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公开(公告)号:US20150224748A1
公开(公告)日:2015-08-13
申请号:US14428759
申请日:2013-09-20
CPC分类号: B32B27/08 , B05D3/007 , B05D2201/04 , B29C45/14 , B29C45/14778 , B29K2033/08 , B29K2995/0026 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2250/24 , B32B2270/00 , B32B2307/412 , B32B2307/536 , B32B2307/558 , B32B2307/71 , B32B2307/738 , B32B2457/00 , B32B2601/00 , B32B2605/003 , C08L33/12 , C08L67/02 , C08L69/00 , Y10T428/24802 , Y10T428/2495 , Y10T428/24967 , Y10T428/31507
摘要: The present invention has an object of providing a synthetic resin laminate that is usable for a transparent substrate material or protective material, has high thermoformability (pressure formability, thermal-bending formability), high insert moldability, and high surface hardness and/or impact resistance, and also providing a molded body formed by molding such a synthetic resin laminate. The synthetic resin laminate includes a polycarbonate-based substrate layer; and a resin laminated on one of, or both of, two surfaces of the polycarbonate-based substrate layer, the resin containing a specific (meth)acrylate copolymer resin and a specific polycarbonate resin. The polycarbonate-based substrate layer includes a polymer alloy and thus has a glass transition temperature (Tg) of 110 to 130° C. Thus, the resultant synthetic resin laminate has high thermoformability and high surface hardness.
摘要翻译: 本发明的目的是提供一种可用于透明基板材料或保护材料的合成树脂层压体,具有高的热成型性(压力成形性,热弯曲成形性),高嵌入成型性和高表面硬度和/或耐冲击性 并且还提供通过模制这种合成树脂层压体而形成的成型体。 合成树脂层压体包括聚碳酸酯基底层; 以及层压在聚碳酸酯类基材层的两面或两面的树脂,该树脂含有特定的(甲基)丙烯酸酯共聚物树脂和特定的聚碳酸酯树脂。 聚碳酸酯类基材层包含聚合物合金,玻璃化转变温度(Tg)为110〜130℃。因此,所得合成树脂层压体的热成型性高,表面硬度高。
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公开(公告)号:US09802395B2
公开(公告)日:2017-10-31
申请号:US15104397
申请日:2014-12-17
发明人: Takeshi Onishi , Yasuyoshi Nakayasu , Kishin Ozawa
IPC分类号: B32B27/08 , C09D4/00 , C08F220/18 , C09D183/06 , B32B27/30 , B32B27/36 , C08L69/00 , B32B27/06 , C08L33/12
CPC分类号: B32B27/08 , B32B27/06 , B32B27/18 , B32B27/30 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2255/10 , B32B2255/20 , B32B2255/26 , B32B2270/00 , B32B2307/30 , B32B2307/306 , B32B2307/308 , B32B2307/412 , B32B2307/536 , B32B2307/558 , B32B2307/726 , B32B2307/732 , B32B2307/734 , B32B2405/00 , B32B2457/208 , C08F220/18 , C08L33/12 , C08L69/00 , C09D4/00 , C09D183/06
摘要: The present invention provides a synthetic resin laminate, which is excellent in terms of shape stability in a high-temperature or high-humidity environment, surface hardness, heat resistance, coating adhesion and the like. The synthetic resin laminate is formed by laminating a resin layer (A) including 5% to 55% by mass of a (meth)acrylate copolymer (C) and 95% to 45% by mass of a polycarbonate (D) on one surface or both surfaces of a base material layer (B) comprising polycarbonate, wherein the synthetic resin laminate is characterized: in that the (meth)acrylate copolymer (C) includes an aromatic (meth)acrylate unit (c1) and a methyl methacrylate unit (c2) at a mass ratio (c1/c2) of 5 to 80/20 to 95; in that the mass average molecular weight of the (meth)acrylate copolymer (C) is 5,000 to 30,000; and in that the viscosity average molecular weight of the polycarbonate (D) is 21,000 to 40,000.
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公开(公告)号:US09446567B2
公开(公告)日:2016-09-20
申请号:US14428759
申请日:2013-09-20
IPC分类号: B32B27/08 , B32B27/36 , B29C45/14 , C08L33/12 , C08L69/00 , B32B27/30 , B05D3/00 , C08L67/02 , B29K33/00
CPC分类号: B32B27/08 , B05D3/007 , B05D2201/04 , B29C45/14 , B29C45/14778 , B29K2033/08 , B29K2995/0026 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2250/24 , B32B2270/00 , B32B2307/412 , B32B2307/536 , B32B2307/558 , B32B2307/71 , B32B2307/738 , B32B2457/00 , B32B2601/00 , B32B2605/003 , C08L33/12 , C08L67/02 , C08L69/00 , Y10T428/24802 , Y10T428/2495 , Y10T428/24967 , Y10T428/31507
摘要: The present invention has an object of providing a synthetic resin laminate that is usable for a transparent substrate material or protective material, has high thermoformability (pressure formability, thermal-bending formability), high insert moldability, and high surface hardness and/or impact resistance, and also providing a molded body formed by molding such a synthetic resin laminate. The synthetic resin laminate includes a polycarbonate-based substrate layer; and a resin laminated on one of, or both of, two surfaces of the polycarbonate-based substrate layer, the resin containing a specific (meth)acrylate copolymer resin and a specific polycarbonate resin. The polycarbonate-based substrate layer includes a polymer alloy and thus has a glass transition temperature (Tg) of 110 to 130° C. Thus, the resultant synthetic resin laminate has high thermoformability and high surface hardness.
