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公开(公告)号：US5424379A
公开(公告)日：1995-06-13
申请号：US229311
申请日：1994-05-16
IPC分类号： C08F4/64 , C08F4/649 , C08F136/06
CPC分类号： C08F136/06
摘要： A catalyst for production of 1,4-polybutadiene which comprisesas the catalyst component (A) a transition metal compound represented by the formula M(R).sub.l (OR').sub.m X.sub.n-(l+m), wherein M denotes a transition metal atom, R and R' each denote a hydrocarbon group of 1-20 carbon atoms, X denotes a halogen atom, and l, m and n denote numerals satisfying the equations l.gtoreq.0, m.gtoreq.0 and n-(l+m).gtoreq.0, n corresponding to the valence of the transition metal,as the catalyst component (B) an organoaluminum compound represented by the formula AlR.sup.1.sub.a X'.sub.3-a, wherein R.sup.1 denotes a hydrocarbon group of 1-20 carbon atoms, X denotes a halogen atom, and a denotes a numeral satisfying the equation 1.gtoreq.a.gtoreq.3, or an aluminoxane obtained by the reaction of said organoaluminum compound with water, andas the catalyst component (C) an organic compound having at least two hydroxyl groups.
摘要翻译： 一种用于生产1,4-聚丁二烯的催化剂，其包含作为催化剂组分（A）由式M（R）l（OR'）m Xn-（1 + m）表示的过渡金属化合物，其中M表示过渡金属 金属原子，R和R'各自表示1-20个碳原子的烃基，X表示卤素原子，l，m和n表示满足式l> / = 0，m> / = 0和n- （I + m）> / = 0，对应于过渡金属的化合价的n，作为催化剂组分（B）由式AlR1aX'3-a表示的有机铝化合物，其中R1表示1-20的烃基 碳原子，X表示卤素原子，a表示满足式1的化合物或通过所述有机铝化合物与水反应得到的铝氧烷，作为催化剂成分（C）， 具有至少两个羟基的有机化合物。
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公开(公告)号：US5349034A
公开(公告)日：1994-09-20
申请号：US95050
申请日：1993-07-22
IPC分类号： C08F4/64 , C08F4/649 , C08F136/06
CPC分类号： C08F136/06
摘要： A catalyst for production of 1,4-polybutadiene which comprisesas the catalyst component (A) a transition metal compound represented by the formula M(R)l(OR')m X.sub.n-(l+m), wherein M denotes a transition metal atom, R and R' each denote a hydrocarbon group of 1-20 carbon atoms, X denotes a halogen atom, and l, m and n denote numerals satisfying the equations l.gtoreq.0, m.gtoreq.0 and n-(l+m).gtoreq.0, n corresponding to the valence of the transition metal,as the catalyst component (B) an organoaluminum compound represented by the formula AlR.sup.1.sub.a X'.sub.3-a, wherein R.sup.1 denotes a hydrocarbon group of 1-20 carbon atoms, X denotes a halogen atom, and a denotes a numeral satisfying the equation 1.ltoreq.a.ltoreq.3, or an aluminoxane obtained by the reaction of said organoaluminum compound with water, andas the catalyst component (C) an organic compound having at least two hydroxyl groups.
摘要翻译： 一种用于生产1,4-聚丁二烯的催化剂，其包含作为催化剂组分（A）由式M（R）l（OR'）m Xn-（1 + m）表示的过渡金属化合物，其中M表示过渡金属 金属原子，R和R'各自表示1-20个碳原子的烃基，X表示卤素原子，l，m和n表示满足式l> / = 0，m> / = 0和n- （I + m）> / = 0，对应于过渡金属的化合价的n，作为催化剂组分（B）由式AlR1aX'3-a表示的有机铝化合物，其中R1表示1-20的烃基 碳原子，X表示卤素原子，a表示满足式1的数字，或通过所述有机铝化合物与水反应而得到的铝氧烷，作为催化剂成分（C）， 具有至少两个羟基的有机化合物。
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3.发明授权Ethylene-aromatic vinyl compound alternating copolymer and process for the production thereof 失效乙烯 - 芳族乙烯基化合物交替共聚物及其制备方法
公开(公告)号：US5043408A
公开(公告)日：1991-08-27
申请号：US538713
申请日：1990-06-15
申请人： Masahiro Kakugo , Tatsuya Miyatake , Koozi Mizunuma , Yoshio Yagi
发明人： Masahiro Kakugo , Tatsuya Miyatake , Koozi Mizunuma , Yoshio Yagi
IPC分类号： C08F4/609 , C08F210/02 , C08F212/04
CPC分类号： C08F212/04 , C08F210/02
摘要： Alternating copolymers having a high alternating degree and high isotacticity, which can be produced by copolymerizing ethylene and an aromatic vinyl monomer in the presence, as a catalyst, of a transition metal compound, aluminoxane and a specific organic compound having at least two hydroxyl groups.
