公开(公告)号：US06538159B2

公开(公告)日：2003-03-25

申请号：US09872576

申请日：2001-06-01

申请人： Martin Zeller ,  André Jeanguenat ,  Clemens Lamberth

发明人： Martin Zeller ,  André Jeanguenat ,  Clemens Lamberth

IPC分类号： A61K3116

CPC分类号： A01N41/06 ,  C07C307/06 ,  C07C311/06 ,  C07C311/07 ,  C07C311/11

摘要： The invention relates to &agr;-sulfin- and &agr;-sulfonamino acid amides of the general formula I including the optical isomers thereof and mixtures of such isomers, wherein n is a number zero or one; R1 is C1-C12alkyl, C1-C12alkyl substituted with C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylsulfonyl, C3-C8cycloalkyl, cyano, C1-C6alkoxycarbonyl, C3-C6alkenyloxycarbonyl or C3-C6alkenyloxycarbonyl; C3-C8cycloalkyl; C2-C12alkenyl; C2-C12alkynyl; C1-C12haloalkyl; or a group NR12R13 wherein R12 and R13 are each independently of the other hydrogen or C1-C6-alkyl, or together are tetra- or penta-methylene; R2 and R3 are each independently hydrogen; C1-C8alkyl; C1-C8alkyl substituted with hydroxy, mercapto, C1-C4alkoxy or C1-C4alkylthio; C3-C8alkenyl; C3-C8alkynyl; C3-C8cycloalkyl; C3-C8cycloalkyl-C1-C4alkyl; or the two groups R2 and R3 together with the carbon atom to which they are bonded form a three- to eight-membered hydrocarbon ring; R4, R5, R6 and R7 are each independently hydrogen or C1-C4alkyl; R8 is C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl; R9, R10, R14, R15, R16 and R17 are each independently hydrogen or C1-C4alkyl; A is optionally substituted phenyl, and to the preparation of those substances and to agrochemical compositions comprising at least one of those compounds as active ingredient. The invention relates also to the preparation of the said compositions and to the use of the compounds or of the compositions in controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.

摘要翻译： 本发明涉及包含其光学异构体的通式I的α-亚磺酸和α-磺氨基酰胺和这些异构体的混合物，其中n是数个零或一个; R 1是C 1 -C 12烷基，被C 1 -C 12取代的C 1 -C 12烷基， C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基磺酰基，C 3 -C 8环烷基，氰基，C 1 -C 6烷氧基羰基，C 3 -C 6烯氧基羰基或C 3 -C 6烯氧基羰基; C 3 -C 8环烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 1 -C 12卤代烷基; 或NR 12 R 13基团，其中R 12和R 13各自独立地为氢或C 1 -C 6 - 烷基，或一起为四或五亚甲基; R 2和R 3各自独立地为氢; C1-C8烷基; 被羟基，巯基，C 1 -C 4烷氧基或C 1 -C 4烷硫基取代的C 1 -C 8烷基; C3-C8链烯基; C3-C8炔基; C 3 -C 8环烷基; C 3 -C 8环烷基-C 1 -C 4烷基; 或两个R 2和R 3与它们所键合的碳原子一起形成三至八元烃环; R 4，R 5，R 6和R 7各自独立地为氢或C 1 -C 4烷基; R 8为C 1 -C 6烷基， C 3 -C 6烯基或C 3 -C 6炔基; R 9，R 10，R 14，R 15，R 16和R 17各自独立地为氢或C 1 -C 4烷基; A为任选取代的苯基，并且为这些物质的制备以及包含至少一种 化合物作为活性成分。 本发明还涉及所述组合物的制备以及化合物或组合物在控制或预防植物病原微生物特别是真菌侵染植物中的用途。