摘要翻译: 本发明的目的是提供一种可用于透明基板材料或保护材料的合成树脂层压体,具有高的热成型性(压力成形性,热弯曲成形性),高嵌入成型性和高表面硬度和/或耐冲击性 并且还提供通过模制这种合成树脂层压体而形成的成型体。 合成树脂层压体包括聚碳酸酯基底层; 以及层压在聚碳酸酯类基材层的两面或两面的树脂,该树脂含有特定的(甲基)丙烯酸酯共聚物树脂和特定的聚碳酸酯树脂。 聚碳酸酯类基材层包含聚合物合金,玻璃化转变温度(Tg)为110〜130℃。因此,所得合成树脂层压体的热成型性高,表面硬度高。
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公开(公告)号:US20150017408A1
公开(公告)日:2015-01-15
申请号:US14379401
申请日:2013-02-19
发明人: Toshinari Aoki , Takeshi Onishi , Kosei Hino
CPC分类号: B32B27/08 , B32B27/16 , B32B27/30 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2250/24 , B32B2255/10 , B32B2255/26 , B32B2270/00 , B32B2307/306 , B32B2307/412 , B32B2307/536 , B32B2307/558 , B32B2307/702 , B32B2307/712 , B32B2307/726 , B32B2307/732 , B32B2307/734 , C08L33/12 , C08L69/00 , Y10T428/24967 , Y10T428/31507
摘要: The present invention has an object of providing a synthetic resin laminate that is excellent in shape stability against a high temperature and high humidity environment, surface hardness and the like. The above object is achieved by a synthetic resin laminate, comprising a substrate layer (B) containing polycarbonate; and a resin layer (A) laminated on one or both of two surfaces of the resin layer (B), the resin layer (A) containing 5 to 55% by mass of (meth)acrylate copolymer (C) and 95 to 45% by mass of polycarbonate (D), wherein the (meth)acrylate copolymer (C) contains an aromatic (meth)acrylate unit (c1) and a methyl methacrylate unit (c2) at a mass ratio (c1/c2) of 5-80/20-95, and the (meth)acrylate copolymer (C) has a mass-average molecular weight of 5,000 to 30,000; and the polycarbonate (D) has a mass-average molecular weight of 21,000 to 40,000.
摘要翻译: 本发明的目的是提供一种对高温高湿环境,表面硬度等形状稳定性优异的合成树脂层压体。 上述目的是通过合成树脂层压材料实现的,包括含有聚碳酸酯的基底层(B) 和层叠在树脂层(B)的两面的一面或两面的树脂层(A),含有5〜55质量%的(甲基)丙烯酸酯共聚物(C)的树脂层(A)和95〜45重量% (甲基)丙烯酸酯单元(c1)和甲基丙烯酸甲酯单元(c2)的质量比(c1 / c2)为5-80的(甲基)丙烯酸酯共聚物(C) (甲基)丙烯酸酯共聚物(C)的质均分子量为5000〜30,000, 聚碳酸酯(D)的质均分子量为21,000〜40,000。
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公开(公告)号:US10414133B2
公开(公告)日:2019-09-17
申请号:US14399705
申请日:2013-05-15
发明人: Kosei Hino , Takeshi Onishi , Osamu Kakinoki , Hidetaka Shimizu , Hirohiko Aikawa , Toshinari Aoki
摘要: A synthetic resin laminate is excellent in shape stability in high-temperature high-humidity environments and in surface hardness and usable for a transparent substrate material or protection material. A synthetic resin laminate includes a substrate layer containing a polycarbonate (B); and a resin layer laminated on one or both surfaces of the substrate layer, the resin layer containing a resin (A) that contains a (meth)acrylate copolymer (a1) and a polycarbonate (a2); wherein (a1) is a (meth)acrylate copolymer composed of 5 to 80% by mass of an aromatic (meth)acrylate unit (a11) and 20 to 95% by mass of a methyl methacrylate unit (a12); (a2) is a polycarbonate containing a constituent unit represented by formula [1]; and the ratio of (a1) with respect to the resin (A) is 5 to 55% by mass, and the ratio of (a2) with respect to the resin (A) is 95 to 45% by mass.
