公开(公告)号：US08354136B2

公开(公告)日：2013-01-15

申请号：US12624859

申请日：2009-11-24

申请人： Xiaoping Li ,  Thomas Kodenkandath ,  Edward J. Siegal ,  Wei Zhang ,  Martin W. Rupich ,  Yibing Huang

发明人： Xiaoping Li ,  Thomas Kodenkandath ,  Edward J. Siegal ,  Wei Zhang ,  Martin W. Rupich ,  Yibing Huang

IPC分类号： B05D5/12 ,  H01L39/24

CPC分类号： H01L39/2425 ,  C23C18/1216 ,  C23C18/1225 ,  C23C18/127 ,  H01L39/2483 ,  Y10T29/49014

摘要： A method for producing a thick film includes disposing a precursor solution onto a substrate to form a precursor film. The precursor solution contains precursor components to a rare-earth/alkaline-earth-metal/transition-metal oxide including a salt of a rare earth element, a salt of an alkaline earth metal, and a salt of a transition metal in one or more solvents, wherein at least one of the salts is a fluoride-containing salt, and wherein the ratio of the transition metal to the alkaline earth metal is greater than 1.5. The precursor solution is treated to form a rare earth-alkaline earth-metal transition metal oxide superconductor film having a thickness greater than 0.8 μm. precursor solution.

摘要翻译： 制造厚膜的方法包括将前体溶液设置在基板上以形成前体膜。 前体溶液含有稀土/碱土金属/过渡金属氧化物的前体成分，所述稀土/碱土金属/过渡金属氧化物包括稀土元素的盐，碱土金属的盐和过渡金属的盐在一个或多个 溶剂，其中至少一种盐是含氟化物的盐，其中过渡金属与碱土金属的比例大于1.5。 处理前体溶液以形成厚度大于0.8μm的稀土 - 碱土金属过渡金属氧化物超导体膜。 前体溶液。

公开(公告)号：US07781376B2

公开(公告)日：2010-08-24

申请号：US11494993

申请日：2006-07-28

申请人： Thomas Kodenkandath ,  Wei Zhang ,  Yibing Huang ,  Xiaoping Li ,  Edward J. Siegal ,  Martin W. Rupich

发明人： Thomas Kodenkandath ,  Wei Zhang ,  Yibing Huang ,  Xiaoping Li ,  Edward J. Siegal ,  Martin W. Rupich

IPC分类号： H01B12/00 ,  H01L39/00 ,  H01F6/00

CPC分类号： H01L39/143 ,  H01F6/06 ,  H01F41/048 ,  H01P1/203 ,  Y10S505/704 ,  Y10S505/705 ,  Y10T29/49014

摘要： A superconducting wire includes first and second superconducting layers disposed on one or more substrates in stacked relationship, the first superconducting layer comprising a high temperature superconducting oxide of a first composition and the second superconducting layer comprising a high temperature superconducting layer of a second composition, wherein the first and second compositions are different. The first superconductor layer optionally includes a high temperature superconductor composition selected to provide enhanced critical current (Ic(c)) in the presence of magnetic fields perpendicular to surface of the superconducting layer (H//c). The second superconductor layer optionally includes a high temperature superconductor composition selected to provide enhanced critical current (Ic) in the presence of magnetic fields parallel to surface of the superconducting layer (H//ab).

摘要翻译： 超导线包括以堆叠关系设置在一个或多个衬底上的第一和第二超导层，第一超导层包括第一组合物的高温超导氧化物，第二超导层包含第二组合物的高温超导层，其中 第一和第二组合物是不同的。 第一超导体层任选地包括在垂直于超导层（H // c）的表面的磁场的存在下选择用于提供增强的临界电流（Ic（c））的高温超导体组合物。 第二超导体层任选地包括选择用于在平行于超导层的表面的磁场存在下提供增强的临界电流（Ic）的高温超导体组合物（H // ab）。

公开(公告)号：US20100112192A1

公开(公告)日：2010-05-06

申请号：US12624859

申请日：2009-11-24

申请人： Xiaoping Li ,  Thomas Kodenkandath ,  Edward J. Siegal ,  Wei Zhang ,  Martin W. Rupich ,  Yibing Huang