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4.发明授权Catalyst for olefin polymerization and process for producing olefin polymer using the catalyst 失效用于烯烃聚合的催化剂和使用催化剂生产烯烃聚合物的方法
公开(公告)号：US5280000A
公开(公告)日：1994-01-18
申请号：US746157
申请日：1991-08-14
CPC分类号： C08F10/00 , Y10S526/943
摘要： The present invention relates to a novel catalyst used for homopolymerization of an olefin of 2 or more carbon atoms or for copolymerization of two or more olefins of 2 or more carbon atoms, as well as to a process for producing an olefin polymer using said catalyst. High molecular olefin polymers can be produced at a high yield, by homopolymerizing an olefin or copolymerizing olefins using a catalyst system consisting of a transition metal compound of the general formula M(R).sub.l (OR').sub.m X.sub.n-(l+m) and an aluminoxane or a catalyst system comprising a transition metal compound of the general formula M(R).sub.l (OR').sub.m X.sub.n-(l+m), an aluminoxane and an organic compound having at least 2 hydroxyl groups.
摘要翻译： PCT No.PCT / JP86 / 00515 Sec。 371日期1987年5月29日 102（e）日期1987年5月29日PCT提交1986年10月9日PCT公布。 出版物WO87 / 02370 日本1987年4月23日。本发明涉及用于2个以上碳原子的烯烃的均聚或2个以上碳原子数2以上的烯烃的共聚合的新型催化剂，以及制造方法 使用所述催化剂的烯烃聚合物。 高分子量烯烃聚合物可以通过使用由通式M（R）1（OR'）m Xn-（1 + m）的过渡金属化合物和 包含通式M（R）l（OR'）m Xn-（1 + m）的过渡金属化合物，铝氧烷和具有至少2个羟基的有机化合物的铝氧烷或催化剂体系。
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公开(公告)号：US4769284A
公开(公告)日：1988-09-06
申请号：US854803
申请日：1986-04-23
IPC分类号： C08L23/00 , B32B27/32 , C08L7/00 , C08L21/00 , C08L23/14 , C08L23/16 , C08L101/00 , B32B27/00
CPC分类号： B32B27/32 , Y10T428/2826 , Y10T428/31913
摘要： A polypropylene multi-layer film which comprises a substrate layer formed of crystalline polypropylene and a composition laminated on at least one side of said substrate layer, said composition comprising 70 to 95% by weight of (A) a crystalline propylene-ethylene copolymer having an ethylene content of 1.5 to 6.0% by weight and/or a crystalline propylene-.alpha.-olefin copolymer having a propylene content of 80 to 98% by weight, a butene-1 content of 2 to 20% by weight, and an ethylene content of 0 to 5% by weight, and 5 to 30% by weight of (B) a crystalline propylene-butene-1 copolymer which is a copolymer obtained by decomposing a crystalline propylene-butene-1 copolymer having a butene-1 content of 25 to 45% by weight, an intrinsic viscosity of 2.5 dl/g or more as determined in tetralin at 135.degree. C., and a proportion of 35% by weight or more of a polymer component soluble in xylene at 20.degree. C., and containing 1.5% by weight or less of a polymer component having a molecular weight calculated in terms of polystyrene of 10,000 or less as determined by GPC.
