公开(公告)号：US08367210B2

公开(公告)日：2013-02-05

申请号：US10533655

申请日：2003-11-07

申请人： Masanori Naritomi ,  Naoki Ando ,  Masao Takahashi

发明人： Masanori Naritomi ,  Naoki Ando ,  Masao Takahashi

IPC分类号： B32B7/04 ,  B32B15/04 ,  C23C22/56

CPC分类号： B32B15/08 ,  B29C45/14311 ,  B29C45/14778 ,  B29K2081/04 ,  B29K2705/00 ,  B29K2705/02 ,  B32B15/20 ,  B32B27/28 ,  B32B2398/20 ,  C23F1/20 ,  C23F1/36 ,  Y10T428/31536 ,  Y10T428/31678 ,  Y10T428/31681

摘要： The invention provides the advantages of a metallic housing and those of a synthetic resin structure for electronic devices, home electrical devices, etc., achieves high productivity and mass productivity, and enables a desired configuration and structure to be designed freely. As a pretreatment, a shaped aluminum alloy material is dipped in an aqueous solution of at least one selected from the group consisting of ammonia, hydrazine, and a water-soluble amine compound. A thermoplastic resin composition containing polyphenylene sulfide as a component is integrally bonded to the surface of the treated shaped aluminum alloy material by injection molding or other method. The molded article is a product made of the shaped aluminum alloy material and the thermoplastic resin composition containing PPS. Thus, the characteristic features of metal can be utilized in terms of mechanical strength and external appearance design. Moreover, a complicated configuration and structure can be formed inside the housing.

摘要翻译： 本发明提供金属壳体和电子装置，家用电器等的合成树脂结构的优点，实现了高生产率和批量生产率，并且能够自由地设计所需的构造和结构。 作为预处理，将成形的铝合金材料浸渍在选自氨，肼和水溶性胺化合物中的至少一种的水溶液中。 含有聚苯硫醚作为成分的热塑性树脂组合物通过注射成型或其它方法与处理成型的铝合金材料的表面一体地结合。 模制品是由成形铝合金材料和含有PPS的热塑性树脂组合物制成的产品。 因此，可以在机械强度和外观设计方面利用金属的特征。 此外，可以在壳体内形成复杂的构造和结构。

公开(公告)号：US20100159196A1

公开(公告)日：2010-06-24

申请号：US12594919

申请日：2008-04-04

申请人： Masanori Naritomi ,  Naoki Ando

发明人： Masanori Naritomi ,  Naoki Ando

IPC分类号： B32B3/00 ,  C23F1/00

CPC分类号： B32B37/02 ,  B29C70/088 ,  B29K2705/10 ,  B29K2995/0072 ,  B32B3/18 ,  B32B7/12 ,  B32B15/14 ,  B32B15/20 ,  B32B27/04 ,  B32B27/06 ,  B32B27/32 ,  B32B27/322 ,  B32B2255/06 ,  B32B2255/26 ,  B32B2260/021 ,  B32B2260/046 ,  B32B2262/0269 ,  B32B2262/101 ,  B32B2262/106 ,  B32B2264/101 ,  B32B2264/102 ,  B32B2264/104 ,  B32B2307/302 ,  B32B2307/714 ,  B32B2457/00 ,  B32B2535/00 ,  B32B2605/00 ,  B32B2605/12 ,  B32B2605/18 ,  C23F1/18 ,  Y10T428/24355 ,  Y10T428/24997 ,  Y10T428/31678

摘要： An integrated product whose joint strength between a copper alloy and a carbon fiber prepreg is extremely high. A copper alloy given a certain special surface shape yields tremendous bonding strength through compatibility with an epoxy resin adhesive. With a composite part in which this technology is utilized to integrate a copper alloy member as a cover material with a CFRP, it is possible to take advantage of the characteristics of both the copper alloy and the FRP due to the tremendous bonding strength. In a step in which an FRP prepreg is put into a mold and heated and cured, usually the mold is first coated with a release agent to facilitate release from the mold, but with high-technology CFRP, bleeding of the release agent often diminishes the properties. A copper alloy sheet 21 is used as a cover material, and a CFRP 22 is cured.

