Preparation of isocyanatosilanes
    2.
    发明授权

    公开(公告)号:US11655263B2

    公开(公告)日:2023-05-23

    申请号:US17259268

    申请日:2019-07-02

    CPC classification number: C07F7/1892 B01D3/009 B01D3/143 B01D3/32

    Abstract: There is provided herein a method and an apparatus for producing an isocyanatoorganosilane which method includes feeding a carbamatoorganosilane to a cracking device where it is thermally dissociated into a reaction product mixture comprising isocyanatoorganosilane, alcohol, and heavies, followed by separating the mixture in a distillation column of two parts and collecting the isocyanatoorganosilane from the distillation column via a side stream having a predetermined location between the top and bottom parts of the column; and wherein the distillation column is configured to have a ratio of the length of the bottom part of the distillation column to the length of the top part of the distillation column which is effective to provide a side stream having a high purity and high weight percent of isocyanatoorganosilane.

    Siloxane coordination polymers
    6.
    发明授权

    公开(公告)号:US10287398B2

    公开(公告)日:2019-05-14

    申请号:US15538212

    申请日:2015-12-29

    Abstract: A functionalized siloxane includes a ligand capable of coordinating a metal. The functionalized siloxane includes a pyridine-containing ligand attached to a siloxane polymer. The functionalized siloxanes can be employed to provide complexes including a metal that may impart a desired property to the polymer. In one embodiment, the polymer can complex lanthanide metals that are capable of phosphorescing upon exposure to UV irradiation. Such polymers can be employed to provide functional materials such as, for example, luminescent films, coatings, etc.

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