公开(公告)号：US06538016B2

公开(公告)日：2003-03-25

申请号：US09872577

申请日：2001-06-01

申请人： Martin Zeller ,  André Jeanguenat ,  Clemens Lamberth

发明人： Martin Zeller ,  André Jeanguenat ,  Clemens Lamberth

IPC分类号： A61K3116

CPC分类号： C07C323/12 ,  C07C307/06 ,  C07C311/06

摘要： The invention relates to &agr;-sulfin- and &agr;-sulfonamino acid amides of the general formula I including the optical isomers thereof and mixtures of such isomers, wherein n is a number zero or one; R1 is C1-C12alkyl, C1-C12alkyl substituted with C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylsulfonyl, C3-C8cycloalkyl, cyano, C1-C6alkoxycarbonyl, C3-C6alkenyloxycarbonyl or C3-C6alkynyloxycarbonyl; C3-C8cycloalkyl; C2-C12alkenyl; C2-C12alkynyl; C1-C12haloalkyl; or a group NR12R13 wherein R12 and R13 are each independently of the other hydrogen or C1-C6-alkyl, or together are tetra- or penta-methylene; R2 and R3 are each independently hydrogen; C1-C8alkyl; C1-C8alkyl substituted with hydroxy, mercapto, C1-C4alkoxy or C1-C4alkylthio; C3-C8alkenyl; C3-C8alkynyl; C3-C8cycloalkyl; C3-C8cycloalkyl-C1-C4alkyl; or the two groups R2 and R3 together with the carbon atom to which they are bonded form a three- to eight-membered hydrocarbon ring; R4, R5, R6 and R7 are each independently hydrogen or C1-C4alkyl; R8 is C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl; R9 and R10 are each independently hydrogen or C1-C4alkyl; and R11 is either  in wherein R14, R,15, R16 and R17 are each independently hydrogen or C1-C4alkyl, X is oxygen, sulfur or —NR18—, wherein R18 is hydrogen or C1-C4alkyl, and A is optionally substituted mono- or polycylic aryl or heteroaryl, and to the preparation of those substances and to agrochemical compositions comprising at least one of those compounds as active ingredient. The invention relates also to the preparation of compositions and to the use of the compounds or of the compositions in controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi.

摘要翻译： 本发明涉及包含其光学异构体的通式I的α-亚磺酸和α-磺氨基酰胺和这些异构体的混合物，其中n是数个零或一个; R 1是C 1 -C 12烷基，被C 1 -C 12取代的C 1 -C 12烷基， C4烷氧基，C1-C4烷硫基，C1-C4烷基磺酰基，C3-C8环烷基，氰基，C1-C6烷氧基羰基，C3-C6烯氧基羰基或C3-C6炔氧基羰基; C 3 -C 8环烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 1 -C 12卤代烷基; 或NR 12 R 13基团，其中R 12和R 13各自独立地为氢或C 1 -C 6 - 烷基，或一起为四或五亚甲基; R 2和R 3各自独立地为氢; C1-C8烷基; 被羟基，巯基，C 1 -C 4烷氧基或C 1 -C 4烷硫基取代的C 1 -C 8烷基; C3-C8链烯基; C3-C8炔基; C 3 -C 8环烷基; C 3 -C 8环烷基-C 1 -C 4烷基; 或两个R 2和R 3与它们所键合的碳原子一起形成三至八元烃环; R 4，R 5，R 6和R 7各自独立地为氢或C 1 -C 4烷基; R 8为C 1 -C 6烷基， C 3 -C 6烯基或C 3 -C 6炔基; R 9和R 10各自独立地为氢或C 1 -C 4烷基; 并且R 11在其中R 14，R 15，R 16和R 17各自独立地为氢或C 1 -C 4烷基，X为氧，硫或-NR 18 - ，其中R 18为氢或C 1 -C 4烷基，A为任选取代的单或多环芳基 或杂芳基，以及这些物质的制备以及包含这些化合物中的至少一种作为活性成分的农药组合物。 本发明还涉及组合物的制备以及化合物或组合物在通过植物病原微生物特别是真菌控制或预防植物感染中的用途。

