films overcome drawbacks of fiber-reinforced composites, and provide resistance to microcracking, ply delamination and impact. They have high temperature capability (over 300.degree. C.), low temperature (cryogenic) capability and the capability for hardening and survivability. The modulus and dimensional stability of film-based ultralightweight honeycomb sandwich structures is better than currently possible with aluminum or fiber-reinforced composite materials. Other thin-walled structures such as tension web beams and thin facesheets also show similar stiffness-to-weight advantages over current materials.
摘要翻译： 基于薄膜的复合结构满足高度重量的SDI空间系统的要求。 这些结构是刚性的，重量轻的，尺寸稳定的，并且具有高度的结构阻尼。 由自增强有序聚合物膜制成的薄壁结构（壁厚小于50微米）克服了纤维增强复合材料的缺点，提供了抗裂纹，层压分层和冲击的能力。 它们具有高温能力（超过300℃），低温（低温）能力和硬化和生存能力。 薄膜超轻型蜂窝夹层结构的模量和尺寸稳定性优于铝或纤维增强复合材料。 其他薄壁结构，例如张力腹板梁和薄面板，也显示出与现有材料相似的刚度与重量的优点。
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7.发明授权
公开(公告)号：US4975312A
公开(公告)日：1990-12-04
申请号：US209281
申请日：1988-06-20
IPC分类号： B32B15/08 , B29C55/02 , B29C55/10 , B29K67/00 , B29L7/00 , B29L31/34 , B32B27/06 , C08J5/18 , H05K1/03 , H05K3/00
CPC分类号： B32B27/06 , H05K1/0313 , Y10S428/901 , Y10T428/24917 , Y10T428/266 , Y10T428/31533
摘要： The present invention is directed to the use of multiaxially oriented (e.g., biaxially) thermotropic polymers as a substrate material for the preparation of printed wire boards (PWB). In preferred embodiments, the PWB of the present invention comprises a generic, high density, organic multilayer PWB comprising XYDAR.RTM. and/or VECTRA.RTM. films, capable of being employed as a high density leadless perimeter and in grid array ceramic chip packages.
摘要翻译： 本发明涉及多轴取向（例如双轴）热致聚合物作为制备印刷线路板（PWB）的基材的用途。 在优选实施例中，本发明的PWB包括通用的高密度有机多层PWB，其包括XYDAR TM和/或VECTRA TM膜，能够被用作高密度无引线周界和栅格阵列陶瓷芯片封装。
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公开(公告)号：US5995361A
公开(公告)日：1999-11-30
申请号：US781393
申请日：1997-01-10
申请人： Kumaraswamy Jayaraj , James M. Burnett , Joseph W. Piche , Paul J. Glatkowski , Richard W. Lusignea
发明人： Kumaraswamy Jayaraj , James M. Burnett , Joseph W. Piche , Paul J. Glatkowski , Richard W. Lusignea
CPC分类号： H01G4/18 , Y10T428/1023 , Y10T428/31522
摘要： This invention relates in general to capacitors including one or more layers of dielectric material wherein at least one of the layers including a multiaxially oriented lyotropic liquid crystalline polymer (LCP) film. The present invention also provides lyotropic LCPs films having less than 0.5% residual ionic contaminants and a method of preparing such films and capacitors including such films. In preferred embodiments, the invention further provides a capacitor wherein the liquid crystalline polymer film has less than 0.5% residual ionic contaminants.
