公开(公告)号：US3687988A

公开(公告)日：1972-08-29

申请号：US3687988D

申请日：1970-11-18

Applicant: MOBIL OIL CORP

Inventor： CHEN ALBERT C ,  BUTTER STEPHEN A ,  HOBSON RICHARD W

IPC: C07C51/353 ,  C07C53/126 ,  C07C55/02 ,  C07C55/10 ,  C07C55/14 ,  C07C55/20 ,  C07C55/21 ,  C07C53/00 ,  C07C57/00

CPC classification number: C07C55/10 ,  C07C51/353 ,  C07C53/126 ,  C07C55/02 ,  C07C55/14 ,  C07C55/20 ,  C07C55/21 ,  Y02P20/584

Abstract: This specification discloses a process of reacting an acetic acid derivative with ethylene in the presence of a catalyst. The acetic acid derivatives include esters, the amide, substituted amides, and the anhydride of acetic acid. The catalyst is insoluble in the acetic acid derivatives, the ethylene, and the reaction products thereof and is an oxide of manganese wherein the manganese has a valence at least as great as 3. The catalyst, following the reaction, can be separated from the reaction mixture and regenerated by heating in the presence of an oxygencontaining gas. Thereafter, the regenerated catalyst may be employed further for the reaction of an acetic acid derivative with ethylene.

Abstract translation: 本说明书公开了在催化剂存在下使乙酸衍生物与乙烯反应的方法。 乙酸衍生物包括酯，酰胺，取代的酰胺和乙酸的酸酐。 催化剂不溶于乙酸衍生物，乙烯及其反应产物，并且是锰的氧化物，其中锰的价数至少为3。反应后​​的催化剂可以与反应物分离 混合物，并在含氧气体存在下加热再生。 此后，再生催化剂可以进一步用于乙酸衍生物与乙烯的反应。

公开(公告)号：US3911041A

公开(公告)日：1975-10-07

申请号：US50830774

申请日：1974-09-23

Applicant: MOBIL OIL CORP

Inventor： KAEDING WARREN W ,  BUTTER STEPHEN A

IPC: B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J37/28 ,  C07C1/20 ,  C07C2/00 ,  C07C2/12 ,  C07C2/66 ,  C07C2/86 ,  C07C4/06 ,  C10G11/05 ,  C10G35/095

CPC classification number: C10G35/095 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J37/28 ,  C07C1/20 ,  C07C2/00 ,  C07C2/12 ,  C07C2/66 ,  C07C2/861 ,  C07C2/864 ,  C07C2/865 ,  C07C2/868 ,  C07C4/06 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  C10G2400/20 ,  Y02P20/52 ,  C07C15/02 ,  C07C15/073 ,  C07C15/08

Abstract: Methanol and dimethyl ether are converted to a reaction product containing olefins. The conversion is carried out employing a catalyst comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12, a constraint index of about 1 to 12, and containing phosphorus incorporated with the crystal structure thereof in an amount of at least about 0.78 percent by weight.

Abstract translation: 将甲醇和二甲醚转化为含有烯烃的反应产物。 转化是使用包含二氧化硅与氧化铝比至少约12，约约指数为约1至12的结晶硅铝酸盐沸石和含有其晶体结构的磷的催化剂，其量至少约为 0.78重量％。

公开(公告)号：US3700706A

公开(公告)日：1972-10-24

申请号：US3700706D

申请日：1970-08-17

Applicant: MOBIL OIL CORP

Inventor： BUTTER STEPHEN A

IPC: B01J31/24 ,  B01J31/26 ,  C07C51/14 ,  C07C67/03 ,  C07C67/38

CPC classification number: B01J31/2404 ,  B01J31/122 ,  B01J31/24 ,  B01J31/26 ,  B01J2231/321 ,  B01J2531/824 ,  C07C51/14 ,  C07C67/03 ,  C07C67/38 ,  C07C69/24

Abstract: A carbonylation process is provided for conversion of olefinically unsaturated hydrocarbons to a mixture of esters or acids with an increased ratio of normal:iso (i.e., straight: branched) ester or acid by reaction with carbon monoxide and a hydroxylic compound, said process being carried out in the presence of a palladium salt complexed with a phosphine ligand as a catalyst and tin cocatalysts or promoters. For example, the catalyst may be palladium dichloride bis(triphenylphosphine) and the tin cocatalyst or promoter present may be stannous chloride dihydrate.

