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    USE OF SUBSTITUTED METHOXYALKOXYPHENYLALKYL DERIVATIVES AS PRESERVATIVE, PRESERVING METHOD, COMPOUNDS AND COMPOSITION
    1.
    发明申请
    USE OF SUBSTITUTED METHOXYALKOXYPHENYLALKYL DERIVATIVES AS PRESERVATIVE, PRESERVING METHOD, COMPOUNDS AND COMPOSITION 有权
    作为保存，保存方法，化合物和组合物的替代的甲氧基甲基戊烯衍生物的使用

    公开(公告)号：US20130230473A1

    公开(公告)日：2013-09-05

    申请号：US13824172

    申请日：2011-10-06

    Applicant: Maria Dalko ,  Laurent Gilbert

    Inventor： Maria Dalko ,  Laurent Gilbert

    IPC: A61K8/35 ,  A61Q19/04 ,  A61Q17/04 ,  A61Q19/00 ,  C07C49/255 ,  A61Q5/00

    CPC classification number: A61K8/35 ,  A61K8/34 ,  A61K8/347 ,  A61K9/0014 ,  A61K47/08 ,  A61K2800/524 ,  A61Q5/00 ,  A61Q17/04 ,  A61Q19/00 ,  A61Q19/002 ,  A61Q19/04 ,  C07C43/23 ,  C07C49/255

    Abstract: The present invention relates to the use as a preserving agent, in particular in cosmetic or dermatological composition, of at least one compound of formula (I): in which:—X represents ═O or —OH;—R1 represents a hydrogen atom or a methyl;—R2 represents a hydrogen atom, a methyl or an ethyl;—R3 represents a C1-C12, saturated or unsaturated, linear hydrocarbon-based radical, optionally substituted with a hydroxyl group (OH); with the exclusion of the compound of formula (I) in which X represents ═O, R1=methyl, R2=H and R3=—(CH2)6—CH3. The invention also relates to certain novel compounds and to the cosmetic or dermatological compositions comprising same.

    Abstract translation: 本发明涉及至少一种式（I）化合物的防腐剂，特别是化妆品或皮肤病学组合物的用途：其中：-X表示= O或-OH; -R1表示氢原子或 甲基; -R 2表示氢原子，甲基或乙基; -R 3表示任选被羟基（OH）取代的C 1 -C 12饱和或不饱和直链烃基自由基。 排除其中X表示= O，R 1 =甲基，R 2 = H和R 3 = - （CH 2）6 -CH 3的式（I）化合物。 本发明还涉及某些新化合物和包含其的化妆品或皮肤病学组合物。

    Aromatic thioether acylation method
    4.
    发明授权
    Aromatic thioether acylation method 失效
    芳香硫醚酰化法

    公开(公告)号：US6121496A

    公开(公告)日：2000-09-19

    申请号：US68625

    申请日：1998-08-03

    Applicant: Laurent Gilbert ,  Michel Spagnol

    Inventor： Laurent Gilbert ,  Michel Spagnol

    IPC: B01J29/70 ,  C07B41/06 ,  C07B61/00 ,  C07C319/20 ,  C07C323/22 ,  C07C319/14

    CPC classification number: C07C319/20

    Abstract: The present invention relates to a process for the acylation of an aromatic thioether. In its preferred variant, the invention resides in a process for the condensation of acetic anhydride or acetyl chloride with thioanisole. The process for the acylation of an aromatic thioether according to the invention is characterised in that it consists in reacting said thioether with an acylating agent chosen from the group formed by the halides of carboxylic acids and the anhydrides of carboxylic acids, in the presence of an effective quantity of an acid zeolite.

    Abstract translation: PCT No.PCT / FR96 / 01763 Sec。 371日期1998年8月3日 102（e）1998年8月3日PCT PCT 1996年11月8日PCT公布。 出版物WO97 / 17324 PCT 日期：1997年5月15日本发明涉及一种酰化芳族硫醚的方法。 在其优选的变体中，本发明在于使乙酸酐或乙酰氯与硫代苯甲醚缩合的方法。 根据本发明的酰化芳族硫醚的方法的特征在于它使所述硫醚与酰化剂反应，所述酰化剂选自由羧酸的卤化物和羧酸的酸酐形成的基团， 有效量的酸性沸石。

    Phenol compound hydroxylation method
    5.
    发明授权
    Phenol compound hydroxylation method 失效
    苯酚化合物羟基化法

