公开(公告)号：US20100209733A1

公开(公告)日：2010-08-19

申请号：US12682297

申请日：2008-10-07

申请人： Markus Beukenberg ,  Sharad Chandra ,  Norbert Czech ,  Roland Herzog

发明人： Markus Beukenberg ,  Sharad Chandra ,  Norbert Czech ,  Roland Herzog

IPC分类号： B32B15/18 ,  B32B15/01

CPC分类号： C23C30/00 ,  B23K35/30 ,  B32B15/01 ,  B32B15/015 ,  B32B15/18 ,  B32B15/20 ,  C22C38/005 ,  C22C38/06 ,  C22C38/18 ,  C23C30/005 ,  F01D5/28 ,  F01D5/286 ,  F01D5/288 ,  Y10T428/12931 ,  Y10T428/12937 ,  Y10T428/12944 ,  Y10T428/12951 ,  Y10T428/12972 ,  Y10T428/12979

摘要： A The hot-gas conducting component for a flow machine has a nickel-base wrought alloy as structural material and a hot gas-side lining made from the group of iron-chromium-aluminum-yttrium alloys and a flow machine having a component of this type.

摘要翻译： A流动机的热气体导电组件具有镍基锻造合金作为结构材料，由一组铁 - 铬 - 铝 - 钇合金制成的热气侧衬里和具有该组分的流动机 类型。

公开(公告)号：US09926629B2

公开(公告)日：2018-03-27

申请号：US12682297

申请日：2008-10-07

申请人： Markus Beukenberg ,  Sharad Chandra ,  Norbert Czech ,  Roland Herzog

发明人： Markus Beukenberg ,  Sharad Chandra ,  Norbert Czech ,  Roland Herzog

IPC分类号： B32B15/01 ,  B32B15/18 ,  F01D5/28 ,  C23C30/00 ,  B32B15/20 ,  B23K35/30 ,  C22C38/00 ,  C22C38/06 ,  C22C38/18

CPC分类号： C23C30/00 ,  B23K35/30 ,  B32B15/01 ,  B32B15/015 ,  B32B15/18 ,  B32B15/20 ,  C22C38/005 ,  C22C38/06 ,  C22C38/18 ,  C23C30/005 ,  F01D5/28 ,  F01D5/286 ,  F01D5/288 ,  Y10T428/12931 ,  Y10T428/12937 ,  Y10T428/12944 ,  Y10T428/12951 ,  Y10T428/12972 ,  Y10T428/12979

摘要： A hot-gas conducting component for a flow machine has a nickel-base wrought alloy as structural material and a hot gas-side lining made from the group of iron-chromium-aluminum-yttrium alloys and a flow machine having a component of this type.

公开(公告)号：US20140141276A1

公开(公告)日：2014-05-22

申请号：US14122495

申请日：2012-05-31

申请人： Norbert Czech ,  Sharad Chandra ,  Roland Herzog

发明人： Norbert Czech ,  Sharad Chandra ,  Roland Herzog

IPC分类号： F01D5/28 ,  C23C4/12 ,  C23C4/10

CPC分类号： F01D5/288 ,  C23C4/02 ,  C23C4/10 ,  C23C4/134 ,  C23C4/18 ,  C23C10/02 ,  C23C10/60 ,  Y10T428/12611

摘要： A method for applying a protective layer resistant to high-temperature degradation by corrosion and erosion to a base metal, comprises: applying a MCrAlY-based bond layer to the base metal; coating, by overaluminizing with an Al diffusion layer, the bond layer; subjecting the Al diffusion layer (14) to abrasion treatment so that an outer build-up layer is removed from the Al diffusion layer; and applying a ceramic thermal barrier coating of yttria partially stabilized zirconia to the remaining Al diffusion layer. The ceramic thermal barrier coating is applied to the remaining Al diffusion layer by air plasma spraying. The applied bond layer is subjected to a polishing treatment before being overaluminized such that a surface roughness of Ra≦2 μm is produced at the bond layer.