Abstract translation: 提供了一种羰基化方法，用于通过与一氧化碳和羟基化合物的反应将烯属不饱和烃转化为酯或酸的混合物与正常：异（即直链：支链）酯或酸的比例增加，所述方法被携带 在与膦配体作为催化剂络合的钯盐和锡助催化剂或助催化剂的存在下进行。 例如，催化剂可以是二氯化钯双（三苯基膦），存在的锡助催化剂或促进剂可以是氯化亚锡二水合物。

公开(公告)号：US3906054A

公开(公告)日：1975-09-16

申请号：US50830674

申请日：1974-09-23

Applicant: MOBIL OIL CORP

Inventor： KAEDING WARREN W ,  BUTTER STEPHEN A

IPC: B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J37/28 ,  C07C1/20 ,  C07C2/00 ,  C07C2/12 ,  C07C2/66 ,  C07C2/86 ,  C07C4/06 ,  C10G11/05 ,  C10G35/095 ,  C07C3/52

CPC classification number: C10G35/095 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J37/28 ,  B01J2229/36 ,  C07C1/20 ,  C07C2/00 ,  C07C2/12 ,  C07C2/861 ,  C07C2/864 ,  C07C2/865 ,  C07C2/868 ,  C07C4/06 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  C10G2400/20 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/08 ,  C07C11/02

Abstract: This specification discloses a process for the alkylation of olefins. The olefins are alkylated by contacting in the presence of an alkylating agent with a catalyst. The catalyst comprises a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12, a constraint index of about 1 to 12, and containing phosphorus incorporated with the crystal structure thereof in an amount of at least about 0.78 percent by weight. The zeolite, preferably, also has a dried crystal density of not less than about 1.6 grams per cubic centimeter. Olefins that may be alkylated include ethylene, propylene, butene-2 and isobutylene. Alkylating agents include methanol, dimethyl ether, and methyl chloride.

Abstract translation: 本说明书公开了烯烃烷基化方法。 通过在烷基化剂与催化剂的存在下接触将烯烃烷基化。 该催化剂包含二氧化硅与氧化铝之比至少约为12，约1到12的约束指数和含有其晶体结构的磷的至少约0.78％（重量）的结晶硅铝酸盐沸石。 沸石优选还具有不小于约1.6克/立方厘米的干燥晶体密度。 可被烷基化的烯烃包括乙烯，丙烯，丁烯-2和异丁烯。 烷基化剂包括甲醇，二甲醚和甲基氯。

公开(公告)号：US3894107A

公开(公告)日：1975-07-08

申请号：US38722373

申请日：1973-08-09

Applicant: MOBIL OIL CORP

Inventor： BUTTER STEPHEN A ,  JUREWICZ ANTHONY T ,  KAEDING WARREN W

IPC: B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C10G3/00 ,  C07C15/02

CPC classification number: B01J29/40 ,  B01J29/18 ,  B01J29/65 ,  B01J29/70 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2521/04 ,  C07C2529/40 ,  C07C2529/42 ,  C07C2529/44 ,  C07C2529/46 ,  C07C2529/65 ,  C07C2529/70 ,  C10G3/49 ,  C10G2300/1092 ,  C10G2300/4006 ,  C10G2300/4018 ,  C10G2400/30 ,  Y02P30/20

Abstract: Process of converting alcohols, aliphatic mercaptans, aliphatic sulfides, aliphatic halides and/or aliphatic amines to other desirable products by contacting such with a particular type of aluminosilicate molecular sieve catalyst at elevated temperature. Products produced by such conversion vary with temperature, with conversion to aromatic rings and substituted aromatic rings predominating at higher temperatures of about 300* to 500*C. The catalyst is a zeolite having a high silica to alumina ratio of at least about 12 and a constraint index of about 1 to 12. It also preferably has a crystal density in the hydrogen form of not substantially less than about 1.6.

Abstract translation: 通过在高温下与特定类型的硅铝酸盐分子筛催化剂接触，将醇，脂族硫醇，脂族硫化物，脂族卤化物和/或脂族胺转化成其它所需产物的方法。 通过这种转化产生的产物随着温度而变化，转化成芳环，取代的芳环主要在约300-500℃的较高温度下进行。催化剂是二氧化硅与氧化铝比高至少约12的沸石和 约1至12的约束指数。它还优选具有基本不小于约1.6的氢形式的晶体密度。

公开(公告)号：US3647835A

公开(公告)日：1972-03-07

申请号：US3647835D

申请日：1969-11-12

Applicant: MOBIL OIL CORP

Inventor： BUTTER STEPHEN A

IPC: B01J31/04 ,  C01G45/02 ,  C07C51/41 ,  C07F13/00 ,  C07C11/26 ,  C07D103/00

CPC classification number: B01J31/0237 ,  B01J31/04 ,  B01J31/1805 ,  B01J2531/72 ,  C01G45/02 ,  C01P2006/80 ,  C07C51/412 ,  C07F13/005 ,  C07C53/10

Abstract: A METHOD IN WHICH AN AQUEOUS MANGANESE (II) SOLUTION IS TREATED WITH A TERTIARY AMINE OR AMMONIA IN A FREE OXYGEN-CONTAINING ATMOSPHERE RESULTS IN MANGANESE (II) OXIDE OR MANGANESE (II) HYDROXIDE PRECIPITATION WHICH, IN SITU, IS RAPIDLY OXIDIZED TO MANGANESE (III) OXIDE FROM WHICH, UPON TREATMENT WITH A SUITABLE ACID, PARTICULARLY AN ALIPHATIC CARBOXYLIC ACID, THE MANGANESE (III) SALT OF SAID ACID IS OBTAINED. THE COMPOUNDS ARE USEFUL AS CATALYSTS FOR THE SYNTHESIS OF LACTONES FROM OLEFINS.