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公开(公告)号:US10011095B2
公开(公告)日:2018-07-03
申请号:US14379401
申请日:2013-02-19
发明人: Toshinari Aoki , Takeshi Onishi , Kosei Hino
CPC分类号: B32B27/08 , B32B27/16 , B32B27/30 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2250/24 , B32B2255/10 , B32B2255/26 , B32B2270/00 , B32B2307/306 , B32B2307/412 , B32B2307/536 , B32B2307/558 , B32B2307/702 , B32B2307/712 , B32B2307/726 , B32B2307/732 , B32B2307/734 , C08L33/12 , C08L69/00 , Y10T428/24967 , Y10T428/31507
摘要: The present invention has an object of providing a synthetic resin laminate that is excellent in shape stability against a high temperature and high humidity environment, surface hardness and the like. The above object is achieved by a synthetic resin laminate, comprising a substrate layer (B) containing polycarbonate; and a resin layer (A) laminated on one or both of two surfaces of the resin layer (B), the resin layer (A) containing 5 to 55% by mass of (meth)acrylate copolymer (C) and 95 to 45% by mass of polycarbonate (D), wherein the (meth)acrylate copolymer (C) contains an aromatic (meth)acrylate unit (c1) and a methyl methacrylate unit (c2) at a mass ratio (c1/c2) of 5-80/20-95, and the (meth)acrylate copolymer (C) has a mass-average molecular weight of 5,000 to 30,000; and the polycarbonate (D) has a mass-average molecular weight of 21,000 to 40,000.
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公开(公告)号:US10509252B2
公开(公告)日:2019-12-17
申请号:US15577038
申请日:2016-06-02
发明人: Takeshi Onishi , Masahide Takeda , Shotaro Ohno , Shohei Takahagi
IPC分类号: G02F1/1335 , F21V3/00 , F21S2/00 , F21V3/04 , G02B5/02 , B29C48/30 , B29C48/305
摘要: Provided is a polymer film which can eliminate both moire and glitter and is suitable for use as a diffusion film. The above-mentioned problems are solved with a polymer film, a surface of which has an arithmetic average roughness Ra of 0.63-1.80 μm, a root mean square roughness Rq of 0.76-2.40 μm, and an average height Rc of roughness-curve elements of 2.45-7.20 μm.
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公开(公告)号:US10067271B2
公开(公告)日:2018-09-04
申请号:US15514348
申请日:2015-09-29
摘要: An optical sheet is formed by laminating, by co-extrusion molding, a first layer containing a polycarbonate resin, a second layer containing a polyamide resin, and a third layer, wherein the second layer is laminated between the first layer and the third layer, the first layer and second layer, and the second layer and third layer can each be peeled at the interface, and the outer surface of the first layer has a fine grooved structure. The optical sheet, which is provided with a plurality of layers in such a way, is capable of retaining, a sufficient amount of heat in a laminate in a mold since the entire sheet can be made thick during melt extrusion molding, and is able to improve the transferability of the fine grooved structure. In addition, the optical sheet can be made thinner by using only the peeled first layer as an optical sheet.
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公开(公告)号:US20150111015A1
公开(公告)日:2015-04-23
申请号:US14399705
申请日:2013-05-15
发明人: Kosei Hino , Takeshi Onishi , Osamu Kakinoki , Hidetaka Shimizu , Hirohiko Aikawa , Toshinari Aoki
CPC分类号: B32B27/08 , B32B27/308 , B32B27/36 , B32B27/365 , B32B2250/02 , B32B2250/03 , B32B2250/24 , B32B2250/244 , B32B2270/00 , B32B2307/306 , B32B2307/412 , B32B2307/536 , B32B2307/558 , B32B2307/584 , B32B2307/71 , B32B2307/734 , B32B2333/12 , B32B2369/00 , C08L69/00 , Y10T428/2495 , Y10T428/24967 , Y10T428/31507 , C08L33/06
摘要: A synthetic resin laminate is excellent in shape stability in high-temperature high-humidity environments and in surface hardness and usable for a transparent substrate material or protection material. A synthetic resin laminate includes a substrate layer containing a polycarbonate (B); and a resin layer laminated on one or both surfaces of the substrate layer, the resin layer containing a resin (A) that contains a (meth)acrylate copolymer (a1) and a polycarbonate (a2); wherein (a1) is a (meth)acrylate copolymer composed of 5 to 80% by mass of an aromatic (meth)acrylate unit (a11) and 20 to 95% by mass of a methyl methacrylate unit (a12); (a2) is a polycarbonate containing a constituent unit represented by formula [1]; and the ratio of (a1) with respect to the resin (A) is 5 to 55% by mass, and the ratio of (a2) with respect to the resin (A) is 95 to 45% by mass.
摘要翻译: 合成树脂层压体在高温高湿环境下的形状稳定性和表面硬度优异,可用于透明基材或保护材料。 合成树脂层压体包括含有聚碳酸酯(B)的基材层; 以及层叠在基材层的一面或两面的树脂层,所述树脂层含有含有(甲基)丙烯酸酯共聚物(a1)和聚碳酸酯(a2)的树脂(A) 其中(a1)是由5〜80质量%的芳香族(甲基)丙烯酸酯单元(a11)和20〜95质量%的甲基丙烯酸甲酯单元(a12)构成的(甲基)丙烯酸酯共聚物。 (a2)是含有式[1]表示的结构单元的聚碳酸酯。 (a1)相对于树脂(A)的比例为5〜55质量%,(a2)相对于树脂(A)的比例为95〜45质量%。
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