公开(公告)号：US06469005B1

公开(公告)日：2002-10-22

申请号：US09903651

申请日：2001-07-11

申请人： Martin Zeller ,  André Jeanguenat ,  Clemens Lamberth ,  Walter Kunz

发明人： Martin Zeller ,  André Jeanguenat ,  Clemens Lamberth ,  Walter Kunz

IPC分类号： A01N4358

CPC分类号： A01N43/40 ,  A01N37/36 ,  A01N37/38 ,  A01N37/42 ,  A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/28 ,  A01N43/30 ,  A01N43/32 ,  A01N43/54 ,  A01N47/12 ,  C07C235/34 ,  C07C235/80 ,  C07C251/40 ,  C07C271/22 ,  C07C323/62

摘要： Propargylether derivatives of formula I including the optical isomers thereof and mixtures of such isomers, wherein R1 is hydrogen, alkyl, cycloalkyl or optionally substituted aryl, R2 and R3 are each independently hydrogen or alkyl, R4 is alkyl, alkenyl or alkynyl, R5, R6, R7, and R8 are each independently hydrogen or alkyl and R9 is a group R10 is optionally substituted aryl or optionally substituted heteroaryl, R11 is hydrogen or optionally substituted alkyl, alkenyl or alkynyl, Z is hydrogen —CO—R16, —COOR16, —CO—COOR16 or —CONR16R17, R12 is hydrogen, or optionally substituted alkyl, alkenyl or alkynyl, R13 is hydrogen or alkyl, R14 is hydrogen, alkyl, cycloalkyl or cycloalkyl-alkyl, R15 is alkyl, alkenyl, alkynyl, optionally substituted aryl or optionally substituted aryl-alkyl, and R16 and R17 are independently of each other hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted aryl or optionally substituted heteroaryl, have been found to be useful for controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi. The invention relates the novel compounds and also to the preparation thereof and to the use of the compounds for plant protection, and to compositions suitable for applying the novel compounds in agricultural techniques.

摘要翻译： 式I的丙酰醚衍生物包括其光学异构体和这些异构体的混合物，其中R 1是氢，烷基，环烷基或任选取代的芳基，R 2和R 3各自独立地是氢或烷基，R 4是烷基，烯基或炔基，R 5，R 6，R 7 ，和R 8各自独立地为氢或烷基，R 9为基团R 10为任选取代的芳基或任选取代的杂芳基，R 11为氢或任选取代的烷基，烯基或炔基，Z为氢-CO-R 16，-COOR 16，-CO-COOR 16或 -CONR 16 R 17，R 12是氢或任选取代的烷基，烯基或炔基，R 13是氢或烷基，R 14是氢，烷基，环烷基或环烷基 - 烷基，R 15是烷基，烯基，炔基，任选取代的芳基或任选取代的芳基 - 烷基，R16和R17彼此独立地为氢，任选取代的烷基，任选取代的环烷基，任选取代的芳基或任选取代的杂芳基，已被发现是有用的 用于控制或防止由植物病原微生物，特别是真菌侵染植物。本发明涉及新化合物以及其制备方法以及本发明化合物用于植物保护的用途，以及适用于农业技术中的新型化合物的组合物 。

公开(公告)号：US06391918B1

公开(公告)日：2002-05-21

申请号：US09623160

申请日：2000-08-25

申请人： André Jeanguenat ,  Martin Zeller

发明人： André Jeanguenat ,  Martin Zeller

IPC分类号： A61K3116

CPC分类号： A01N41/02 ,  A01N41/06 ,  C07C237/08 ,  C07C307/06 ,  C07C311/06 ,  C07C323/63 ,  C07C2603/18 ,  C07D307/54 ,  C07D333/24 ,  C07D333/28

