公开(公告)号：US06566436B1

公开(公告)日：2003-05-20

申请号：US09806863

申请日：2001-04-05

申请人： Norbert Güntherberg ,  Heiner Görrissen ,  Graham Edmund Mc Kee ,  Norbert Niessner ,  Martin Weber

发明人： Norbert Güntherberg ,  Heiner Görrissen ,  Graham Edmund Mc Kee ,  Norbert Niessner ,  Martin Weber

IPC分类号： C08L500

CPC分类号： C08L23/16 ,  C08L25/12 ,  C08L33/02 ,  C08L51/00 ,  C08L69/00 ,  C08L2666/04

摘要： The use of a thermoplastic molding composition which is not ABS, comprising, based on the total of the amounts of components A, B, C, and, where appropriate, D, this total being 100% by weight, a: as component A, from 1 to 48% by weight of at least one particulate emulsion polymer which has one or more phases and has a glass transition temperature below 0° C. in at least one phase, and has a median particle size from 50 to 1000 nm, b: as component B, from 1 to 48% by weight of at least one amorphous or semicrystalline polymer, c: as component C, from 51 to 90% by weight of polycarbonates, and d: as component D, from 0 to 47% by weight of conventional addictives and/or fibrous or particulate fillers, or a mixture of these, for producing moldings, or corresponding semifinished products, for the garden sector or animal-keeping sector.

摘要翻译： 使用不是ABS的热塑性模塑组合物，其包含基于组分A，B，C的总量，并且在合适的情况下，D总计为100重量％，a：作为组分A， 1至48重量％的至少一种具有一个或多个相的至少一种微粒乳液聚合物，并且在至少一个相中具有低于0℃的玻璃化转变温度，并且中值粒度为50-1000nm，b ：作为组分B，1至48重量％的至少一种无定形或半结晶聚合物，c：作为组分C，51至90重量％的聚碳酸酯，和d：作为组分D，0至47重量％ 的常规上瘾剂和/或纤维或颗粒填料，或它们的混合物，用于生产模制品或相应的半成品，用于花园部门或动物饲养部门。

公开(公告)号：US06531543B1

公开(公告)日：2003-03-11

申请号：US09913121

申请日：2001-08-09

申请人： Norbert Güntherberg ,  Martin Weber ,  Gerhard Lindenschmidt ,  Hans Peter Rath

发明人： Norbert Güntherberg ,  Martin Weber ,  Gerhard Lindenschmidt ,  Hans Peter Rath

IPC分类号： C08L5100

CPC分类号： C08L23/08 ,  C08F265/04 ,  C08L23/22 ,  C08L25/14 ,  C08L51/003 ,  C08L51/06 ,  C08L2666/04 ,  C08L2666/24 ,  C08L2666/02

摘要： Thermoplastic molding compositions, comprising (A) from 20 to 99% by weight of at least one graft copolymer, (B) from 1 to 80% by weight of a copolymer obtained from at least one alpha-olefin and from at least one polar comonomer, with the proviso that the monomers used are not vinyl acetate or any vinylaromatic monomer, and (C) from 0 to 80% by weight of a thermoplastic polymer, obtained by polymerizing a monomer mixture, of (c1) from 50 to 100% by weight of at least one vinylaromatic monomer and/or of a C1-C8-alkyl (meth)acrylate, and (c2) 0 to 50% by weight of at least one monofunctional comonomer, and (D) from 0.5 to 30% by weight of a (co)polymer made from (d1) from 50 to 100% by weight of isobutene and (d2) from 0 to 50% by weight of one or more other monomers, process of preparing same and their uses.

摘要翻译： 热塑性模塑组合物，其包含（A）20至99重量％的至少一种接枝共聚物，（B）1至80重量％的由至少一种α-烯烃和至少一种极性共聚单体获得的共聚物 条件是使用的单体不是乙酸乙烯酯或任何乙烯基芳族单体，和（C）0至80重量％的热塑性聚合物，通过聚合单体混合物获得（c1）为50-100％的（c1）为50-100％ 至少一种乙烯基芳族单体和/或（甲基）丙烯酸C 1 -C 8烷基酯和（c 2）0至50重量％的至少一种单官能共聚单体的重量，和（D）0.5至30重量％ 由（d1）制备的（共）聚合物，其为50至100重量％的异丁烯和（d2）0至50重量％的一种或多种其它单体，其制备方法及其用途。