发明人： Xiaoping Li ,  Thomas Kodenkandath ,  Edward J. Siegal ,  Wei Zhang ,  Martin W. Rupich ,  Yibing Huang

IPC分类号： B05D5/12

CPC分类号： H01L39/2425 ,  C23C18/1216 ,  C23C18/1225 ,  C23C18/127 ,  H01L39/2483 ,  Y10T29/49014

摘要： A method for producing a thick film includes disposing a precursor solution onto a substrate to form a precursor film. The precursor solution contains precursor components to a rare-earth/alkaline-earth-metal/transition-metal oxide including a salt of a rare earth element, a salt of an alkaline earth metal, and a salt of a transition metal in one or more solvents, wherein at least one of the salts is a fluoride-containing salt, and wherein the ratio of the transition metal to the alkaline earth metal is greater than 1.5. The precursor solution is treated to form a rare earth-alkaline earth-metal transition metal oxide superconductor film having a thickness greater than 0.8 μm. precursor solution.

摘要翻译： 制造厚膜的方法包括将前体溶液设置在基板上以形成前体膜。 前体溶液含有稀土/碱土金属/过渡金属氧化物的前体成分，所述稀土/碱土金属/过渡金属氧化物包括稀土元素的盐，碱土金属的盐和过渡金属的盐在一个或多个 溶剂，其中至少一种盐是含氟化物的盐，其中过渡金属与碱土金属的比例大于1.5。 处理前体溶液以形成厚度大于0.8μm的稀土 - 碱土金属过渡金属氧化物超导体膜。 前体溶液。

公开(公告)号：US07622424B2

公开(公告)日：2009-11-24

申请号：US11241636

申请日：2005-09-30

申请人： Xiaoping Li ,  Thomas Kodenkandath ,  Edward J. Siegal ,  Wei Zhang ,  Martin W. Rupich ,  Yibing Huang

发明人： Xiaoping Li ,  Thomas Kodenkandath ,  Edward J. Siegal ,  Wei Zhang ,  Martin W. Rupich ,  Yibing Huang

IPC分类号： H01B12/00

CPC分类号： H01L39/2425 ,  C23C18/1216 ,  C23C18/1225 ,  C23C18/127 ,  H01L39/2483 ,  Y10T29/49014

摘要： A method for producing a thick film includes disposing a precursor solution onto a substrate to form a precursor film. The precursor solution contains precursor components to a rare-earth/alkaline-earth-metal/transition-metal oxide including a salt of a rare earth element, a salt of an alkaline earth metal, and a salt of a transition metal in one or more solvents, wherein at least one of the salts is a fluoride-containing salt, and wherein the ratio of the transition metal to the alkaline earth metal is greater than 1.5. The precursor solution is treated to form a rare earth-alkaline earth-metal transition metal oxide superconductor film having a thickness greater than 0.8 μm. precursor solution.

摘要翻译： 制造厚膜的方法包括将前体溶液设置在基板上以形成前体膜。 前体溶液含有稀土/碱土金属/过渡金属氧化物的前体成分，所述稀土/碱土金属/过渡金属氧化物包括稀土元素的盐，碱土金属的盐和过渡金属的盐在一个或多个 溶剂，其中至少一种盐是含氟化物的盐，其中过渡金属与碱土金属的比例大于1.5。 处理前体溶液以形成厚度大于0.8μm的稀土 - 碱土金属过渡金属氧化物超导体膜。 前体溶液。

公开(公告)号：US06537689B2

公开(公告)日：2003-03-25

申请号：US09995420

申请日：2001-11-26

申请人： Urs-Detlev Schoop ,  Suresh Annavarapu ,  Martin W. Rupich ,  Xiaoping Li ,  Wei Zhang ,  Edward J. Siegal ,  Qi Li

发明人： Urs-Detlev Schoop ,  Suresh Annavarapu ,  Martin W. Rupich ,  Xiaoping Li ,  Wei Zhang ,  Edward J. Siegal ,  Qi Li

IPC分类号： C09K1900

CPC分类号： H01L39/248 ,  C30B23/02 ,  C30B29/16 ,  H01L39/143 ,  H01L39/2425 ,  H01L39/2451 ,  H01L39/2461 ,  Y10S428/93

摘要： The invention relates to multi-layer articles and methods of making such articles. The multi-layer superconductors can have one or more layers with an oriented termination plane. The methods include first conditioning the termination plane of an underlying layer, such as a buffer layer or a superconductor layer, then disposing a layer of material on the conditioned termination plane. The conditioned termination plane can be a high quality termination plane. Superconductor articles formed by these methods can exhibit relatively high critical current densities.

