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公开(公告)号：US5015796A
公开(公告)日：1991-05-14
申请号：US450799
申请日：1989-12-14
CPC分类号： C07C2/864 , B01J29/061 , C07C2529/06
摘要： This invention relates to a process for the alkylation of methylbenzene to produce ethylbenzene and styrene. In this process methylbenzene and methanol are contacted with a catalyst formed from a zeolite and an alkali(ne earth) metal compound wherein said compound is selected from alkaline earth metal compound and a mixture of alkaline earth metal compound and alkali metal compound and wherein the sum of the amount of the alkali(ne earth) metal in the compound plus any metal cation exchanged into the zeolite is in excess of that required to provide a fully metal cation-exchanged zeolite.
摘要翻译： 本发明涉及甲苯烷基化生产乙苯和苯乙烯的方法。 在该方法中，甲苯和甲醇与由沸石和碱（ne earth）金属化合物形成的催化剂接触，其中所述化合物选自碱土金属化合物和碱土金属化合物与碱金属化合物的混合物，其中总和 化合物中加上任何金属阳离子交换成沸石的碱金属（碱土金属）的量超过提供完全金属阳离子交换的沸石所需的量。
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公开(公告)号：US5194244A
公开(公告)日：1993-03-16
申请号：US354586
申请日：1989-05-22
CPC分类号： C07C29/50 , B01J29/061 , C07C45/33 , C07C2529/04
摘要： This invention relates to basic compositions comprising a zeolite and an alkali metal compound wherein the sum of the amount of the alkali metal in the compound plus any metal cation exchanged into the zeolite is in excess of that required to provide a fully metal cation-exchanged zeolite. This invention further relates to methods for preparing the instant compositions. In a preferred embodiment the instant compositions are prepared by impregnating a zeolite with a solution of an alkali metal salt wherein said alkali metal impregnated in the zeolite is in excess of that required to exchange out the ion exchangable sites present in the zeolite, drying the resultant impregnated material and then calcining the resultant composition.
摘要翻译： 本发明涉及包含沸石和碱金属化合物的碱性组合物，其中化合物中的碱金属的量加上交换成沸石的任何金属阳离子的总和超过提供完全金属阳离子交换的沸石所需的量 。 本发明还涉及制备本发明组合物的方法。 在优选的实施方案中，本发明的组合物通过用碱金属盐溶液浸渍沸石来制备，其中浸渍在沸石中的所述碱金属超过了沸石中存在的可离子交换位点所需的碱金属，干燥所得物 然后煅烧所得组合物。
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公开(公告)号：US5070052A
公开(公告)日：1991-12-03
申请号：US586120
申请日：1990-09-21
CPC分类号： B01J29/80 , B01J29/061 , B01J29/08 , B01J29/7003
摘要： This invention relates to a composition comprising a zeolite and a zinc or a zinc plus an alkali metal and/or an alkaline earth metal compound wherein the sum of the amount of the zinc or zinc plus alkali metal and/or alkaline earth metal in the compound plus any metal cation exchanged into the zeolite is in excess of that required to provide a fully metal cation-exchanged zeolite. The catalyst is preferably activated before use as a catalyst by heating to 400.degree. C. to 650.degree. C., typically in a nitrogen or air atmosphere.
摘要翻译： 本发明涉及包含沸石和锌或锌加碱金属和/或碱土金属化合物的组合物，其中化合物中锌或锌与碱金属和/或碱土金属的量之和 加上交换到沸石中的任何金属阳离子超过提供完全金属阳离子交换的沸石所需的金属阳离子。 催化剂优选在使用前通过加热至400℃至650℃，通常在氮气或空气气氛中作为催化剂活化。
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4.发明授权Cobalt-catalyzed process for preparing 1,3-propanediol using a lipophilic dihydroxyarene promoter 失效使用亲脂性二羟基芳烃助催化剂制备1,3-丙二醇的钴催化方法
公开(公告)号：US5576471A
公开(公告)日：1996-11-19
申请号：US316669
申请日：1994-09-30
IPC分类号： C07C29/141 , C07C29/16 , C07C45/58 , C07C45/80 , C07C27/04
CPC分类号： C07C45/58 , C07C29/141 , C07C29/16 , C07C45/80
摘要： 1,3-Propanediol is prepared in a process which involves reacting ethylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of a non-phosphine-ligated cobalt catalyst and a lipophilic dihydroxyarene promoter to produce an intermediate product mixture containing 3-hydroxypropanal in an amount less than 15 wt %; extracting the 3-hydroxypropanal from the intermediate product mixture into an aqueous liquid at a temperature less than about 100.degree. C. and separating the aqueous phase containing 3-hydroxypropanal from the organic phase containing cobalt catalyst; hydrogenating the 3-hydroxypropanal in the aqueous phase to 1,3-propanediol; and recovering the 1,3-propanediol.The process enables the production of 1,3-propanediol in high yields and selectivity without the use of a phosphine ligand-modified cobalt catalyst.
