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    Polystyrene Nanocomposites for Blow Molding Applications
    1.
    发明申请
    Polystyrene Nanocomposites for Blow Molding Applications 有权
    聚苯乙烯纳米复合材料的吹塑应用

    公开(公告)号：US20110020571A1

    公开(公告)日：2011-01-27

    申请号：US12508598

    申请日：2009-07-24

    申请人： Luyi Sun ,  Jose Sosa ,  Juan Aguirre ,  Mark Leland ,  Ted Harris

    发明人： Luyi Sun ,  Jose Sosa ,  Juan Aguirre ,  Mark Leland ,  Ted Harris

    IPC分类号： B32B1/00 ,  B29C49/06

    CPC分类号： C08K9/04 ,  B29C49/0005 ,  B29C49/06 ,  B29D22/003 ,  B29K2025/00 ,  B29K2105/162 ,  Y10T428/1352 ,  Y10T428/1397

    摘要： Disclosed is a polystyrene based polymer/layered compound nanocomposite for injection blow molding or injection stretch blow molding of articles. The nanocomposite can reduce shrinkage and warpage to the preform during the reheating process compared to neat polystyrene. The incorporation of layered compounds can increase the processability of PS preforms, help improve heating efficiency, and improve bottle mechanical properties. The layered compound can be treated with chemicals or compounds having an affinity with the styrene monomer or polystyrene, thus producing a treated layered compound having an affinity with the styrene monomer or polystyrene. The monomer and the layered compound can be combined prior to polymerization. The polymer and layered compound can be combined by solution mixing in a solvent. The layered compound can also be incorporated into the mixture by compounding a polymer product with the layered compound, or the combination of any of the above three approaches

    摘要翻译： 公开了用于注射吹塑或注射拉伸吹塑成型的聚苯乙烯基聚合物/层状复合纳米复合材料。 与纯聚苯乙烯相比，纳米复合材料可以在再加热过程中减少预成型件的收缩和翘曲。 结合层状化合物可以增加PS预制件的加工性能，有助于提高加热效率，并提高瓶子的机械性能。 层状化合物可以用与苯乙烯单体或聚苯乙烯具有亲和性的化学品或化合物处理，从而产生与苯乙烯单体或聚苯乙烯具有亲和性的经处理的层状化合物。 单体和层状化合物可以在聚合之前进行组合。 聚合物和层状化合物可以通过在溶剂中的溶液混合来组合。 也可以通过将聚合物与层状化合物混合，或者将上述三种方法中的任一种

    Polystyrene nanocomposites for blow molding applications
    2.
    发明授权
    Polystyrene nanocomposites for blow molding applications 有权
    用于吹塑应用的聚苯乙烯纳米复合材料

    公开(公告)号：US08697208B2

    公开(公告)日：2014-04-15

    申请号：US12508598

    申请日：2009-07-24

    申请人： Luyi Sun ,  Jose Sosa ,  Juan Aguirre ,  Mark Leland ,  Theodore Harris

    发明人： Luyi Sun ,  Jose Sosa ,  Juan Aguirre ,  Mark Leland ,  Theodore Harris

    IPC分类号： B32B1/02 ,  C08K3/34

    CPC分类号： C08K9/04 ,  B29C49/0005 ,  B29C49/06 ,  B29D22/003 ,  B29K2025/00 ,  B29K2105/162 ,  Y10T428/1352 ,  Y10T428/1397

    摘要： Disclosed is a polystyrene based polymer/layered compound nanocomposite for injection blow molding or injection stretch blow molding of articles. The nanocomposite can reduce shrinkage and warpage to the preform during the reheating process compared to neat polystyrene. The incorporation of layered compounds can increase the processability of PS preforms, help improve heating efficiency, and improve bottle mechanical properties. The layered compound can be treated with chemicals or compounds having an affinity with the styrene monomer or polystyrene, thus producing a treated layered compound having an affinity with the styrene monomer or polystyrene. The monomer and the layered compound can be combined prior to polymerization. The polymer and layered compound can be combined by solution mixing in a solvent. The layered compound can also be incorporated into the mixture by compounding a polymer product with the layered compound, or the combination of any of the above three approaches.

