摘要:
A catalyst composition for use in the conversion of oxygenates to olefins comprises a first crystalline silicoaluminophosphate molecular sieve comprising at least one intergrown form of an AEI structure type material and a CHA structure type material, and a second crystalline material different from said first molecular sieve and resulting from dehydration of an aluminophosphate or silicoaluminophosphate hydrate.
摘要:
A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about 55/45 as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.
摘要翻译:公开了一种硅铝磷酸盐分子筛,其包含CHA骨架型和AEI骨架型的第一和第二共生相,其中所述第一共生相的AEI / CHA比为约5/95至约40/60,如通过DIFFaX 分析,第二共生相具有通过DIFFaX分析确定的约30/70至约55/45的AEI / CHA比,并且所述分子筛具有二氧化硅与氧化铝的摩尔比(Si / Al 2 O 3 )为约0.13至约0.24。
摘要:
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a molecular sieve catalyst composition of a molecular sieve, a binder and a matrix material, wherein the weight ratio of the binder to the molecular sieve is controlled to provide an improved attrition resistant catalyst composition, particularly useful in a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
摘要:
The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a making a molecular sieve catalyst composition by forming a slurry by combining a molecular sieve, a binder and a matrix material, wherein the slurry has a pH, above or below the isoelectric point of the molecular sieve. The catalyst composition has improved attrition resistance, particularly useful in a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
摘要:
A catalyst composition that comprises an over flocculated molecular sieve and a phosphorous compound and, optionally, a non-over flocculated molecular sieve. A method of preparing a catalyst composition that comprises mixing an over flocculated molecular sieve and a phosphorous compound and, optionally, a non-over flocculated molecular sieve.
摘要:
This invention provides an attrition resistant metalloaluminophosphate molecular sieve catalyst composition, methods of making the catalyst composition and processes for using the catalyst composition. The metalloaluminophosphate molecular sieve catalyst composition is highly attrition resistant in dried as well as fully calcined forms.
摘要:
This invention provides methods of making molecular sieve catalyst particles, molecular sieve slurries that can be used in such methods, molecular sieve catalyst compositions and their use in catalytic hydrocarbon conversion processes. In one of its aspects, the invention provides a method of making molecular sieve catalyst particles, the method comprising the steps of: a) providing a solution or suspension of an aluminum-containing inorganic oxide precursor in a liquid medium; b) combining the solution or suspension of aluminum-containing inorganic oxide precursor with a molecular sieve, and optionally other formulating agents, to form a catalyst formulation slurry; c) aging the catalyst formulation slurry to generate in said slurry a percentage, or increase in said slurry the existing percentage, of aluminum atoms of the aluminum-containing precursor in the form of oligomers having a sharp 27Al NMR peak at 62-63 ppm; and d) forming molecular sieve catalyst particles from the catalyst formulation slurry. The catalyst compositions obtained by the methods of the present invention have improved attrition resistance, and are particularly useful in hydrocarbon conversion processes.
摘要翻译:本发明提供制备分子筛催化剂颗粒,可用于这些方法的分子筛浆料,分子筛催化剂组合物及其在催化烃转化方法中的应用的方法。 在其一个方面,本发明提供了制备分子筛催化剂颗粒的方法,该方法包括以下步骤:a)提供含铝无机氧化物前体在液体介质中的溶液或悬浮液; b)将含铝的无机氧化物前体的溶液或悬浮液与分子筛和任选的其它配制剂组合以形成催化剂配方浆料; c)使催化剂配方浆料老化,以在所述浆料中产生百分比,或增加所述浆料中现有百分比的含铝前体的铝原子具有在62℃具有尖锐的27 C NMR峰的低聚物形式, 63 ppm; 和d)从催化剂配方浆料形成分子筛催化剂颗粒。 通过本发明的方法获得的催化剂组合物具有改善的耐磨耗性,并且在烃转化方法中特别有用。
摘要:
This invention provides methods of making molecular sieve catalyst particles, molecular sieve slurries that can be used in such methods, molecular sieve catalyst compositions and their use in catalytic hydrocarbon conversion processes. In one of its aspects, the invention provides a method of making molecular sieve catalyst particles, the method comprising the steps of: a) providing a solution or suspension of an aluminum-containing inorganic oxide precursor in a liquid medium; b) combining the solution or suspension of aluminum-containing inorganic oxide precursor with a molecular sieve, and optionally other formulating agents, to form a catalyst formulation slurry; c) aging the catalyst formulation slurry to generate in said slurry a percentage, or increase in said slurry the existing percentage, of aluminum atoms of the aluminum-containing precursor in the form of oligomers having a sharp 27Al NMR peak at 62-63 ppm; and d) forming molecular sieve catalyst particles from the catalyst formulation slurry. The catalyst compositions obtained by the methods of the present invention have improved attrition resistance, and are particularly useful in hydrocarbon conversion processes.
摘要翻译:本发明提供制备分子筛催化剂颗粒,可用于这些方法的分子筛浆料,分子筛催化剂组合物及其在催化烃转化方法中的应用的方法。 在其一个方面,本发明提供了制备分子筛催化剂颗粒的方法,该方法包括以下步骤:a)提供含铝无机氧化物前体在液体介质中的溶液或悬浮液; b)将含铝的无机氧化物前体的溶液或悬浮液与分子筛和任选的其它配制剂组合以形成催化剂配方浆料; c)使所述催化剂配方浆料老化以在所述浆料中产生一种百分比,或增加所述浆料中含铝前体的铝原子的现有百分比,其具有尖锐的Al 2 O 3 在62-63ppm的NMR峰; 和d)从催化剂配方浆料形成分子筛催化剂颗粒。 通过本发明的方法获得的催化剂组合物具有改善的耐磨耗性,并且在烃转化方法中特别有用。
摘要:
This invention is directed to a hardened molecular sieve catalyst composition, a method of making the composition and a method of using the composition. The catalyst composition is made by mixing together molecular sieve, liquid, and an effective hardening amount of a dried molecular sieve catalyst to form a slurry. The slurry is dried, and then calcined to form the hardened molecular sieve catalyst composition. The hardened molecular sieve catalyst is highly attrition resistant.
摘要:
A catalyst composition that comprises an over flocculated molecular sieve and optionally, a phosphorous compound and, optionally, a non-over flocculated molecular sieve. A method of preparing a catalyst composition that comprises mixing an over flocculated molecular sieve and optionally, a phosphorous compound and, optionally, a non-over flocculated molecular sieve.