摘要翻译： 一种聚丙烯多层膜，其包含由结晶聚丙烯形成的基材层和层压在所述基材层的至少一侧上的组合物，所述组合物包含70-95重量％的（A）结晶丙烯 - 乙烯共聚物，其具有 乙烯含量为1.5〜6.0重量％，和/或丙烯含量为80〜98重量％，丁烯-1含量为2〜20重量％的结晶性丙烯-α-烯烃共聚物，乙烯含量为 0至5重量％，和5至30重量％的（B）结晶丙烯 - 丁烯-1共聚物，其是通过将丁烯-1含量为25的结晶丙烯 - 丁烯-1共聚物分解得到的共聚物， 45重量％，在135℃下在四氢化萘中测定的特性粘度为2.5dl / g以上，在20℃下可溶于二甲苯的聚合物成分的比例为35重量％以上， 1.5重量％以下的具有分子量的聚合物组分 以GPC测定的聚苯乙烯换算为10,000以下。
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公开(公告)号：US5147942A
公开(公告)日：1992-09-15
申请号：US476687
申请日：1990-02-08
申请人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Takeshi Sanada , Masahiro Kakugo
发明人： Hiroomi Abe , Taichi Nishio , Yasurou Suzuki , Takeshi Sanada , Masahiro Kakugo
IPC分类号： C08L51/00 , C08G65/48 , C08L51/06 , C08L53/00 , C08L67/00 , C08L71/00 , C08L71/12 , C08L75/00 , C08L77/00 , C08L81/00 , C08L101/00
CPC分类号： C08L71/12 , C08G65/485 , C08L77/00 , C08L67/00 , C08L71/00 , C08L75/00 , C08L81/00 , Y10S525/905
摘要： Disclosed is a thermoplastic resin composition improved in low-temperature impact resistance and processability which comprises:(A) 5-95% by weight of a polyamide resin which has a relative viscosity of 3.1-4.5 and has a ratio .alpha. of terminal amino group to terminal carboxyl group of 0
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公开(公告)号：US4603174A
公开(公告)日：1986-07-29
申请号：US686865
申请日：1984-12-27
申请人： Tadayuki Okada , Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
发明人： Tadayuki Okada , Masahiro Kakugo , Yoshiharu Fukui , Kizuku Wakatsuki , Seiichiro Ima , Junichi Kimura
IPC分类号： B29C55/00 , B29C55/02 , B29K23/00 , B29L7/00 , C08J5/18 , C08L23/12 , C08L23/14 , C08L23/20 , C08L23/04
CPC分类号： C08J5/18 , C08L23/12 , C08L23/142 , C08J2323/10 , C08L23/20 , C08L2314/02 , Y10S428/91 , Y10T428/31913
摘要： A stretched polypropylene film having excellent see-through characteristics, which is prepared by stretching in at least one direction a polypropylene resin sheet containing 0.05 ppm to 10,000 ppm by weight of a 3-position branched .alpha.-olefin unit and/or a vinyl cycloalkane unit, each having at least 6 carbon atoms.
摘要翻译： 一种拉伸聚丙烯薄膜，具有优异的透视特性，其通过至少一个方向拉伸含有0.05ppm至10,000ppm重量的3-位支链α-烯烃单元和/或乙烯基环烷烃单元的聚丙烯树脂板 各自具有至少6个碳原子。
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公开(公告)号：US4414373A
公开(公告)日：1983-11-08
申请号：US399146
申请日：1982-07-16
申请人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
发明人： Akinobu Shiga , Kiyoshi Matsuyama , Masahiro Kakugo , Yukio Naito , Seiichiro Ima , Katsuyoshi Yamashita
IPC分类号： C08F4/00 , C08F2/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/06 , C08F210/00 , C08F210/06 , C08F210/16
CPC分类号： C08F210/06
摘要： In a process for producing polypropylene comprising polymerizing propylene in the presence of hydrogen and a catalyst system comprising (A) titanium trichloride obtained by reducing titanium tetrachloride with an organoaluminum compound and reacting the reduced solid with an ether represented by the formula:R.sup.1 --O--R.sup.2wherein R.sup.1 and R.sup.2 are defined hereinbefore, and a halogen compound selected from the group consisting of (i) halogen or interhalogen compounds of the formula, X.sup.1 X.sup.2.sub.a (wherein X.sup.1, X.sup.2 and a are defined hereinbefore), (ii) titanium halides, and (iii) organic halogen compounds, simultaneously or successively and (B) an organoaluminum compound, the improvement which comprises supplying ethylene together with propylene to the polymerization system such that the ethylene concentration in the vapor phase of the system based on the total amount of propylene, ethylene and hydrogen in the vapor phase of the system is 0.15 to 1.5 mol % to obtain a propylene-ethylene copolymer having an ethylene content of from 0.1 to 1.0 wt % is disclosed. The propylene-ethylene copolymer is improved in stretchability.