    摘要翻译： 公开了用于注射吹塑或注射拉伸吹塑成型的聚苯乙烯基聚合物/层状复合纳米复合材料。 与纯聚苯乙烯相比，纳米复合材料可以在再加热过程中减少预成型件的收缩和翘曲。 结合层状化合物可以增加PS预制件的加工性能，有助于提高加热效率，并提高瓶子的机械性能。 层状化合物可以用与苯乙烯单体或聚苯乙烯具有亲和性的化学品或化合物处理，从而产生与苯乙烯单体或聚苯乙烯具有亲和性的经处理的层状化合物。 单体和层状化合物可以在聚合之前进行组合。 聚合物和层状化合物可以通过在溶剂中的溶液混合来组合。 层叠的化合物也可以通过将聚合物产物与层状化合物混合，或通过上述三种方法中的任一种的组合将其掺入混合物中。

    Expandable Polystyrene and Methods of Forming the Same
    7.
    发明申请
    Expandable Polystyrene and Methods of Forming the Same 审中-公开
    可膨胀聚苯乙烯及其形成方法

    公开(公告)号：US20110306689A1

    公开(公告)日：2011-12-15

    申请号：US12796747

    申请日：2010-06-09

    申请人： Joe Shuler ,  Jon Tippet ,  John Gaustad ,  Jose Sosa

    发明人： Joe Shuler ,  Jon Tippet ,  John Gaustad ,  Jose Sosa

    IPC分类号： C08J9/16 ,  C08J9/228

    CPC分类号： C08J9/122 ,  C08J2201/032 ,  C08J2203/06 ,  C08J2300/30 ,  C08J2325/06

    摘要： Expanded polystyrene, foamed articles and methods of making the same are described herein. The expanded polystyrene generally includes polystyrene selected from expandable polystyrene and extrusion polystyrene, the polystyrene exhibiting a molecular weight of from about 130,000 Daltons to about 220,000 Daltons; a melt flow index of from about 20 to about 30 and a density of from about 0.1 lb/ft3 to about 10 lb/ft3; and wherein the expanded polystyrene exhibits a density of from about 0.1 lb/ft3 to about 10 lb/ft3.

    摘要翻译： 膨胀聚苯乙烯，发泡制品及其制备方法在本文中描述。 发泡聚苯乙烯通常包括选自可发性聚苯乙烯和挤出聚苯乙烯的聚苯乙烯，聚苯乙烯的分子量为约130,000道尔顿至约220,000道尔顿; 熔体流动指数为约20至约30，密度为约0.1lb / ft 3至约10lb / ft 3; 并且其中所述发泡聚苯乙烯的密度为约0.1lb / ft 3至约10lb / ft 3。

    Production of polystyrene for foaming applications using a combination of peroxide initiators
    8.
    发明申请
    Production of polystyrene for foaming applications using a combination of peroxide initiators 审中-公开
    使用过氧化物引发剂的组合生产用于发泡应用的聚苯乙烯

    公开(公告)号：US20070135529A1

    公开(公告)日：2007-06-14

    申请号：US11654425

    申请日：2007-01-17

    申请人： Douglas Berti ,  Jose Sosa ,  Jay Reimers

    发明人： Douglas Berti ,  Jose Sosa ,  Jay Reimers

    IPC分类号： B29C44/34

    CPC分类号： C08F297/04 ,  C08F12/08 ,  C08F257/02 ,  C08F236/06 ,  C08F2/38 ,  C08F4/36 ,  C08F4/38

    摘要： It has been discovered that improved polystyrene products may be obtained by polymerizing styrene in the presence of at least one multifunctional initiator that is trifunctional or tetrafunctional and at least one lower functionality initiator that is difunctional or monofunctional. These polymers may have increased Mz, increased MFI, and increased MWD. Optionally the resin may include at least one chain transfer agent, at least one cross-linking agent and/or a styrene-conjugated diene-styrene block copolymer. The presence of the multifunctional initiator tends to cause more branched structures in the polystyrene.

