摘要:
Disclosed is a method for producing semi-finished products from a shape memory alloy, particularly an NiTi shape memory alloy, wherein a powder is first produced from a shape memory alloy, and subsequently the powder is divided into a coarse fraction and a fine fraction in a separating cut T. While the fine fraction is required, in particular, for the production of a first semi-finished product, employing the metal injection molding (MIM) method, the coarse fraction can be used for the production of a second semi-finished product, employing the hot isostatic pressing (HIP) method. The advantages of the invention can be summarized as follows. The MIM method for producing semi-finished products from a shape memory alloy is qualitatively improved and more cost-effective to implement if the coarse fraction that is typically obtained during powder production, but not used for the MIM process, can advantageously be supplied to a further process, in this case the HIP process. Due to the use of particularly fine powder, the semi-finished products produced by way of the MIM method have an advantageous, powder-metallurgical microstructure. In particular, the alloying elements are distributed particularly homogeneously in these semi-finished products, casting flaws or segregations do not usually occur, no anisotropy of the structure occurs as a result of the processing steps, and ternary alloys can be processed, which due to the mechanical properties thereof, cannot be processed by way of conventional forming methods.
摘要:
Disclosed is a method for producing semi-finished products from a shape memory alloy, particularly an NiTi shape memory alloy, wherein a powder is first produced from a shape memory alloy, and subsequently the powder is divided into a coarse fraction and a fine fraction in a separating cut T. While the fine fraction is required, in particular, for the production of a first semi-finished product, employing the metal injection molding (MIM) method, the coarse fraction can be used for the production of a second semi-finished product, employing the hot isostatic pressing (HIP) method. The advantages of the invention can be summarized as follows. The MIM method for producing semi-finished products from a shape memory alloy is qualitatively improved and more cost-effective to implement if the coarse fraction that is typically obtained during powder production, but not used for the MIM process, can advantageously be supplied to a further process, in this case the HIP process. Due to the use of particularly fine powder, the semi-finished products produced by way of the MIM method have an advantageous, powder-metallurgical microstructure. In particular, the alloying elements are distributed particularly homogeneously in these semi-finished products, casting flaws or segregations do not usually occur, no anisotropy of the structure occurs as a result of the processing steps, and ternary alloys can be processed, which due to the mechanical properties thereof, cannot be processed by way of conventional forming methods.
摘要:
The invention relates to a composite membrane for selective gas separation, comprising a layer system having a through-and-through porous, mechanically stable carrier layer, which has an average pore size in the μm range, further having at least one through-and-through porous intermediate layer, which is disposed on the carrier layer and has an average pore size in the range between 2 and 200 nm, and further having a gas-tight functional layer, which is disposed on the intermediate layer and is made of mixed-conductive material having a maximum layer thickness of 1 μm. The carrier layer comprises structural ceramics, a metal or a cermet and has a layer thickness of no more than 1 mm. The intermediate layer is present in a total layer thickness of no more than 100 μm and has an average pore size in the range of 10 and 100 nm. The functional layer comprises a perovskite, a fluorite, or a material having a K2NiF4structure, such as La1-xSrxCo1-yFeyO3-δ(LSCF). The layer thickness of the functional layer is no more than 50 nm, particularly between 25 and 400 nm. In order to produce said composite membrane, at least one porous intermediate layer is applied onto a through-and-through porous, mechanically stable carrier layer, which has an average pore size in the μm range, said intermediate layer having an average pore size in the range between 2 and 200 nm. A further gas-tight, functional layer made of a mixed-conductive material and having a maximum layer thickness of 1 μm is applied onto said intermediate layer.
摘要:
The invention relates to an anode for a high-temperature fuel cell having an anode substrate and/or a functional anode layer, comprising a porous ceramic structure having a first predominantly electron-conducting phase with the general empirical formula Sr1-xLnxTiO3 wherein Ln=Y, Gd to Lu and 0.03
摘要翻译:本发明涉及一种具有阳极基板和/或功能性阳极层的高温燃料电池的阳极,其包括具有第一主要电子传导相的多孔陶瓷结构,其具有通常的经验式Sr1-xLnxTiO3,其中Ln = Y ,Gd至Lu和0.03
摘要:
The material according to the invention is based on a material having the composition Ln6WO12 with a defect fluorite structure in which the cations, at least partially, have been substituted in a defined manner in the A and/or B position. It has the following composition: Ln1-xAx)6(W1-yBy)zO12-δ where Ln=an element from the group (La, Pr, Nd, Sm), A=at least one element from the group (La, Ce, Pr, Nd, Eu, Gd, Tb, Er, Yb, Ca, Mg, Sr, Ba, Th, In, Pb), B=at least one element from the group (Mo, Re, U, Cr, Nb), 0≦x≦0.7 and 0≦y≦0.5, wherein, however, either x or y>0, 1.00≦z≦1.25 and 0≦δ≦0.3. The mixed proton-electron conducting material exhibits an improved mixed conductivity, good chemical stability as well as good sintering properties, and can be used in particular as a material for a hydrogen-separating membrane or as a electrolyte at higher temperatures.