公开(公告)号：US20110178205A1

公开(公告)日：2011-07-21

申请号：US12986718

申请日：2011-01-07

申请人： Martin Weber ,  Marko Blinzler ,  Norbert Güntherberg

发明人： Martin Weber ,  Marko Blinzler ,  Norbert Güntherberg

IPC分类号： C08K5/151

CPC分类号： C08L77/00 ,  C08K5/1539 ,  C08K7/00 ,  C08L25/12 ,  C08L33/20 ,  C08L51/04

摘要： The invention relates to processes for producing thermoplastic molding compositions, where the thermoplastic molding compositions comprise a) as component A, from 3 to 79% by weight of one or more (methyl)styrene-acrylonitrile copolymers, which have no maleic-anhydride-derived units. b) as component B, from 15 to 91% by weight of one or more polyamides, c) as component C, from 5 to 50% by weight of one or more rubbers, d) as component D, from 1 to 25% by weight of one or more compatibilizers, e) as component E, from 0 to 2% by weight of one or more low-molecular-weight compounds which comprise a dicarboxylic anhydride group, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, and g) as component G, from 0 to 40% by weight of further additives, where each of the % by weight values is based on the total weight of components A to G, and these give a total of 100% by weight, via mixing of components A to G in the melt, which comprises producing a melt comprising components A, B, and C in a first step of the process, in the absence of component D, and delaying the mixing to incorporate component D into this melt until a subsequent second step of the process, and also to thermoplastic molding compositions obtainable by these processes, the use of these thermoplastic molding compositions, and also moldings, fibers, and foils comprising these thermoplastic molding compositions.

摘要翻译： 本发明涉及生产热塑性模塑组合物的方法，其中热塑性模塑组合物包含a）作为组分A，3至79重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其不具有马来酸酐衍生物 单位。 b）作为组分B，15至91重量％的一种或多种聚酰胺，c）作为组分C，5至50重量％的一种或多种橡胶，d）作为组分D，1至25重量％ 一种或多种增容剂的重量，e）作为组分E，0至2重量％的一种或多种低分子量化合物，其包含二羧酸酐基团，f）作为组分F，0至50重量％ 的一种或多种纤维或颗粒填料，和g）作为组分G，0至40重量％的另外的添加剂，其中每个重量％的值基于组分A至G的总重量，并且这些给出 总共100重量％，通过混合熔体中的组分A至G，其包括在该方法的第一步中产生包含组分A，B和C的熔体，在不存在组分D的情况下，并延迟 混合以将组分D掺入该熔体中，直到该方法的随后的第二步，以及可通过这些方法获得的热塑性模塑组合物 这些热塑性模塑组合物的使用，以及包含这些热塑性模塑组合物的模制品，纤维和箔。

公开(公告)号：US06235839B1

公开(公告)日：2001-05-22

申请号：US09254917

申请日：1999-03-17

申请人： Norbert Güntherberg ,  Martin Weber ,  Konrad Knoll ,  Gerhard Lindenschmidt

发明人： Norbert Güntherberg ,  Martin Weber ,  Konrad Knoll ,  Gerhard Lindenschmidt

IPC分类号： C08L5100

CPC分类号： C08L51/003 ,  C08F265/04 ,  C08L25/12 ,  C08L53/02 ,  C08L2666/24

摘要： Thermoplastic molding compositions comprising A) a graft polymer comprising 1) an elastomeric graft core, obtainable by copolymerization of one or more C1-C10-alkyl acrylates, and a monomer with crosslinking effect, and 2) a graft shell comprising a styrene compound or a C1-C8-alkyl acrylate or methacrylate, or a mixture of the styrene compound and the C1-C8-alkyl acrylate or methacrylate, and B) a thermoplastic polymer comprising C) an elastomeric block copolymer in which all or virtually all of the olefinic double bonds have been hydrogenated, comprising at least one block A, which forms a hard phase and contains, in its polymer chain, units of a vinylaromatic monomer, and/or a block B, which forms a first elastomeric (soft) phase and contains diene monomers, and at least one elastomeric block B/A, which forms a soft phase, and contains, randomly in its polymer chain, units of both a vinylaromatic monomer and a diene, where the glass transition temperature Tg of the block A is above 25° C. and that of the block B/A is below 25° C. and the phase-volume ratio of block A to block B/A is chosen so that the proportion of the hard phase in the entire block copolymer is from 1 to 40% by volume and the proportion by weight of the diene is less than 50% by weight.

