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    Continuous process for the synthesis of nano-scale precious metal particles
    1.
    发明授权
    Continuous process for the synthesis of nano-scale precious metal particles 失效
    用于合成纳米级贵金属颗粒的连续工艺

    公开(公告)号：US06706902B2

    公开(公告)日：2004-03-16

    申请号：US10074274

    申请日：2002-02-12

    申请人： Martin Stürmann ,  Markus Weisbeck ,  Gerhard Wegener ,  Frank Zbrozek

    发明人： Martin Stürmann ,  Markus Weisbeck ,  Gerhard Wegener ,  Frank Zbrozek

    IPC分类号： B01J2106

    CPC分类号： B01J29/89 ,  B01J23/48 ,  B01J23/52 ,  B01J31/0274 ,  B01J35/006 ,  B01J37/0045 ,  B01J2231/72 ,  C07D301/10

    摘要： The present invention relates to the continuous production of nano-scale precious metal particles on SiH-containing support materials, the compositions themselves, and the use of these precious metal-containing compositions as catalyst. The continuous process according to the invention includes impregnating support materials and, after thermal activation, drying the support materials by spraying or by fluidized bed technology leads to form precious metal-containing support compositions that are active in the catalysis of oxidation reactions. The catalytically active precious metal-containing support compositions exhibit high selectivities and productivities and have very long catalyst service lives without deactivation. The invention also relates to a process for the oxidation of hydrocarbons in the presence of oxygen, a reducing agent and the precious-metal containing support compositions of the present invention.

    摘要翻译： 本发明涉及在含SiH的载体材料上的纳米级贵金属颗粒的连续生产，组合物本身以及这些含贵金属的组合物作为催化剂的用途。 根据本发明的连续方法包括浸渍支撑材料，并且在热活化之后，通过喷雾或通过流化床干燥载体材料技术导致形成对催化氧化反应有活性的贵重金属的载体组合物。 催化活性的含贵金属的载体组合物表现出高的选择性和生产率，并且具有非常长的催化剂使用寿命而不失活。 本发明还涉及在氧气，还原剂和含贵金属的载体组合物存在下氧化烃的方法。

    Catalyst
    3.
    发明申请
    Catalyst 失效
    催化剂

    公开(公告)号：US20080015371A1

    公开(公告)日：2008-01-17

    申请号：US11891800

    申请日：2007-08-13

    申请人： Markus Weisbeck ,  Marie-Therese Heinen ,  Jorg Schmitt ,  Gerhard Wegener ,  Markus Dugal

    发明人： Markus Weisbeck ,  Marie-Therese Heinen ,  Jorg Schmitt ,  Gerhard Wegener ,  Markus Dugal

    IPC分类号： B01J29/06 ,  B01J37/00 ,  C07D301/03

    CPC分类号： B01J29/89 ,  C07D301/12

    摘要： The present invention provides a catalyst containing titanium in bonded form, non-crystalline silicon dioxide and at least one crystalline silicate phase which has a zeolite structure, wherein the non-crystalline silicon dioxide is applied to at least one of the crystalline silicate phases which have a zeolite structure and wherein at least one of the crystalline silicate phases which have a zeolite structure contains silicon-carbon bonds with which non-hydrolytically separable organic groups R are bonded to silicon. Furthermore, the present invention provides a process for preparing this catalyst and a process for producing an epoxide from a compound which contains a carbon-carbon double bond (preferably from propene) comprising reacting the compound which contains a carbon-carbon double bond with hydrogen peroxide in the presence of the catalyst according to the invention.

    摘要翻译： 本发明提供一种催化剂，其含有键合形式的钛，非结晶二氧化硅和至少一种具有沸石结构的结晶硅酸盐相，其中将非结晶二氧化硅施加到至少一个结晶硅酸盐相，其具有 沸石结构，并且其中具有沸石结构的结晶硅酸盐相中的至少一个含有硅 - 碳键，非水解可分离的有机基团R与硅键合。 此外，本发明提供了一种制备该催化剂的方法和由含有碳 - 碳双键（优选丙烯）的化合物制备环氧化物的方法，包括使含有碳 - 碳双键的化合物与过氧化氢 在根据本发明的催化剂的存在下。

    Catalyst
    4.
    发明授权
    Catalyst 失效
    催化剂

    公开(公告)号：US07271116B2

    公开(公告)日：2007-09-18

    申请号：US10842994

    申请日：2004-05-11

    申请人： Markus Weisbeck ,  Marie-Therese Heinen ,  Jörg Schmitt ,  Gerhard Wegener ,  Markus Dugal