摘要翻译： 一种通过腐蚀和腐蚀对基底金属施加耐高温劣化的保护层的方法包括：将MCrAlY基接合层施加到母材上; 通过用Al扩散层过度镀覆所述接合层; 对Al扩散层（14）进行磨损处理，从而从Al扩散层除去外积层; 以及将氧化钇部分稳定的氧化锆的陶瓷热障涂层施加到剩余的Al扩散层。 通过空气等离子体喷涂将陶瓷热障涂层施加到剩余的Al扩散层。 施加的接合层在被过度光化之前进行抛光处理，使得在接合层处产生Ra＆lt; NlE;2μm的表面粗糙度。

公开(公告)号：US07736704B2

公开(公告)日：2010-06-15

申请号：US11225660

申请日：2005-09-13

申请人： Sharad Chandra ,  Norbert Czech

发明人： Sharad Chandra ,  Norbert Czech

IPC分类号： B05D3/12 ,  B05D7/14 ,  B05D7/22 ,  B05D1/38

CPC分类号： C23C10/60 ,  C23C10/02 ,  C23C28/3215 ,  C23C28/322 ,  C23C28/3455 ,  C23C28/36

摘要： To protect a base metal layer (1) against high-temperature corrosion and high-temperature erosion, an adhesive layer (3) based on MCrAlY is applied to the base metal layer (1). The adhesive layer (3) is coated with an Al diffusion layer (4) by alitizing. The diffusion layer (4) is subjected to an abrasive treatment, so that the outer built-up layer (4.2) on the diffusion layer (4) prepared by alitizing is removed by the abrasive treatment. A ceramic heat insulation layer (2) consisting of zirconium oxide, which is partially stabilized by yttrium oxide, is applied to the diffusion layer (4) thus treated.

摘要翻译： 为了保护贱金属层（1）免受高温腐蚀和高温侵蚀，将基于MCrAlY的粘合剂层（3）施加到基底金属层（1）上。 粘合剂层（3）通过AlI涂覆有Al扩散层（4）。 对扩散层（4）进行研磨处理，通过研磨处理除去通过脱气制备的扩散层（4）上的外层积层（4.2）。 将由氧化钇部分稳定的氧化锆组成的陶瓷绝热层（2）施加到如此处理的扩散层（4）上。

公开(公告)号：US20100266409A1

公开(公告)日：2010-10-21

申请号：US12086511

申请日：2006-12-12

申请人： Sharad Chandra ,  Norbert Czech

发明人： Sharad Chandra ,  Norbert Czech

IPC分类号： F01D5/18 ,  C23C16/06 ,  C23C4/06 ,  C23C28/02

CPC分类号： C23C10/14 ,  C23C4/073 ,  C23C4/18 ,  C23C10/08 ,  C23C10/60 ,  C23C14/025 ,  C23C14/028 ,  C23C14/083 ,  C23C14/30 ,  C23C28/3215 ,  C23C28/322 ,  C23C28/325 ,  C23C28/3455 ,  C23C30/00 ,  F01D5/187 ,  F01D5/288 ,  F05D2230/312 ,  F05D2300/132 ,  F05D2300/21

摘要： A method is provided for coating a hollow, internally cooled blade (1) of a gas turbine, in which method an outer coating (5) comprising an MCrAlY-based bonding layer (6) and a ceramic thermal barrier layer (9) of zirconium oxide is applied to the base material (3) of the blade (1) on the outer side of the blade (1) and an inner coating (4) comprising a Cr diffusion layer (7) is applied to the base material (3) of the blade (1) on the inner side of the blade (1). The MCrAlY-based bonding layer (6) is thereby applied to the finished blade (1). At the same time, along with the inner coating (4), the Cr diffusion layer (7) is also applied to the MCrAlY-based bonding layer (6) of the outer coating (5) by chemical vapour deposition. Subsequently, an Al diffusion layer (8) and an outer brittle Al build-up layer are applied by chemical vapour deposition to the bonding layer (6) coated with the Cr diffusion layer (7). After that, the outer brittle Al build-up layer is removed by an abrasive treatment and the ceramic thermal barrier layer (9) is applied to the Al diffusion layer (8).