摘要翻译： 包含A）接枝聚合物的热塑性成型组合物，其包含1）通过一种或多种丙烯酸C 1 -C 10烷基酯的共聚获得的弹性体接枝核心和具有交联效应的单体，和2）包含苯乙烯化合物或C 1 -C 8 烷基丙烯酸酯或甲基丙烯酸酯，或苯乙烯化合物和丙烯酸或甲基丙烯酸C 1 -C 8烷基酯的混合物，和B）包含C）弹性体嵌段共聚物的热塑性聚合物，其中所有或几乎所有的烯属双键已被氢化， 包含至少一个嵌段A，其形成硬质相并且在其聚合物链中包含乙烯基芳族单体和/或嵌段B的单元，所述单元形成第一弹性体（软）相并含有二烯单体，并且至少 一个弹性体嵌段B / A，其形成软相，并且在其聚合物链中随机含有乙烯基芳族单体和二烯的单元，其中嵌段A的玻璃化转变温度Tg高于25° 并且块B / A的相体积比低于25℃，并且选择块A与嵌段B / A的相体积比，使得整个嵌段共聚物中硬相的比例为1至40 体积比，二烯重量比小于50重量％。

公开(公告)号：US09212281B2

公开(公告)日：2015-12-15

申请号：US13515894

申请日：2010-12-14

申请人： Martin Weber ,  Christian Maletzko ,  Susanne Zeiher ,  Mark Völkel ,  Norbert Güntherberg ,  Rüdiger Bluhm

发明人： Martin Weber ,  Christian Maletzko ,  Susanne Zeiher ,  Mark Völkel ,  Norbert Güntherberg ,  Rüdiger Bluhm

IPC分类号： C08G18/42 ,  C08F283/00 ,  C08G65/48 ,  C08L81/06

CPC分类号： C08L81/06 ,  C08G2650/40 ,  C08L2205/02 ,  C08L81/02 ,  C08L71/00

摘要： The present invention relates to thermoplastic molding materials comprising the following components: (A) at least one polyarylene ether, (B) at least one polyarylene sulfide, (C) optionally at least one functionalized polyarylene ether comprising carboxyl groups, (D) at least one fibrous or particulate filler and (E) optionally further additives and/or processing assistants, the ratio of the apparent viscosity of the component (A) to that of the component (B), determined at 350° C. and a shear rate of 1150 s−1, being from 2.5 to 3.7.

摘要翻译： 本发明涉及包含以下组分的热塑性模塑材料：（A）至少一种聚亚芳基醚，（B）至少一种聚芳硫醚，（C）任选至少一种包含羧基的官能化聚亚芳基醚，（D）至少 一种纤维或颗粒填料和（E）任选的其它添加剂和/或加工助剂，组分（A）与组分（B）的表观粘度的比例在350℃下测定，剪切速率 1150 s-1，从2.5到3.7。

公开(公告)号：US08648143B2

公开(公告)日：2014-02-11

申请号：US13547830

申请日：2012-07-12

申请人： Martin Weber ,  Marko Blinzler ,  Norbert Güntherberg

发明人： Martin Weber ,  Marko Blinzler ,  Norbert Güntherberg

IPC分类号： C08G81/02 ,  C08L67/02 ,  C09B67/00

CPC分类号： C08L77/00 ,  C08K5/1539 ,  C08K7/00 ,  C08L25/12 ,  C08L33/20 ,  C08L51/04

摘要： Processes for producing thermoplastic molding compositions, which comprise a) from 3 to 79% by weight of one or more (methyl)styrene-acrylonitrile copolymers, which have no maleic-anhydride-derived units, b) from 15 to 91% by weight of one or more polyamides, c) from 5 to 50% by weight of one or more rubbers, d) from 1 to 25% by weight of one or more compatibilizers, e) from 0 to 2% by weight of one or more low-molecular-weight compounds which comprise a dicarboxylic anhydride group, f) from 0 to 50% by weight of one or more fibrous or particulate fillers, and g) from 0 to 40% by weight of further additives, by producing a melt comprising components A, B, and C in a first step and subsequently incorporating D, Also, thermoplastic molding compositions obtainable by these processes, the use of these thermoplastic molding compositions, and moldings, fibers, and foils comprising these thermoplastic molding compositions.

摘要翻译： 制备热塑性模塑组合物的方法，其包含a）3至79重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其不具有马来酸酐衍生的单元，b）15至91重量％ 一种或多种聚酰胺，c）5至50重量％的一种或多种橡胶，d）1至25重量％的一种或多种相容剂，e）0至2重量％的一种或多种低聚物， 包含二羧酸酐基团的分子量化合物，f）0至50重量％的一种或多种纤维或颗粒填料，和g）0至40重量％的其它添加剂，通过制备包含组分A ，B和C，并且随后掺入D。此外，可通过这些方法获得的热塑性模塑组合物，这些热塑性模塑组合物的使用以及包含这些热塑性模塑组合物的模制品，纤维和箔。

