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1.发明授权Hindered polyalicyclic alkyl catalysts and their use in a gas-phase polymerization reactor 有权受阻的多环脂族烷基催化剂及其在气相聚合反应器中的应用公开(公告)号：US07414099B2
公开(公告)日：2008-08-19
申请号：US11249193
申请日：2005-10-13
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/69 , C08F4/22 , C08F2500/12 , C08F2500/18 , C08F210/14 , C08F4/025
摘要： Embodiments of the present invention include a method of polymerizing olefins comprising contacting olefins with a catalyst composition made by the process of combining a hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form a catalyst composition. Embodiments of the present invention also include catalyst compositions comprising a hindered polyalicyclic alkyl catalyst precursor made by the process of combining the hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form the catalyst composition. In one embodiment, the hindered polyalicyclic alkyl catalyst precursor is formed by first combining an acid, a compound having the formula RX, and a metal oxide selected from the group consisting of Group 3 to Group 10 oxide compounds to produce a catalyst precursor; characterized in that R is selected from the group consisting of hindered polyalicyclic alkyls, and substituted derivatives thereof, and X is selected from the group consisting of any suitable leaving group.
摘要翻译： 本发明的实施方案包括使烯烃聚合的方法，其包括使烯烃与通过将受阻多环脂族烷基催化剂前体与颗粒无机氧化物结合沉积时间大于2小时的方法制备的催化剂组合物形成催化剂组合物。 本发明的实施方案还包括催化剂组合物，其包含通过将受阻多环脂族烷基催化剂前体与颗粒无机氧化物结合沉积时间大于2小时的方法制备的受阻多环脂族烷基催化剂前体，以形成催化剂组合物。 在一个实施方案中，受阻多环脂族烷基催化剂前体通过首先组合酸，具有式RX的化合物和选自第3族至第10族氧化物化合物的金属氧化物以形成催化剂前体而形成; 其特征在于R选自受阻多环脂族烷基及其取代衍生物，X选自任何合适的离去基团。
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2.发明申请公开(公告)号：US20080242821A1
公开(公告)日：2008-10-02
申请号：US12156762
申请日：2008-06-04
IPC分类号： C07F11/00 , C08F210/00
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/69 , C08F4/22 , C08F2500/12 , C08F2500/18 , C08F210/14 , C08F4/025
摘要： Embodiments of the present invention include a method of polymerizing olefins comprising contacting olefins with a catalyst composition made by the process of combining a hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form a catalyst composition. Embodiments of the present invention also include catalyst compositions comprising a hindered polyalicyclic alkyl catalyst precursor made by the process of combining the hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form the catalyst composition. In one embodiment, the hindered polyalicyclic alkyl catalyst precursor is formed by first combining an acid, a compound having the formula RX, and a metal oxide selected from the group consisting of Group 3 to Group 10 oxide compounds to produce a catalyst precursor; characterized in that R is selected from the group consisting of hindered polyalicyclic alkyls, and substituted derivatives thereof, and X is selected from the group consisting of any suitable leaving group.
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3.发明申请HINDERED POLYALICYCLIC ALKYL CATALYSTS AND THEIR USE IN A GAS-PHASE POLYMERIZATION REACTOR 有权有吸引力的聚丙烯酰胺催化剂及其在气相聚合反应器中的应用公开(公告)号：US20100137533A1
公开(公告)日：2010-06-03
申请号：US12690606
申请日：2010-01-20
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/69 , C08F4/22 , C08F2500/12 , C08F2500/18 , C08F210/14 , C08F4/025
摘要： Embodiments of the present invention include a method of polymerizing olefins comprising contacting olefins with a catalyst composition made by the process of combining a hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form a catalyst composition. Embodiments of the present invention also include catalyst compositions comprising a hindered polyalicyclic alkyl catalyst precursor made by the process of combining the hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form the catalyst composition. In one embodiment, the hindered polyalicyclic alkyl catalyst precursor is formed by first combining an acid, a compound having the formula RX, and a metal oxide selected from the group consisting of Group 3 to Group 10 oxide compounds to produce a catalyst precursor; characterized in that R is selected from the group consisting of hindered polyalicyclic alkyls, and substituted derivatives thereof, and X is selected from the group consisting of any suitable leaving group.