公开(公告)号：US07902120B2

公开(公告)日：2011-03-08

申请号：US11880533

申请日：2007-07-23

申请人： Martin W. Rupich ,  Wei Zhang ,  Yibing Huang ,  Xiaoping Li

发明人： Martin W. Rupich ,  Wei Zhang ,  Yibing Huang ,  Xiaoping Li

IPC分类号： H01B12/00 ,  H01B13/00

CPC分类号： H01L39/2425 ,  H01L39/143 ,  H01L39/2451 ,  H01L39/2483 ,  Y10S428/93 ,  Y10S505/742 ,  Y10T29/49014

摘要： Superconductor wires or layers having improved properties and methods for making the same are described. The superconducting layer includes a rare earth element-alkaline earth element-transition metal oxide having an average stacking fault density that is greater than about 0.01 nm−1, wherein two or more rare earth cations form the rare earth element. To form the superconductor layer of the present invention, a layer having a rare earth element-alkaline earth element-transition metal oxide substantially in a first crystal structure can be provided to a substrate where two or more rare earth cations form the rare earth element. The layer can then be heated at a temperature that is greater than 550° C. under oxidizing conditions to form a high-temperature superconducting layer substantially in a second crystal structure.

摘要翻译： 描述了具有改进性能的超导体线或层或其制造方法。 超导层包括平均堆垛层错密度大于约0.01nm-1的稀土元素 - 碱土金属 - 过渡金属氧化物，其中两种或更多种稀土阳离子形成稀土元素。 为了形成本发明的超导体层，可以在其中两种或更多种稀土阳离子形成稀土元素的基板上提供具有基本上为第一晶体结构的稀土元素 - 碱土金属 - 过渡金属氧化物的层。 然后可以在氧化条件下在大于550℃的温度下加热该层，以形成基本上在第二晶体结构中的高温超导层。

公开(公告)号：US20080153709A1

公开(公告)日：2008-06-26

申请号：US11880533

申请日：2007-07-23

申请人： Martin W. Rupich ,  Wei Zhang ,  Yibing Huang ,  Xiaoping Li

发明人： Martin W. Rupich ,  Wei Zhang ,  Yibing Huang ,  Xiaoping Li

IPC分类号： H01B12/00 ,  H01B13/00

CPC分类号： H01L39/2425 ,  H01L39/143 ,  H01L39/2451 ,  H01L39/2483 ,  Y10S428/93 ,  Y10S505/742 ,  Y10T29/49014

摘要： Superconductor wires or layers having improved properties and methods for making the same are described. The superconducting layer includes a rare earth element—alkaline earth element—transition metal oxide having an average stacking fault density that is greater than about 0.01 nm−1, wherein two or more rare earth cations form the rare earth element. To form the superconductor layer of the present invention, a layer having a rare earth element—alkaline earth element—transition metal oxide substantially in a first crystal structure can be provided to a substrate where two or more rare earth cations form the rare earth element. The layer can then be heated at a temperature that is greater than 550° C. under oxidizing conditions to form a high-temperature superconducting layer substantially in a second crystal structure.

摘要翻译： 描述了具有改进性能的超导体线或层或其制造方法。 超导层包括平均堆垛层错密度大于约0.01nm -1的稀土元素 - 碱土金属 - 过渡金属氧化物，其中两种或更多种稀土阳离子形成稀土 元件。 为了形成本发明的超导体层，可以将具有实质上为第一晶体结构的稀土元素 - 碱土金属 - 过渡金属氧化物的层提供给其中两种或更多种稀土阳离子形成稀土元素的基板。 然后可以在氧化条件下，在大于550℃的温度下加热该层，以形成基本上在第二晶体结构中的高温超导层。

公开(公告)号：US20060094603A1

公开(公告)日：2006-05-04

申请号：US11241636

申请日：2005-09-30

申请人： Xiaoping Li ,  Thomas Kodenkandath ,  Edward Siegal ,  Wei Zhang ,  Martin Rupich ,  Yibing Huang