摘要： Novel &agr;-amino acid amides of formula (I) as well as possible isomers and mixtures of isomers thereof, wherein the substituents are defined as follows: n is the number zero or one; R1 is optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl; or a group NRaRb wherein Ra and Rb are each independently of the other hydrogen, alkyl or form together an alkylene bridge; R2 is hydrogen or alkyl; R3 is optionally substituted aryl or heteroaryl; A is alkylene; and B is optionally substituted aryl; with the exception of the following compounds 2-phenyl-N-(1-phenyl-ethyl)-2-(4-methylphenyl)-sulfonylamino-acetamide, 2-phenyl-N-(1-phenyl-ethyl)-2-(4-chlorophenyl)-sulfonylamino-acetamide, 2-phenyl-N-(1-phenyl-ethyl)-2-(4-nitrolphenyl)-sulfonylamino-acetamide, 2-phenyl-N-(1-phenyl-ethyl)-2-(4-methoxyphenyl)-sulfonylamino-acetamide, 2-phenyl-N-(1-phenyl-ethyl)-2-(4-fluorophenyl)-sulfonylamino-acetamide, 2-phenyl-N-(1-phenyl-ethyl)-2-phenyl-sulfonylamino-acetamide and 2-phenyl-N-(1-phenyl-ethyl)-2-methane-sulfonylamino-acetamide. The novel compounds have plant-protective properties and are suitable for protecting plants against infestations by phytopathogenic microorganisms, in particular fungi.

摘要翻译： 式（I）的新型α-氨基酸酰胺以及可能的异构体及其异构体的混合物，其中取代基定义如下：n为0或1; R 1是任选取代的烷基，烯基，炔基，环烷基，环烷基烷基，芳基或芳基烷基; 或NRaRb基团，其中Ra和Rb各自独立地为氢，烷基或一起形成亚烷基桥; R2是氢或烷基; R3是任选取代的芳基或杂芳基; A是亚烷基; 和B是任选取代的芳基; 除了下列化合物之外，2-苯基-N-（1-苯基 - 乙基）-2-（4-甲基苯基） - 磺酰基氨基 - 乙酰胺，2-苯基-N-（1-苯基 - 乙基）-2-（ 4-氯苯基） - 磺酰基氨基 - 乙酰胺，2-苯基-N-（1-苯基 - 乙基）-2-（4-硝基苯基） - 磺酰基氨基 - 乙酰胺，2-苯基-N-（1-苯基 - 乙基）-2 - （4-甲氧基苯基） - 磺酰基氨基 - 乙酰胺，2-苯基-N-（1-苯基 - 乙基）-2-（4-氟苯基） - 磺酰基氨基 - 乙酰胺，2-苯基-N-（1-苯基 - 乙基） -2-苯基 - 磺酰基氨基 - 乙酰胺和2-苯基-N-（1-苯基 - 乙基）-2-甲磺酰基氨基 - 乙酰胺。 新化合物具有植物保护性质，并且适用于通过植物病原微生物特别是真菌来保护植物免受侵袭。

公开(公告)号：US06479550B1

公开(公告)日：2002-11-12

申请号：US09906374

申请日：2001-07-16

申请人： André Jeanguenat ,  Martin Zeller ,  Hugo Ziegler

发明人： André Jeanguenat ,  Martin Zeller ,  Hugo Ziegler

IPC分类号： A61K3116

CPC分类号： C07C313/20 ,  A01N37/50 ,  A01N41/00 ,  A01N41/04 ,  A01N41/06 ,  A01N41/12 ,  A01N43/10 ,  A01N43/30 ,  A01N47/34

摘要： &agr;-Sulfenimino acid derivatives of formula I including the optical isomers thereof and mixtures of such isomers, wherein A is cycloalkyl, cycloalkenyl, aryl or heteroaryl, each optionally substituted, B is a direct bond or optionally substituted alkylene, E is hydrogen or optionally substituted aryl, R is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl, each optionally substituted, and T is NH or oxygen, have been found to be useful for controlling or preventing the infestation of plants by phytopathogenic microorganisms, especially fungi. The invention relates the novel compounds and also to the preparation thereof and to the use of the compounds for plant protection, and to compositions suitable for applying the novel compounds in agricultural techniques.