摘要翻译： 1,3-丁二醇的制备方法是在非磷化氢连接的钴催化剂和亲脂性二羟基芳烃助催化剂存在下，使环氧乙烷与一氧化碳和氢气在基本上不与水相混溶的溶剂中进行反应，生成中间体 含有小于15重量％的3-羟基丙醛的产物混合物; 在低于约100℃的温度下将中间产物混合物中的3-羟基丙醛萃取到含水液体中，并从含钴催化剂的有机相中分离出含有3-羟基丙醛的水相; 将水相中的3-羟基丙醛氢化为1,3-丙二醇; 并回收1,3-丙二醇。 该方法能够以高产率和选择性生产1,3-丙二醇，而不需要使用膦配体改性的钴催化剂。
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公开(公告)号：US5344993A
公开(公告)日：1994-09-06
申请号：US130258
申请日：1993-10-01
申请人： Lynn H. Slaugh , Juan P. Arhancet
发明人： Lynn H. Slaugh , Juan P. Arhancet
摘要： This invention relates to a process for making 3-hydroxyaldehydes having 4 or more carbon atoms by intimately contacting(a) 1,2-epoxides having 3 or more carbon numbers,(b) ditertiary phosphine-modified cobalt carbonyl catalyst, said phosphine being a hydrocarbylene-bis(monophosphabicyclononane) in which each phosphorus atom is joined to hydrocarbylene and is a member of a bridge linkage without being a bridgehead atom and which hydrocarbylene-bis(monophosphabicyclononane) has 11 to 80 carbon atoms, 5 to 12 carbon atoms thereof together with a phosphorus atom being members of each of the two bicyclic skeletal structures,(c) carbon monoxide, and(d) hydrogen, the molar ratio of carbon monoxide to hydrogen being from about 4:1 to about 1:6, in liquid-phase solution in an inert reaction solvent, at a temperature of from about 30.degree. C. to about 150.degree. C. and a pressure of from about 50 psi to about 10,000 psi. Acids and promoter salts may be added to the reaction mixture to promote the hydroformylation reaction.
摘要翻译： 本发明涉及一种通过紧密接触（a）具有3个或更多个碳数的1,2-环氧化物制备具有4个或更多个碳原子的3-羟基醛的方法，（b）二膦膦改性的羰基钴催化剂，所述膦是 其中每个磷原子连接到亚烃基并且不是桥头原子的桥连构件的亚烃基 - 双（单磷酰基二环壬烷），并且亚烃基 - 双（单磷杂二环壬烷）具有11至80个碳原子，5至12个碳原子在一起 其中磷原子是两个双环骨架结构中的每一个的成员，（c）一氧化碳和（d）氢，一氧化碳与氢的摩尔比为约4:1至约1:6， 在惰性反应溶剂中，在约30℃至约150℃的温度和约50psi至约10,000psi的压力下进行。 可以向反应混合物中加入酸和促进剂盐以促进加氢甲酰化反应。
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6.发明授权Melt stabilized polyketone blend containing a mixture of magnesium oxide and alumina 失效含有氧化镁和氧化铝混合物的熔融稳定的聚酮共混物
公开(公告)号：US5126496A
公开(公告)日：1992-06-30
申请号：US738410
申请日：1991-07-31
申请人： Lynn H. Slaugh
发明人： Lynn H. Slaugh
IPC分类号： C08K3/22
CPC分类号： C08K3/22
摘要： A stabilized polymer composition comprising a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon, and a melt stabilizer comprising a mixture of magnesium oxide and alumina. A process of preparing the composition and articles of manufacture made of the composition are also disclosed.
摘要翻译： 一种稳定的聚合物组合物，其包含一氧化碳和至少一种烯属不饱和烃的线性交替聚合物和包含氧化镁和氧化铝的混合物的熔体稳定剂。 还公开了制备由该组合物制成的组合物和制品的方法。
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7.发明授权Hydrogenation catalyst and hydrogenation process wherein said catalyst is used 失效氢化催化剂和氢化方法，其中使用所述催化剂
公开(公告)号：US5057582A
公开(公告)日：1991-10-15
申请号：US289158
申请日：1988-12-23
申请人： Ronald J. Hoxmeier , Lynn H. Slaugh
发明人： Ronald J. Hoxmeier , Lynn H. Slaugh
CPC分类号： C08F8/04 , B01J31/0225 , B01J31/04 , B01J31/143 , B01J31/2234 , C08C19/02 , B01J2231/645 , B01J2531/845 , B01J2531/847
摘要： A hydrogenation catalyst prepared by combining a Group VIIIA metal compound and an alkylalumoxane and a hydrogenation process wherein said catalyst is used to hydrogenate compounds or materials containing ethylenic and/or aromatic unsaturation. The Group VIIIA metal compound is selected from the group of compounds consisting of carboxylates, chelates, alkoxides, salts of acids containing sulfur, salts of partial half esters of acids containing sulfur and salts of aliphatic and aromatic sulfonic acids. Nickel and cobalt compounds are preferred for use in preparing the hydrogenation catalyst. Hydrogenation catalysts prepared with methylalumoxane initially exhibit less hydrogenation activity than catalysts known heretofore in the prior art and prepared with a metal alkyl of a metal selected from Groups I, II and III. These catalysts, then, permit or enable greater control over the extent of hydrogenation, particularly when partial hydrogenation is a desired end result. Ultimately, however, the catalyst permits substantially complete hydrogenation of both ethylenic and aromatic unsaturation. Hydrogenation catalysts prepared with higher alkyl (C.sub.2 -C.sub.8) alumoxanes on the other hand are generally more active at all hydrogenation times at least those greater than about 30 minutes.
