Abstract:
There is provided a decorative sheet having excellent design properties, i.e., low gloss, and having fingerprint resistance, high durability (particularly scratch resistance or contamination resistance), and processability. A decorative sheet (1) according to this embodiment includes: a base material layer (2); and a surface protective layer (5) provided on one surface of the base material layer (2), in which the surface protective layer (5) has ridge-like parts provided to project in a ridge-like shape and form an irregular shape on the surface, RSm/Ra of the irregular shape of the surface protective layer (5) is within the range of 10 or more and 300 or less, the surface protective layer (5) contains an ionizing radiation curable resin as a main material, the ionizing radiation curable resin contains, as a main component, a tetrafunctional acrylic resin containing a repeating structure, the repeating structure is any one of the structures of ethylene oxide, propylene oxide, and ε-caprolactone, and the number of repetitions of the repeating structure is 12 or more.
Abstract:
The present invention is a process for uniformly depositing nanomaterials having particles smaller than 1 μm (i.e., nanoparticles) onto a surface of a base material (substrate or surface). The process is used to deposit any solid (nanoparticle) of any shape such as nanofibers, nanotubes, nanoclays (e.g., platelet shaped), nano-spheres, or irregularly shaped granules. The base material upon which the nano-particles are deposited can be made of any material. The method substantially prevents the deposition on the base material of larger particles (contaminants or clusters of the nanoparticles) which are often mixed with the nanomaterials. The amount of deposition and the range of particle sizes to be deposited can also be controlled by this method. Maintaining deposition uniformity, controlling the amount of deposition, and the elimination of larger particles enhances the utility of nanomaterials, and by subsequent processing, enables the development of multifunctional composite materials (or other coated substrates) to be used in commercial applications. In the present invention nanoparticles are applied to other base materials by substantially eliminating deposition of larger clusters or aggregates of nano-sized materials or other large impurities of other materials upon or in the base materials by positioning the base material within an upper portion of a deposition chamber.
Abstract:
The present invention relates to a method of coating fluorocarbon or hydrocarbon on the surface of a workpiece using atmospheric pressure plasma. More particularly, the present invention relates to a method of coating hydrocarbon or fluorocarbon on the surface of a workpiece using plasma generated under atmospheric pressure such that the workpiece can have a hydrophobic or super-hydrophobic surface.The method of coating a surface of a workpiece with fluorocarbon to be hydrophobic or super-hydrophobic according to the present invention comprises the steps of generating first atmospheric pressure glow plasma by supplying a reaction gas into a discharge space formed between a first electrode and a second electrode, the reaction gas containing hydrogen gas, fluorocarbon gas and inert gas, the first and second electrodes being connected to an RF power supply of an atmospheric pressure plasma generator; and approaching the workpiece to the first electrode downstream of a reaction gas flow passing through the discharge space, such that the plasma created in the discharge space is transferred into a space between the first electrode and the workpiece to generate a second atmospheric pressure glow plasma therein, whereby a fluorocarbon coating layer can be formed on the surface of the workpiece.
Abstract:
A gas barrier laminate including a resin substrate, a first coating layer containing a carboxylic acid polymer; and a second coating layer containing a polyvalent metal compound and a resin, laminated in this order; a ratio of a thickness of the second coating layer to the first coating layer in the range of 1.0 or more and 4.0 or less; and the second coating layer satisfies at least one of the following: (condition 1) a haze of the second coating layer is 8% or less; (condition 2) a surface roughness Ra of the second coating layer is ½ or less of the thickness of the second coating layer; and (condition 3) the number of concave portions having a diameter of 1.5 μm or more per unit area on a surface of the second coating layer opposite to the first coating layer is 2/0.01 mm2 or less.
Abstract:
The present invention has an object of providing a synthetic resin laminate that is usable for a transparent substrate material or protective material, has high thermoformability (pressure formability, thermal-bending formability), high insert moldability, and high surface hardness and/or impact resistance, and also providing a molded body formed by molding such a synthetic resin laminate. The synthetic resin laminate includes a polycarbonate-based substrate layer; and a resin laminated on one of, or both of, two surfaces of the polycarbonate-based substrate layer, the resin containing a specific (meth)acrylate copolymer resin and a specific polycarbonate resin. The polycarbonate-based substrate layer includes a polymer alloy and thus has a glass transition temperature (Tg) of 110 to 130° C. Thus, the resultant synthetic resin laminate has high thermoformability and high surface hardness.
Abstract:
A metal oxide-polymer laminate includes a polymer layer, and a metal oxide layer laminated on a surface of the polymer layer and formed by an aerosol deposition method. At least a portion of the metal oxide layer is embedded in the polymer layer in a thickness direction thereof.
Abstract:
The present invention relates to a method comprising as method steps: a) providing a sheetlike composite precursor comprising a carrier layer; b) overlaying the sheetlike composite precursor on an outer face of the sheetlike composite precursor with a liquid first polymer composition; c) hardening the liquid first polymer composition, thereby obtaining a first polymer layer; and d) overlaying the sheetlike composite precursor on the outer face of the sheetlike composite precursor with a liquid second polymer composition; wherein the first polymer layer in method step d) comprises an isocyanate content in a range from 0.1% to 50% by weight, based on the weight of the first polymer layer. The invention further relates to a sheetlike composite obtainable by the method; a container precursor and a closed container, each comprising the sheetlike composite; and to uses of a liquid primer and the sheetlike composite.
Abstract:
A metal oxide-polymer laminate includes a polymer layer, and a metal oxide layer laminated on a surface of the polymer layer and formed by an aerosol deposition method. At least a portion of the metal oxide layer is embedded in the polymer layer in a thickness direction thereof.
Abstract:
There is provided a method of producing a composite which is capable of suitably forming a silicone resin layer for preventing the facilitated transport film from entering the porous support in an acidic gas separation film formed by forming a facilitated transport film on a porous support, and the composite. The problem is solved by the method of producing a composite including hydrophilizing the surface of the porous support using a roll-to-roll system; and coating the hydrophilized surface of the porous support with a silicone coating solution that becomes the silicone resin layer using the roll-to-roll system.
Abstract:
A process for the production of a multi-layer composite comprising applying a coating layer from a pigmented coating composition A onto the back face of a transparent plastic film and then applying an NIR-opaque coating layer from a pigmented coating composition B, wherein the pigment content of coating composition A consists 50 to 100 wt. % of black pigment with low NIR absorption and 0 to 50 wt. % of further pigment, which is selected in such a way that coating layer A′ exhibits low NIR absorption and that the multi-layer composite exhibits a brightness L* of at most 10 units, wherein the pigment content of coating composition B is either a pigment content PC1 consisting 90 to 100 wt. % of aluminum flake pigment and 0 to 10 wt. % of further pigment, which is selected in such a way that NIR-opaque coating layer B′ exhibits low NIR absorption, or a pigment content PC2 comprising