    公开(公告)号：US6040484A

    公开(公告)日：2000-03-21

    申请号：US125163

    申请日：1998-08-13

    Applicant: Michel Costantini ,  Laurent Gilbert ,  Michel Spagnol

    Inventor： Michel Costantini ,  Laurent Gilbert ,  Michel Spagnol

    IPC: B01J31/02 ,  C07B61/00 ,  C07C37/60 ,  C07C39/08

    CPC classification number: C07C37/60

    Abstract: The present invention relates to a process for the hydroxylation of phenolic compounds and, more particularly, to a process for the hydroxylation of phenols and phenolic ethers with hydrogen peroxide. The invention relates to a process for the hydroxylation of phenolic compounds using hydrogen peroxide, said process being characterized in that the reaction is carried out in the presence of an effective quantity of at least one rare earth or bismuth triflate.

    Abstract translation: PCT No.PCT / FR97 / 00223 Sec。 371日期1998年8月13日 102（e）日期1998年8月13日PCT提交1997年2月5日PCT公布。 公开号WO97 / 29066 日期1997年8月14日本发明涉及一种酚类化合物的羟基化方法，更具体地说涉及用过氧化氢使苯酚和酚类醚羟基化的方法。 本发明涉及使用过氧化氢使酚类化合物羟基化的方法，所述方法的特征在于反应在有效量的至少一种稀土或三氟化铋的存在下进行。

    Process for the synthesis of acid halides and reactants useful for its implementation
    6.
    发明授权
    Process for the synthesis of acid halides and reactants useful for its implementation 失效
    用于合成可用于其实施的酰卤和反应物的方法

    公开(公告)号：US5493054A

    公开(公告)日：1996-02-20

    申请号：US313402

    申请日：1994-09-27

    Applicant: Gerard Forat ,  Laurent Gilbert

    Inventor： Gerard Forat ,  Laurent Gilbert

    IPC: B01J27/128 ,  C07B41/10 ,  C07B61/00 ,  C07C51/60 ,  C07C53/38 ,  C07C63/10 ,  C07C51/58

    CPC classification number: C07C51/60

    Abstract: The subject of the present invention is a new catalytic system and a process for the synthesis of acid halides, especially from haloforms. This process for halogenating by means of a haloform is characterized by the use of a metal chloride, advantageously trivalent, as a catalyst, the solubility of which in the reaction mixture is at least equal to one millimole, preferably 1/100 mole per liter, and the metal chloride also being at least half, advantageously two-thirds and preferably three-quarters in the dissolved state.

    Abstract translation: 本发明的主题是新的催化体系和用于合成酰卤的方法，特别是卤代。 通过卤代甲醛卤化的该方法的特征在于使用有利地为三价的金属氯化物作为催化剂，其在反应混合物中的溶解度至少等于1毫摩尔，优选1/100摩尔/升， 并且金属氯化物在溶解状态下也至少为一半，有利地为三分之二，优选为四分之三。

    Process for the synthesis of perfluorosulphonamides, of perfluorosulphonimides and of their salts, and a sulphonylation reagent
    7.
    发明授权
    Process for the synthesis of perfluorosulphonamides, of perfluorosulphonimides and of their salts, and a sulphonylation reagent 有权
    全氟磺酰胺及其盐的全氟磺酰胺的合成方法和磺酰化试剂

    公开(公告)号：US06399821B2

    公开(公告)日：2002-06-04

    申请号：US09923493

    申请日：2001-08-07

    Applicant: Virginie Pevere ,  Emmanuel Marx ,  Laurent Gilbert

    Inventor： Virginie Pevere ,  Emmanuel Marx ,  Laurent Gilbert

    IPC: C07C30318

    CPC classification number: C07C303/38 ,  C07C311/48

    Abstract: The invention concerns a method of sulphonation characterised in that it consists in contacting a nucleophile whose nucleophilic atom is a nitrogen atom with a reagent comprising by successive or simultaneous addition: a heavy sulphonyl halide (i.e. whose atomic number is not less than that of chlorine), advantageously suphonyl chloride; and an organic base both not capable of alkylation and lipid soluble; and the organic part of said sulphonyl is perfluorinated on the carbon carried by the sulphur. The invention is applicable to organic synthesis.