摘要翻译： 通过组合ⅦA族金属化合物和烷基铝氧烷制备的氢化催化剂和氢化方法，其中所述催化剂用于氢化含有烯属和/或芳族不饱和度的化合物或材料。 VIIIA族金属化合物选自羧酸盐，螯合物，醇盐，含硫酸盐，含硫酸的部分半酯盐和脂族和芳族磺酸盐组成的化合物。 镍和钴化合物优选用于制备氢化催化剂。 用甲基铝氧烷制备的氢化催化剂最初显示出比现有技术中已知的催化剂更少的氢化活性，并用选自I，II和III族的金属的金属烷基制备。 然后，这些催化剂允许或可以更好地控制氢化的程度，特别是当部分氢化是期望的最终结果时。 然而，最终催化剂允许乙烯和芳族不饱和基团完全氢化。 另一方面，由高级烷基（C 2 -C 8）铝氧烷制备的氢化催化剂在所有氢化时间通常在大于约30分钟的时间内更具活性。
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公开(公告)号：US5030792A
公开(公告)日：1991-07-09
申请号：US64356
申请日：1987-06-22
申请人： Lynn H. Slaugh
发明人： Lynn H. Slaugh
IPC分类号： B01J31/04 , B01J31/22 , C07B61/00 , C07C1/213 , C07C11/02 , C07C67/055 , C07C67/297
CPC分类号： C07C1/213 , C07C11/02 , C07C67/055
摘要： This invention relates to a process for producing 1-octenes comprising reacting conjugated dienes and carboxylic acids in the presence of palladium, platinum or ruthenium catalysts to produce 2,7-alkadienyl esters, contacting the 2,7-alkadienyl esters with hydrogen to produce alkyl esters and subsequently pyrolyzing the alkyl esters to produce 1-octene and carboxylic acid.
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9.发明授权Stabilized polymer compositions of linear alternating polyketones and zinc aluminate 失效线性交替聚酮和铝酸锌的稳定聚合物组合物
公开(公告)号：US5028652A
公开(公告)日：1991-07-02
申请号：US474919
申请日：1990-02-05
申请人： Edgar J. Smutny , Lynn H. Slaugh
发明人： Edgar J. Smutny , Lynn H. Slaugh
摘要： Stabilized polymer compositions comprise a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon incorporating a stabilizing quantity of a zinc aluminate and, optionally, an acidic polymer containing moieties of an .alpha.-olefin and an .alpha.,.beta.-ethylenically unsaturated carboxylic acid. The compositions demonstrate improved melt stability.
摘要翻译： 稳定的聚合物组合物包含一氧化碳和至少一种烯键式不饱和烃的线性交替聚合物，其包含稳定量的铝酸锌和任选的含有α-烯烃和α，β-烯属不饱和羧酸部分的酸性聚合物 。 该组合物显示出改进的熔体稳定性。
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公开(公告)号：US4891446A
公开(公告)日：1990-01-02
申请号：US252284
申请日：1988-09-30
申请人： Lynn H. Slaugh
发明人： Lynn H. Slaugh
IPC分类号： C07C45/00
CPC分类号： C07C45/002
摘要： This invention relates to a process for converting saturated aliphatic primary alcohols to aldehydes by passing said alcohols over a fixed bed of brass catalyst particles at a temperature ranging from about 375.degree. to about 550.degree. C. in the presence of hydrogen passing over the bed at a gaseous hourly space velocity of greater than about 250 hour.sup.-1 and recovering the product aldehyde from an effluent passing out of the fixed bed.
摘要翻译： 本发明涉及将饱和脂肪族伯醇转化成醛的方法，该方法是在约375℃至约550℃的温度范围内，通过所述醇在黄色催化剂颗粒的固定床上， 大于约250小时-1的气时空速，并从通过固定床的流出液中回收产物醛。
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