公开(公告)号：US20110315199A1

公开(公告)日：2011-12-29

申请号：US13139594

申请日：2009-12-15

申请人： Marc Vogt ,  Dominique Jousset ,  Stéphane Bizet ,  Jean-Jacques Flat

发明人： Marc Vogt ,  Dominique Jousset ,  Stéphane Bizet ,  Jean-Jacques Flat

IPC分类号： H01L31/048 ,  H01L31/0216 ,  C08L77/00 ,  C08F291/06 ,  C08L51/00 ,  B32B37/00 ,  H01L31/0203

CPC分类号： C08G81/028 ,  C08L23/0869 ,  H01L31/049 ,  Y02E10/50 ,  C08L2666/20

摘要： One subject of the invention is the use of α film as a protective backsheet in a photovoltaic module, said film comprising at least one layer of a composition containing a polyamide-grafted polymer, this polyamide-grafted polymer comprising a polyolefin backbone containing a residue of at least one unsaturated monomer (X) and at least one polyamide graft, in which: • the polyamide graft is attached to the polyolefin backbone by the residue of the unsaturated monomer (X) that comprises a functional group capable of reacting via a condensation reaction with a polyamide having at least one amine end group and/or at least one carboxylic acid end group; • the residue of the unsaturated monomer (X) is attached to the backbone by grafting or copolymerization; said polyamide-grafted polymer comprising, relative to its total weight: • from 40 to 95% by weight of the polyolefin backbone comprising the unsaturated monomer (X); and • from 5 to 60% by weight of polyamide grafts, and the melting point or glass transition temperature of the polyamide grafts being greater than or equal to 85° C. The invention also relates to a process of manufacturing a photovoltaic module, to a photovoltaic module and also to the use of this module for producing electricity.

摘要翻译： 本发明的一个主题是在光伏模块中使用α膜作为保护性底片，所述膜包括至少一层含有聚酰胺接枝聚合物的组合物，该聚酰胺接枝聚合物包含聚烯烃主链，其含有 至少一种不饱和单体（X）和至少一种聚酰胺接枝物，其中：•聚酰胺接枝物通过不饱和单体（X）的残基连接到聚烯烃主链上，该不饱和单体（X）包含能够通过缩合反应进行反应的官能团 与具有至少一个胺端基和/或至少一个羧酸端基的聚酰胺; •不饱和单体（X）的残基通过接枝或共聚连接到骨架上; 所述聚酰胺接枝聚合物相对于其总重量包含：•40至95重量％的包含不饱和单体（X）的聚烯烃主链; 和•5至60重量％的聚酰胺接枝物，并且聚酰胺接枝物的熔点或玻璃化转变温度大于或等于85℃。本发明还涉及制造光伏组件的方法， 光伏组件以及该模块用于生产电力。

公开(公告)号：US08883899B2

公开(公告)日：2014-11-11

申请号：US13881491

申请日：2011-10-18

申请人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

发明人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

IPC分类号： H01B3/44 ,  F16L57/04 ,  C08L53/00 ,  C08G81/02 ,  C08L87/00 ,  C08L33/16

CPC分类号： H01B3/447 ,  C08G81/028 ,  C08L33/16 ,  C08L53/00 ,  C08L87/005 ,  F16L57/04

摘要： A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.

摘要翻译： 一种阻燃热塑性组合物，其包含含有聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和平均至少一个聚酰胺接枝物组成，其中移植物通过具有功能的不饱和单体（X）的残基连接到主链上 能够与聚酰胺反应，不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上，其中组合物包括：含有聚酰胺的接枝共聚物的60重量％至70重量％ （聚丙烯酸五溴苄酯）的22重量％至28重量％，4重量％至8重量％的协同阻燃剂，其选自三氧化锑，锡，钼和/或铋的衍生物，以及硼 和氧化锌，硼酸钙，硫酸钙和/或锡酸锌，占亲水处理粘土的0.5重量％至5重量％。

公开(公告)号：US20130247983A1

公开(公告)日：2013-09-26

申请号：US13879959

申请日：2011-10-18

申请人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

发明人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

IPC分类号： H01L31/0203

CPC分类号： H01L31/0203 ,  C08G81/028 ,  C09K21/12 ,  H01L31/0481 ,  Y02E10/50

摘要： A transparent, fireproof thermoplastic composition which is free from halogen compounds and includes a polyamide-block graft copolymer formed by a polyolefin backbone and, on average, at least one polyamide graft. The grafts are attached to the backbone by the radicals of an unsaturated monomer (X) that has a function capable of reacting with a polyamide, and the radicals of the unsaturated monomer (X) are attached to the backbone by grafting or co-polymerisation from the double bond thereof. The composition includes, as a weight percentage of the total composition: 90 to 99 wt % of the polyamide-block graft copolymer, and 1 to 10 wt % of metal salts of phosphoric acid.