摘要翻译:根据本发明的材料基于具有缺陷萤石结构的组成为Ln6WO12的材料,其中阳离子至少部分地以限定的方式在A和/或B位置被取代。 它具有以下组成:Ln1-xAx)6(W1-yBy)zO12-delta其中Ln =来自基团的元素(La,Pr,Nd,Sm),A =至少一种元素(La,Ce ,Pr,Nd,Eu,Gd,Tb,Er,Yb,Ca,Mg,Sr,Ba,Th,In,Pb),B =至少一种元素(Mo,Re,U,Cr,Nb) ,0 @ x @ 0.7和0 @ y @ 0.5,其中,然而,x或y> 0,1.00 @ z @ 1.25和0 @ 混合的质子 - 电子导电材料具有改进的混合导电性,良好的化学稳定性以及良好的烧结性能,并且特别可用作氢分离膜或更高温度下的电解质的材料。
摘要:
A cathode for high-temperature fuel cell, comprising a layer of porous particles applied on a sintered electrolyte, the layer having a surface area of 15 to 900 m2 per gram and the average size of the porous particles do not exceed 30 nm and a method for preparing the same.
摘要:
Anode-supported high-temperature fuel cells with a substrate and an anode of stabilised zirconium dioxide and metallic nickel can be destroyed by air penetrating on the fuel gas side. Reoxidation causes the volume of the nickel in the anode to change. The resultant mechanical stresses may destroy the gas-impermeable electrolyte. The invention provides oxygen scavengers that can be produced at low cost for the anode, which more effectively bind the oxygen that penetrates on the fuel gas side than oxygen scavengers according to the prior art.
摘要:
A composite membrane for selective gas separation, comprises a layer system having a continuously porous, mechanically stable carrier layer, which has an average pore size in the μm range, further having at least one continuously porous intermediate layer, which is disposed on the carrier layer and has an average pore size in the range of 2 to 200 nm, and further having a gastight functional layer, which is disposed on the intermediate layer and is made of a mixed-conductive material having a maximum layer thickness of 1 μm. The carrier layer comprises a structural ceramic, a metal, or a cermet and has a layer thickness of no more than 1 mm. The intermediate layer is present with a total layer thickness of no more than 100 μm and has an average pore size in the range of 10 to 100 nm. The functional layer comprises a perovskite, a fluorite, or a material having a K2NiF4 structure, such as La1-xSrxCo1-yFeyO3-8 (LSCF). The layer thickness of the functional layer is no more than 50 nm, and particularly between 25 and 400 nm. In order to produce this composite membrane, at least one porous intermediate layer is applied onto a continuously porous, mechanically stable carrier layer, which has an average pore size in the μm range, wherein the intermediate layer has an average pore size in the range of 2 to 200 nm. A further gastight, functional layer made of a mixed-conductive material and having a maximum layer thickness of 1 μm is applied onto the intermediate layer.
摘要:
The invention relates to an anode for a high-temperature fuel cell having an anode substrate and/or a functional anode layer, comprising a porous ceramic structure having a first predominantly electron-conducting phase with the general empirical formula Sr1-xLnxTiO3 wherein Ln=Y, Gd to Lu and 0.03
摘要翻译:本发明涉及一种具有阳极基板和/或功能性阳极层的高温燃料电池的阳极,其包括具有第一主要电子传导相的多孔陶瓷结构,其具有通常的经验式Sr1-xLnxTiO3,其中Ln = Y ,Gd至Lu和0.03
摘要:
A heat-insulating layer system for a metallic structural component, especially for a structural component of a gas turbine such as an aircraft engine, includes an adhesion promoting layer (12), an inner contact layer (14), and an outer cover layer (15) , whereby the adhesion promoting layer (12). is disposed on a surface (11) of the gas turbine structural component (10). The inner contact layer (14) is formed of a zirconium oxide partially stabilized with yttrium or yttrium oxide, and the outer cover layer (15) is formed of a material that consists of at least one component with at least one phase, which stoichiometrically comprises 1 to 80 Mol-% Mx2O3, 0.5 to 80 Mol-% MyO and Al2O3 as a remainder with incidental impurities, wherein Mx is selected from the elements chromium and barium or mixtures thereof, and wherein My is selected from the alkaline earth metals, the transition metals and the rare earths or mixtures thereof.
摘要翻译:用于金属结构部件的隔热层系统,特别是用于诸如飞机发动机的燃气轮机的结构部件,包括粘附促进层(12),内接触层(14)和外覆盖层 15),由此附着促进层(12)。 设置在燃气轮机结构部件(10)的表面(11)上。 内部接触层(14)由用钇或氧化钇部分稳定的氧化锆形成,并且外覆盖层(15)由至少一种具有至少一个相的成分组成的材料形成,所述至少一个相包含化学计量 1至80摩尔%Mx 2 O 3 3,0.5至80摩尔%MyO和Al 2 O 3 3 / >其中M x选自元素铬和钡或其混合物,其中My选自碱土金属,过渡金属和稀土或其混合物。