摘要翻译： 铜合金与碳纤维预浸料坯的接合强度极高的一体化产品。 赋予一定特殊表面形状的铜合金通过与环氧树脂粘合剂的相容性而产生极大的粘结强度。 利用该技术用于将铜合金构件作为覆盖材料与CFRP进行集成的复合部件，由于具有巨大的接合强度，可以利用铜合金和FRP两者的特性。 在将FRP预浸料放入模具并加热固化的步骤中，通常首先用脱模剂涂覆模具以便于从模具中脱模，但是使用高技术的CFRP，脱模剂的渗出通常会减少 属性。 铜合金板21用作覆盖材料，CFRP22固化。

公开(公告)号：US20060257624A1

公开(公告)日：2006-11-16

申请号：US10534228

申请日：2003-11-07

申请人： Masanori Naritomi ,  Naoki Ando

发明人： Masanori Naritomi ,  Naoki Ando

IPC分类号： B32B15/20 ,  B32B15/08 ,  B32B15/09 ,  B29C45/14

CPC分类号： B32B15/08 ,  B29C45/14311 ,  B29C45/14778 ,  B29C2045/14286 ,  B29C2045/14868 ,  B29K2081/04 ,  B29K2705/00 ,  B29K2705/02 ,  B32B3/30 ,  B32B15/09 ,  B32B15/20 ,  B32B27/36 ,  B32B2367/00 ,  Y10T428/24355 ,  Y10T428/31678 ,  Y10T428/31681

摘要： A composite characterized by comprising an aluminum alloy shaped item having a surface roughness of 5 to 50 μm or more, the surface provided with 1 μm or less fine depressions or protrusions, and a thermoplastic resin composition composed mainly of a polyphenylene sulfide or polybutylene terephthalate resin whose average of lengthwise and crosswise linear expansion coefficients is in the range of 2 to 4×10−5° C.−1, the thermoplastic resin composition penetrating and anchored in the depressions or protrusions. The thermoplastic resin composition is not easily detached from the aluminum alloy shaped item. Thus, in, for example, electronic equipments and household electrical appliances, the advantage of metallic cage body can be reconciled with the advantage of synthetic resin structure. This composite can ensure high production efficiency and is suitable for mass production. Further, morphology and structure designing thereof can be accomplished freely.

摘要翻译： 一种复合材料，其特征在于，其特征在于，具有表面粗糙度为5〜50μm以上的铝合金成形品，所述表面设置有1μm以下的微细凹凸或突起，以及主要由聚苯硫醚或聚对苯二甲酸丁二醇酯树脂构成的热塑性树脂组合物 其纵向和横向线膨胀系数的平均值在2至4×10 -5℃的范围内，热塑性树脂组合物穿透并锚定在凹陷或 突起 热塑性树脂组合物不容易从铝合金成形品中分离。 因此，在例如电子设备和家用电器中，金属笼体的优点可以与合成树脂结构的优点相协调。 该复合材料可以保证生产效率高，适合批量生产。 此外，其形态和结构设计可以自由地实现。

公开(公告)号：US10350857B2

公开(公告)日：2019-07-16

申请号：US12595774

申请日：2008-04-11

申请人： Masanori Naritomi ,  Naoki Ando

发明人： Masanori Naritomi ,  Naoki Ando

IPC分类号： B32B15/08 ,  B32B15/14 ,  B32B27/38 ,  C09J163/00 ,  B32B5/14 ,  B32B15/092 ,  B32B15/06 ,  B32B27/20 ,  B32B27/28 ,  B32B27/32

摘要： An object of the present invention is to create, from a titanium alloy and an FRP prepreg, a composite of a titanium alloy and an FRP material that is suitable for bolt fastening. The composite can bring out excellent characteristics in CFRP members in mobile electronic-electric devices, mobile equipment, medical instruments, marine devices and the like. It has been found that titanium alloy having a special constant surface shape adheres strongly with an epoxy adhesive. In a composite obtained using this technique to integrate a titanium alloy member as a cover material and a CFRP material, the metal alloy portion deforms and disperses locally strong forces so that the CFRP material is not damaged, even when the composite is assembled to another metal member through bolt-fastening. As a result, the composite is expected to be effective for applications in mobile equipment or mobile device casings, where lightweightness, corrosion resistance, toughness and ease of assembly are required.