摘要翻译： 一种不含卤素化合物的透明耐火热塑性组合物，包括由聚烯烃主链和平均至少一个聚酰胺接枝物形成的聚酰胺嵌段接枝共聚物。 移植物通过具有能够与聚酰胺反应的功能的不饱和单体（X）的基团连接到主链上，并且不饱和单体（X）的基团通过接枝或共聚从 其双键。 该组合物包含总组合物的重量百分数：聚酰胺 - 嵌段共聚物的90-99重量％和磷酸金属盐的1-10重量％。

公开(公告)号：US09331215B2

公开(公告)日：2016-05-03

申请号：US13879959

申请日：2011-10-18

申请人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

发明人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

IPC分类号： H01L31/0203 ,  C08G81/02 ,  C09K21/12 ,  H01L31/048

CPC分类号： H01L31/0203 ,  C08G81/028 ,  C09K21/12 ,  H01L31/0481 ,  Y02E10/50

摘要： A transparent, fireproof thermoplastic composition which is free from halogen compounds and includes a polyamide-block graft copolymer formed by a polyolefin backbone and, on average, at least one polyamide graft. The grafts are attached to the backbone by the radicals of an unsaturated monomer (X) that has a function capable of reacting with a polyamide, and the radicals of the unsaturated monomer (X) are attached to the backbone by grafting or co-polymerisation from the double bond thereof. The composition includes, as a weight percentage of the total composition: 90 to 99 wt % of the polyamide-block graft copolymer, and 1 to 10 wt % of metal salts of phosphoric acid.

摘要翻译： 一种不含卤素化合物的透明耐火热塑性组合物，包括由聚烯烃骨架和平均至少一种聚酰胺接枝物形成的聚酰胺嵌段接枝共聚物。 移植物通过具有能够与聚酰胺反应的功能的不饱和单体（X）的基团连接到主链上，并且不饱和单体（X）的基团通过接枝或共聚从 其双键。 该组合物包含总组合物的重量百分数：聚酰胺 - 嵌段共聚物的90-99重量％和磷酸金属盐的1-10重量％。

公开(公告)号：US20130261244A1

公开(公告)日：2013-10-03

申请号：US13881491

申请日：2011-10-18

申请人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

发明人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

IPC分类号： H01B3/44 ,  F16L57/04

CPC分类号： H01B3/447 ,  C08G81/028 ,  C08L33/16 ,  C08L53/00 ,  C08L87/005 ,  F16L57/04

摘要： A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.

摘要翻译： 一种阻燃热塑性组合物，其包含含有聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和平均至少一个聚酰胺接枝物组成，其中移植物通过具有功能的不饱和单体（X）的残基连接到主链上 能够与聚酰胺反应，不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上，其中组合物包括：含有聚酰胺的接枝共聚物的60重量％至70重量％ （聚丙烯酸五溴苄酯）的22重量％至28重量％，4重量％至8重量％的协同阻燃剂，其选自三氧化锑，锡，钼和/或铋的衍生物，以及硼 和氧化锌，硼酸钙，硫酸钙和/或锡酸锌，占亲水处理粘土的0.5重量％至5重量％。

