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    Method for the emulsion polymerization of olefins
    1.
    发明授权
    Method for the emulsion polymerization of olefins 失效
    烯烃乳液聚合方法

    公开(公告)号：US07129292B1

    公开(公告)日：2006-10-31

    申请号：US10168113

    申请日：2000-10-18

    申请人： Marc Oliver Kristen ,  Lambertus Manders ,  Stefan Mecking ,  Florian M. Bauers ,  Rolf Mülhaupt

    发明人： Marc Oliver Kristen ,  Lambertus Manders ,  Stefan Mecking ,  Florian M. Bauers ,  Rolf Mülhaupt

    IPC分类号： C08F2/16

    CPC分类号： C08F10/02 ,  C08F10/00 ,  C08F2/22 ,  C08F4/80 ,  C08F4/7006 ,  C08F4/7031 ,  C08F4/7022 ,  C08F4/7027 ,  C08F4/7019

    摘要： A process for emulsion polymerizing one or more olefins involves reacting it/them with at least one complex compound of the formula Ia or b where M is a transition metal from groups 7 to 10 of the Periodic Table of the Elements and is preferably Ni in aqueous dispersion and at least one radical R1 to R3 and optionally one radical R4 to R9 contains a hydrophilic group X, selection being made from —SO3−, —O—PO32−, NH(R15)2+, N(R15)3+ or —(OCH2CH2)nOH, where n is an integer between 1 and 15. For the process of the invention it is optional to use an activator such as, for example, olefin complexes of rhodium or of nickel. This invention further relates to dispersions of polyolefins such as polyethylene and ethylene copolymers in water, for example, and to the use of the aqueous dispersions of the invention for paper applications such as paper coating or surface sizing, paints, adhesive base materials, molded foams such as mattresses, textile and leather applications, carpet back coatings, or pharmaceutical applications.

    摘要翻译： 用于将一种或多种烯烃乳液聚合的方法涉及使其与至少一种式Ia或b的络合物反应，其中M是元素周期表第7至10族的过渡金属，并且优选为Ni 分散体和至少一个R 1至R 3基团和任选的一个基团R 4至R 9包含一个 亲水基团X，选自-SO 3 - ， - O-PO 3 - ， - NH 2， - NH （R 15）2 N 2 O 3 N（R 15）3 或+ - 或 - （OCH 2 CH 2）n OH，其中n是1和15之间的整数。对于 本发明的方法任选使用活化剂，例如铑或镍的烯烃络合物。 本发明还涉及聚烯烃如聚乙烯和乙烯共聚物在水中的分散体，以及本发明的水性分散体用于纸张涂布或表面施胶，涂料，粘合剂基材，模塑泡沫 例如床垫，纺织和皮革应用，地毯背部涂层或药物应用。

    CATALYST SYSTEM FOR POLYMERIZATION OF OLEFINIC MONOMERS, PROCESS FOR PREPARING POLYMERS, AND POLYMERS PREPARED BY THE PROCESS
    2.
    发明申请
    CATALYST SYSTEM FOR POLYMERIZATION OF OLEFINIC MONOMERS, PROCESS FOR PREPARING POLYMERS, AND POLYMERS PREPARED BY THE PROCESS 失效
    烯烃单体聚合催化剂体系，制备聚合物的方法和工艺制备的聚合物