摘要翻译： 提供了一种用于涂覆燃气轮机的中空的内部冷却的叶片（1）的方法，其中包括基于MCrAlY的结合层（6）和锆的陶瓷热障层（9）的外涂层（5） 氧化物施加到叶片（1）的外侧上的叶片（1）的基材（3）上，并且将包含Cr扩散层（7）的内涂层（4）施加到基材（3）上， （1）的内侧。 由此将MCrAlY基接合层（6）施加到成品刀片（1）上。 同时，与内涂层（4）一起，通过化学气相沉积也将Cr扩散层（7）施加到外涂层（5）的MCrAlY基结合层（6）上。 随后，通过化学气相沉积将Al扩散层（8）和外部脆性Al累积层施加到涂覆有Cr扩散层（7）的接合层（6）。 之后，通过研磨处理去除外部脆性Al堆积层，并将陶瓷热障层（9）施加到Al扩散层（8）。

公开(公告)号：US09109279B2

公开(公告)日：2015-08-18

申请号：US12086511

申请日：2006-12-12

申请人： Sharad Chandra ,  Norbert Czech

发明人： Sharad Chandra ,  Norbert Czech

IPC分类号： B32B15/01 ,  C23C10/14 ,  C23C4/08 ,  C23C4/18 ,  C23C10/08 ,  C23C10/60 ,  C23C14/02 ,  C23C14/08 ,  C23C14/30 ,  C23C30/00 ,  F01D5/18 ,  C23C28/00 ,  F01D5/28

CPC分类号： C23C10/14 ,  C23C4/073 ,  C23C4/18 ,  C23C10/08 ,  C23C10/60 ,  C23C14/025 ,  C23C14/028 ,  C23C14/083 ,  C23C14/30 ,  C23C28/3215 ,  C23C28/322 ,  C23C28/325 ,  C23C28/3455 ,  C23C30/00 ,  F01D5/187 ,  F01D5/288 ,  F05D2230/312 ,  F05D2300/132 ,  F05D2300/21

摘要： A method is provided for coating a hollow, internally cooled blade (1) of a gas turbine, in which method an outer coating (5) comprising an MCrAlY-based bonding layer (6) and a ceramic thermal barrier layer (9) of zirconium oxide is applied to the base material (3) of the blade (1) on the outer side of the blade (1) and an inner coating (4) comprising a Cr diffusion layer (7) is applied to the base material (3) of the blade (1) on the inner side of the blade (1). The MCrAlY-based bonding layer (6) is thereby applied to the finished blade (1). At the same time, along with the inner coating (4), the Cr diffusion layer (7) is also applied to the MCrAlY-based bonding layer (6) of the outer coating (5) by chemical vapor deposition. Subsequently, an Al diffusion layer (8) and an outer brittle Al build-up layer are applied by chemical vapor deposition to the bonding layer (6) coated with the Cr diffusion layer (7). After that, the outer brittle Al build-up layer is removed by an abrasive treatment and the ceramic thermal barrier layer (9) is applied to the Al diffusion layer (8).

摘要翻译： 提供了一种用于涂覆燃气轮机的中空的内部冷却的叶片（1）的方法，其中包括基于MCrAlY的结合层（6）和锆的陶瓷热障层（9）的外涂层（5） 氧化物施加到叶片（1）的外侧上的叶片（1）的基材（3）上，并且将包含Cr扩散层（7）的内涂层（4）施加到基材（3）上， （1）的内侧。 由此将MCrAlY基接合层（6）施加到成品刀片（1）上。 同时，与内涂层（4）一起，通过化学气相沉积也将Cr扩散层（7）施加到外涂层（5）的MCrAlY基结合层（6）上。 随后，通过化学气相沉积将Al扩散层（8）和外部脆性Al累积层施加到涂覆有Cr扩散层（7）的接合层（6）。 之后，通过研磨处理去除外部脆性Al堆积层，并将陶瓷热障层（9）施加到Al扩散层（8）。