公开(公告)号：US07897673B2

公开(公告)日：2011-03-01

申请号：US12303174

申请日：2007-06-01

申请人： Jean-Jacques Flat ,  Philippe Blondel ,  David Meslet

发明人： Jean-Jacques Flat ,  Philippe Blondel ,  David Meslet

IPC分类号： C08K3/32 ,  C08K3/34

CPC分类号： C09K21/12 ,  C08G81/028 ,  C08L23/02 ,  C09D5/18 ,  C09K21/04 ,  H01B7/295 ,  H01R13/527 ,  C08L2666/20

摘要： The invention concerns flexible high thermomechanical stress-resistant and fire retardant halogen-free thermoplastic compositions, comprising a polyamide block-graft copolymer consisting of a trunk and on average at least one polyamide graft, wherein the grafts are bound to the trunk by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide at the amine-terminal, the unsaturated monomer residues (X) being bound on the trunk by grafting or copolymerization from the double bond thereof. The invention is characterized in that the compositions comprise a mixture: 50 to 70 wt. % of polyamide block copolymer, 25 to 35 wt. % of a flame-retardant agent selected among ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, about 2 wt. % of zeolite, or hydrotalcitemolecular sieves. Said compositions are particularly useful for making electric cables, electric components, for molding electrotechnical housings, or for making coating layers or thermal protection sleeves for fluid transfer lines in the automotive industry.

摘要翻译： 本发明涉及柔性高的热机械应力阻力和阻燃无卤热塑性组合物，其包含由树干和平均至少一个聚酰胺接枝物组成的聚酰胺嵌段共聚物共聚物，其中移植物通过残留物 具有能够在胺末端与聚酰胺反应的功能的不饱和单体（X），不饱和单体残基（X）通过从其双键接枝或共聚而结合在树干上。 本发明的特征在于，所述组合物包含混合物：50至70wt。 ％的聚酰胺嵌段共聚物，25〜35重量％ 选自磷酸铵，次膦酸盐，焦磷酸盐和多磷酸盐的阻燃剂的百分比为约2重量％ ％的沸石或水分子分子筛。 所述组合物特别可用于制造用于汽车工业中的流体输送线的电缆，用于模制电工技术外壳的电气部件或用于制造涂层或热保护套管。

公开(公告)号：US20100099817A1

公开(公告)日：2010-04-22

申请号：US12526097

申请日：2008-02-06

申请人： Stephane Bizet ,  Jean-Jacques Flat

发明人： Stephane Bizet ,  Jean-Jacques Flat

IPC分类号： C08L77/00 ,  C08F287/00

CPC分类号： C08L51/08 ,  C08F255/00 ,  C08F255/02 ,  C08G81/028 ,  C08L23/0861 ,  C08L51/06 ,  C08L2666/24 ,  C08L2666/20 ,  C08L2666/02 ,  C08L2666/04

摘要： The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerisation from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.

摘要翻译： 本发明涉及耐油性的老化作用的柔性热塑性组合物，所述组合物包含含聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和至少一种聚酰胺接枝物组成。 根据本发明，移植物通过具有可与包含胺末端或羧酸端的聚酰胺反应的功能的不饱和单体（X）的残基连接到芯上; 不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上; 并且所述组合物包含40-90重量％的包含不饱和单体（X）的聚烯烃芯; 5〜40重量％的聚酰胺接枝物; 和5至40％的至少一种选自皂化乙烯/乙酸乙烯酯共聚物和聚酰胺的聚合物。

公开(公告)号：US09579838B2

公开(公告)日：2017-02-28

申请号：US13976640

申请日：2011-12-23

申请人： Frederic Malet ,  Jean-Jacques Flat ,  Francois Touchaleaume ,  Jacques Devaux ,  Patricia Krawczak ,  Michel Sclavons ,  Jeremie Soulestin

发明人： Frederic Malet ,  Jean-Jacques Flat ,  Francois Touchaleaume ,  Jacques Devaux ,  Patricia Krawczak ,  Michel Sclavons ,  Jeremie Soulestin

IPC分类号： B29C47/00 ,  B29C47/10 ,  B29C47/80 ,  C08G63/91 ,  C08G69/40 ,  B29C47/76 ,  B29K77/00 ,  B29K105/00 ,  B29K105/16

CPC分类号： B29C47/0071 ,  B29C47/0004 ,  B29C47/0011 ,  B29C47/0019 ,  B29C47/0023 ,  B29C47/1045 ,  B29C47/1063 ,  B29C47/762 ,  B29C47/805 ,  B29K2077/00 ,  B29K2105/0005 ,  B29K2105/16 ,  C08G63/916 ,  C08G69/40

摘要： The invention relates to a method for converting a polycondensed elastomeric thermoplastic polymer, including a step of extruding the polycondensed elastomeric thermoplastic polymer in the presence of water. The polycondensed elastomeric thermoplastic polymer is in particular chosen from copolymer block amides, copolyethers or copolyester block urethanes, copolyether block esters and the mixtures thereof, and is preferably a copolyether block amide.