    公开(公告)号：US20100190931A1

    公开(公告)日：2010-07-29

    申请号：US12452713

    申请日：2008-07-22

    申请人： Marc Oliver Kristen ,  Rolf Mülhaupt ,  Georg Müller

    发明人： Marc Oliver Kristen ,  Rolf Mülhaupt ,  Georg Müller

    IPC分类号： C08F4/64 ,  C08L23/06 ,  B32B5/02 ,  B01J32/00 ,  B01J31/14 ,  B01J31/06

    CPC分类号： C08F10/00 ,  C08F4/65925 ,  Y10S526/943 ,  Y10T428/249924 ,  C08F4/027

    摘要： The present invention relates to new catalyst supports comprising nanofibers, a catalyst system comprising these supports as well as a process for preparing nanocomposites and the nanocomposites prepared. The invention especially concerns a supported catalyst system for polymerization of olefins, comprising a support made of fibers or a fleece of fibers, wherein the mean fiber diameter is less than 1000 nm, preferably less than 500 nm and the mean fiber length is more than 200,000 nm, preferably more than 500,000 nm and especially preferred more than 1,000,000 nm as well as a process for polymerizing olefinic systems in the presence of these catalyst systems and the resulting nanocomposites.

    摘要翻译： 本发明涉及包含纳米纤维的新催化剂载体，包含这些载体的催化剂体系以及制备纳米复合材料的方法和制备的纳米复合材料。 本发明特别涉及用于烯烃聚合的负载型催化剂体系，其包括由纤维制成的载体或纤维的绒毛，其中平均纤维直径小于1000nm，优选小于500nm，平均纤维长度大于20万 nm，优选大于500,000nm，特别优选大于1,000,000nm，以及在这些催化剂体系存在下聚合烯属体系的方法和所得的纳米复合材料。

    Catalyst system for polymerization of olefinic monomers, process for preparing polymers, and polymers prepared by the process
    5.
    发明授权
    Catalyst system for polymerization of olefinic monomers, process for preparing polymers, and polymers prepared by the process 失效
    用于聚合烯烃单体的催化剂体系，制备聚合物的方法和通过该方法制备的聚合物

    公开(公告)号：US08133832B2

    公开(公告)日：2012-03-13

    申请号：US12452713

    申请日：2008-07-22

    申请人： Marc Oliver Kristen ,  Rolf Mülhaupt ,  Georg Müller

    发明人： Marc Oliver Kristen ,  Rolf Mülhaupt ,  Georg Müller

    IPC分类号： C08F4/02 ,  C08F4/642 ,  C08F4/6592

    CPC分类号： C08F10/00 ,  C08F4/65925 ,  Y10S526/943 ,  Y10T428/249924 ,  C08F4/027

    摘要： The present invention relates to new catalyst supports comprising nanofibers, a catalyst system comprising these supports as well as a process for preparing nanocomposites and the nanocomposites prepared. The invention especially concerns a supported catalyst system for polymerization of olefins, comprising a support made of fibers or a fleece of fibers, wherein the mean fiber diameter is less than 1000 nm, preferably less than 500 nm and the mean fiber length is more than 200,000 nm, preferably more than 500,000 nm and especially preferred more than 1,000,000 nm as well as a process for polymerizing olefinic systems in the presence of these catalyst systems and the resulting nanocomposites.

    摘要翻译： 本发明涉及包含纳米纤维的新催化剂载体，包含这些载体的催化剂体系以及制备纳米复合材料的方法和制备的纳米复合材料。 本发明特别涉及用于烯烃聚合的负载型催化剂体系，其包括由纤维制成的载体或纤维的绒毛，其中平均纤维直径小于1000nm，优选小于500nm，平均纤维长度大于20万 nm，优选大于500,000nm，特别优选大于1,000,000nm，以及在这些催化剂体系存在下聚合烯属体系的方法和所得的纳米复合材料。

    Organophilic phyllosilicates
    6.
    发明授权
    Organophilic phyllosilicates 失效
    亲缘页硅酸盐

    公开(公告)号：US06197849B1

    公开(公告)日：2001-03-06

    申请号：US09248649

    申请日：1999-02-11

    申请人： Carsten Zilg ,  Rolf Mülhaupt ,  Jürgen Finter

    发明人： Carsten Zilg ,  Rolf Mülhaupt ,  Jürgen Finter

    IPC分类号： C08K900

    CPC分类号： C08K9/04 ,  C08L63/00

    摘要： Organophilic phyllosilicates which have been prepared by treating a naturally occurring or synthetic phyllosilicate, or a mixture of such silicates, with a salt of a quaternary or other cyclic amidine compound, or with a mixture of such salts; polymeric systems, in particular thermoplastic polymers and thermosetting polymer systems, preferably epoxy resins, polyurethanes and rubbers, which comprise novel organophilic phyllosilicates, and also shapable moulding materials and finished mouldings in the form of composite materials, in particular in the form of nanocomposites.