公开(公告)号：US20100189958A1

公开(公告)日：2010-07-29

申请号：US12669143

申请日：2008-07-17

申请人： Masanori Naritomi ,  Naoki Ando

发明人： Masanori Naritomi ,  Naoki Ando

IPC分类号： B32B3/06 ,  C23F1/00

CPC分类号： B29C45/14311 ,  B29C45/14778 ,  B29C2045/14868 ,  B29K2705/00 ,  B29K2705/02 ,  Y10T428/24355

摘要： A metal and resin composite in which a metal and a resin, especially a shaped base made of an ordinary steel material and a resin composition can be strongly joined to and integrated with each other; and a method for producing the composite.The surface of a shaped ordinary steel material is treated by chemical etching or the like to form a thin layer of a natural oxide of iron, substantially completely covered with ultra-fine irregularities, onto which hydrazine, ammonia or a water-soluble amine is chemically adsorbed. The resulting ferrous material shaped article 1 is inserted into an injection mold 10 and a specific resin composition 4 is injected thereinto. The surface of the ferrous material formed-article 1 may have a thin layer of a metal oxide or metal phosphate. The above injection yields a composite 7 in which an ordinary steel material is strongly joined to a resin. The resin composition 4 that is used contains a crystalline polyphenylene sulfide resin (PPS) or polybutylene terephthalate resin (PBT) as the main resin component.

摘要翻译： 金属和树脂复合物，其中金属和树脂，特别是由普通钢材和树脂组合物制成的成形基底可以牢固地接合并相互结合; 以及该复合体的制造方法。 通过化学蚀刻等处理成形的普通钢材的表面以形成基本上完全覆盖有超微细凹凸的铁的天然氧化物的薄层，其中肼，氨或水溶性胺是化学上 吸附。 将所得到的铁质材料成型品1插入注射模具10中，向其中注入特定的树脂组合物4。 形成物品1的铁质材料的表面可以具有金属氧化物或金属磷酸盐的薄层。 上述注射产生复合材料7，其中普通钢材与树脂强烈接合。 使用的树脂组合物4含有结晶性聚苯硫醚树脂（PPS）或聚对苯二甲酸丁二醇酯树脂（PBT）作为主要树脂成分。

公开(公告)号：US20100151200A1

公开(公告)日：2010-06-17

申请号：US12595774

申请日：2008-04-11

申请人： Masanori Naritomi ,  Naoki Ando

发明人： Masanori Naritomi ,  Naoki Ando

IPC分类号： B32B3/00 ,  C23F1/00

CPC分类号： B32B15/08 ,  B32B5/147 ,  B32B15/06 ,  B32B15/092 ,  B32B15/14 ,  B32B27/20 ,  B32B27/285 ,  B32B27/286 ,  B32B27/32 ,  B32B27/38 ,  B32B2262/0269 ,  B32B2262/101 ,  B32B2262/106 ,  B32B2264/101 ,  B32B2264/102 ,  B32B2264/104 ,  B32B2307/714 ,  C09J163/00 ,  Y10T428/24355 ,  Y10T428/24405

摘要： An object of the present invention is to create, from a titanium alloy and an FRP prepreg, a composite of a titanium alloy and an FRP material that is suitable for bolt fastening. The composite can bring out excellent characteristics in CFRP members in mobile electronic-electric devices, mobile equipment, medical instruments, marine devices and the like. It has been found that titanium alloy having a special constant surface shape adheres strongly with an epoxy adhesive. In a composite obtained using this technique to integrate a titanium alloy member as a cover material and a CFRP material, the metal alloy portion deforms and disperses locally strong forces so that the CFRP material is not damaged, even when the composite is assembled to another metal member through bolt-fastening. As a result, the composite is expected to be effective for applications in mobile equipment or mobile device casings, where lightweightness, corrosion resistance, toughness and ease of assembly are required.

摘要翻译： 本发明的目的是从钛合金和FRP预浸料制备适合于螺栓紧固的钛合金和FRP材料的复合材料。 复合材料可以在移动电子电气设备，移动设备，医疗仪器，船舶设备等中的CFRP构件中产生优异的特性。 已经发现，具有特殊恒定表面形状的钛合金与环氧粘合剂强烈粘合。 在使用这种技术来获得的用于将钛合金构件作为覆盖材料和CFRP材料进行集成的复合材料中，金属合金部分变形和分散局部强力，使得CFRP材料不被损坏，即使当复合材料组装到另一种金属 会员通过螺栓紧固。 结果，复合材料预期对于需要轻量化，耐腐蚀性，韧性和易于组装的移动设备或移动设备外壳中的应用是有效的。