摘要翻译： 本发明涉及一种用于转化聚缩聚弹性体热塑性聚合物的方法，包括在水存在下挤出缩聚的弹性体热塑性聚合物的步骤。 聚缩聚弹性体热塑性聚合物特别地选自共聚物嵌段酰胺，共聚醚或共聚酯嵌段聚氨酯，共聚醚嵌段酯及其混合物，并且优选为共聚醚嵌段酰胺。

公开(公告)号：US08227543B2

公开(公告)日：2012-07-24

申请号：US12526097

申请日：2008-02-06

申请人： Stephane Bizet ,  Jean-Jacques Flat

发明人： Stephane Bizet ,  Jean-Jacques Flat

IPC分类号： C08G63/48

CPC分类号： C08L51/08 ,  C08F255/00 ,  C08F255/02 ,  C08G81/028 ,  C08L23/0861 ,  C08L51/06 ,  C08L2666/24 ,  C08L2666/20 ,  C08L2666/02 ,  C08L2666/04

摘要： The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.

摘要翻译： 本发明涉及耐油性的老化作用的柔性热塑性组合物，所述组合物包含含聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和至少一种聚酰胺接枝物组成。 根据本发明，移植物通过具有可与包含胺末端或羧酸端的聚酰胺反应的功能的不饱和单体（X）的残基连接到芯上; 不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上; 并且所述组合物包含40-90重量％的包含不饱和单体（X）的聚烯烃芯; 5〜40重量％的聚酰胺接枝物; 和5至40％的至少一种选自皂化乙烯/乙酸乙烯酯共聚物和聚酰胺的聚合物。

公开(公告)号：US07235604B2

公开(公告)日：2007-06-26

申请号：US10602005

申请日：2003-06-24

申请人： Philippe Blondel ,  Benoît Brule ,  Nicolas Frenois ,  Jean-Jacques Flat

发明人： Philippe Blondel ,  Benoît Brule ,  Nicolas Frenois ,  Jean-Jacques Flat

IPC分类号： C08K5/523

CPC分类号： C08L77/00 ,  C08L23/02 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/0853 ,  C08L23/10 ,  C08L51/06 ,  C08L77/02 ,  C08L77/06 ,  C08L2201/02 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/84 ,  C08L51/00 ,  C08L23/00

摘要： The present invention relates to fire-retarded compositions comprising, by weight, the total being 100 parts: 50 to 75 parts of a blend of a polyamide (A) and a polyolefin (B), 25 to 50 parts of a blend comprising: 0.1 to 48.8 parts of a fire retardant, 0.1 to 30 parts of a phosphorus-containing plasticizer, 0.1 to 10 parts of a zeolite, the total of these three products being between 25 and 50. These compositions have a V0 or V1 classification according to the UL94-VB test when a fire test is carried out on test specimens 1.6 mm in thickness. They have many advantages, in particular the elongation at break measured according to ISO R 527-1B exceeds 100%. As regards the impact strength, they have a non-brittle behaviour in multiaxial impact at room temperature according to ISO 6603-2 (at a rate of 7.7 m/s). They retain at least 50% of their mechanical properties after ageing for seven days at 120° C. in hot air. These compositions are useful for insulating and protecting electrical cables and optical fibres and for moulding electrical cases and connectors.

摘要翻译： 本发明涉及阻燃组合物，其包含总重量为100份：50至75份聚酰胺（A）和聚烯烃（B）的共混物，25至50份共混物，其包含：0.1 至48.8份阻燃剂，0.1至30份含磷增塑剂，0.1至10份沸石，这三种产品的总量在25-50之间。这些组合物具有根据本发明的V0或V1分类 对在1.6mm厚的试样进行耐火试验时，进行UL94-VB试验。 它们具有许多优点，特别是根据ISO R 527-1B测量的断裂伸长率超过100％。 关于冲击强度，根据ISO 6603-2（以7.7m / s的速率）在室温下在多轴冲击中具有非脆性。 它们在120℃下在热空气中老化7天后，保持其机械性能的至少50％。 这些组合物可用于绝缘和保护电缆和光纤以及用于模制电气外壳和连接器。