公开(公告)号：US20090011260A1

公开(公告)日：2009-01-08

申请号：US12084726

申请日：2006-11-07

申请人： Sharad Chandra ,  Norbert Czech

发明人： Sharad Chandra ,  Norbert Czech

IPC分类号： B32B15/00 ,  C23C8/06

CPC分类号： C23C10/02 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/31678

摘要： Disclosed is a heat-insulating protective layer for a component located within the hot gas zone of a gas turbine. Said protective layer is composed of an adhesive layer, a diffusion layer, and a ceramic layer which is applied to the high temperature-resistant basic metal of the component. The adhesive layer comprises a metal alloy [MCrAlY (M=Ni, Co)] containing Ni, Co, Cr, Al, Y, the diffusion layer is produced by calorizing the adhesive layer, and the ceramic layer is composed of ZrO2 which is partially stabilized by means of yttrium oxide. One or several chemical metal elements that have a large atomic diameter and are selected among the group comprising Re, W, Si, Hf, and/or Ta are alloyed to the material of the adhesive layer. The adhesive layer has the following chemical composition after being applied: Co 15 to 30 percent, Cr 15 to 25 percent, Al 6 to 13 percent, Y 0.2 to 0.7 percent, Re up to 5 percent, W up to 5 percent, Si up to 3 percent, Hf up to 3 percent, Ta up to 5 percent, the remainder being composed of Ni.

摘要翻译： 公开了一种用于位于燃气轮机的热气区内的部件的绝热保护层。 所述保护层由施加到所述部件的耐高温碱性金属的粘合剂层，扩散层和陶瓷层构成。 粘合剂层包含含有Ni，Co，Cr，Al，Y的金属合金[MCrAlY（M = Ni，Co）]，扩散层通过加热粘合剂层而产生，陶瓷层由部分地由ZrO 2组成 通过氧化钇稳定。 具有大原子直径并且选自Re，W，Si，Hf和/或Ta的组中的一种或几种化学金属元素与粘合剂层的材料合金化。 粘合剂层在施用后具有以下化学组成：Co 15〜30％，Cr 15〜25％，Al 6〜13％，Y 0.2〜0.7％，Re：5％以下，W：5％以上，Si： 至3％，Hf高达3％，Ta高达5％，其余由Ni组成。

公开(公告)号：US09139896B2

公开(公告)日：2015-09-22

申请号：US12084726

申请日：2006-11-07

申请人： Sharad Chandra ,  Norbert Czech

发明人： Sharad Chandra ,  Norbert Czech

IPC分类号： B32B15/00 ,  C23C10/02 ,  C23C28/00

CPC分类号： C23C10/02 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/31678

摘要： Disclosed is a heat-insulating protective layer for a component located within the hot gas zone of a gas turbine. Said protective layer is composed of an adhesive layer, a diffusion layer, and a ceramic layer which is applied to the high temperature-resistant basic metal of the component. The adhesive layer comprises a metal alloy [MCrAlY (M=Ni, Co)] containing Ni, Co, Cr, Al, Y, the diffusion layer is produced by calorizing the adhesive layer, and the ceramic layer is composed of ZrO2 which is partially stabilized by means of yttrium oxide. One or several chemical metal elements that have a large atomic diameter and are selected among the group comprising Re, W, Si, Hf, and/or Ta are alloyed to the material of the adhesive layer. The adhesive layer has the following chemical composition after being applied: Co 15 to 30 percent, Cr 15 to 25 percent, Al 6 to 13 percent, Y 0.2 to 0.7 percent, Re up to 5 percent, W up to 5 percent, Si up to 3 percent, Hf up to 3 percent, Ta up to 5 percent, the remainder being composed of Ni.

