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公开(公告)号：US20060094603A1
公开(公告)日：2006-05-04
申请号：US11241636
申请日：2005-09-30
申请人： Xiaoping Li , Thomas Kodenkandath , Edward Siegal , Wei Zhang , Martin Rupich , Yibing Huang
发明人： Xiaoping Li , Thomas Kodenkandath , Edward Siegal , Wei Zhang , Martin Rupich , Yibing Huang
IPC分类号： H01L39/24
CPC分类号： H01L39/2425 , C23C18/1216 , C23C18/1225 , C23C18/127 , H01L39/2483 , Y10T29/49014
摘要： A method for producing a thick film includes disposing a precursor solution onto a substrate to form a precursor film. The precursor solution contains precursor components to a rare-earth/alkaline-earth-metal/transition-metal oxide including a salt of a rare earth element, a salt of an alkaline earth metal, and a salt of a transition metal in one or more solvents, wherein at least one of the salts is a fluoride-containing salt, and wherein the ratio of the transition metal to the alkaline earth metal is greater than 1.5. The precursor solution is treated to form a rare earth-alkaline earth-metal transition metal oxide superconductor film having a thickness greater than 0.8 μm. precursor solution.
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公开(公告)号：US20070111893A1
公开(公告)日：2007-05-17
申请号：US11494993
申请日：2006-07-28
申请人： Thomas Kodenkandath , Wei Zhang , Yibing Huang , Xiaoping Li , Edward Siegal , Martin Rupich
发明人： Thomas Kodenkandath , Wei Zhang , Yibing Huang , Xiaoping Li , Edward Siegal , Martin Rupich
IPC分类号： H01P1/203
CPC分类号： H01L39/143 , H01F6/06 , H01F41/048 , H01P1/203 , Y10S505/704 , Y10S505/705 , Y10T29/49014
摘要： A superconducting wire includes first and second superconducting layers disposed on one or more substrates in stacked relationship, the first superconducting layer comprising a high temperature superconducting oxide of a first composition and the second superconducting layer comprising a high temperature superconducting layer of a second composition, wherein the first and second compositions are different. The first superconductor layer optionally includes a high temperature superconductor composition selected to provide enhanced critical current (Ic(c)) in the presence of magnetic fields perpendicular to surface of the superconducting layer (H//c). The second superconductor layer optionally includes a high temperature superconductor composition selected to provide enhanced critical current (Ic) in the presence of magnetic fields parallel to surface of the superconducting layer (H//ab).
摘要翻译： 超导线包括以堆叠关系设置在一个或多个衬底上的第一和第二超导层，第一超导层包括第一组合物的高温超导氧化物，第二超导层包含第二组合物的高温超导层，其中 第一和第二组合物是不同的。 第一超导体层任选地包括在垂直于超导层（H // c）的表面的磁场的存在下选择用于提供增强的临界电流（Ic（c））的高温超导体组合物。 第二超导体层任选地包括选择用于在平行于超导层的表面的磁场存在下提供增强的临界电流（Ic）的高温超导体组合物（H // ab）。
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公开(公告)号：US20050159298A1
公开(公告)日：2005-07-21
申请号：US10758710
申请日：2004-01-16
申请人： Martin Rupich , Thomas Kodenkandath , Wei Zhang , Xiaoping Li
发明人： Martin Rupich , Thomas Kodenkandath , Wei Zhang , Xiaoping Li
CPC分类号： H01L39/2483 , H01L39/2425
摘要： A method for producing a thin film includes disposing a precursor solution onto a substrate to form a precursor film. The precursor solution contains precursor components to a rare-earth/alkaline-earth-metal/transition-metal oxide including a salt of a rare earth element, a salt of an alkaline earth metal, and a salt of a transition metal in one or more solvents, wherein at least one of the salts is a fluoride-containing salt. The precursor solution also contains an additive component comprising one or more metal compounds capable of forming a second phase nanoparticle, either alone or in combination with one or more of the precursor components of the precursor solution or a dopant component comprising one or more metal compounds capable of substituting for an element of the rare-earth/alkaline-earth-metal/transition-metal oxide, and treating the precursor film to form an intermediate metal oxyfluoride including the rare earth, the alkaline earth metal, the transition metal and the additive metal or dopant metal of the precursor solution.