公开(公告)号：US20110218294A1

公开(公告)日：2011-09-08

申请号：US13040593

申请日：2011-03-04

申请人： Martin Weber ,  Christian Maletzko ,  Susanne Zeiher ,  Mark Völkel ,  Norbert Güntherberg ,  Rüdiger Bluhm

发明人： Martin Weber ,  Christian Maletzko ,  Susanne Zeiher ,  Mark Völkel ,  Norbert Güntherberg ,  Rüdiger Bluhm

IPC分类号： C08L81/04

CPC分类号： C08L81/04

摘要： The present invention relates to thermoplastic molding compositions comprising the following components: (A) at least one polyarylene ether (A1) having an average of at most 0.1 phenolic end group per polymer chain and at least one polyarylene ether (A2) having an average of at least 1.5 phenolic end groups per polymer chain, (B) at least one polyarylene sulfide, (C) at least one functionalized polyarylene ether comprising carboxy groups, (D) at least one fibrous or particulate filler, and (E) optionally further additives and/or processing aids. The present invention further relates to a process for producing the thermoplastic molding compositions of the invention, to the use of these for producing moldings, fibers, foams, or films, and to the resultant moldings, fibers, foams, and films.

摘要翻译： 本发明涉及包含以下组分的热塑性模塑组合物：（A）每个聚合物链平均具有至多0.1个酚端基的至少一个聚亚芳基醚（A1）和至少一个具有平均值的聚亚芳基醚（A2） 每个聚合物链具有至少1.5个酚类端基，（B）至少一种聚芳硫醚，（C）至少一种包含羧基的官能化聚亚芳基醚，（D）至少一种纤维或颗粒填料，和（E）任选的其它添加剂 和/或加工助剂。 本发明还涉及本发明的热塑性模塑组合物的制造方法，其用于制造模制品，纤维，泡沫或薄膜以及所得模制品，纤维，泡沫和薄膜。

公开(公告)号：US20130023619A1

公开(公告)日：2013-01-24

申请号：US13547830

申请日：2012-07-12

申请人： Martin Weber ,  Marko Blinzler ,  Norbert Güntherberg

发明人： Martin Weber ,  Marko Blinzler ,  Norbert Güntherberg

IPC分类号： C08L77/00 ,  C08L21/00 ,  C08L33/20

CPC分类号： C08L77/00 ,  C08K5/1539 ,  C08K7/00 ,  C08L25/12 ,  C08L33/20 ,  C08L51/04

摘要： Processes for producing thermoplastic molding compositions, which comprise a) from 3 to 79% by weight of one or more (methyl)styrene-acrylonitrile copolymers, which have no maleic-anhydride-derived units, b) from 15 to 91% by weight of one or more polyamides, c) from 5 to 50% by weight of one or more rubbers, d) from 1 to 25% by weight of one or more compatibilizers, e) from 0 to 2% by weight of one or more low-molecular-weight compounds which comprise a dicarboxylic anhydride group, f) from 0 to 50% by weight of one or more fibrous or particulate fillers, and g) from 0 to 40% by weight of further additives, by producing a melt comprising components A, B, and C in a first step and subsequently incorporating D, Also, thermoplastic molding compositions obtainable by these processes, the use of these thermoplastic molding compositions, and moldings, fibers, and foils comprising these thermoplastic molding compositions.

摘要翻译： 制备热塑性模塑组合物的方法，其包含a）3至79重量％的一种或多种（甲基）苯乙烯 - 丙烯腈共聚物，其不具有马来酸酐衍生的单元，b）15至91重量％ 一种或多种聚酰胺，c）5至50重量％的一种或多种橡胶，d）1至25重量％的一种或多种相容剂，e）0至2重量％的一种或多种低聚物， 包含二羧酸酐基团的分子量化合物，f）0至50重量％的一种或多种纤维或颗粒填料，和g）0至40重量％的其它添加剂，通过制备包含组分A ，B和C，并且随后掺入D。此外，可通过这些方法获得的热塑性模塑组合物，这些热塑性模塑组合物的使用以及包含这些热塑性模塑组合物的模制品，纤维和箔。

公开(公告)号：US20110237693A1

公开(公告)日：2011-09-29

申请号：US13053872

申请日：2011-03-22

申请人： Martin Weber ,  Christian Maletzko ,  Susanne Zeiher ,  Mark Völkel ,  Norbert Güntherberg ,  Rüdiger Bluhm ,  Bernd Bruchmann

发明人： Martin Weber ,  Christian Maletzko ,  Susanne Zeiher ,  Mark Völkel ,  Norbert Güntherberg ,  Rüdiger Bluhm ,  Bernd Bruchmann