公开(公告)号：US07640646B2

公开(公告)日：2010-01-05

申请号：US12010472

申请日：2008-01-25

申请人： Masanori Naritomi ,  Naoki Ando ,  Masao Takahashi ,  Masao Shiraishi

发明人： Masanori Naritomi ,  Naoki Ando ,  Masao Takahashi ,  Masao Shiraishi

IPC分类号： B23P25/00

CPC分类号： B29C45/14311 ,  B29C45/14336 ,  B29C45/14778 ,  B29C2045/14868 ,  B29K2067/006 ,  B29K2705/00 ,  B29K2705/02 ,  B29L2031/3437 ,  Y10T29/49885 ,  Y10T29/4998 ,  Y10T29/49982 ,  Y10T29/49986 ,  Y10T428/12007

摘要： The present invention is useful for achieving a reduction in weight and for attaining increased strength in not only electronic devices and domestic electric devices but also various parts and structures. As a pretreatment, a rib (3) is dipped in an aqueous solution of ammonia, hydrazine, a hydrazine derivative, or a water-soluble amine compound. A metal frame (2) is inserted into an injection mold for forming ribs (3) by injection molding. A thermoplastic resin composition is injected to the surface of the metal frame (2) by injection molding to form ribs (3). In the housing of a casing cover (1) thus formed, the metal frame (2) and the ribs (3) made of the thermoplastic resin composition are integrally bonded together. Thus, the housing improves strength and external appearance. Moreover, a complicated configuration and structure can be formed in the housing.

摘要翻译： 本发明不仅可以实现电子设备和家用电器，还可以实现各种部件和结构，实现重量的减轻和强度的提高。 作为预处理，将肋（3）浸渍在氨，肼，肼衍生物或水溶性胺化合物的水溶液中。 金属框架（2）通过注射成型插入到用于形成肋（3）的注射模具中。 将热塑性树脂组合物通过注射模塑注入金属框架（2）的表面以形成肋（3）。 在如此形成的壳体盖（1）的壳体中，金属框架（2）和由热塑性树脂组合物制成的肋（3）整体地结合在一起。 因此，壳体提高了强度和外观。 此外，可以在壳体中形成复杂的构造和结构。

公开(公告)号：US20080127479A1

公开(公告)日：2008-06-05

申请号：US12010472

申请日：2008-01-25

申请人： Masanori Naritomi ,  Naoki Ando ,  Masao Takahashi ,  Masao Shiraishi

发明人： Masanori Naritomi ,  Naoki Ando ,  Masao Takahashi ,  Masao Shiraishi

IPC分类号： B23P17/00

CPC分类号： B29C45/14311 ,  B29C45/14336 ,  B29C45/14778 ,  B29C2045/14868 ,  B29K2067/006 ,  B29K2705/00 ,  B29K2705/02 ,  B29L2031/3437 ,  Y10T29/49885 ,  Y10T29/4998 ,  Y10T29/49982 ,  Y10T29/49986 ,  Y10T428/12007

摘要： The present invention is useful for achieving a reduction in weight and for attaining increased strength in not only electronic devices and domestic electric devices but also various parts and structures. As a pretreatment, a rib (3) is dipped in an aqueous solution of ammonia, hydrazine, a hydrazine derivative, or a water-soluble amine compound. A metal frame (2) is inserted into an injection mold for forming ribs (3) by injection molding. A thermoplastic resin composition is injected to the surface of the metal frame (2) by injection molding to form ribs (3). In the housing of a casing cover (1) thus formed, the metal frame (2) and the ribs (3) made of the thermoplastic resin composition are integrally bonded together. Thus, the housing improves strength and external appearance. Moreover, a complicated configuration and structure can be formed in the housing.

摘要翻译： 本发明不仅可以实现电子设备和家用电器，还可以实现各种部件和结构，实现重量的减轻和强度的提高。 作为预处理，将肋（3）浸渍在氨，肼，肼衍生物或水溶性胺化合物的水溶液中。 金属框架（2）通过注射成型插入到用于形成肋（3）的注射模具中。 将热塑性树脂组合物通过注射模塑注入金属框架（2）的表面以形成肋（3）。 在如此形成的壳体盖（1）的壳体中，金属框架（2）和由热塑性树脂组合物制成的肋（3）整体地结合在一起。 因此，壳体提高了强度和外观。 此外，可以在壳体中形成复杂的构造和结构。