摘要翻译： 本发明的实施方案包括使烯烃聚合的方法，其包括使烯烃与通过将受阻多环脂族烷基催化剂前体与颗粒无机氧化物结合沉积时间大于2小时的方法制备的催化剂组合物形成催化剂组合物。 本发明的实施方案还包括催化剂组合物，其包含通过将受阻多环脂族烷基催化剂前体与颗粒无机氧化物结合沉积时间大于2小时的方法制备的受阻多环脂族烷基催化剂前体，以形成催化剂组合物。 在一个实施方案中，受阻多环脂族烷基催化剂前体通过首先组合酸，具有式RX的化合物和选自第3族至第10族氧化物化合物的金属氧化物以形成催化剂前体而形成; 其特征在于R选自受阻多环脂族烷基及其取代衍生物，X选自任何合适的离去基团。
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4.发明授权Hindered polyalicyclic alkyl catalysts and their use in a gas-phase polymerization reactor 有权受阻的多环脂族烷基催化剂及其在气相聚合反应器中的应用公开(公告)号：US07816296B2
公开(公告)日：2010-10-19
申请号：US12690606
申请日：2010-01-20
CPC分类号： C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/69 , C08F4/22 , C08F2500/12 , C08F2500/18 , C08F210/14 , C08F4/025
摘要： Embodiments of the present invention include a method of polymerizing olefins comprising contacting olefins with a catalyst composition made by the process of combining a hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form a catalyst composition. Embodiments of the present invention also include catalyst compositions comprising a hindered polyalicyclic alkyl catalyst precursor made by the process of combining the hindered polyalicyclic alkyl catalyst precursor with a particulate inorganic oxide for a deposition time greater than 2 hours to form the catalyst composition. In one embodiment, the hindered polyalicyclic alkyl catalyst precursor is formed by first combining an acid, a compound having the formula RX, and a metal oxide selected from the group consisting of Group 3 to Group 10 oxide compounds to produce a catalyst precursor; characterized in that R is selected from the group consisting of hindered polyalicyclic alkyls, and substituted derivatives thereof, and X is selected from the group consisting of any suitable leaving group.
摘要翻译： 本发明的实施方案包括使烯烃聚合的方法，其包括使烯烃与通过将受阻多环脂族烷基催化剂前体与颗粒无机氧化物结合沉积时间大于2小时的方法制备的催化剂组合物形成催化剂组合物。 本发明的实施方案还包括催化剂组合物，其包含通过将受阻多环脂族烷基催化剂前体与颗粒无机氧化物结合沉积时间大于2小时的方法制备的受阻多环脂族烷基催化剂前体，以形成催化剂组合物。 在一个实施方案中，受阻多环脂族烷基催化剂前体通过首先组合酸，具有式RX的化合物和选自第3族至第10族氧化物化合物的金属氧化物以形成催化剂前体而形成; 其特征在于R选自受阻多环脂族烷基及其取代衍生物，X选自任何合适的离去基团。
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公开(公告)号：US08129484B2
公开(公告)日：2012-03-06
申请号：US11988712
申请日：2006-07-21
申请人： Kevin J. Cann , Ronald S. Eisinger , Mark G. Goode , John H. Moorhouse , Cliff R. Mure , Stephen P. Jaker , Maria A. Apecetche
发明人： Kevin J. Cann , Ronald S. Eisinger , Mark G. Goode , John H. Moorhouse , Cliff R. Mure , Stephen P. Jaker , Maria A. Apecetche
CPC分类号： C08F210/16 , C08F2/34 , C08F4/24 , C08F210/14 , C08F2500/14 , C08F2500/13 , C08F2500/12 , C08F2500/04 , C08F210/08
摘要： Disclosed herein are various processes, including continuous fluidized-bed gas-phase polymerization processes for making a high strength, high density polyethylene copolymer, comprising (including): contacting monomers that include ethylene and optionally at least one non-ethylene monomer with fluidized catalyst particles in a gas phase in the presence of hydrogen gas at an ethylene partial pressure of 100 psi or more and a polymerization temperature of 120° C. or less to produce a polyethylene copolymer having a density of 0.945 g/cc or more and an ESCR Index of 1.0 or more wherein the catalyst particles are prepared at an activation temperature of 700° C. or less, and include silica, chromium, and titanium.
摘要翻译： 本文公开了各种方法，包括用于制备高强度，高密度聚乙烯共聚物的连续流化床气相聚合方法，包括（包括）：使包含乙烯和任选的至少一种非乙烯单体的单体与流化催化剂颗粒接触 在气相中，在乙烯分压为100psi以上，聚合温度为120℃以下的氢气存在下，制成密度为0.945g / cc以上的聚乙烯共聚物，ESCR指数 为1.0以上，其中催化剂颗粒在700℃或更低的活化温度下制备，并且包括二氧化硅，铬和钛。
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公开(公告)号：US20090215970A1
公开(公告)日：2009-08-27
申请号：US11988712
申请日：2006-07-21
申请人： Kevin J. Cann , Ronald S. Eisinger , Mark G. Goode , John H. Moorhouse , Cliff R. Mure , Stephen P. Jaker , Maria A. Apecetche
发明人： Kevin J. Cann , Ronald S. Eisinger , Mark G. Goode , John H. Moorhouse , Cliff R. Mure , Stephen P. Jaker , Maria A. Apecetche
CPC分类号： C08F210/16 , C08F2/34 , C08F4/24 , C08F210/14 , C08F2500/14 , C08F2500/13 , C08F2500/12 , C08F2500/04 , C08F210/08
摘要： Disclosed herein are various processes, including continuous fluidized-bed gas-phase polymerization processes for making a high strength, high density polyethylene copolymer, comprising (including): contacting monomers that include ethylene and optionally at least one non-ethylene monomer with fluidized catalyst particles in a gas phase in the presence of hydrogen gas at an ethylene partial pressure of 100 psi or more and a polymerization temperature of 120° C. or less to produce a polyethylene copolymer having a density of 0.945 g/cc or more and an ESCR Index of 1.0 or more wherein the catalyst particles are prepared at an activation temperature of 700° C. or less, and include silica, chromium, and titanium.