摘要翻译： 本发明一般涉及包括一层或多层介电材料的电容器，其中至少一层包括多轴取向溶致液晶聚合物（LCP）膜。 本发明还提供了具有小于0.5％的残余离子污染物的溶致LCP膜，以及制备这种膜和电容器的方法，包括这种膜。 在优选实施例中，本发明还提供一种电容器，其中液晶聚合物膜具有小于0.5％的残留离子污染物。
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9.发明授权Coextrusion of liquid crystal polymers and thermoplastic polymers to form a container 失效共挤出液晶聚合物和热塑性聚合物以形成容器
公开(公告)号：US5843539A
公开(公告)日：1998-12-01
申请号：US398092
申请日：1995-03-03
IPC分类号： B65D1/00 , B29B11/08 , B29C47/06 , B29C47/24 , B29C47/28 , B29C49/04 , B29C49/22 , B29C49/42 , B29C55/00 , C09K19/38 , C09K19/00
CPC分类号： B29C47/065 , B29C47/0023 , B29C47/0026 , B29C47/009 , B29C47/24 , B29C47/268 , B29C47/28 , B29C55/00 , C09K19/38 , B29C2791/007 , B29C47/0021 , B29C47/26 , B29K2105/0079 , B29L2031/7158 , Y10S428/913 , Y10T428/1036 , Y10T428/24942 , Y10T428/2826 , Y10T428/31786 , Y10T428/31797 , Y10T428/31913 , Y10T428/31928
摘要： A flat and nearly mechanically isotropic polymer film or sheet, or a tube, can be formed by laminating two or more films, preferably by coextrusion of a liquid crystal polymer film and a thermoplastic polymer film. A liquid crystal polymer layer may be combined with one or more thermoplastic polymer layer in various arrangements. The liquid crystal, and possibly the thermoplastic as well, may have a controlled molecular orientation. The film may also be formed by passing a polymer through a set of two or three tubular rotors which are concentric and have facing surfaces which define inner and outer annular polymer flow channels.
摘要翻译： 可以通过层叠两个或更多个膜，优选通过共挤出液晶聚合物膜和热塑性聚合物膜来形成扁平且几乎机械各向同性的聚合物膜或片或管。 液晶聚合物层可以与一种或多种热塑性聚合物层以各种布置组合。 液晶以及可能的热塑性材料也可以具有受控的分子取向。 膜也可以通过使聚合物通过一组两个或三个管状转子而形成，这两个或三个管状转子是同心的并且具有限定内部和外部环形聚合物流动通道的相对表面。
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10.发明授权Ordered polymer/sol-gel microcomposite laminates with peek resin adhesive 失效有序聚合物/溶胶 - 凝胶微复合层压板与窥视树脂粘合剂
公开(公告)号：US5344703A
公开(公告)日：1994-09-06
申请号：US137897
申请日：1993-10-13
CPC分类号： B32B17/10009 , B32B17/1055 , B32B17/10981 , B32B7/12 , Y10T428/249953 , Y10T428/249967 , Y10T428/249969 , Y10T428/249978 , Y10T428/24998 , Y10T428/249985 , Y10T428/249987 , Y10T428/249993 , Y10T428/31504 , Y10T428/31627
摘要： Provided are methods for laminating ordered polymers such as PBZT/sol-gel glass microcomposite film layers by first roughing the bonding surfaces of such film layers and then inserting therebetween a PEEK resin adhesive layer and compressing the film and adhesive layers together at sufficient temperature and pressure to laminate such layers. In one embodiment the ordered polymer layers are hot-pressed before surface roughing, stacking and laminating of film and adhesive layers. The invention also includes the novel laminates prepared thereby which exhibit high tensile strength, high compressive strength and good interlaminar strength, suitable for high-performance structures in e.g. aircraft, spacecraft or other structures or vehicles.
摘要翻译： 提供了通过首先将这些膜层的接合表面粗化并然后将PEEK树脂粘合剂层插入其中并在足够的温度和压力下将膜和粘合剂层压在一起的方法来层压有序聚合物如PBZT /溶胶 - 凝胶玻璃微复合膜层的方法 以层压这些层。 在一个实施方案中，有序聚合物层在表面粗糙化，层压和层压薄膜和粘合剂层之前被热压。 本发明还包括由此制备的新型层压制品，其具有高拉伸强度，高抗压强度和良好的层间强度，适用于例如高性能结构。 飞机，航天器或其他结构或车辆。
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