Abstract:
Disclosed is a vacuum circuit breaker (1) including a vacuum interrupter (3) accommodated in a ground tank (2) filled with insulating gas. At least one of a fixed electrode (10) and a movable electrode (11) of the vacuum interrupter (3) uses an electrode material in which particles containing a solid solution of a heat resistant element and Cr are finely and uniformly dispersed and in which Cu textures as a high conductive component are finely and uniformly dispersed. The electrode material contains 20 to 70% by weight of Cu, 1.5 to 64% by weight of Cr and 6 to 76% by weight of the heat resistant element relative to a weight of the electrode material. The particles of the solid solution in the electrode material have an average particle size of 20 μm or smaller.
Abstract:
It is an electrode material that is used as an electrode contact of a vacuum interrupter and that contains one or more parts by weight of a heat-resistant element and one part by weight of Cr, the remainder being Cu and an unavoidable impurity. A part of Cr powder and the heat-resistant element powder are mixed together, and this mixed powder is sintered such that a peak corresponding to Cr element disappears in X-ray diffraction measurement. A solid solution powder obtained by pulverizing a sintered body of the heat-resistant element and Cr obtained by the sintering is mixed with the remaining Cr powder, and this mixed powder is shaped and then sintered. A sintered body obtained by this sintering is infiltrated with Cu.
Abstract:
It is a method for manufacturing an electrode material containing Cu, Cr, a heat-resistant element, and a low melting metal. A Cr powder and a heat-resistant element powder are mixed together in a ratio such that the Cr is greater than the heat-resistant element by weight. The mixed powder of the heat-resistant element and the Cr powder is baked. A MoCr solid solution obtained by the baking and containing a solid solution of the heat-resistant element and the Cr is pulverized and then classified. The classified MoCr solid solution powder, a Cu powder, and a low-melting metal powder are mixed together, followed by sintering at a temperature that is 1010° C. or higher and is lower than 1038° C., thereby obtaining the electrode material.
Abstract:
What is disclosed is an electrode material including a sintered body containing a heat resistant element and Cr and being infiltrated with a highly conductive material. A powder mixture of a heat resistant element powder and a Cr powder is subjected to a provisional sintering in advance, thereby causing solid phase diffusion of the heat resistant element and Cr. After a Mo—Cr solid solution obtained by the provisional sintering is pulverized, the pulverized Mo—Cr solid solution powder is molded and sintered. A sintered body obtained by sintering is subjected to a HIP treatment. The highly conductive metal is disposed on the sintered body after the HIP treatment, and infiltrated into the sintered body by heating at a predetermined temperature. By conducting the HIP treatment, the withstand voltage capability and current-interrupting capability of the electrode material are improved.
Abstract:
There is disclosed a method for manufacturing an electrode by pressing and sintering a mixed powder of a solid solution powder of Cr and a heat-resistant element, which contains Cr and the heat-resistant element in a ratio such that Cr is greater than the heat-resistant element by weight, a Cu powder, and a low melting metal powder (Bi, Sn, Se, Pb, etc.). The low melting metal powder of 0.30 weight % to 0.50 weight % is added to a mixed powder of a solid solution powder of Cr and the heat-resistant element and the Cu powder, and then a mixed powder prepared by adding the low melting metal powder is sintered at a temperature of from 1010° C. to 1035° C. As the low melting metal powder, there is used a powder having a median size of from 5 μm to 20 μm.
Abstract:
It is a method for producing an electrode material containing Cu, Cr and a heat-resistant element. A heat-resistant element powder and a Cr powder are mixed together in a ratio such that the heat-resistant element is less than the Cr by weight. A mixed powder of the heat-resistant element powder and the Cr powder is baked. A sintered body obtained by the baking and containing a solid solution of the heat-resistant element and the Cr is pulverized, and a solid solution powder obtained by the pulverizing is classified, to have a particle size of 200 μm or less. 10-60 parts by weight of the classified solid solution powder and 90-40 parts by weight of a Cu powder are mixed together, followed by sintering to obtain the electrode material. If a low melting metal powder having a median size of 5-40 μm is mixed with a mixed powder of the solid solution powder and the Cu powder, the deposition resistance property is further improved.
Abstract:
An electrode material wherein Cr-containing particles are finely miniaturized and uniformly dispersed while a Cu portion, which is highly conductive component, is also finely miniaturized and uniformly dispersed. The electrode material is prepared, for example, by: a mixing step (S1) for mixing a Cr powder and a heat resistant element powder; a provisional sintering step (S2) for provisionally sintering the mixed powder to obtain a solid solution of Cr and the heat resistant element; a pulverizing step (S3) for pulverizing the solid solution of Cr and the heat resistant element to obtain a solid solution powder of Cr and the heat resistant element; a molding step (S4) for molding the solid solution powder; a main sintering step (S5) for performing main sintering of the obtained molded body to obtain a sintered body (skeleton) of Cr and the heat resistant element; and a Cu infiltration step (S6) for infiltrating the sintered body of Cr and the heat resistant element with Cu.A method for producing an electrode material, involving: (i) a step of preparing a powder of a solid solution of Cr and a heat resistant material selected from the group consisting of Mo, W, Ta, Nb, V and Zr, wherein either a peak corresponding to Cr element or a peak corresponding to the heat resistant element, which are observed by X ray diffraction measurement made on the powder of the solid solution, disappears; (ii) a step of molding the powder of the solid solution to obtain a molded body and then sintering the molded body to produce a sintered body; and (iii) a Cu infiltration step of infiltrating the sintered body with Cu.
Abstract:
A composite metal where a phase of particles of solid solution is uniformly dispersed in a Cu phase, the solid solution containing a solid solution of a heat resistant element selected from Mo, W, Ta, Nb, V and Zr and Cr. The composite metal is provided to contain: 20-70% of Cu; 1.5-64% of Cr; and 6-76% of a heat resistant element by weight relative to the composite metal, wherein a remainder is comprised of inevitable impurities. In the composite metal, the particles of the solid solution, contained in the composite metal, are provided to have an average particle diameter of not larger than 20 μm and to uniformly disperse in the Cu phase with an index of the dispersion state of not higher than 1.0.
Abstract:
A process for producing an electrode material by infiltrating a highly conductive metal such as Cu into a porous object containing heat-resistant elements. Before an infiltration step in which the highly conductive metal is infiltrated, a HIP treatment is given to a powder containing the heat-resistant elements (or to a molded object obtained by molding a powder containing the heat-resistant elements). The composition is controlled so that the HIP treatment yields a porous object which has a degree of filling of 70% or higher, more preferably 75% or higher. The highly conductive metal is infiltrated into the porous object having the controlled composition.
Abstract:
An electrode material obtained by press molding a mixed powder where a Cu powder, a Cr powder and a refractory metal powder (for example, a Mo powder) are mixed and then sintering the thus-obtained molded body in a non-oxidizing atmosphere at a temperature that is not higher than the melting point of Cu. As the Cr powder to be mixed in the mixed powder, a Cr powder wherein the volume-based relative particle amount of particles having particle diameters of 40 μm or less is less than 10% is used. The Cr powder is mixed in the mixed powder in an amount of 10-50% by weight, while the refractory metal powder is mixed in the mixed powder in an amount of 1-10% by weight.