摘要翻译： 本文公开了各种方法，包括用于制备高强度，高密度聚乙烯共聚物的连续流化床气相聚合方法，包括（包括）：使包含乙烯和任选的至少一种非乙烯单体的单体与流化催化剂颗粒接触 在气相中，在乙烯分压为100psi以上，聚合温度为120℃以下的氢气存在下，制成密度为0.945g / cc以上的聚乙烯共聚物，ESCR指数 为1.0以上，其中催化剂颗粒在700℃或更低的活化温度下制备，并且包括二氧化硅，铬和钛。
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7.发明授权公开(公告)号：US09303103B2
公开(公告)日：2016-04-05
申请号：US12919979
申请日：2008-12-10
IPC分类号： B01J21/00 , B01J23/00 , C08F4/24 , C08F4/52 , C08F4/12 , C08F110/02 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , Y10T29/49345 , C08F4/025 , C08F4/24 , C08F4/69 , C08F210/14 , C08F2500/18 , C08F2500/12 , C08F2500/24
摘要： Embodiments disclosed herein generally relate to olefin polymerization catalysts, and more specifically to chromium-based catalysts and methods of use of chromium-based catalysts for the production of polyolefins, and even more specifically to methods for controlling or tailoring the flow index response of chromium-based catalysts through the controlled addition of a reducing agent to the catalysts under controlled mixing conditions.
摘要翻译： 本文公开的实施方案通常涉及烯烃聚合催化剂，更具体地涉及铬基催化剂和用于生产聚烯烃的铬基催化剂的方法，甚至更具体地涉及用于控制或定制铬 - 通过在受控的混合条件下将还原剂控制加入到催化剂中。
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8.发明申请公开(公告)号：US20110010938A1
公开(公告)日：2011-01-20
申请号：US12919979
申请日：2008-12-10
IPC分类号： B21D51/16
CPC分类号： C08F10/00 , C08F210/16 , Y10T29/49345 , C08F4/025 , C08F4/24 , C08F4/69 , C08F210/14 , C08F2500/18 , C08F2500/12 , C08F2500/24
摘要： Embodiments disclosed herein generally relate to olefin polymerization catalysts, and more specifically to chromium-based catalysts and methods of use of chromium-based catalysts for the production of polyolefins, and even more specifically to methods for controlling or tailoring the flow index response of chromium-based catalysts through the controlled addition of a reducing agent to the catalysts under controlled mixing conditions.
摘要翻译： 本文公开的实施方案通常涉及烯烃聚合催化剂，更具体地涉及铬基催化剂和用于生产聚烯烃的铬基催化剂的方法，甚至更具体地涉及用于控制或定制铬 - 通过在受控的混合条件下将还原剂控制加入到催化剂中。
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公开(公告)号：US20110218307A1
公开(公告)日：2011-09-08
申请号：US13127937
申请日：2009-12-11
CPC分类号： C08F210/16 , C08F4/69 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/07
摘要： The present invention is broadly directed to various methods and systems for gas and liquid phase polymer production. In certain embodiments, the methods are performed in conjunction with a polymerization reactor system such as gas phase reactor system or liquid phase reactor system. The invention is also broadly directed to various systems in which polymer properties are manipulated by addition of DEALE directly to a polymerization reactor system.
摘要翻译： 本发明广泛地涉及用于气相和液相聚合物生产的各种方法和系统。 在某些实施方案中，该方法与聚合反应器系统如气相反应器系统或液相反应器系统一起进行。 本发明还广泛地涉及通过将DEALE直接加入聚合反应器系统来操作聚合物性质的各种体系。
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公开(公告)号：US20110237763A1
公开(公告)日：2011-09-29
申请号：US13128160
申请日：2009-12-17
申请人： Mark G. Goode , Maria Pollard , Kevin J. Cann , Ronald S. Eisinger , Barbara J. Kopp , John H. Moorhouse
发明人： Mark G. Goode , Maria Pollard , Kevin J. Cann , Ronald S. Eisinger , Barbara J. Kopp , John H. Moorhouse
CPC分类号： C08F10/00 , C08F210/16 , Y10S526/905 , C08F4/24 , C08F4/78 , C08F2/34 , C08F2500/12
摘要： Disclosed herein are various methods and systems for gas and liquid phase polymer production. In certain embodiments, the methods comprise manipulating properties of polymers produced by adjusting the hydrogen feed rate.
摘要翻译： 本文公开了用于气相和液相聚合物生产的各种方法和系统。 在某些实施方案中，所述方法包括操纵通过调节氢气进料速率产生的聚合物的性质。
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