    发明人： Markus Weisbeck ,  Marie-Therese Heinen ,  Jörg Schmitt ,  Gerhard Wegener ,  Markus Dugal

    IPC分类号： B01J29/06 ,  B01J29/89

    CPC分类号： B01J29/89 ,  C07D301/12

    摘要： The present invention provides a catalyst containing titanium in bonded form, non-crystalline silicon dioxide and at least one crystalline silicate phase which has a zeolite structure, wherein the non-crystalline silicon dioxide is applied to at least one of the crystalline silicate phases which have a zeolite structure and wherein at least one of the crystalline silicate phases which have a zeolite structure contains silicon-carbon bonds with which non-hydrolytically separable organic groups R are bonded to silicon. Furthermore, the present invention provides a process for preparing this catalyst and a process for producing an epoxide from a compound which contains a carbon-carbon double bond (preferably from propene) comprising reacting the compound which contains a carbon-carbon double bond with hydrogen peroxide in the presence of the catalyst according to the invention.

    摘要翻译： 本发明提供一种催化剂，其含有键合形式的钛，非结晶二氧化硅和至少一种具有沸石结构的结晶硅酸盐相，其中将非结晶二氧化硅施加到至少一个结晶硅酸盐相，其具有 沸石结构，并且其中具有沸石结构的结晶硅酸盐相中的至少一个含有硅 - 碳键，非水解可分离的有机基团R与硅键合。 此外，本发明提供了一种制备该催化剂的方法和由含有碳 - 碳双键（优选丙烯）的化合物制备环氧化物的方法，包括使含有碳 - 碳双键的化合物与过氧化氢 在根据本发明的催化剂的存在下。

    Catalyst
    8.
    发明授权
    Catalyst 失效

    公开(公告)号：US07456303B2

    公开(公告)日：2008-11-25

    申请号：US11891800

    申请日：2007-08-13

    申请人： Markus Weisbeck ,  Marie-Therese Heinen ,  Jorg Schmitt ,  Gerhard Wegener ,  Markus Dugal

    发明人： Markus Weisbeck ,  Marie-Therese Heinen ,  Jorg Schmitt ,  Gerhard Wegener ,  Markus Dugal

    IPC分类号： C07D301/12

    CPC分类号： B01J29/89 ,  C07D301/12

    摘要： The present invention provides a catalyst containing titanium in bonded form, non-crystalline silicon dioxide and at least one crystalline silicate phase which has a zeolite structure, wherein the non-crystalline silicon dioxide is applied to at least one of the crystalline silicate phases which have a zeolite structure and wherein at least one of the crystalline silicate phases which have a zeolite structure contains silicon-carbon bonds with which non-hydrolytically separable organic groups R are bonded to silicon. Furthermore, the present invention provides a process for preparing this catalyst and a process for producing an epoxide from a compound which contains a carbon-carbon double bond (preferably from propene) comprising reacting the compound which contains a carbon-carbon double bond with hydrogen peroxide in the presence of the catalyst according to the invention.

    Integrated method for producing epoxides from olefins
    9.
    发明授权
    Integrated method for producing epoxides from olefins 失效
    从烯烃生产环氧化物的综合方法

    公开(公告)号：US06504040B1

    公开(公告)日：2003-01-07

    申请号：US09857674

    申请日：2001-06-07

    申请人： Peter Vogtel ,  Ernst-Ulrich Dorf ,  Gerhard Wegener ,  Markus Weisbeck

    发明人： Peter Vogtel ,  Ernst-Ulrich Dorf ,  Gerhard Wegener ,  Markus Weisbeck

    IPC分类号： C07D30114

    CPC分类号： C07D301/12 ,  Y02P20/125

    摘要： The invention relates to an integrated process for the preparation of epoxidised olefins. In the first stage, dilute hydrogen peroxide solutions are prepared from the elements hydrogen and oxygen and are reacted in a subsequent liquid-phase epoxidation with olefin in the presence of titanium silicalite to form epoxidised olefins, and the solvents are returned to the H2O2 process again.

    摘要翻译： 本发明涉及制备环氧化烯烃的综合方法。 在第一阶段，稀释的过氧化氢溶液由元素氢和氧制备，并在钛硅沸石存在下与随后的液相环氧化与烯烃反应形成环氧化烯烃，并将溶剂再次回到H 2 O 2过程 。