摘要翻译： 制造薄膜的方法包括将前体溶液设置在基板上以形成前体膜。 前体溶液含有稀土/碱土金属/过渡金属氧化物的前体成分，所述稀土/碱土金属/过渡金属氧化物包括稀土元素的盐，碱土金属的盐和过渡金属的盐在一个或多个 溶剂，其中至少一种盐是含氟化物的盐。 前体溶液还包含添加剂组分，其包含一种或多种能够形成第二相纳米颗粒的金属化合物，单独或与前体溶液的一种或多种前体组分或包含一种或多种金属化合物的掺杂剂组分组合 代替稀土/碱土金属/过渡金属氧化物的元素，并处理前体膜以形成包括稀土，碱土金属，过渡金属和添加金属的中间体金属氟氧化物 或前体溶液的掺杂剂金属。
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公开(公告)号：US20050217568A1
公开(公告)日：2005-10-06
申请号：US10812676
申请日：2004-03-30
IPC分类号： B32B15/18 , C30B7/00 , C30B23/00 , C30B25/00 , C30B28/12 , C30B28/14 , C30B29/16 , C30B29/22 , H01L39/12 , H01L39/24
CPC分类号： C30B29/16 , C30B7/005 , C30B29/22 , H01L39/2461 , Y10S505/929
摘要： A method of making a multilayer article includes depositing a first material on the surface of a metal substrate to form a seed layer of the first material, the first material being deposited under reducing conditions relative to the metal substrate, and then epitaxially depositing a second material on a surface of the seed layer, wherein the second material is deposited from a solution-based precursor under second conditions that are more oxidizing than the reducing conditions used in the deposition of the first material.
摘要翻译： 制造多层制品的方法包括在金属基材的表面上沉积第一材料以形成第一材料的籽晶层，第一材料相对于金属基底在还原条件下沉积，然后外延沉积第二材料 在种子层的表面上，其中第二材料在比在沉积第一材料中使用的还原条件更加氧化的第二条件下从基于溶液的前体沉积。
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公开(公告)号：US08354136B2
公开(公告)日：2013-01-15
申请号：US12624859
申请日：2009-11-24
申请人： Xiaoping Li , Thomas Kodenkandath , Edward J. Siegal , Wei Zhang , Martin W. Rupich , Yibing Huang
发明人： Xiaoping Li , Thomas Kodenkandath , Edward J. Siegal , Wei Zhang , Martin W. Rupich , Yibing Huang
CPC分类号： H01L39/2425 , C23C18/1216 , C23C18/1225 , C23C18/127 , H01L39/2483 , Y10T29/49014
摘要： A method for producing a thick film includes disposing a precursor solution onto a substrate to form a precursor film. The precursor solution contains precursor components to a rare-earth/alkaline-earth-metal/transition-metal oxide including a salt of a rare earth element, a salt of an alkaline earth metal, and a salt of a transition metal in one or more solvents, wherein at least one of the salts is a fluoride-containing salt, and wherein the ratio of the transition metal to the alkaline earth metal is greater than 1.5. The precursor solution is treated to form a rare earth-alkaline earth-metal transition metal oxide superconductor film having a thickness greater than 0.8 μm. precursor solution.
摘要翻译： 制造厚膜的方法包括将前体溶液设置在基板上以形成前体膜。 前体溶液含有稀土/碱土金属/过渡金属氧化物的前体成分，所述稀土/碱土金属/过渡金属氧化物包括稀土元素的盐，碱土金属的盐和过渡金属的盐在一个或多个 溶剂，其中至少一种盐是含氟化物的盐，其中过渡金属与碱土金属的比例大于1.5。 处理前体溶液以形成厚度大于0.8μm的稀土 - 碱土金属过渡金属氧化物超导体膜。 前体溶液。
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公开(公告)号：US07781376B2
公开(公告)日：2010-08-24
申请号：US11494993
申请日：2006-07-28
申请人： Thomas Kodenkandath , Wei Zhang , Yibing Huang , Xiaoping Li , Edward J. Siegal , Martin W. Rupich
发明人： Thomas Kodenkandath , Wei Zhang , Yibing Huang , Xiaoping Li , Edward J. Siegal , Martin W. Rupich
CPC分类号： H01L39/143 , H01F6/06 , H01F41/048 , H01P1/203 , Y10S505/704 , Y10S505/705 , Y10T29/49014
摘要： A superconducting wire includes first and second superconducting layers disposed on one or more substrates in stacked relationship, the first superconducting layer comprising a high temperature superconducting oxide of a first composition and the second superconducting layer comprising a high temperature superconducting layer of a second composition, wherein the first and second compositions are different. The first superconductor layer optionally includes a high temperature superconductor composition selected to provide enhanced critical current (Ic(c)) in the presence of magnetic fields perpendicular to surface of the superconducting layer (H//c). The second superconductor layer optionally includes a high temperature superconductor composition selected to provide enhanced critical current (Ic) in the presence of magnetic fields parallel to surface of the superconducting layer (H//ab).
