公开(公告)号：US09856376B2

公开(公告)日：2018-01-02

申请号：US13528047

申请日：2012-06-20

申请人： Limin Sun ,  Dong Zhang ,  Frank W. Harris ,  Jiaokai Jing

发明人： Limin Sun ,  Dong Zhang ,  Frank W. Harris ,  Jiaokai Jing

IPC分类号： C08L77/10 ,  C08J5/18 ,  C08G69/32

CPC分类号： C08L77/10 ,  C08G69/32 ,  C08J5/18 ,  C08J2377/10 ,  Y10T428/2495 ,  Y10T428/269 ,  C08L63/00

摘要： Films with optical transmittance of >80% between 400 and 750 nm and with coefficient of thermal expansion less than 20 ppm/° C. are prepared from aromatic polyamides that are soluble in polar organic solvents yet have glass transition temperatures >300° C. The films are crosslinked in the solid state by heating at elevated temperatures for short periods of time in the presence of multifunctional epoxides. Surprisingly, the optical and thermal properties of the films do not change significantly during the curing process. The temperature required for the crosslinking process to take place can be reduced by the presence of a few free, pendant carboxyl groups along the polyamide backbones. The films are useful as flexible substrates for electronic displays and photovoltaic devices.

公开(公告)号：US09457496B2

公开(公告)日：2016-10-04

申请号：US13172564

申请日：2011-06-29

申请人： Limin Sun ,  Frank W. Harris ,  Jiaokai Jing ,  Haci B. Erdem ,  John D. Harvey ,  Dong Zhang

发明人： Limin Sun ,  Frank W. Harris ,  Jiaokai Jing ,  Haci B. Erdem ,  John D. Harvey ,  Dong Zhang

IPC分类号： C08G69/32 ,  B32B27/34 ,  B29C41/24 ,  C08J5/18 ,  C09D177/10 ,  B29K77/00

CPC分类号： C08J5/18 ,  B29C35/02 ,  B29C39/14 ,  B29C41/24 ,  B29K2077/00 ,  B29K2077/10 ,  B29K2995/0026 ,  B29L2007/008 ,  B29L2031/3475 ,  B32B17/064 ,  B32B27/34 ,  B32B2457/206 ,  C08G69/32 ,  C08J2377/10 ,  C09D177/10 ,  Y10T428/24975 ,  Y10T428/265

摘要： The present invention is directed toward transparent films prepared from soluble aromatic copolyamides with glass transition temperatures greater than 300 C. The copolyamides, which contain pendant carboxylic groups are solution cast into films using N,N-dimethylacetamide (DMAc), N-methyl-2-pyrrolidinone (NMP), or other polar solvents. The films are thermally cured at temperatures near the copolymer glass transition temperature. After curing, the polymer films display transmittances >80% from 400 to 750 nm, have coefficients of thermal expansion of less than 20 ppm, and are solvent resistant. The films are useful as flexible substrates for microelectronic devices.

摘要翻译： 本发明涉及由玻璃化转变温度大于300℃的可溶性芳族共聚酰胺制备的透明膜。使用N，N-二甲基乙酰胺（DMAc），N-甲基-2 - 吡咯烷酮（NMP）或其它极性溶剂。 膜在接近共聚物玻璃化转变温度的温度下热固化。 固化后，聚合物膜的透光率从400〜750nm显示> 80％，热膨胀系数小于20ppm，耐溶剂性。 这些膜可用作微电子器件的柔性基板。

公开(公告)号：US20140084499A1

公开(公告)日：2014-03-27

申请号：US14035363

申请日：2013-09-24

申请人： Frank W. HARRIS ,  Dong Zhang ,  Limin Sun ,  Jiaokai Jing ,  Toshimasa Eguchi ,  Hideo Umeda ,  Ritsuya Kawasaki ,  Toshihiko Katayama ,  Yusuke Inoue ,  Jun Okada ,  Fumihiro Maeda ,  Mizuho Inoue ,  Manabu Naito