摘要翻译： 公开了一种用于位于燃气轮机的热气区内的部件的绝热保护层。 所述保护层由施加到所述部件的耐高温碱性金属的粘合剂层，扩散层和陶瓷层构成。 粘合剂层包含含有Ni，Co，Cr，Al，Y的金属合金[MCrAlY（M = Ni，Co）]，扩散层通过加热粘合剂层而产生，陶瓷层由部分地由ZrO 2组成 通过氧化钇稳定。 具有大原子直径并且选自Re，W，Si，Hf和/或Ta的组中的一种或几种化学金属元素与粘合剂层的材料合金化。 粘合剂层在施用后具有以下化学组成：Co 15〜30％，Cr 15〜25％，Al 6〜13％，Y 0.2〜0.7％，Re：5％以下，W：5％以上，Si： 至3％，Hf高达3％，Ta高达5％，其余由Ni组成。

公开(公告)号：US20060177582A1

公开(公告)日：2006-08-10

申请号：US11225660

申请日：2005-09-13

申请人： Sharad Chandra ,  Norbert Czech

发明人： Sharad Chandra ,  Norbert Czech

IPC分类号： B05D3/12

CPC分类号： C23C10/60 ,  C23C10/02 ,  C23C28/3215 ,  C23C28/322 ,  C23C28/3455 ,  C23C28/36

摘要： To protect a base metal layer (1) against high-temperature corrosion and high-temperature erosion, an adhesive layer (3) based on MCrAlY is applied to the base metal layer (1). The adhesive layer (3) is coated with an Al diffusion layer (4) by alitizing. The diffusion layer (4) is subjected to an abrasive treatment, so that the outer built-up layer (4.2) on the diffusion layer (4) prepared by alitizing is removed by the abrasive treatment. A ceramic heat insulation layer (2) consisting of zirconium oxide, which is partially stabilized by yttrium oxide, is applied to the diffusion layer (4) thus treated.

摘要翻译： 为了保护贱金属层（1）免受高温腐蚀和高温侵蚀，将基于MCrAlY的粘合剂层（3）施加到基底金属层（1）上。 粘合剂层（3）通过AlI涂覆有Al扩散层（4）。 对扩散层（4）进行研磨处理，通过研磨处理除去通过脱气制备的扩散层（4）上的外层积层（4.2）。 将由氧化钇部分稳定的氧化锆组成的陶瓷绝热层（2）施加到如此处理的扩散层（4）上。

公开(公告)号：US07824738B2

公开(公告)日：2010-11-02

申请号：US11587857

申请日：2005-02-04

申请人： John Smith ,  Sharad Chandra

发明人： John Smith ,  Sharad Chandra

IPC分类号： B05D3/00

CPC分类号： C23C10/52 ,  C23C10/38 ,  C23C10/42 ,  C23C10/48 ,  C23C10/50

摘要： This invention relates to the simultaneous treatment of the internal and external surfaces of turbine blades or vanes. In particular it provides a process for coating an external and an internal surface of a turbine blade or vane with aluminium and chromium, respectively, at substantially the same time. The process comprises the following steps (i) and (ii) in either order: (i) applying to the external surface an aluminising compound comprising aluminium, a moderator, an energiser and a diluent; and (ii) applying to the internal surface a chromising compound comprising chromium, an energiser and a diluent. These steps are followed by (iii) heating the turbine blade or vane to form an aluminium layer on the external surface and a chromium layer on the internal surface. The invention also provides a suitable aluminising compound and a chromising compound per se.

摘要翻译： 本发明涉及同时处理涡轮叶片或叶片的内表面和外表面。 特别地，它提供了一种在大致相同的时间分别用铝和铬涂覆涡轮叶片或叶片的外表面和内表面的方法。 该方法按以下顺序包括以下步骤（i）和（ii）：（i）向外表面施加包含铝，慢化剂，激发剂和稀释剂的铝化合物; 和（ii）向内表面施加包含铬，能量器和稀释剂的铬化合物。 这些步骤之后是（iii）加热涡轮机叶片或叶片以在外表面上形成铝层，并在内表面上形成铬层。 本发明还提供合适的铝化合物和铬化合物本身。