摘要翻译： 式I的亚磺酰亚氨基酸衍生物包括其旋光异构体和这些异构体的混合物，其中A是环烷基，环烯基，芳基或杂芳基，各自任意取代，B是直接键或任选取代的亚烷基，E是氢或任选取代的芳基， 已经发现R是氢，烷基，烯基，炔基，环烷基，环烷基烷基，芳基或芳基烷基，各自任选被取代，并且T是NH或氧，可用于通过植物病原微生物，特别是真菌来控制或防止植物侵染。 本发明涉及新化合物以及其制备方法以及该化合物用于植物保护的用途，以及适于在农业技术中施用新化合物的组合物。

公开(公告)号：US06482859B1

公开(公告)日：2002-11-19

申请号：US09485280

申请日：2000-02-04

申请人： Martin Zeller ,  André Jeanguenat

发明人： Martin Zeller ,  André Jeanguenat

IPC分类号： A61K3118

CPC分类号： C07C311/06 ,  A01N41/06 ,  A01N43/10 ,  C07C217/60 ,  C07C237/08 ,  C07C307/06 ,  C07C311/11 ,  C07C313/06 ,  C07C2601/14 ,  C07D333/16

摘要： The invention relates to novel pesticidally active compounds of the general formula I as well as possible isomers and mixtures of isomers thereof, wherein n is a number zero or one; and R1 is C1-C12alkyl that is unsubstituted or may be substituted by C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylsulfonyl, C3-C8cycloalkyl, cyano, C1C6alkoxycarbonyl, C3-C6alkenyloxycarbonyl or by C3-C6alkynyloxycarbonyl; C3-C8cycloalkyl; C2-C12alkenyl; C2-C12alkynyl; C1-C12haloalkyl: or a group NR11R12 wherein R11 and R12 are each independently of the other hydrogen or C1-C8alkyl, or together are tetra- or penta-methylene; R2 and R3 are each independently of the other hydrogen; C1-C8alkyl; C1-C8alkyl substituted by hydroxy, C1-C4alkoxy, mercapto or by C1-C4alkylthio; C3-C8alkenyl; C3-C8alkynyl; C3-C8cycloalkyl; C3-C8cycloalkyl-C1-C4alkyl; or the two groups R2 and R3 together with the carbon atom to which they are bonded form a three- to eight-membered ring; R4, R5, R6 and R7 are identical or different and are each independently of the others hydrogen or C1-C4alkyl; R8 is C1-C6alkyl, C3-C6alkenyl or C3-C6alkynyl; A is C1-C6alkylene; and B is optionally mono- or poly-nuclear, unsubstituted or substituted aryl; optionally mono- or poly-nuclear, unsubstituted or substituted heteroaryl; C4-C12alkyl; or C3-C8cycloalkyl. The novel compounds have plant-protecting properties and are suitable for protecting plants against infestation by phytopathogenic microorganisms.