发明人： Frank W. HARRIS ,  Dong Zhang ,  Limin Sun ,  Jiaokai Jing ,  Toshimasa Eguchi ,  Hideo Umeda ,  Ritsuya Kawasaki ,  Toshihiko Katayama ,  Yusuke Inoue ,  Jun Okada ,  Fumihiro Maeda ,  Mizuho Inoue ,  Manabu Naito

IPC分类号： C08L77/00 ,  B29C33/58 ,  C08L77/06

CPC分类号： C08L77/00 ,  B29C33/58 ,  C08G69/265 ,  C08G69/32 ,  C08L77/06 ,  C08L77/10

摘要： The present disclosure is directed toward solutions, transparent films prepared from aromatic copolyamides, and a display element, an optical element or an illumination element using the solutions and/or the films. The copolyamides, which contain pendant carboxylic groups are solution cast into films using cresol, xylene, N,N-dimethylacetamide (DMAc), N-methyl-2-pyrrolidinone (NMP), dimethylsulfoxide (DMSO), or butyl cellosolve or other solvents or mixed solvent which has more than two solvents. When the films are thermally cured at temperatures near the copolymer glass transition temperature, after curing, the polymer films display transmittances >80% from 400 to 750 nm, have coefficients of thermal expansion of less than 20 ppm, and are solvent resistant.

公开(公告)号：US11084906B2

公开(公告)日：2021-08-10

申请号：US13588414

申请日：2012-08-17

申请人： Limin Sun ,  Dong Zhang ,  Jiaokai Jing ,  Frank W. Harris

发明人： Limin Sun ,  Dong Zhang ,  Jiaokai Jing ,  Frank W. Harris

IPC分类号： C08L79/08 ,  C08G73/10 ,  B32B27/28 ,  C08J5/18 ,  C08J5/04 ,  B32B17/10

摘要： A class of solvent resistant, flexible copolyimide substrates having high optical transparency (>80% from 400 to 750 nm) that is retained after brief exposure to 300° C., near-zero birefringence (

公开(公告)号：US20140083624A1

公开(公告)日：2014-03-27

申请号：US14035446

申请日：2013-09-24

申请人： Frank W. Harris ,  Dong Zhang ,  Limin Sun ,  Jiaokai Jing ,  Toshimasa Eguchi ,  Hideo Umeda ,  Ritsuya Kawasaki ,  Toshihiko Katayama ,  Yusuke Inoue ,  Jun Okada ,  Fumihiro Maeda ,  Mizuho Inoue ,  Manabu Naito

发明人： Frank W. Harris ,  Dong Zhang ,  Limin Sun ,  Jiaokai Jing ,  Toshimasa Eguchi ,  Hideo Umeda ,  Ritsuya Kawasaki ,  Toshihiko Katayama ,  Yusuke Inoue ,  Jun Okada ,  Fumihiro Maeda ,  Mizuho Inoue ,  Manabu Naito

IPC分类号： H01L51/00 ,  B29D11/00

CPC分类号： H01L51/0097 ,  B29D11/0073 ,  C08G69/265 ,  C08G69/28 ,  C08G69/32 ,  C09D177/10 ,  G02B1/04 ,  Y10T156/11 ,  C08L77/10

摘要： The present disclosure is directed toward solutions, transparent films prepared from aromatic copolyamides, and a display element, an optical element or an illumination element using the solutions and/or the films. The copolyamides, which contain pendant carboxylic groups are solution cast into films using cresol, xylene, N,N-dimethylacetamide (DMAc), N-methyl-2-pyrrolidinone (NMP), dimethylsulfoxide (DMSO), or butyl cellosolve or other solvents or mixed solvent which has more than two solvents. When the films are thermally cured at temperatures near the copolymer glass transition temperature, after curing, the polymer films display transmittances >80% from 400 to 750 nm, have coefficients of thermal expansion of less than 20 ppm, and are solvent resistant.

