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    Polyhydroxyalkyl polycarbonamides for the production of flame-resistant polyurethane rigid foams and integral foams
    2.
    发明授权
    Polyhydroxyalkyl polycarbonamides for the production of flame-resistant polyurethane rigid foams and integral foams 失效
    用于生产耐火聚氨酯硬质泡沫和整体泡沫的聚羟基烷基聚碳酰胺

    公开(公告)号：US4540626A

    公开(公告)日：1985-09-10

    申请号：US645205

    申请日：1984-08-29

    申请人： Peter Haas ,  Geza Avar ,  Hartwig Grammes

    发明人： Peter Haas ,  Geza Avar ,  Hartwig Grammes

    IPC分类号： C08G18/38 ,  C08G18/14 ,  B32B29/00

    CPC分类号： C08G18/3825 ,  Y10T428/249989

    摘要： The invention relates to the use of poly-N,N-di-(hydroxyalkyl)-polycarbonamides of aliphatic or cycloaliphatic polycarboxylic acids as reactive flame-retardants for polyurethane foams, and in particular polyurethane integral skin foams and polyurethane rigid foams which are produced with the aid of organic blowing agents. These reactive flame-retardants are added in quantities of from 11.5 to 50 parts by weight, and most preferably from 12 to 25 parts by weight, based on 100 parts of the relatively high molecular weight polyol used for the preparation of the foam. The integral skin or rigid foams produced are flame-resistant and because of their reduced flammability are capable of passing various regulation fire tests, and in particular those testing foams for use in vehicles for transport.

    摘要翻译： 本发明涉及脂肪族或脂环族多羧酸的聚-N，N-二（羟基烷基） - 聚碳酰胺作为聚氨酯泡沫的反应性阻燃剂，特别是聚氨酯整体皮泡沫和聚氨酯硬质泡沫的用途， 有机发泡剂的帮助。 基于100份用于制备泡沫的相对较高分子量的多元醇，这些反应性阻燃剂的加入量为11.5至50重量份，最优选为12至25重量份。 所生产的整体皮肤或刚性泡沫具有阻燃性，并且由于其可燃性降低，能够通过各种调节性火灾试验，特别是用于运输车辆的测试泡沫。

    Polyurethanes prepared or combined with another material and a process for their manufacture
    3.
    发明授权
    Polyurethanes prepared or combined with another material and a process for their manufacture 失效
    制备或与另一种材料组合的聚氨酯及其制造方法

    公开(公告)号：US4775558A

    公开(公告)日：1988-10-04

    申请号：US98099

    申请日：1987-09-17

    申请人： Peter Haas ,  Geza Avar

    发明人： Peter Haas ,  Geza Avar

    IPC分类号： C08G18/00 ,  C08G18/64 ,  C08K5/1515 ,  C08L75/04 ,  C08G18/14

    CPC分类号： C08K5/1515 ,  C08L75/04 ,  Y10T428/31573 ,  Y10T428/31576 ,  Y10T428/3158 ,  Y10T428/31587

    摘要： Polyurethanes which have been prepared or combined with another material are made by combining or applying a polyurethane-forming reaction mixture or polyurethane to another material such as a PVC foil or textile. The polyurethane-forming mixture or polyurethane is made up of an organic polyisocyanate, a high molecular weight isocyanate reactive material, a catalyst and a stabilizer against thermolysis and contact discoloration. The required stabilizer is an epoxide having an epoxide equivalent weight between 57 and 10,000. Other additives commonly used in polyurethane chemistry such as blowing agents, chain extenders and surfactants may also be employed. The polyurethane composites thus produced are characterized by improved thermal stability and reduced discoloration.

    摘要翻译： 已经制备或与另一种材料组合的聚氨酯通过将形成聚氨酯的反应混合物或聚氨酯与另外的材料如PVC箔或织物组合或施加而制成。 聚氨酯形成混合物或聚氨酯由有机多异氰酸酯，高分子量异氰酸酯反应性材料，催化剂和抗热分解和接触变色的稳定剂组成。 所需的稳定剂是环氧当量为57至10,000的环氧化物。 还可以使用通常用于聚氨酯化学中的其它添加剂，例如发泡剂，扩链剂和表面活性剂。 如此制备的聚氨酯复合材料的特征在于改善的热稳定性和减少的变色。