摘要翻译： 本发明涉及具有通式的新的杀虫活性化合物，以及可能的异构体及其异构体的混合物，其中n为数个零或一; 并且R 1是未被取代或可以被C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基磺酰基，C 3 -C 8环烷基，氰基，C 1 -C 6烷氧基羰基，C 3 -C 6炔氧基羰基或C 3 -C 6炔氧基羰基取代的C 1 -C 12烷基; C 3 -C 8环烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 1 -C 12卤代烷基或NR 11 R 12基团，其中R 11和R 12各自独立地为氢或C 1 -C 8烷基，或一起为四或五亚甲基; R 2和R 3各自独立地为氢; C1-C8烷基; 由羟基，C 1 -C 4烷氧基，巯基或被C 1 -C 4烷硫基取代的C 1 -C 8烷基; C3-C8链烯基; C3-C8炔基; C 3 -C 8环烷基; C 3 -C 8环烷基-C 1 -C 4烷基; 或两个R 2和R 3与它们所键合的碳原子一起形成三至八元环; R 4，R 5，R 6和R 7相同或不同，各自独立地为氢或C 1 -C 4烷基 ; R 8为C 1 -C 6烷基，C 3 -C 6烯基或C 3 -C 6炔基; A为C 1 -C 6亚烷基; 和B是任选的单核或多核，未取代或取代的芳基; 任选的单核或多核，未取代或取代的杂芳基; C4-C12烷基; 或C3-C8环烷基。新化合物具有植物保护性质，并且适合于保护植物免受植物病原微生物侵扰。

公开(公告)号：US08658801B2

公开(公告)日：2014-02-25

申请号：US12278807

申请日：2007-02-14

申请人： Olivier Loiseleur ,  Patricia Durieux ,  Stephan Trah ,  Andrew Edmunds ,  André Jeanguenat ,  André Stoller ,  David John Hughes

发明人： Olivier Loiseleur ,  Patricia Durieux ,  Stephan Trah ,  Andrew Edmunds ,  André Jeanguenat ,  André Stoller ,  David John Hughes

IPC分类号： C07D401/14

CPC分类号： C07D401/14 ,  A01N43/56 ,  A01N43/60 ,  A01N43/78 ,  A01N43/82 ,  A01N43/86 ,  C07D409/14 ,  C07D413/14 ,  C07D417/14

摘要： Compounds of formula (I), wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts and all stereoisomers and tautomeric forms of the compounds of formula I can be used as agrochemical active ingredients and can be prepared in a manner known per se.

摘要翻译： 式（I）的化合物，其中取代基如权利要求1中所定义，以及式I化合物的农业化学上可接受的盐和所有立体异构体和互变异构形式可用作农业化学活性成分，并且可以以已知的方式制备 se。

公开(公告)号：US20120077991A1

公开(公告)日：2012-03-29

申请号：US13314564

申请日：2011-12-08

申请人： Michel Muehlebach ,  André Jeanguenat ,  Roger Graham Hall

发明人： Michel Muehlebach ,  André Jeanguenat ,  Roger Graham Hall

IPC分类号： C07D331/04

CPC分类号： A01N43/56 ,  C07D331/04 ,  C07D401/12 ,  C07D401/14 ,  C07D403/12 ,  C07D403/14 ,  C07D405/12 ,  C07D405/14 ,  C07D409/12 ,  C07D409/14 ,  C07F9/65681

摘要： Compounds of formula wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts and all stereoisomers and tautomeric forms of the compounds of formula I can be used as agrochemical active ingredients and can be prepared in a manner known per se.

摘要翻译： 式的化合物，其中取代基如权利要求1所定义，并且式I化合物的农业化学上可接受的盐和所有立体异构体和互变异构形式可用作农业化学活性成分，并且可以以本身已知的方式制备。

公开(公告)号：US06723720B2

公开(公告)日：2004-04-20

申请号：US10006954

申请日：2001-11-05

申请人： Arthur Steiger ,  Werner Zambach ,  André Jeanguenat ,  Martin Eberle ,  Stephan Trah ,  Saleem Farooq

发明人： Arthur Steiger ,  Werner Zambach ,  André Jeanguenat ,  Martin Eberle ,  Stephan Trah ,  Saleem Farooq