摘要翻译： 本公开涉及溶液，由芳族共聚酰胺制备的透明膜，以及使用该溶液和/或膜的显示元件，光学元件或照明元件。 使用甲酚，二甲苯，N，N-二甲基乙酰胺（DMAc），N-甲基-2-吡咯烷酮（NMP），二甲基亚砜（DMSO）或丁基溶纤剂或其他溶剂将含有侧挂羧基的共聚酰胺溶液浇铸成膜， 具有两种以上溶剂的混合溶剂。 当膜在接近共聚物玻璃化转变温度的温度下热固化时，固化后，聚合物膜显示400〜750nm的透射率> 80％，热膨胀系数小于20ppm，耐溶剂性。

公开(公告)号：US20100208180A1

公开(公告)日：2010-08-19

申请号：US12686269

申请日：2010-01-12

申请人： Frank W. Harris ,  Limin Sun ,  Dong Zhang ,  Zhikuan Lu ,  John D. Harvey ,  Koji Kigawa

发明人： Frank W. Harris ,  Limin Sun ,  Dong Zhang ,  Zhikuan Lu ,  John D. Harvey ,  Koji Kigawa

IPC分类号： G02F1/13363 ,  G02B5/30

CPC分类号： G02B1/04 ,  B29D11/0074 ,  G02B5/3083

摘要： A non-stretched, negative birefringent copolyester film, which has been solution cast from toluene and/or MIBK and mixtures of these with other solvents on a substrate, and has a Δn⊥ of >0.02 and a DP between 0.90 and 1.10.

摘要翻译： 已经从甲苯和/或MIBK溶液中流延的非拉伸的负双折射共聚酯膜，以及它们与其它溶剂的混合物在基材上，并且具有> 0.02和约0.90至1.10的DP。

公开(公告)号：US20090197019A1

公开(公告)日：2009-08-06

申请号：US11867372

申请日：2007-10-04

申请人： Frank W. Harris ,  Limin Sun ,  Dong Zhang ,  Stephen Z. D. Cheng

发明人： Frank W. Harris ,  Limin Sun ,  Dong Zhang ,  Stephen Z. D. Cheng

IPC分类号： C09K19/02 ,  C08G69/32 ,  B32B27/08

CPC分类号： C08G73/1039 ,  C08G73/1042 ,  C08G73/1067 ,  C08J5/18 ,  C08J2379/08 ,  G02B5/3083 ,  G02F1/133634 ,  Y10T428/1027 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/31721

摘要： A negative birefringence film prepared from a poly(aryletherimide) which is the reaction product of a dianhydride and a diamine, where the dianhydride is BisADA, ODPA, BPEDA, BPQDA, BPDA, or 6FDA, alone or a mixture with one or more of: BPDA, 6FDA, BisADA, Bis-AF-DA, BPQDA, BPEDA, and ODPA; and where the diamine is 4,4′-diaminophenyl ether, 2-trifluoromethyl-4,4′-diaminophenyl ether, 2-trifluoromethyl-2′-methyl-4,4′-diaminophenyl ether, 1,4-bis(4-aminophenoxy)benzene, 4,4′-bis(4-aminophenoxy)biphenyl, 4,4′-bis(3-aminophenoxy)biphenyl, 4,4′-bis(4-aminophenoxy)terphenyl, 4,4′-bis(3-aminophenoxy)terphenyl, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]1,1,1,3,3,3-hexafluoropropane, 1,4-bis(4-amino-2-trifluoromethylphenoxy)benzene, 2,2′-bis(trifluoromethyl)-4,4′-diaminophenyl ether (6FODA), 4,4′-bis(4-amino-2-trifluoromethylphenoxy)biphenyl (6FOBDA), 4,4′-bis(4-amino-2-trifluoromethylphenoxy)-3,3′,5,5′-tetramethylbiphenyl, 4,4′-bis(4-amino-2-trifluoromethylphenoxy)-3,3′,5,5′-tetra(tert-butyl)biphenyl, 4,4′-bis(3-amino-trifluoromethylphenoxy)biphenyl, 4,4′-bis(4-amino-2-trifluoromethylphenoxy)terphenyl, 2,2-bis[4-(4-amino-2-trifluoromethylphenoxy)-phenyl]propane, 2,2-bis[4-(4-amino-2-trifluoromethylphenoxy)-phenyl]1,1,1,3,3,3-hexafluoropropane, 1,4-bis(2-trifluoromethyl-4-aminophenoxy)-2,5-di(t-butyl)benzene (BTBDA), 3,3′-dimethyl-4,4′-diamino biphenyl (OTOL), 1,4-bis(2-trifluoromethyl-4-aminophenoxy)-2-t-butylbenzene, or mixtures thereof and wherein when a mixture of dianhydrides is present, they are present in a molar amount of between 99 to 1 (99:1) and 1 to 99 (1:99), and the film has a negative birefringence greater than 0.01, at a thickness of less than 15 μm, when the poly(aryletherimide) is solution cast or coated onto a substrate.