    Process for the production of optionally foamed polyurethanes which are combined or fabricated with another material
    4.
    发明授权
    Process for the production of optionally foamed polyurethanes which are combined or fabricated with another material 失效
    用于生产任选发泡的聚氨酯的方法，其与另一种材料组合或制造

    公开(公告)号：US4761307A

    公开(公告)日：1988-08-02

    申请号：US817222

    申请日：1986-01-08

    申请人： Peter Haas ,  Hans-Albrecht Freitag ,  Geza Avar

    发明人： Peter Haas ,  Hans-Albrecht Freitag ,  Geza Avar

    IPC分类号： C08G18/00 ,  C08G18/18 ,  C08G18/20 ,  C08J9/02 ,  B05D5/00 ,  B05D3/02 ,  B32B5/18

    CPC分类号： C08G18/1825 ,  C08G18/2081

    摘要： The present invention is directed to a process for the production of optionally foamed polyurethanes which are combined or fabricated with another material, comprising reacting compounds with molecular weights from 400 to 10,000 containing at least 2 isocyanate reactive hydrogen atoms with polyisocyanates in the presence of catalysts containing tertiary amino groups and combining or fabricating the resulting polyurethane with another material, characterized in that the catalysts used are diffusion resistant aminoalkanols corresponding to the general formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may be identical or different and represent hydrogen or a C.sub.1 -C.sub.6 alkyl group,R.sup.5, R.sup.6, R.sup.7 and R.sup.8 may be identical or different and represent a C.sub.1 -C.sub.6 alkyl group or together form a C.sub.2 -C.sub.6 alkylene group which may contain hetero atoms such as O or NR (R=C.sub.1 -C.sub.4 alkyl), and n and m may be identical or different and represent integers from 1 to 6.

    摘要翻译： 本发明涉及生产任选发泡的聚氨酯的方法，其与另一种材料组合或制造，包括在含有至少2个异氰酸酯反应性氢原子的化合物中含有至少2个异氰酸酯反应性氢原子的化合物与多异氰酸酯反应，所述催化剂含有 叔氨基，并且将所得聚氨酯与另一种材料组合或制造，其特征在于所用的催化剂是对应于通式为“IMAGE”的扩散阻力氨基链烷醇，其中R 1，R 2，R 3和R 4可以相同或不同，表示氢或 C1-C6烷基，R5，R6，R7和R8可以相同或不同，表示C1-C6烷基或一起形成可含有杂原子如O或NR的C 2 -C 6亚烷基（R = C1- C4烷基），n和m可以相同或不同，表示1〜6的整数。

    Use of polyhydroxyalkyl monoureas for polyurethane foams, dispersions of the polyhydroxyalkyl monoureas in polyols and new tris-hydroxyalkyl monoureas
    7.
    发明授权
    Use of polyhydroxyalkyl monoureas for polyurethane foams, dispersions of the polyhydroxyalkyl monoureas in polyols and new tris-hydroxyalkyl monoureas 失效
    聚羟基烷基单脲在聚氨酯泡沫中的应用，多羟基烷基单脲在多元醇中的分散和新的三羟基烷基单脲

    公开(公告)号：US4546121A

    公开(公告)日：1985-10-08

    申请号：US645204

    申请日：1984-08-29

    申请人： Peter Haas ,  Geza Avar ,  Hartwig Grammes

    发明人： Peter Haas ,  Geza Avar ,  Hartwig Grammes

    IPC分类号： C07C275/10 ,  C08G18/38 ,  C08G18/14

    CPC分类号： C08G18/3829 ,  C07C275/10 ,  Y10S516/07

    摘要： This invention relates to the use of mono- to tetrahydroxyalkyl monoureas corresponding to the following general formula ##STR1## in which A represents a C.sub.2 -C.sub.6 -alkylene group optionally containing OH-groups,n=0, 1 or 2.n'=1 or 2 andn+n'=1, 2, 3 or 4, preferably 2-4 and, more preferably, 3,as reactive flameproofing agents in quantities of from 3 to 100 parts by weight and preferably in quantities of from 11.5 to 50 parts by weight, based on 100 parts by weight of relatively high molecular weight compounds having molecular weights of from 400 to 10,000, preferably relatively high molecular weight polyols, for the production of flameproofed polyurethane foams, and preferably integral skin foams or semirigid to rigid foams. The invention also relates to dispersions or suspensions of mono- to tetrapolyhydroxyalkyl monoureas corresponding to the above formula in relatively high molecular weight compounds containing terminal hydroxyl, primary or secondary amino, carboxyl or hydrazide groups. Preferred are relatively high molecular weight polyols, having a molecular weight in the range from 400 to 10,000. The content of polyhydroxyalkyl monoureas amounts to between 3 and 50% by weight. Finally, the invention relates to tris-hydroxyalkyl monoureas corresponding to the above formula in which n=2, n'=1 and the sum of n+n'=3.