IPC分类号： C07D253065

CPC分类号： A01N57/22 ,  A01N43/707 ,  C07D253/07

摘要： A compound of formula wherein R1 is unsubstituted or substituted aryl or heteroaryl, the substituents of the aryl and heteroaryl rings being selected, for example, from the group consisting of OH, halogen, CN, NO2, C1-C6alkyl, C3-C8cycloalkyl, C1-C6alkyl-C3-C8cycloalkyl, C3-C8cycloalkyl-C1-C6alkyl, C1-C6haloalkyl, C3-C8halocycloalkyl, C1-C6alkoxy and phenyl; phenoxy; phenylthio; phenylamino; and phenyl-(C1-C6alkyl)-amino; the substituents of the phenoxy, phenylthio, phenylamino and phenyl-(C1-C6alkyl)-amino groups being selected from the group consisting of halogen, CN, NO2, C1-C6alkyl, C3-C8cycloalkyl, C1-C6haloalkyl, C3-C8halocycloalkyl, C1-C6alkoxy, C3-C8cycloalkoxy, C1-C6alkylthio, C3-C8cycloalkylthio, C1-C6haloalkylthio and C3-C8halocycloalkylthio; R2 is, for example, H, OH, halogen, CN, NO2, C1-C6alkyl or C1-C6alkoxy; A is, for example, a single bond, C1-C12alkylene, O or O(C1-C12alkylene); R4 is H, C1-C6alkyl, C3-C8cycloalkyl, C1-C6haloalkyl, C1-C6alkoxy, N(R5)2 or C1-C6alkoxy-C2-C6alkyl; R5 is H, C1-C6alkyl, C3-C8cycloalkyl, C1-C6haloalkyl or aryl-C1-C6alkyl; X1 is R10; X2 and X3 are each independently of the other H or R10; R10 is, for example, halogen, CN, NO2, C1-C6alkyl or C3-C8cycloalkyl; and n is 0, 1 or 2, and to their physiologically tolerable and agrochemically acceptable addition compounds, and where appropriate to E/Z isomers, to mixtures of E/Z isomers and/or to tautomers, in each case in free form or in salt form. The compounds, in free form or in agrochemically acceptable salt form, exhibit advantageous pesticidal properties. They are suitable especially in the control of pests in agriculture and stored goods and also in the keeping of domestic animals.

摘要翻译： 化合物R1是未取代或取代的芳基或杂芳基，芳基和杂芳基环的取代基选自例如由OH，卤素，CN，NO 2，C 1 -C 6烷基，C 3 -C 8环烷基，C 1 -C 6烷基 - C 3 -C 8环烷基，C 3 -C 8环烷基-C 1 -C 6烷基，C 1 -C 6卤代烷基，C 3 -C 8卤代环烷基，C 1 -C 6烷氧基和苯基; 苯氧基 苯硫基 苯基氨基; 苯基 - （C 1 -C 6烷基） - 氨基;苯氧基，苯硫基，苯基氨基和苯基 - （C 1 -C 6烷基） - 氨基的取代基选自卤素，CN，NO 2，C 1 -C 6烷基， C 3 -C 8卤代烷基，C 1 -C 6卤代烷基，C 3 -C 8卤代环烷基，C 1 -C 6烷氧基，C 3 -C 8环烷氧基，C 1 -C 6烷硫基，C 3 -C 8环烷硫基，C 1 -C 6卤代烷硫基和C 3 -C 8卤代环烷硫基; R 2为例如H，OH，卤素，CN， C1-C6烷基或C1-C6烷氧基; A是例如单键，C1-C12亚烷基，O或O（C1-C12亚烷基）; R4是H，C1-C6烷基，C3-C8环烷基，C1-C6卤代烷基，C1-C6烷氧基 ，N（R 5）2或C 1 -C 6烷氧基-C 2 -C 6烷基; R 5是H，C 1 -C 6烷基，C 3 -C 8环烷基，C 1 -C 6卤代烷基或芳基-C 1 -C 6烷基; X 1是R 10; X 2和X 3各自独立地为H或R 10; R 10为例如卤素，CN，NO 2，C 1 -C 6烷基或C 3 -C 8环烷基; 和n为0,1或2，以及其生理上可耐受和农业化学上可接受的加成化合物，以及适用于E / Z异构体的E / Z异构体和/或互变异构体的混合物，在每种情况下为游离形式或 游离形式或农业化学上可接受的盐形式的化合物表现出有利的杀虫性质。 它们特别适用于控制农业和储存物中的害虫以及保存家畜。