公开(公告)号：US20070014938A1

公开(公告)日：2007-01-18

申请号：US11488929

申请日：2006-07-18

申请人： Frank Harris ,  Limin Sun ,  Dong Zhang ,  Stephen Cheng

发明人： Frank Harris ,  Limin Sun ,  Dong Zhang ,  Stephen Cheng

IPC分类号： C09K19/00

CPC分类号： C08G73/1039 ,  C08G73/1042 ,  C08G73/1067 ,  C08J5/18 ,  C08J2379/08 ,  G02B5/3083 ,  G02F1/133634 ,  Y10T428/1027 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/31721

摘要： A class of soluble poly(aryletherimides) (PAEIs) having flexible backbones, useful in the manufacture of polymeric optical films are disclosed. The poly(aryletherimides) are dissolved in organic solvents, such as ketones and ketone solvent mixtures and coated on variety of substrates such as triacetyl cellulose (TAC), to form clear thin-layer films which display negative birefringence. The thin films can serve as compensation layers in liquid crystal displays (LCDs), and can be combined with other types of optical films, such as polarizers, brightness enhancement films, or other compensation films, to from multi-layered films that are especially useful in the manufacture of LCDs.

摘要翻译： 公开了一类可用于制造聚合物光学薄膜的可溶性聚（芳基酰亚胺）（PAEI）（PAEI）），其具有柔性主链。 将聚（芳基酰亚胺）溶于有机溶剂如酮和酮溶剂混合物中并涂覆在各种基材如三乙酰纤维素（TAC）上，以形成显示出负双折射的透明薄膜。 薄膜可以用作液晶显示器（LCD）中的补偿层，并且可以与其他类型的光学膜（例如偏振器，亮度增强膜或其他补偿膜）组合到特别有用的多层膜 在LCD的制造中。

公开(公告)号：US07820253B2

公开(公告)日：2010-10-26

申请号：US11867372

申请日：2007-10-04

申请人： Frank Harris ,  Limin Sun ,  Dong Zhang ,  Stephen Z. D. Cheng

发明人： Frank Harris ,  Limin Sun ,  Dong Zhang ,  Stephen Z. D. Cheng

IPC分类号： G02F1/13363

CPC分类号： C08G73/1039 ,  C08G73/1042 ,  C08G73/1067 ,  C08J5/18 ,  C08J2379/08 ,  G02B5/3083 ,  G02F1/133634 ,  Y10T428/1027 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/31721