    Abstract translation: 本发明涉及一种磺化方法，其特征在于它包括使亲核原子是氮原子的亲核试剂与通过连续或同时加入的试剂接触：重磺酰卤（即其原子序数不小于氯原子数） ，有利地是异丙基氯; 和不能烷基化和脂溶性的有机碱; 并且所述磺酰基的有机部分在由硫携带的碳上全氟化。 本发明适用于有机合成。

    Process for cleaving the by-products of the direct synthesis of alkylchlorosilanes
    9.
    发明授权
    Process for cleaving the by-products of the direct synthesis of alkylchlorosilanes 失效
    裂解烷基氯硅烷的直接合成副产物的方法

    公开(公告)号：US5627297A

    公开(公告)日：1997-05-06

    申请号：US628179

    申请日：1996-04-04

    Applicant: Laurent Gilbert ,  Gilles Laroze

    Inventor： Laurent Gilbert ,  Gilles Laroze

    IPC: B01J27/18 ,  C07B61/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/14

    CPC classification number: C07F7/128 ,  C07F7/123 ,  C07F7/126

    Abstract: The process for cleaving the heavy by-products derived from the synthesis of alkylchlorosilanes, in particular C.sub.1 to C.sub.6 alkylchlorosilanes, more particularly methylchlorosilanes, in particular for the cleavage of alkylchlorodisilanes, in particular methylchlorodisilanes having from one to five chlorine atoms, is carried out by treatment with hydrochloric acid in the presence of a catalytic system which comprises at least one metal phosphate, preferably associated with a basic impregnation compound.The metal phosphate may in particular correspond to the formula:M(XPO.sub.4).sub.yin which M represents a metal chosen from:monovalent metals, in which case X is 2H and y=1divalent metals, in which case X is H and y=1trivalent metals, in which case X is absent and y=1tetravalent metals, in which case X is: H and y=2pentavalent metals, in which case X is 0 and y=1.

    Abstract translation: 用于切割衍生自烷基氯硅烷，特别是C1至C6烷基氯硅烷，特别是甲基氯硅烷的重质副产物的方法，特别是用于切割烷基氯代二硅烷，特别是具有1至5个氯原子的甲基氯代二硅烷的方法，是通过 在含有至少一种金属磷酸盐的催化体系存在下用盐酸处理，优选与碱性浸渍化合物缔合。 金属磷酸盐可以特别对应于下式：M（XPO4）y，其中M表示选自以下的金属：一价金属，在这种情况下X为2H且y = 1的二价金属，在这种情况下，X为H且y = 1个三价金属，在这种情况下X不存在，y = 1四价金属，在这种情况下X为：H和y = 2的五价金属，在这种情况下X为0且y = 1。

    Preparation of lactams
    10.
    发明授权
    Preparation of lactams 失效
    内酰胺的制备

    公开(公告)号：US5493021A

    公开(公告)日：1996-02-20

    申请号：US360623

    申请日：1994-12-21

    Applicant: David Barratt ,  Laurent Gilbert

    Inventor： David Barratt ,  Laurent Gilbert

    IPC: C07D223/12 ,  B01J27/18 ,  B01J27/195 ,  C07D201/02 ,  C07D201/08

    CPC classification number: C07D201/08 ,  Y02P20/52

    Abstract: Lactams, in particular epsilon-caprolactam (a basic starting material for the production of nylon 6), are selectively prepared by cyclizing/reacting the corresponding aminonitriles with water, in the presence of a catalytically effective amount of a deactivation-resistant solid metal phosphate having the general formula (II):MH.sub.h (PO.sub.4).sub.n .multidot.(Imp).sub.pin which M is a divalent, trivalent, tetravalent or pentavalent element selected from among those of Groups 2a, 3b, 4b, 5b, 6b, 7b, 8, 2b, 3a, 4a and 5a of the Periodic Table, or mixture thereof, or M=0; Imp is a basic impregnating compound which comprises an alkali or alkaline earth metal, or mixture thereof, together with an electrical neutrality-ensuing counteranion therefor; n is 1, 2 or 3; h is 0, 1 or 2; and p is a number ranging from 0 to 1/3, corresponding to the molar ratio between the moiety Imp and the moiety MH.sub.h (PO.sub.4).sub.n.

    Abstract translation: 特别是ε-己内酰胺（用于生产尼龙6的基本起始材料）的内酰胺可以通过在催化有效量的具有失活性的固体金属磷酸盐的存在下使相应的氨基腈与水环化/反应来选择性地制备， 通式（II）：MHh（PO4）nx（Imp）p，其中M是选自组2a，3b，4b，5b，6b，7b，8,2b中的二价，三价，四价或五价元素 ，3a，4a和5a，或其混合物，或M = 0; Imp是包含碱金属或碱土金属或它们的混合物的基本浸渍化合物，以及随之而来的电中性的抗衡阴离子; n为1,2或3; h为0,1或2; p是0至1/3的数，对应于部分Imp与部分MHh（PO4）n之间的摩尔比。

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