公开(公告)号：US06686469B2

公开(公告)日：2004-02-03

申请号：US10011012

申请日：2001-11-05

申请人： Martin Eberle ,  André Jeanguenat ,  Werner Zambach ,  Arthur Steiger ,  Saleem Farooq

发明人： Martin Eberle ,  André Jeanguenat ,  Werner Zambach ,  Arthur Steiger ,  Saleem Farooq

IPC分类号： C07D2412

CPC分类号： C07D239/26 ,  A01N43/54 ,  C07D239/28 ,  C07D239/34 ,  C07D239/36 ,  C07D239/42 ,  C07D239/54

摘要： The invention relates to compounds of the general formula wherein R1 is unsubstituted or mono- to penta-substituted aryl, whereby the substituents are selected from the group consisting for instance of OH, Halogen, CN, C1-C6-alkyl, optionally substituted C3-C8-cycloalkyl and optionally substituted C3-C8-cycloalkenyl; A is for instance a single bond, C1-C12-alkylene or O; X1 and X2, independently of one another, are R10; X3 is H or R10; R10 is for instance halogen, CN, NO2, C1-C6-alkyl, C3-C8-cycloalkyl or C1-C6-haloalkyl; R21 and R22, independently of one another are for instance H, halogen, CN, NO2, OH, SH, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-alkyl-C3-C8-cycloalkyl or C3-C8-cycloalkyl-C1-C6-alkyl; R23 and R24, independently of one another, are for instance H, C1-C6-alkyl, C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C6-alkyl, C1-C6-haloalkyl or C3-C8-halocycloalkyl; m is 1, 2, 3 or 4; and n is 0, 1 or 2; as well as the physiologically acceptable addition compounds, a method of producing these compounds and the usage of these compounds, pesticide compositions whose active ingredient is chosen from these compounds, each in free form or in agrochemically employable salt form, and a method of producing and using these compositions. The active ingredients, in free form or in agrochemically employable salt form, have advantageous pesticidal properties. The are especially suitable for the control of pests in agriculture and in storage, as well as in the care of domestic animals.

摘要翻译： 本发明涉及通式为化学式R 1的化合物是未取代的或一至五取代的芳基，其中取代基选自例如OH，卤素，CN，C 1 -C 6 - 烷基，任选取代的C 3 -C 8 - 环烷基和任选取代的C 3 -C 8 - 环烯基; A为例如单键，C 1 -C 12 - 亚烷基或O; X 1和X 2彼此独立地为R 10; X3为H或R10; R10为卤素，CN，NO2，C1-C6-烷基，C3-C8-环烷基或C1-C6-卤代烷基; R21和R22彼此独立地为例如H，卤素，CN ，NO 2，OH，SH，C 1 -C 6烷基，C 3 -C 8 - 环烷基，C 1 -C 6烷基-C 3 -C 8 - 环烷基或C 3 -C 8环烷基-C 1 -C 6烷基; R 23和R 24独立地为 另一个例子是H，C 1 -C 6烷基，C 3 -C 8环烷基，C 3 -C 8环烷基-C 1 -C 6烷基，C 1 -C 6卤代烷基或C 3 -C 8卤代环烷基; m是1,2,3 或4; 和n为0,1或2;以及生理上可接受的加成化合物，这些化合物的制备方法和这些化合物的用途，其活性成分选自这些化合物的农药组合物，各自为游离形式或农业化学可使用的盐 形式，以及生产和使用这些组合物的方法。 活性成分，游离形式或具有农业化学应用的盐形式，具有有利的杀虫特性。 特别适用于农业，仓储以及家畜照顾中的害虫控制。