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    Radiation-curable water-dilutable urethane resins, preparation process and use
    1.
    发明授权
    Radiation-curable water-dilutable urethane resins, preparation process and use 失效
    可辐射固化水可稀释的聚氨酯树脂，制备方法和用途

    公开(公告)号：US5990192A

    公开(公告)日：1999-11-23

    申请号：US57583

    申请日：1998-04-09

    申请人： Martin Gerlitz ,  Rami-Raimund Awad ,  Ulrike Kuttler ,  Thomas Fraydl ,  Martin Leitner ,  Andreas Kocsar

    发明人： Martin Gerlitz ,  Rami-Raimund Awad ,  Ulrike Kuttler ,  Thomas Fraydl ,  Martin Leitner ,  Andreas Kocsar

    IPC分类号： C08G18/67 ,  C09D175/14 ,  C08G18/62

    CPC分类号： C09D175/14 ,  C08G18/6705 ,  C08G18/675 ,  Y10T428/31591

    摘要： Radiation-curable water-dilutable urethane resins obtainable by reacting cycloaliphatic and/or aromatic diisocyanates with a mixture of a (meth)acryloyl-containing dihydroxy compound in an amount such that the amount of reactive hydroxyl groups present therein is from 0.2 to 0.6 mol, and with a tri or tetrahydric polyol which has been partly esterified with (meth)acrylic acid and has a residual average hydroxyl functionality of from 1.0 to 1.4 in the molecule, in an amount such that the amount of the reactive hydroxyl groups is from 0.4 to 0.8 mol, the sum of the amounts of the reactive hydroxyl groups always being 1.0 mol, and from 40 to 60% of the isocyanate groups being converted into urethane groups, and reacting the resulting intermediate with an aliphatic saturated monocarboxylic acid having at least two hydroxyl groups in an amount such that the amount of the reactive hydroxyl groups is from 0.6 to 1 mol, until the hydroxyl groups have undergone complete reaction and reacting this product, if desired, with further part-esterified polyol in an amount such that the amount of hydroxyl groups in the polyol is from 0 to 0.5 mol until the remaining free isocyanate groups have undergone complete reaction, the molar proportions of the components being chosen so that the ratio of the number of isocyanate groups to the number of hydroxyl groups is from 0.9:1 to 1:1 and the reaction product possesses carboxyl groups in accordance with an acid number of from 20 to 40 mg/g and has a specific double bond content of not more than 3.5 mol/kg.

    摘要翻译： 可通过使脂环族和/或芳族二异氰酸酯与含（甲基）丙烯酰基的二羟基化合物的混合物使其中存在的反应性羟基的量为0.2至0.6mol的量反应得到的可辐射固化水可稀释的聚氨酯树脂， 和与（甲基）丙烯酸部分酯化并且在分子中具有1.0至1.4的残余平均羟基官能度的三元或四元多元醇，其量使得反应性羟基的量为0.4至 0.8mol，反应性羟基的总量总计为1.0mol，异氰酸酯基的40-60％转化为氨基甲酸酯基团，并使得到的中间体与具有至少两个羟基的脂族饱和一元羧酸反应 基团的量使得反应性羟基的量为0.6至1mol，直到羟基已经完全反应并使其反应 是产物，如果需要，还有部分酯化的多元醇的量使得多元醇中羟基的量为0至0.5mol，直到剩余的游离异氰酸酯基团经历了完全反应，选择的组分的摩尔比例 使得异氰酸酯基数与羟基数的比例为0.9:1至1:1，并且反应产物具有根据酸值为20至40mg / g的羧基，并且具有特定的 双键含量不超过3.5 mol / kg。

    High-solids, radiation-curable water-soluble combinations of polyester resins
    2.
    发明授权
    High-solids, radiation-curable water-soluble combinations of polyester resins 有权
    高固体，可辐射固化的聚酯树脂的水溶性组合

