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    Compositions of 1-butene based polymers
    7.
    发明授权
    Compositions of 1-butene based polymers 失效
    1-丁烯基聚合物的组合物

    公开(公告)号：US08097679B2

    公开(公告)日：2012-01-17

    申请号：US12735953

    申请日：2009-02-26

    申请人： Luigi Resconi ,  Davide Balboni

    发明人： Luigi Resconi ,  Davide Balboni

    IPC分类号： C08F8/00 ,  C08L23/00

    CPC分类号： C08L23/20 ,  C08L2205/02 ,  C08L2666/06

    摘要： A 1-butene polymer composition comprising: a) from 10% to 90% by weight of an isotactic 1-butene polymer having the following features: i) isotactic pentad (mmmm) measured by 13C-NMR, higher than 90%; ii) melting point (TmII) higher than 90° C.; and iii) intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135° C. comprised between 0.5 dl/g and 5.0 dl/g. b) from 90% to 10% by weight of a copolymer of 1-butene and at least a C8-C12 alpha-olefin derived units, containing from 0% to 10% by mole of propylene or pentene derived units, and/or containing from 0% to 5% by mole of ethylene derived units having a content of C8-C12 alpha-olefin derived units higher than 4.0% by mol and lower than 20.0% by mol; endowed with the following features: i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135° C. comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C8-C12 alpha-olefin content fulfil the following relationship: TmI

    摘要翻译： 1-丁烯聚合物组合物，其包含：a）10重量％至90重量％的具有以下特征的全同立构1-丁烯聚合物：i）通过13 C-NMR测量的全同立构五单元组（mmmm）高于90％; ii）高于90℃的熔点（TmII）。 和iii）在135℃下在四氢化萘（THN）中测量的特性粘度（IV）为0.5dl / g至5.0dl / g。 b）90重量％至10重量％的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元的共聚物，其含有0至10摩尔％的丙烯或戊烯衍生的单元，和/或含 来自具有高于4.0摩尔％且低于20.0摩尔％的C 8 -C 12α-烯烃衍生单元的乙烯衍生单元的0摩尔％至5摩尔％ 具有以下特征：i）等于或等于90％的全同立构五单位mmmm; 低于4的五单元组（mmrr + mrrm）和不能通过C NMR检测的五元组。 ii）在135℃下在四氢化萘中测得的特性粘度（Ⅳ）为0.8至5.0dL / g; iii）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI <130×C-0.3其中C是C8-C12α-烯烃衍生单元的摩尔含量，TmI是 第一次熔融转变中最高的熔融峰; 否则熔点Tm1是不可检测的。

    Preparation of silicon-bridged metallocene compounds
    8.
    发明申请
    Preparation of silicon-bridged metallocene compounds 有权
    硅桥联金属茂化合物的制备

    公开(公告)号：US20050080244A1

    公开(公告)日：2005-04-14

    申请号：US10500542

    申请日：2002-12-30

    申请人： Luigi Resconi ,  Simona Guidotti ,  Davide Balboni

    发明人： Luigi Resconi ,  Simona Guidotti ,  Davide Balboni

    IPC分类号： C07F7/08 ,  C07F7/00 ,  C07F17/00 ,  C07F5/00

    CPC分类号： C07F17/00 ,  Y10S526/943

    摘要： A process for obtaining silicon-bridged metallocene compounds comprising the following steps: a) reacting, at a temperature of between −10° C. and 70° C., the starting ligand with about 2 molar equivalents of an alkylating agent; b) after the reaction has been completed, adding at least 2 molar equivalents of an alkylating agent that can be also different from the first one; and c) reacting, at a temperature of between −10° C. and 70° C., the product obtained from step b) with at least 1 molar equivalent of a compound of formula ML′s, wherein M is a transition metal; s is an integer corresponding to the oxidation state of the metal; and L′ is an halogen atom selected from chlorine, bromine and iodine.

    摘要翻译： 一种获得硅桥连茂金属化合物的方法，包括以下步骤：a）在-10℃至70℃的温度下，将起始配体与约2摩尔当量的烷基化剂反应; b）反应完成后，加入至少2摩尔当量的也可以不同于第一种烷基化剂的烷基化剂; 和c）在-10℃至70℃的温度下，将从步骤b）获得的产物与至少1摩尔当量的式ML'化合物反应，其中M是过渡金属; s是与金属的氧化态对应的整数; L'是选自氯，溴和碘的卤素原子。

    COMPOSITIONS OF 1-BUTENE BASED POLYMERS
    10.
    发明申请
    COMPOSITIONS OF 1-BUTENE BASED POLYMERS 失效
    基于1-BOTENE的聚合物的组合物

    公开(公告)号：US20110003938A1

    公开(公告)日：2011-01-06

    申请号：US12735953

    申请日：2009-02-26

    申请人： Luigi Resconi ,  Davide Balboni

    发明人： Luigi Resconi ,  Davide Balboni

    IPC分类号： C08L23/20

    CPC分类号： C08L23/20 ,  C08L2205/02 ,  C08L2666/06

    摘要： A 1-butene polymer composition comprising: a) from 10% to 90% by weight of an isotactic 1-butene polymer having the following features: i) isotactic pentad (mmmm) measured by 13C-NMR, higher than 90%; ii) melting point (TmII) higher than 90° C.; and iii) intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135° C. comprised between 0.5 dl/g and 5.0 dl/g. b) from 90% to 10% by weight of a copolymer of 1-butene and at least a C8-C12 alpha-olefin derived units, containing from 0% to 10% by mole of propylene or pentene derived units, and/or containing from 0% to 5% by mole of ethylene derived units having a content of C8-C12 alpha-olefin derived units higher than 4.0% by mol and lower than 20.0% by mol; endowed with the following features: i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135° C. comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C8-C12 alpha-olefin content fulfil the following relationship: TmI

    摘要翻译： 1-丁烯聚合物组合物，其包含：a）10重量％至90重量％的具有以下特征的全同立构1-丁烯聚合物：i）通过13 C-NMR测量的全同立构五单元组（mmmm）高于90％; ii）高于90℃的熔点（TmII）。 和iii）在135℃下在四氢化萘（THN）中测量的特性粘度（IV）为0.5dl / g至5.0dl / g。 b）90重量％至10重量％的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元的共聚物，其含有0至10摩尔％的丙烯或戊烯衍生的单元，和/或含 来自具有高于4.0摩尔％且低于20.0摩尔％的C 8 -C 12α-烯烃衍生单元的乙烯衍生单元的0摩尔％至5摩尔％ 具有以下特征：i）等于或等于90％的全同立构五单位mmmm; 低于4的五单元组（mmrr + mrrm）和不能通过C NMR检测的五元组。 ii）在135℃下在四氢化萘中测得的特性粘度（Ⅳ）为0.8至5.0dL / g; iii）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI <130×C-0.3其中C是C8-C12α-烯烃衍生单元的摩尔含量，TmI是 第一次熔融转变中最高的熔融峰; 否则熔点TmI不可检测;