发明人： Xiaoping Li ,  Thomas Kodenkandath ,  Edward Siegal ,  Wei Zhang ,  Martin Rupich ,  Yibing Huang

IPC分类号： H01L39/24

CPC分类号： H01L39/2425 ,  C23C18/1216 ,  C23C18/1225 ,  C23C18/127 ,  H01L39/2483 ,  Y10T29/49014

摘要： A method for producing a thick film includes disposing a precursor solution onto a substrate to form a precursor film. The precursor solution contains precursor components to a rare-earth/alkaline-earth-metal/transition-metal oxide including a salt of a rare earth element, a salt of an alkaline earth metal, and a salt of a transition metal in one or more solvents, wherein at least one of the salts is a fluoride-containing salt, and wherein the ratio of the transition metal to the alkaline earth metal is greater than 1.5. The precursor solution is treated to form a rare earth-alkaline earth-metal transition metal oxide superconductor film having a thickness greater than 0.8 μm. precursor solution.

公开(公告)号：US20070111893A1

公开(公告)日：2007-05-17

申请号：US11494993

申请日：2006-07-28

申请人： Thomas Kodenkandath ,  Wei Zhang ,  Yibing Huang ,  Xiaoping Li ,  Edward Siegal ,  Martin Rupich

发明人： Thomas Kodenkandath ,  Wei Zhang ,  Yibing Huang ,  Xiaoping Li ,  Edward Siegal ,  Martin Rupich

IPC分类号： H01P1/203

CPC分类号： H01L39/143 ,  H01F6/06 ,  H01F41/048 ,  H01P1/203 ,  Y10S505/704 ,  Y10S505/705 ,  Y10T29/49014

摘要： A superconducting wire includes first and second superconducting layers disposed on one or more substrates in stacked relationship, the first superconducting layer comprising a high temperature superconducting oxide of a first composition and the second superconducting layer comprising a high temperature superconducting layer of a second composition, wherein the first and second compositions are different. The first superconductor layer optionally includes a high temperature superconductor composition selected to provide enhanced critical current (Ic(c)) in the presence of magnetic fields perpendicular to surface of the superconducting layer (H//c). The second superconductor layer optionally includes a high temperature superconductor composition selected to provide enhanced critical current (Ic) in the presence of magnetic fields parallel to surface of the superconducting layer (H//ab).

摘要翻译： 超导线包括以堆叠关系设置在一个或多个衬底上的第一和第二超导层，第一超导层包括第一组合物的高温超导氧化物，第二超导层包含第二组合物的高温超导层，其中 第一和第二组合物是不同的。 第一超导体层任选地包括在垂直于超导层（H // c）的表面的磁场的存在下选择用于提供增强的临界电流（Ic（c））的高温超导体组合物。 第二超导体层任选地包括选择用于在平行于超导层的表面的磁场存在下提供增强的临界电流（Ic）的高温超导体组合物（H // ab）。

公开(公告)号：US07261776B2

公开(公告)日：2007-08-28

申请号：US10812676

申请日：2004-03-30

申请人： Martin W. Rupich ,  Urs-Detlev Schoop ,  Darren Verebelyi ,  Thomas Kodenkandath ,  Xiaoping Li

发明人： Martin W. Rupich ,  Urs-Detlev Schoop ,  Darren Verebelyi ,  Thomas Kodenkandath ,  Xiaoping Li

IPC分类号： C30B29/16

CPC分类号： C30B29/16 ,  C30B7/005 ,  C30B29/22 ,  H01L39/2461 ,  Y10S505/929

摘要： A method of making a multilayer article includes depositing a first material on the surface of a metal substrate to form a seed layer of the first material, the first material being deposited under reducing conditions relative to the metal substrate, and then epitaxially depositing a second material on a surface of the seed layer, wherein the second material is deposited from a solution-based precursor under second conditions that are more oxidizing than the reducing conditions used in the deposition of the first material.

摘要翻译： 制造多层制品的方法包括在金属基材的表面上沉积第一材料以形成第一材料的籽晶层，第一材料相对于金属基底在还原条件下沉积，然后外延沉积第二材料 在种子层的表面上，其中第二材料在比在沉积第一材料中使用的还原条件更加氧化的第二条件下从基于溶液的前体沉积。