摘要： A negative birefringence film prepared from a poly(aryletherimide) which is the reaction product of a dianhydride and a diamine, where the dianhydride is 4,4′-[4,4′-(p-phenyleneoxy)isopropylidene]bis(phthalic anhydride) (BisADA), bis(3,4-dicarboxyphenyl)ether dianhydride (ODPA), 4,4′-bis(3,4-dicarboxyphenoxy)biphenyl dianhydride (BPEDA), 1,4-bis(3,4-dicarboxyphenyloxy)phenyl dianhydride (BPQDA), 3,3′,4,4′-tetracarboxylicbiphenyl dianhydride (BPDA), or 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride (6FDA), alone or a mixture with one or more of: 3,3′,4,4′-tetracarboxylicbiphenyl dianhydride (BPDA), 2,2-bis(3,4-dicarboxyphenyl)-1,1,1,3,3,3-hexafluoropropane dianhydride (6FDA); and where the diamine is 1,4-bis(2-trifluoromethyl-4-aminophenoxy)-2,5-di(t-butyl)benzene (BTBDA), 3,3′-dimethyl-4,4′-diamino biphenyl (OTOL), or mixtures thereof and wherein when a mixture of dianhydrides is present, they are present in a molar amount of between 99 to 1 (99:1) and 1 to 99 (1:99), and the film has a negative birefringence greater than 0.01, at a thickness of less than 15 μm, when the poly(aryletherimide) is solution cast or coated onto a substrate.

摘要翻译： 由二酐与二酐反应产生的聚（芳基醚酰亚胺）制备的负双折射膜，其中二酐是4,4' - [4,4' - （对亚苯基氧）异亚丙基]双（邻苯二甲酸酐） （BisADA），双（3,4-二羧基苯基）醚二酐（ODPA），4,4'-双（3,4-二羧基苯氧基）联苯二酐（BPEDA），1,4-双（3,4-二羧基苯氧基）苯基 二酐（BPQDA），3,3'，4,4'-四羧基联苯二酐（BPDA）或2,2-双（3,4-二羧基苯基）-1,1,1,3,3,3-六氟丙烷二酐（ 6FDA），单独的或与以下的一种或多种的混合物：3,3'，4,4'-四羧基联苯二酐（BPDA），2,2-双（3,4-二羧基苯基）-1,1,1,3， 3,3-六氟丙烷二酐（6FDA）; 其中二胺为1,4-双（2-三氟甲基-4-氨基苯氧基）-2,5-二（叔丁基）苯（BTBDA），3,3'-二甲基-4,4'-二氨基联苯（ OTOL）或其混合物，并且其中当存在二酸酐的混合物时，其存在的摩尔量为99至1（99:1）至1至99（1:99），并且该膜具有负双折射率 当聚（芳基醚酰亚胺）溶液浇铸或涂覆在基底上时，其厚度小于15μm。

公开(公告)号：US07438957B2

公开(公告)日：2008-10-21

申请号：US11488929

申请日：2006-07-18

申请人： Frank Harris ,  Limin Sun ,  Dong Zhang ,  Stephen Z. D. Cheng

发明人： Frank Harris ,  Limin Sun ,  Dong Zhang ,  Stephen Z. D. Cheng

IPC分类号： G02F1/13363

CPC分类号： C08G73/1039 ,  C08G73/1042 ,  C08G73/1067 ,  C08J5/18 ,  C08J2379/08 ,  G02B5/3083 ,  G02F1/133634 ,  Y10T428/1027 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/31721

摘要： A class of soluble poly(aryletherimides) (PAEIs) having flexible backbones, useful in the manufacture of polymeric optical films are disclosed. The poly(aryletherimides) are dissolved in organic solvents, such as ketones and ketone solvent mixtures and coated on variety of substrates such as triacetyl cellulose (TAC), to form clear thin-layer films which display negative birefringence. The thin films can serve as compensation layers in liquid crystal displays (LCDs), and can be combined with other types of optical films, such as polarizers, brightness enhancement films, or other compensation films, to from multi-layered films that are especially useful in the manufacture of LCDs.

摘要翻译： 公开了一类可用于制造聚合物光学薄膜的可溶性聚（芳基酰亚胺）（PAEI）（PAEI）），其具有柔性主链。 将聚（芳基酰亚胺）溶于有机溶剂如酮和酮溶剂混合物中并涂覆在各种基材如三乙酰纤维素（TAC）上，以形成显示出负双折射的透明薄膜。 薄膜可以用作液晶显示器（LCD）中的补偿层，并且可以与其他类型的光学膜（例如偏振器，亮度增强膜或其他补偿膜）组合到特别有用的多层膜 在LCD的制造中。