    公开(公告)号：US06265461B1

    公开(公告)日：2001-07-24

    申请号：US09383091

    申请日：1999-08-25

    申请人： Edmund Urbano ,  Ulrike Kuttler ,  Martin Gerlitz ,  Rami-Raimund Awad

    发明人： Edmund Urbano ,  Ulrike Kuttler ,  Martin Gerlitz ,  Rami-Raimund Awad

    IPC分类号： C09D16707

    CPC分类号： C09D167/07 ,  C08G63/21 ,  C08L67/00

    摘要： Radiation curable polyester composition AB, capable of forming solutions or dispersions in water of high solid content which can be produced by mixing or pre-condensing a water soluble, radiation-curable emulsifying resin A which contains ester and acid groups and has an acid number from 20 to 300 mg/g and water-insoluble, radiation-curable polymer B containing ester and/or ether groups, wherein resin A is a reaction product of an alkoxylated polyol A1 having at least 3 hydroxyl groups and 3 to 10 oxyalkylene units per molecule, these oxyalkylene units containing 2 to 4 carbon atoms each, with an &agr;, &bgr;-unsaturated carboxylic acid A2 having each a free carboxyl group per molecule, and a carboxylic acid A3 which is at least tri-functional and wherein polymer B is a reaction product of aliphatic, linear, branched or cyclic alcohols B1 with compounds B2, selected from alkylene oxides B21, dicarboxylic acids B22 and aliphatic lactones B23 having 4 to 12 carbon atoms as well as compounds B3 selected from &agr;,&bgr;-unsaturated carboxylic acids with 1 to 2 carboxyl groups in the molecule, aqueous coating compositions made therefrom, and a method of using these for coating of heat-sensitive substrates.

    摘要翻译： 可辐射固化的聚酯组合物AB，其能够在高固含量的水中形成溶液或分散体，其可通过将含有酯和酸基团并具有酸值的水溶性可辐射固化的乳化树脂A混合或预冷凝来制备 20至300mg / g和含有酯和/或醚基团的水不溶性可辐射固化聚合物B，其中树脂A是每分子具有至少3个羟基和3至10个氧化烯单元的烷氧基化多元醇A1的反应产物 ，各自含有2至4个碳原子的这些氧化烯单元与每分子具有游离羧基的α，β-不饱和羧酸A2和至少三官能的羧酸A3，其中聚合物B是反应 脂肪族，直链，支链或环状醇B1与化合物B2的选自烯化氧B21，二羧酸B22和碳原子数4〜12的脂肪族内酯B23以及组合物 ds B3选自分子中具有1至2个羧基的α，β-不饱和羧酸，由其制备的水性涂料组合物，以及使用它们来涂覆热敏性基材的方法。

    Aqueous non-ionically stabilized epoxy resins
    5.
    发明授权
    Aqueous non-ionically stabilized epoxy resins 失效
    水性非离子稳定化环氧树脂

    公开(公告)号：US07560143B2

    公开(公告)日：2009-07-14

    申请号：US10531090

    申请日：2003-10-17

    申请人： Rami-Raimund Awad ,  Florian Lunzer ,  Martin Gerlitz

    发明人： Rami-Raimund Awad ,  Florian Lunzer ,  Martin Gerlitz

    IPC分类号： B05D3/06 ,  B05D1/02 ,  B05D1/18 ,  C08F2/46 ,  C08G63/00 ,  C08L63/00 ,  B32B15/092 ,  B32B27/38

    CPC分类号： C08G18/675 ,  C08F299/026 ,  C08G59/1461 ,  C08L63/10 ,  C08L75/14 ,  C09D163/10 ,  C09D175/14 ,  C08L2666/20 ,  C08L2666/22

    摘要： Aqueous radiation curable binders comprising non-ionically stabilized epoxy resins ABC. Resins ABC are an adduct mixture of: adducts formed by the reaction of polyethylene glycol-modified epoxy resins A with olefinically unsaturated acids C, and adducts formed by the reaction of epoxy resins B, that are free from polyethylene glycol derived groups, with olefinically unsaturated acids C. A process for preparing aqueous radiation curable binders comprising non-ionically stabilized epoxy resins ABC, and a process of coating a substrate with aqueous radiation curable binders comprising non-ionically stabilized epoxy resins ABC.

    摘要翻译： 包含非离子稳定化环氧树脂ABC的水性可辐射固化粘合剂。 树脂ABC是以下加合物混合物：由聚乙二醇改性的环氧树脂A与烯属不饱和酸C反应形成的加合物，和不含聚乙二醇衍生基团的环氧树脂B与烯属不饱和酸反应形成的加成物 酸C.制备包含非离子稳定化环氧树脂ABC的水性可辐射固化粘合剂的方法，以及用包含非离子稳定化环氧树脂ABC的水性可辐射固化粘合剂涂覆基材的方法。

    Streptospirole derivatives
    7.
    发明授权
    Streptospirole derivatives 有权
    链球菌衍生物

    公开(公告)号：US08765799B2

    公开(公告)日：2014-07-01

    申请号：US13056751

    申请日：2009-07-16

    申请人： Cosima Dufour-Schroif ,  Joachim Wink ,  Martin Gerlitz ,  Hélène Olivan ,  Michael Kurz

    发明人： Cosima Dufour-Schroif ,  Joachim Wink ,  Martin Gerlitz ,  Hélène Olivan ,  Michael Kurz

    IPC分类号： A61K31/407 ,  C07D491/107 ,  C07D498/10

    CPC分类号： C07D498/10 ,  C07D491/107

    摘要： The invention relates to streptospirole derivatives of the general formula (I), wherein R1, R2, R3, X1, X2, Y1 and Y2 are as defined herein, a process for the preparation of said compounds by fermenting the microorganism Streptomyces sp. ST 108140 (DSM 19369) and optionally derivatizing the compounds produced by said microorganism, a pharmaceutical composition comprising at least one compound of the formula (I), and the use of a compound of the formula (I) for the preparation of a medicament for the treatment and/or prophylaxis of bacterial infections.