摘要翻译： 超导线包括以堆叠关系设置在一个或多个衬底上的第一和第二超导层，第一超导层包括第一组合物的高温超导氧化物，第二超导层包含第二组合物的高温超导层，其中 第一和第二组合物是不同的。 第一超导体层任选地包括在垂直于超导层（H // c）的表面的磁场的存在下选择用于提供增强的临界电流（Ic（c））的高温超导体组合物。 第二超导体层任选地包括选择用于在平行于超导层的表面的磁场存在下提供增强的临界电流（Ic）的高温超导体组合物（H // ab）。
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公开(公告)号：US20100112192A1
公开(公告)日：2010-05-06
申请号：US12624859
申请日：2009-11-24
申请人： Xiaoping Li , Thomas Kodenkandath , Edward J. Siegal , Wei Zhang , Martin W. Rupich , Yibing Huang
发明人： Xiaoping Li , Thomas Kodenkandath , Edward J. Siegal , Wei Zhang , Martin W. Rupich , Yibing Huang
IPC分类号： B05D5/12
CPC分类号： H01L39/2425 , C23C18/1216 , C23C18/1225 , C23C18/127 , H01L39/2483 , Y10T29/49014
摘要： A method for producing a thick film includes disposing a precursor solution onto a substrate to form a precursor film. The precursor solution contains precursor components to a rare-earth/alkaline-earth-metal/transition-metal oxide including a salt of a rare earth element, a salt of an alkaline earth metal, and a salt of a transition metal in one or more solvents, wherein at least one of the salts is a fluoride-containing salt, and wherein the ratio of the transition metal to the alkaline earth metal is greater than 1.5. The precursor solution is treated to form a rare earth-alkaline earth-metal transition metal oxide superconductor film having a thickness greater than 0.8 μm. precursor solution.
摘要翻译： 制造厚膜的方法包括将前体溶液设置在基板上以形成前体膜。 前体溶液含有稀土/碱土金属/过渡金属氧化物的前体成分，所述稀土/碱土金属/过渡金属氧化物包括稀土元素的盐，碱土金属的盐和过渡金属的盐在一个或多个 溶剂，其中至少一种盐是含氟化物的盐，其中过渡金属与碱土金属的比例大于1.5。 处理前体溶液以形成厚度大于0.8μm的稀土 - 碱土金属过渡金属氧化物超导体膜。 前体溶液。
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公开(公告)号：US07622424B2
公开(公告)日：2009-11-24
申请号：US11241636
申请日：2005-09-30
申请人： Xiaoping Li , Thomas Kodenkandath , Edward J. Siegal , Wei Zhang , Martin W. Rupich , Yibing Huang
发明人： Xiaoping Li , Thomas Kodenkandath , Edward J. Siegal , Wei Zhang , Martin W. Rupich , Yibing Huang
IPC分类号： H01B12/00
CPC分类号： H01L39/2425 , C23C18/1216 , C23C18/1225 , C23C18/127 , H01L39/2483 , Y10T29/49014
摘要： A method for producing a thick film includes disposing a precursor solution onto a substrate to form a precursor film. The precursor solution contains precursor components to a rare-earth/alkaline-earth-metal/transition-metal oxide including a salt of a rare earth element, a salt of an alkaline earth metal, and a salt of a transition metal in one or more solvents, wherein at least one of the salts is a fluoride-containing salt, and wherein the ratio of the transition metal to the alkaline earth metal is greater than 1.5. The precursor solution is treated to form a rare earth-alkaline earth-metal transition metal oxide superconductor film having a thickness greater than 0.8 μm. precursor solution.
摘要翻译： 制造厚膜的方法包括将前体溶液设置在基板上以形成前体膜。 前体溶液含有稀土/碱土金属/过渡金属氧化物的前体成分，所述稀土/碱土金属/过渡金属氧化物包括稀土元素的盐，碱土金属的盐和过渡金属的盐在一个或多个 溶剂，其中至少一种盐是含氟化物的盐，其中过渡金属与碱土金属的比例大于1.5。 处理前体溶液以形成厚度大于0.8μm的稀土 - 碱土金属过渡金属氧化物超导体膜。 前体溶液。
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公开(公告)号：US20060051600A1
公开(公告)日：2006-03-09
申请号：US10991738
申请日：2004-11-18
申请人： Martin Rupich , Thomas Kodenkandath
发明人： Martin Rupich , Thomas Kodenkandath
CPC分类号： C30B29/22 , C30B7/005 , H01L39/2425 , H01L39/2451 , Y10S505/734
摘要： Superconductor precursor solutions are disclosed. The precursor solutions contain, for example, a salt of a rare earth metal, a salt of an alkaline earth metal and a salt of a transition metal. The precursor solutions can optionally include a Lewis base. The precursor solutions can be processed relatively quickly to provide a relatively thick and good quality intermediate of a rare earth metal-alkaline earth metal-transition metal oxide.
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公开(公告)号：US07261776B2
公开(公告)日：2007-08-28
申请号：US10812676
申请日：2004-03-30
IPC分类号： C30B29/16
CPC分类号： C30B29/16 , C30B7/005 , C30B29/22 , H01L39/2461 , Y10S505/929
摘要： A method of making a multilayer article includes depositing a first material on the surface of a metal substrate to form a seed layer of the first material, the first material being deposited under reducing conditions relative to the metal substrate, and then epitaxially depositing a second material on a surface of the seed layer, wherein the second material is deposited from a solution-based precursor under second conditions that are more oxidizing than the reducing conditions used in the deposition of the first material.
摘要翻译： 制造多层制品的方法包括在金属基材的表面上沉积第一材料以形成第一材料的籽晶层，第一材料相对于金属基底在还原条件下沉积，然后外延沉积第二材料 在种子层的表面上，其中第二材料在比在沉积第一材料中使用的还原条件更加氧化的第二条件下从基于溶液的前体沉积。
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