摘要翻译： 在制备聚丙烯的方法中，包括在氢气存在下聚合丙烯和催化剂体系，所述催化剂体系包含（A）通过用有机铝化合物还原四氯化钛获得的三氯化钛，并将还原的固体与由下式表示的醚反应：R1-O- 其中R 1和R 2如上定义，卤素化合物选自（ⅰ）卤素或下式的卤代化合物：X1X2a（其中X1，X2和a定义如前），（ⅱ）卤化钛和 （iii）有机卤素化合物，同时或相继和（B）有机铝化合物，其改进包括将乙烯与丙烯一起供应到聚合体系中，使得基于丙烯总量的体系的气相中的乙烯浓度 ，系统的气相中的乙烯和氢为0.15〜1.5摩尔％，得到丙烯 - 乙烯共聚物 公开了乙烯含量为0.1〜1.0重量％。 丙烯 - 乙烯共聚物的拉伸性提高。
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公开(公告)号：US4254237A
公开(公告)日：1981-03-03
申请号：US30523
申请日：1979-04-16
IPC分类号： C08F297/00 , C08F297/08
CPC分类号： C08F297/086
摘要： A process for producing propylene-ethylene block copolymers by a three-step polymerization technique using a stereoregular catalyst, characterized in that the first-step polymerization is carried out by supplying propylene alone or a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 6/94 or less, thereby polymerizing 60 to 95% by weight of the total polymerization amount, the second-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 15/85 to 79/21, thereby polymerizing 1 to 20% by weight of the total polymerization amount, and the third-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 50/50 to 89/11, thereby polymerizing 4 to 35% by weight of the total polymerization amount, with the ethylene/propylene reaction ratio in the third step made larger than that in the second step. Said process can give propylene-ethylene block copolymers markedly well balanced in impact strength, stiffness, transparency and impact blushing.
摘要翻译： 一种通过使用立体规则催化剂的三步聚合技术制备丙烯 - 乙烯嵌段共聚物的方法，其特征在于第一步聚合是通过仅供应丙烯或丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比 为6/94以下，由此聚合60〜95重量％的总聚合量，第二步聚合是通过供给丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比为15/85〜79 / 21，由此聚合1至20重量％的总聚合量，第三步聚合通过供应丙烯/乙烯混合物进行，使得乙烯/丙烯反应比为50/50至89/11， 从而聚合4〜35重量％的总聚合量，第3步骤中的乙烯/丙烯反应比例大于第2步骤。 所述方法可以使丙烯 - 乙烯嵌段共聚物在冲击强度，刚度，透明度和冲击冲刷中显着地平衡。
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公开(公告)号：US4696979A
公开(公告)日：1987-09-29
申请号：US686864
申请日：1984-12-27
摘要： A process for producing a propylene copolymer having improved transparency and rigidity, which comprises carrying out (A) the polymerization of a vinyl cycloalkane having at least 6 carbon atoms and (B) the polymerization of propylene either alone or with ethylene in a multiplicity of steps in the presence of a catalyst system composed of a titanium compound and an organoaluminum compound. The content of the vinyl cycloalkane unit in the resulting copolymer is 0.05 to 10,000 weight ppm.
摘要翻译： 一种制备具有改善的透明度和刚性的丙烯共聚物的方法，其包括进行（A）聚合具有至少6个碳原子的乙烯基环烷烃和（B）单独或与乙烯在多个步骤中聚合丙烯 在由钛化合物和有机铝化合物组成的催化剂体系的存在下。 所得共聚物中乙烯基环烷烃单元的含量为0.05至10,000重量ppm。
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