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    Supported catalysts for the polymerization of olefins
    4.
    发明授权
    Supported catalysts for the polymerization of olefins 失效
    用于烯烃聚合的负载催化剂

    公开(公告)号：US06774194B2

    公开(公告)日：2004-08-10

    申请号：US10184679

    申请日：2002-06-26

    申请人： Enrico Albizzati ,  Tiziano Dall'Occo ,  Luigi Resconi ,  Fabrizio Piemontesi

    发明人： Enrico Albizzati ,  Tiziano Dall'Occo ,  Luigi Resconi ,  Fabrizio Piemontesi

    IPC分类号： C08F402

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/904 ,  Y10S526/943 ,  C08F4/602 ,  C08F4/63916 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/20 ,  C08F210/08

    摘要： Supported catalysts for the polymerization of olefins comprise the following components: (A) a porous organic support functionalised with groups having active hydrogen atoms; (B) an organo-metallic compound of aluminium containing heteroatoms selected from oxygen, nitrogen and sulphur; and (C) a compound of a transition metal selected from those of groups IVb, Vb or VIb of the Periodic Table of the Elements, containing ligands of the cyclopentadienyl type. These supported catalysts, obtainable in the form of spherical particles, can be used in the polymerization reaction of olefins either in liquid or in gas phase, thus producing polymers endowed with a controlled morphology and with a high bulk density.

    摘要翻译： 用于烯烃聚合的载体催化剂包括以下组分：（A）用具有活性氢原子的基团官能化的多孔有机载体;（B）含有选自氧，氮和硫的杂原子的铝的有机金属化合物; 和（C）选自元素周期表IVb，Vb或VIb族的过渡金属的化合物，其含有环戊二烯基型配体。可以使用可以球形颗粒形式获得的这些负载型催化剂 在烯烃在液相或气相中的聚合反应中，从而产生具有受控形态和高体积密度的聚合物。

    Supported catalysts for the polymerization of olefins
    7.
    发明授权
    Supported catalysts for the polymerization of olefins 失效
    用于烯烃聚合的负载催化剂

    公开(公告)号：US06423660B1

    公开(公告)日：2002-07-23

    申请号：US09004867

    申请日：1998-01-09

    申请人： Enrico Albizzati ,  Tiziano Dall'Occo ,  Luigi Resconi ,  Fabrizio Piemontesi

    发明人： Enrico Albizzati ,  Tiziano Dall'Occo ,  Luigi Resconi ,  Fabrizio Piemontesi

    IPC分类号： C08F444

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/904 ,  Y10S526/943 ,  C08F4/602 ,  C08F4/63916 ,  C08F2500/17 ,  C08F2500/18 ,  C08F2500/20 ,  C08F210/08

    摘要： Supported catalysts for the polymerization of olefins comprise the following components: (A) a porous organic support functionalised with groups having active hydrogen atoms; (B) an organo-metallic compound of aluminium containing heteroatoms selected from oxygen, nitrogen and sulphur; and (C) a compound of a transition metal selected from those of groups IVb, Vb or VIb of the Periodic Table of the Elements, containing ligands of the cyclopentadienyl type. These supported catalysts, obtainable in the form of spherical particles, can be used in the polymerization reaction of olefins either in liquid or in gas phase, thus producing polymers endowed with a controlled morphology and with a high bulk density.

    摘要翻译： 用于烯烃聚合的载体催化剂包括以下组分：（A）用具有活性氢原子的基团官能化的多孔有机载体;（B）含有选自氧，氮和硫的杂原子的铝的有机金属化合物; 和（C）选自元素周期表IVb，Vb或VIb族中的过渡金属的化合物，其含有环戊二烯基型配体。可以使用可以球形颗粒形式获得的这些负载型催化剂 在烯烃在液相或气相中的聚合反应中，从而产生具有受控形态和高体积密度的聚合物。

    Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins
    9.
    发明授权
    Metallocene compounds, process for their preparation, and their use in catalysts for the polymerization of olefins 失效
    茂金属化合物，其制备方法及其在烯烃聚合催化剂中的应用

    公开(公告)号：US06051728A

    公开(公告)日：2000-04-18

    申请号：US599483

    申请日：1996-01-23

    申请人： Luigi Resconi ,  Fabrizio Piemontesi ,  Ilya E. Nifant'ev ,  Pavel V. Ivchenko

    发明人： Luigi Resconi ,  Fabrizio Piemontesi ,  Ilya E. Nifant'ev ,  Pavel V. Ivchenko

    IPC分类号： C07F7/00 ,  C07F17/00 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C07F9/00 ,  C07F11/00

    CPC分类号： C08F10/06 ,  C07F17/00 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

    摘要： A class of metallocene compounds having two substituted cyclopentadienyl rings bridged by an alkylidene group wherein the cyclopentadienyl groups can be indenyl groups. The metallocene compounds have the following structures: ##STR1## The metallocenes are characterized by three principal features: (i) the cyclopentadienyl groups are substituted at the 3-position with a substituent other than hydrogen, while R.sup.2 in the 2-position bears a hydrogen (formula (I)) or is part of a condensed benzene ring (formula (II)); (ii) the bridge is a substituted-methylene bridge, i.e. a methylene group bearing at least one substituent other than hydrogen (R.sup.6 is always different from hydrogen); and (iii) the cyclopentadienyl groups are identically substituted (page 2, line 23). These metallocene compounds can be suitably used as catalyst components for the polymerization of olefins. In particular, by polymerizing propylene in the presence of a catalyst based on these metallocene compounds, polymers having very high isotactic indexes, high molecular weights, and narrow molecular weight distributions can be obtained in high yields. A process for preparing the metallocenes from the corresponding organic ligands is also disclosed.

    摘要翻译： 一类具有由亚烷基桥连的取代环戊二烯基环的茂金属化合物，其中环戊二烯基可以是茚基。 茂金属化合物具有以下结构：金属茂的特征在于三个主要特征：（i）环戊二烯基在3位被氢以外的取代基取代，而2-位的R2带有氢（式（式 I））或是稠合苯环的一部分（式（II））; （ii）桥是取代的亚甲基桥，即具有除氢之外的至少一个取代基的亚甲基（R6总是不同于氢）; 和（iii）环戊二烯基相同取代（第2页，第23行）。 这些茂金属化合物可以适合用作烯烃聚合的催化剂组分。 特别地，通过在基于这些茂金属化合物的催化剂的存在下聚合丙烯，可以高产率获得具有非常高的全同立构指数，高分子量和窄分子量分布的聚合物。 还公开了从相应的有机配体制备金属茂的方法。