公开(公告)号：US20060127684A1

公开(公告)日：2006-06-15

申请号：US10533655

申请日：2003-11-07

申请人： Masanori Naritomi ,  Naoki Ando ,  Masao Takahashi

发明人： Masanori Naritomi ,  Naoki Ando ,  Masao Takahashi

IPC分类号： B32B15/08 ,  B29C45/14

CPC分类号： B32B15/08 ,  B29C45/14311 ,  B29C45/14778 ,  B29K2081/04 ,  B29K2705/00 ,  B29K2705/02 ,  B32B15/20 ,  B32B27/28 ,  B32B2398/20 ,  C23F1/20 ,  C23F1/36 ,  Y10T428/31536 ,  Y10T428/31678 ,  Y10T428/31681

摘要： The present invention allows both the advantages of a metallic housing and those of a synthetic resin structure to be exhibited in electronic devices, home electrical devices, etc., and achieves high productivity and mass productivity and further enables a desired configuration and structure to be designed freely. As a pretreatment, a shaped aluminum alloy material is dipped in an aqueous solution of at least one selected from the group consisting of ammonia, hydrazine, and a water-soluble amine compound. A thermoplastic resin composition containing polyphenylene sulfide as a component is integrally bonded to the surface of the treated shaped aluminum alloy material by injection molding or other method. The molded article is a product made of the shaped aluminum alloy material and the thermoplastic resin composition containing PPS. Thus, the characteristic features of metal can be utilized in terms of mechanical strength and external appearance design. Moreover, a complicated configuration and structure can be formed inside the housing.

摘要翻译： 本发明允许金属外壳和合成树脂结构的优点在电子设备，家用电器等中显现，并且实现高生产率和批量生产率，并且还能够设计所需的配置和结构 自由地 作为预处理，将成形的铝合金材料浸渍在选自氨，肼和水溶性胺化合物中的至少一种的水溶液中。 含有聚苯硫醚作为成分的热塑性树脂组合物通过注射成型或其它方法与处理成型的铝合金材料的表面一体地结合。 模制品是由成形铝合金材料和含有PPS的热塑性树脂组合物制成的产品。 因此，可以在机械强度和外观设计方面利用金属的特征。 此外，可以在壳体内形成复杂的构造和结构。

公开(公告)号：US20140065472A1

公开(公告)日：2014-03-06

申请号：US13989943

申请日：2011-11-25

申请人： Masanori Naritomi ,  Naoki Andoh

发明人： Masanori Naritomi ,  Naoki Andoh

IPC分类号： H01M2/04

CPC分类号： H01M2/0478 ,  B29C45/14311 ,  B29C2045/14237 ,  B29K2705/02 ,  B29K2705/10 ,  B29L2031/7146 ,  H01M2/04 ,  H01M2/0404 ,  H01M2/06 ,  H01M2/08 ,  H01M4/661 ,  H01M10/0525 ,  H01M10/058 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  Y10T428/24355

摘要： A metal-resin composite having high gas sealing properties is provided. An aluminum alloy structure having a shape surrounding the copper 63 is firstly formed, and the attached aluminum alloy is made closely contact with the copper electrode 63 and further made engaged into the copper electrode 63 by pressing or forging. It is then machined into a predetermined shape so as to prepare the copper alloy 63 attached with an aluminum alloy part 61a. Subsequently, the surface treatment of the NMT or NMT 2 is given to three members of an aluminum electrode 62, the copper electrode 63 attached with the aluminum alloy part 61a and an aluminum alloy lid 61. These three members are inserted into an injection mold, and a thermoplastic resin composition 64 of PPS resin is injected. The lithium-ion battery lid 60 having a structure as shown in FIG. 11 is thus obtained.

摘要翻译： 提供了一种具有高气密性的金属 - 树脂复合材料。 首先形成具有围绕铜63的形状的铝合金结构，并且将附着的铝合金与铜电极63紧密接触，并通过冲压或锻造进一步与铜电极63接合。 然后将其加工成预定形状，以制备附有铝合金部件61a的铜合金63。 随后，对铝电极62，附着有铝合金部61a的铜电极63和铝合金盖61的三个部件赋予NMT或NMT2的表面处理。这三个部件插入注射模具中， 注入PPS树脂的热塑性树脂组合物64。 具有如图1所示的结构的锂离子电池盖60。 11得到。