    摘要翻译： 本发明涉及对应于以下通式“IMAGE”的单 - 四羟基烷基单脲的用途，其中A表示任选含有OH-基团，n = 0,1或2的C 2 -C 6亚烷基。n'= 1 或2和n + n'= 1,2,3或4，优选2-4和更优选3作为反应性防火剂，其量为3至100重量份，优选为11.5至50 重量份，基于100重量份分子量为400至10,000的较高分子量化合物，优选相对高分子量的多元醇，用于生产防火聚氨酯泡沫，并且优选为整体皮肤泡沫或半刚性至刚性泡沫 。 本发明还涉及对应于上述式的单 - 四羟基烷基单脲的分散体或悬浮液，其含有末端羟基，伯氨基或仲氨基，羧基或酰肼基团的较高分子量化合物。 优选分子量在400至10,000的较高分子量多元醇。 聚羟基烷基单脲的含量为3至50重量％。 最后，本发明涉及对应于上式的三羟基烷基单脲，其中n = 2，n'= 1，n + n'= 3的和。

    Polyisocyanate compositions containing reversibly blocked catalysts and addition products of sulfonyl isocyanates with catalysts having a tin(II)- or tin(IV)-carboxylate structure
    10.
    发明授权
    Polyisocyanate compositions containing reversibly blocked catalysts and addition products of sulfonyl isocyanates with catalysts having a tin(II)- or tin(IV)-carboxylate structure 失效
    含有可逆封闭的催化剂的多异氰酸酯组合物和具有锡（II） - 或锡（IV） - 羧酸盐结构的催化剂的磺酰基异氰酸酯的加成产物

    公开(公告)号：US4824595A

    公开(公告)日：1989-04-25

    申请号：US633732

    申请日：1984-07-23

    申请人： Roland Richter ,  Hanns P. Muller ,  Rudolf Hombach ,  Manfred Dollhausen ,  Geza Avar ,  Hans-Albrecht Freitag

    发明人： Roland Richter ,  Hanns P. Muller ,  Rudolf Hombach ,  Manfred Dollhausen ,  Geza Avar ,  Hans-Albrecht Freitag

    IPC分类号： C08G18/00 ,  C08G18/16 ,  C08G18/24 ,  C08G18/72 ,  C09K3/00

    CPC分类号： C08G18/72 ,  C08G18/16 ,  C08G18/24

    摘要： The present invention relates to polyisocyanate compositions containing reversibly blocked catalysts for the isocyanate addition reaction, characterized in that they contain(a) at least one organic polyisocyanate,(b) at least one addition product dissolved or dispersed in the polyisocyanate compositions, of a sulfonyl isocyanate with a tertiary amine and/or with a catalyst having a tin(II)- or tin(IV)-carboxylate structure as the reversibly blocked catalyst.The present invention also relates to a process for producing these polyisocyanate compositions and to the use of new polyisocyanate compositions as reactants for compounds containing isocyanate-reactive groups for the production of isocyanate addition products such as polyurethane plastics using a one-component or two-component principle. The present invention finally relates to the latent polyurethane catalysts prepared from a sulfonyl isocyanate and a tin(II)- or tin(IV)-carboxylate.

    摘要翻译： 本发明涉及含有用于异氰酸酯加成反应的可逆封闭的催化剂的多异氰酸酯组合物，其特征在于它们含有（a）至少一种有机多异氰酸酯，（b）至少一种溶解或分散在多异氰酸酯组合物中的加成产物， 异氰酸酯与叔胺和/或具有锡（II） - 或锡（IV） - 羧酸盐结构的催化剂作为可逆阻挡的催化剂。 本发明还涉及一种制备这些多异氰酸酯组合物的方法，以及使用新的多异氰酸酯组合物作为含有异氰酸酯反应性基团的化合物的反应物，用于生产异氰酸酯加成产物如聚氨酯塑料，其使用单组分或双组分 原理。 本发明最终涉及由磺酰基异氰酸酯和锡（II） - 或锡（IV） - 羧酸酯制备的潜在聚氨酯催化剂。