    摘要翻译： 已经发现，通过在至少一种具有三官能或四官能的多官能引发剂和至少一种作为二官能或单官能团的低官能度引发剂的存在下聚合苯乙烯，可以获得改进的聚苯乙烯产物。 这些聚合物可能具有增加的Mz，增加的MFI和增加的MWD。 任选地，树脂可以包括至少一种链转移剂，至少一种交联剂和/或苯乙烯 - 共轭二烯 - 苯乙烯嵌段共聚物。 多官能引发剂的存在倾向于在聚苯乙烯中引起更多的支化结构。

    Low temperature initiators for improving the rubber phase volume of HIPS formulations
    9.
    发明申请
    Low temperature initiators for improving the rubber phase volume of HIPS formulations 有权
    用于改善HIPS配方橡胶相体积的低温引发剂

    公开(公告)号：US20070100079A1

    公开(公告)日：2007-05-03

    申请号：US11262641

    申请日：2005-10-31

    申请人： Jose Sosa ,  Shazia Ullah

    发明人： Jose Sosa ,  Shazia Ullah

    IPC分类号： C08F263/00

    CPC分类号： C08F279/02 ,  C08L51/04 ,  C08L2666/02

    摘要： Peroxide initiators are disclosed that can be used at lower temperatures during HIPS production. Enhanced formation of graft polymers between polystyrene and polybutadiene (rubber) can be accomplished by using these lower temperature peroxide initiators that have a 1 hour half-life period at one or more temperatures from 95° C. to less than 111° C. during the pre-inversion stage. “Higher” temperature initiators are used during and/or after inversion. The use of such “low” temperature initiators improves polymerization rates and grafting values, while reducing the swell index and the amount of rubber used, thereby producing improved HIPS more rapidly and at a lower cost. Also disclosed are HIPS compositions and products produced by such “low” temperature initiators as well as a method of producing improved HIPS.

    摘要翻译： 公开了可以在HIPS生产期间在较低温度下使用的过氧化物引发剂。 在聚苯乙烯和聚丁二烯（橡胶）之间增强的接枝聚合物的形成可以通过使用这些低温过氧化物引发剂来实现，该引发剂在一个或多个温度从95℃到小于111℃的时间内具有1小时的半衰期 预转换阶段。 在反转期间和/或之后使用“较高”的温度引发剂。 使用这种“低”温度引发剂提高了聚合速率和接枝值，同时降低了溶胀指数和使用的橡胶的量，从而以更低的成本更快速地生产改进的HIPS。 还公开了由这种“低”温度引发剂生产的HIPS组合物和产物以及生产改进的HIPS的方法。

    BRANCHED IONOMERS
    10.
    发明申请
    BRANCHED IONOMERS 有权
    分支机构

    公开(公告)号：US20080051540A1

    公开(公告)日：2008-02-28

    申请号：US11932053

    申请日：2007-10-31

    申请人： Jay Reimers ,  Jose Sosa

    发明人： Jay Reimers ,  Jose Sosa

    IPC分类号： C08F4/32

    CPC分类号： C08F212/08 ,  C08F220/06 ,  C08K5/0091 ,  C08L35/00

    摘要： A branched aromatic ionomer is prepared by co-polymerizing a first monomer having an aromatic moiety and an unsaturated alkyl moiety and a second monomer having an ionic moiety and at least one unsaturated moiety. The ionic moiety may have a cationic group having a valence of +1 or greater. Styrene is among the useful first monomers and sodium methacrylate and zinc dimethacrylate are among the useful second monomers. The branched aromatic ionomers may be used to prepare articles including foamed polystyrene and microwave save dishes and utensils.

    摘要翻译： 通过共聚具有芳族部分和不饱和烷基部分的第一单体和具有离子部分和至少一个不饱和部分的第二单体来制备支化芳族离聚物。 离子部分可以具有价数为+1或更大的阳离子基团。 苯乙烯是有用的第一单体，甲基丙烯酸钠和二甲基丙烯酸锌是有用的第二单体。 支链芳族离聚物可用于制备包括发泡聚苯乙烯和微波炉保存菜肴和器具的制品。