IPC分类号： C08L81/06 ,  C08L69/00 ,  C08K7/14 ,  C08L81/04

CPC分类号： C08J5/18 ,  C08G2650/32 ,  C08G2650/40 ,  C08J9/0085 ,  C08J2371/12 ,  C08J2381/06 ,  C08L71/00 ,  C08L71/12 ,  C08L81/02 ,  C08L2205/03 ,  C08L67/00 ,  C08L69/00

摘要： The present invention relates to thermoplastic molding compositions comprising the following components: (A1) at least one polyarylene ether having an average of at most 0.5 phenolic end groups per polymer chain, (A2) optionally at least one polyarylene ether having an average of at least 1.5 phenolic end groups per polymer chain, (B) at least one polyarylene sulfide, (C) at least one hyperbranched polymer selected from hyperbranched polycarbonates and hyperbranched polyesters, (D) optionally at least one functionalized polyarylene ether comprising carboxy groups, (E) optionally at least one fibrous or particulate filler, and (F) optionally further additives and/or processing aids. The present invention further relates to a process for producing the thermoplastic molding compositions of the invention, to the use of these for producing moldings, fibers, foams, or films, and to the resultant moldings, fibers, foams, and films.

摘要翻译： 本发明涉及包含以下组分的热塑性模塑组合物：（A1）每个聚合物链平均具有至多0.5个酚端基的至少一个聚亚芳基醚，（A2）任选至少一种平均至少一个的聚亚芳基醚 （B）至少一种聚亚芳基硫醚，（C）至少一种选自超支化聚碳酸酯和超支化聚酯的超支化聚合物，（D）任选至少一种包含羧基的官能化聚芳醚，（E） 任选地至少一种纤维或颗粒填料，和（F）任选的其它添加剂和/或加工助剂。 本发明还涉及本发明的热塑性模塑组合物的制造方法，其用于制造模制品，纤维，泡沫或薄膜以及所得模制品，纤维，泡沫和薄膜。

公开(公告)号：US07728073B2

公开(公告)日：2010-06-01

申请号：US10596344

申请日：2004-12-14

申请人： Martin Stork ,  Martin Weber ,  Axel Gottschalk ,  Sven Riechers ,  Norbert Güntherberg ,  Wolfgang Fischer ,  Ludger Leber ,  Peter Ittemann ,  Stephan Jüngling

发明人： Martin Stork ,  Martin Weber ,  Axel Gottschalk ,  Sven Riechers ,  Norbert Güntherberg ,  Wolfgang Fischer ,  Ludger Leber ,  Peter Ittemann ,  Stephan Jüngling

IPC分类号： C08L51/00 ,  C08L51/04 ,  C08L51/06

CPC分类号： C08L51/04 ,  C08F257/02 ,  C08F279/02 ,  C08F285/00 ,  C08L25/12 ,  C08L33/12 ,  C08L35/06 ,  C08L51/00 ,  C08L51/003 ,  C08L55/02 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/04

摘要： The present invention relates to thermoplastic molding compositions comprising a mixture of (A) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a methyl methacrylate polymer, (B) from 30 to 69% by weight, based on the sum of components (A), (B) and (C), of a copolymer obtainable by polymerizing a styrenic monomer and a vinyl cyanide, and (C) from 1 to 40% by weight, based on the sum of components (A), (B) and (C), of a graft copolymer obtainable from (C1) from 60 to 90% by weight, based on (C), of a core obtainable by polymerizing a 1,3-diene and a styrenic monomer, (C2) from 5 to 20% by weight, based on (C), of a first graft shell, and (C3) from 5 to 20% by weight, based on (C), of a second graft shell composed of an alkyl (meth)acrylate polymer, with the proviso that the ratio of (C2) to (C3) is in the range from 2:1 to 1:2.

摘要翻译： 本发明涉及热塑性模塑组合物，其包含（A）基于甲基丙烯酸甲酯聚合物的组分（A），（B）和（C）的总和为30至69重量％的混合物，（B） 基于通过聚合苯乙烯类单体和乙烯基氰获得的共聚物的组分（A），（B）和（C）的总和的30至69重量％，和（C）1至40重量％ 以（C）为基准，从（C）得到的（C）成分（A），（B）和（C））的总和为基于（C）为60〜90重量％ 1,3-二烯和苯乙烯单体，（C）基于（C）的5-20重量％（C），第一接枝壳和（C）5-20重量％的（C3） ，由（甲基）丙烯酸烷基酯聚合物组成的第二接枝壳，条件是（C2）与（C3）的比例在2:1至1:2的范围内。