    摘要翻译： 本发明涉及通式（I）的链霉菌素衍生物，其中R1，R2，R3，X1，X2，Y1和Y2如本文所定义，通过发酵微生物Streptomyces sp。 ST108404（DSM19369），并任选地衍生由所述微生物产生的化合物，包含至少一种式（I）化合物的药物组合物和式（I）化合物在制备药物中的应用 治疗和/或预防细菌感染。

    STREPTOSPIROLE DERIVATIVES
    9.
    发明申请
    STREPTOSPIROLE DERIVATIVES 有权

    公开(公告)号：US20110295009A1

    公开(公告)日：2011-12-01

    申请号：US13056751

    申请日：2009-07-16

    申请人： Cosima Dufour-Schroif ,  Joachim Wink ,  Martin Gerlitz ,  Helene Olivan ,  Michael Kurz

    发明人： Cosima Dufour-Schroif ,  Joachim Wink ,  Martin Gerlitz ,  Helene Olivan ,  Michael Kurz

    IPC分类号： C07D491/107 ,  C12N1/20 ,  C12P17/16

    CPC分类号： C07D498/10 ,  C07D491/107

    摘要： The invention relates to streptospirole derivatives of the general formula (I), wherein R1, R2, R3, X1, X2, Y1 and Y2 are as defined herein, a process for the preparation of said compounds by fermenting the microorganism Streptomyces sp. ST 108140 (DSM 19369) and optionally derivatizing the compounds produced by said microorganism, a pharmaceutical composition comprising at least one compound of the formula (I), and the use of a compound of the formula (I) for the preparation of a medicament for the treatment and/or prophylaxis of bacterial infections.

    摘要翻译： 本发明涉及通式（I）的链霉菌素衍生物，其中R1，R2，R3，X1，X2，Y1和Y2如本文所定义，通过发酵微生物Streptomyces sp。 ST108404（DSM19369），并任选地衍生由所述微生物产生的化合物，包含至少一种式（I）化合物的药物组合物和式（I）化合物在制备药物中的应用 治疗和/或预防细菌感染。

    Water dilutable amine curing agents for aqueous two component epoxy resin systems
    10.
    发明授权
    Water dilutable amine curing agents for aqueous two component epoxy resin systems 有权
    水可稀释胺固化剂用于水性双组分环氧树脂体系

    公开(公告)号：US06653369B2

    公开(公告)日：2003-11-25

    申请号：US10139461

    申请日：2002-05-06

    申请人： Martin Gerlitz ,  Thomas Fischer ,  Andreas Gollner ,  Manfred Gogg ,  Elfriede Prucher ,  Heike Schneeberger ,  Josef Wenzl

    发明人： Martin Gerlitz ,  Thomas Fischer ,  Andreas Gollner ,  Manfred Gogg ,  Elfriede Prucher ,  Heike Schneeberger ,  Josef Wenzl

    IPC分类号： C08K320

    CPC分类号： C08G59/184

    摘要： Water dilutable amine curing agents for aqueous epoxy resin dispersions, comprising a combination of an epoxide-amine adduct with an emulsifier, the epoxide-amine adduct being obtainable by reacting a polyepoxide with a reaction product of an amine and an epoxide component or an amine and subsequent reaction with an epoxide component, the amount of amine being chosen such that the number of nitrogen-attached hydrogen atoms the number of epoxide groups by a factor of from 2 to 10, and the emulsifier being obtainable by reacting diepoxides or polyepoxides with compounds that are at least difunctional with respect to epoxides, optionally with compounds D that are monofunctional with respect to epoxides, and with amines G which contain at least one tertiary and at least one primary or at least two secondary amino group(s).

    摘要翻译： 用于水性环氧树脂分散体的水可稀释胺固化剂，其包括环氧胺 - 胺加合物与乳化剂的组合，所述环氧胺 - 加合物可通过使多环氧化物与胺和环氧化物组分或胺的反应产物反应获得， 随后与环氧化物组分的反应，选择胺的量使得连接氮原子的氢原子数目为2至10的环氧化物基团数，并且乳化剂可通过使二环氧化物或聚环氧化物与化合物 至少对于环氧化物是双官能的，任选地与化合物D相对于环氧化物是单官能的，以及含有至少一个叔胺和至少一个伯或至少两个仲氨基的胺G.