    摘要翻译： 通过将天然存在的或合成的页硅酸盐或这种硅酸盐的混合物与季铵盐或其它环状脒化合物的盐或这些盐的混合物进行处理而制备的亲有性页硅酸盐; 聚合物系统，特别是热塑性聚合物和热固性聚合物体系，优选环氧树脂，聚氨酯和橡胶，其包含新型有机层状硅酸盐，以及成型模塑材料和复合材料形式的成型模制品，特别是纳米复合材料形式。

    Dental coating materials
    7.
    发明授权
    Dental coating materials 有权
    牙科涂料

    公开(公告)号：US07495037B2

    公开(公告)日：2009-02-24

    申请号：US10928540

    申请日：2004-08-27

    申请人： Norbert Moszner ,  Simone Klapdohr ,  Ulrich Salz ,  Jörg Zimmermann ,  Volker M. Rheinberger ,  Rolf Mülhaupt

    发明人： Norbert Moszner ,  Simone Klapdohr ,  Ulrich Salz ,  Jörg Zimmermann ,  Volker M. Rheinberger ,  Rolf Mülhaupt

    IPC分类号： A61K6/083 ,  A61K6/08 ,  A61K6/00 ,  C08F283/12

    CPC分类号： C09D183/04 ,  A61K6/0017 ,  Y10S522/908 ,  C08L83/16

    摘要： Polymerizable materials which contain (1) 1 to 80 wt.-% of at least one polysiloxane, (2) 0.1 to 5 wt.-% of one or more initiators for radical polymerization, (3) 0 to 60 wt.-% of radically polymerizable monomer and (4) 1 to 50 wt.-% of one or more radically polymerizable monomers which carry at least phosphonic acid group, sulphonic acid group and/or mono- or dihydrogen phosphoric acid ester group, the polysiloxane (1), the monomer (3) or both being substituted by fluorine. The materials are suitable in particular for the coating of natural or artificial teeth.

    摘要翻译： 含有（1）1至80重量％的至少一种聚硅氧烷的可聚合材料，（2）0.1至5重量％的一种或多种用于自由基聚合的引发剂，（3）0至60重量％ 可自由基聚合的单体和（4）1至50重量％的至少携带膦酸基，磺酸基和/或单或二氢磷酸酯基的一种或多种可自由基聚合的单体，聚硅氧烷（1）， 单体（3）或两者均被氟取代。 这些材料特别适用于天然或人造牙齿的涂层。

    Process for preparing polyether polyols
    9.
    发明授权
    Process for preparing polyether polyols 失效
    制备聚醚多元醇的方法

    公开(公告)号：US06469218B1

    公开(公告)日：2002-10-22

    申请号：US10136208

    申请日：2002-05-01

    申请人： Ornulf Rexin ,  Rolf Mülhaupt

    发明人： Ornulf Rexin ,  Rolf Mülhaupt

    IPC分类号： C07C4311

    CPC分类号： C08G65/105 ,  C08G65/2675

    摘要： The invention is directed to a process for preparing a polyether polyol by the polyaddition of an alkylene oxide on to a starter compound containing active hydrogen atoms under basic catalysis in the presence of phosphonium cations.

    摘要翻译： 本发明涉及通过在碱性催化下在鏻阳离子存在下将烯化氧加成到含活性氢原子的起始化合物上制备聚醚多元醇的方法。