摘要:
Crude 2-methyleneglutaronitrile containing as impurities a metal halide, a trialkylamine, and the trimer or a higher polymer of acrylonitrile can be effectively purified by treating the crude 2-methyleneglutaronitrile with hydrochloric acid, sulfuric acid or nitric acid of a concentration of 1 to 30% by weight and then subjecting the treated methyleneglutaronitrile to vacuum distillation.
摘要:
A process for preparing a pentaerythritol-tetrakis(3-alkylthio-propionate) represented by the general formula: ##STR1## wherein R represents an alkyl group having from 8 to 30 carbon atoms, is disclosed, comprising reacting an alkylmercaptan having from 8 to 30 carbon atoms with an acrylic ester or an acrylic amide to form a 3-alkylthio-propionic acid ester or a 3-alkylthio-propionic acid amide, hydrolyzing the ester or amide to form a 3-alkylthio-propionic acid, and then reacting this product with pentaerythritol. The desired product can easily be obtained at high purity and high yield by this process.
摘要:
From an acrylonitrile-dimerization liquid product prepared by contacting acrylonitrile with a specific catalyst composed of a metal halide and a trialkylamine, 2-methyleneglutaronitrile is efficiently recovered by a process which comprises contacting the reaction liquid product under stirring with benzene, toluene or xylene as well as with water in specific ratios, and then separating the resulting aromatic hydrocarbon layer from the mixture to recover 2-methyleneglutaronitrile.
摘要:
A stabilizer composition for synthetic resin is described comprising a piperazine derivative represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents an alkyl group having from 12 to 20 carbon atoms or a 2,2,6,6-tetramethyl-4-piperidyl group; R.sub.3 and R.sub.4 each represents a hydrogen atom or a methyl group; and n and m each represents 2 or 3.A synthetic resin composition is also described comprising polyolefin and the aforesaid piperazine derivative.
摘要翻译:含有下式(I)表示的哌嗪衍生物的合成树脂用稳定剂组合物:其中,R 1和R 2各自表示碳原子数12〜20的烷基或2,2,6 ,6-四甲基-4-哌啶基; R 3和R 4各自表示氢原子或甲基; n和m各自表示2或3.还描述了包含聚烯烃和上述哌嗪衍生物的合成树脂组合物。
摘要:
A washing solution for flexographic ink is disclosed, comprising the components (A) to (E):Component (A):0.05 to 35 wt % of an amine selected from water-soluble aliphatic primary or secondary amines having 2 to 3 carbon atoms, ammonia and morpholine, or an alkaline substance selected from hydroxides, carbonates, borates, silicates, phosphates and alkaline lower fatty acid salts of alkali metal;Component (B):0.001 to 1.0 wt % of a defoaming agent;Component (C):0 to 75 wt % of an aliphatic polyhydric alcohol having a molecular weight of 500 or less;Component (D):0 to 75 wt % of a water-soluble aliphatic monohydric alcohol having 1 to 4 carbon atoms; andComponent (E):25 to 99.9 wt % of water.
摘要:
Dibromo-dicyanobutane is purified by washing with an aqueous solution of a compound wherein a cationic component is an alkali metal, alkaline earth metal, or ammonium ion and an anionic component is an oxygen-containing anion. The process can prevent dibromo-dicyanobutane from coloration, an irritating odor, and caking.
摘要:
Tertiary amines are prepared by reacting a long-chain olefin with carbon monoxide, hydrogen, and a primary or secondary amine in the presence of a catalyst composed of a rhodium- and/or ruthenium-containing compound using a specific solvent, followed by phase separation of the reaction product. This process facilitates recovery and re-use of the expensive catalysts.