摘要:
A process for producing a terminal-modified polyphenylene ether represented by formula (III): ##STR1## wherein Q.sup.1 represents a halogen atom, a primary of secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; Q.sup.2 represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbon oxy group, or a halo-hydrocarbon oxy group; n represents an integer of at least 10; X represents an oxygen atom or a nitrogen atom;R.sup.1 represents an alkylene group having from 1 to 12 carbon atoms; R.sup.2 and R.sup.3 each represents a hydrocarbon group having from 1 to 6 carbon atoms; s represents 1 when X is an oxygen atom, or 2 when X is a nitrogen atom; and t represents an integer of from from 1 to 3,which comprises reacting a polyphenylene ether represented by formula (I): ##STR2## wherein Q.sup.1, Q.sup.2, and n are as defined above, with a compound represented by formula (II): ##STR3## wherein X, R.sup.1, R.sup.2, R.sup.3, s, and t are as defined above; a process for producing an alkoxysilylated polyphenylene ether represented by formula (V): ##STR4## wherein Q.sup.1, Q.sup.2, and n are as defined above; R.sup.11 represents a bond or an alkylene group having from 1 to 12 carbon atoms; R.sup.12 and R.sup.13 each represents a hydrocarbon group having from 1 to 6 carbon atoms; and m represents an integer of from 1 to 3, which comprises reacting a polyphenylene ether represented by formula (I) shown above with a compound represented by formula (IV): ##STR5## wherein R.sup.11, R.sup.12, R.sup.13, and m are as defined above; and Y represents a halogen atom;and a thermoplastic resin composition comprising the modified polyphenylene ether of formula (III) or (IV) with a saturated polyester, a polyamide, or a modified olefin resin.
摘要:
Thermoplastic resin composition comprising the following components A and B is presented which improves the compatibility of component resins, to achieve a thermoplastic resin having excellent molding property and mechanical strength:A. 90 to 10 wt % of a polyolefin resin containing a substituted silyl group represented by general formula;--SiR.sub.n Y.sub.3-n (wherein, R is aliphatic hydrocarbon group; Y is hydrolyzable group or hydroxyl group; n represents 0, 1 or 2), andB. 10 to 90 wt % of saturated polyester resin or hydroxyalkylated polycarbonate resin or hydroxyalkylated polyphenylene ether resin.
摘要:
A contact detecting apparatus for detecting the contact of a workpiece with a tool in a machine tool which includes a magnetic coil mounted on the periphery of a spindle head and connected to an AC power source for generating an induced current in a looped secondary circuit including the workpiece, a work table, a machine body, a spindle head, a tool spindle and the tool, when the workpiece and the tool are moved relatively into contact with each other. A first conductive wire forming a secondary winding of one turn is arranged in a parallel relationship with the looped secondary circuit and a current induced therein by energization of the magnetic coil. A second conductive wire is connected at one end thereof to the looped secondary circuit. A detecting device is connected to the first and second conductive wires for detecting contact between the workpiece and the tool based on the voltage induced across the first and second conductive wires.
摘要:
A thermoplastic resin composition comprising (a) a polyphenylene sulfide resin, (b) a polyphenylene ether resin, (c) a specific organophosphorus compound, and (d) a basic compound is disclosed. The composition exhibits improved compatibility between resinous components (a) and (b) and therefore provides a molded article having high mechanical strength and excellent appearance.
摘要:
A process for producing an amino group terminated polyphenylene ether represented by the following general formula (I) ##STR1## wherein Q.sup.1 s each represents a halogen atom, a primary or secondary alkyl group, a phenyl group, an aminoalkyl group, a hydrocarbon oxy group or a halohydrocarbon oxy group; Q.sup.2 s each represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, a phenyl group, a haloalkyl group, a hydrocarbon oxy group or halohydrocarbon oxy group; R represents an aliphatic hydrocarbon group having 1 to 32 carbon atoms, an aromatic hydrocarbon group or an araliphatic hydrocarbon group; and n is a number of 10 to 500, which process comprises reacting a polyphenylene ether represented by the following general formula (II) ##STR2## wherein Q.sub.1, Q.sub.2 and n are as define above, with a primary amine halide represented by the following general formula (III)X--R--NH.sub.2 (III)wherein R is as defined above, and X represents a halogen atom.
摘要:
A thermoplastic resin composition comprising (A) from about 10 to about 90% by weight of a hydroxyalkylated polyphenylene ether represented by formula (I): ##STR1## wherein A represents a residue of a polyphenylene ether from which a hydroxyl group is removed; and n represents an integer of from 1 to 10, and (B) from about 10 to about 90% by weight of a resin selected from a carboxyl-containing olefin resin, an epoxy-containing olefin resin, a hydroxyl-containing olefin resin, a polyamide resin, and a saturated polyester resin, provided that when (B) is the olefin resin, the hydroxyalkylated polyphenylene ether also can be represented by formula (II): ##STR2## wherein A is defined as above; X represents an oxygen atom or a nitrogen atom; R.sup.1 represents an alkylene group having from 1 to 12 carbon atoms; R.sup.2 and R.sup.3 each represents a hydrocarbon group having from 1 to 6 carbon atoms; s represents 1 when X is an oxygen atom, or 2 when X is a nitrogen atom; and t represents an integer of from 1 to 3.
摘要:
A thermoplastic resin composition comprising (a) from 10 to 90% by weight of polyphenylene sulfide and (b) from 10 to 90% by weight of hydroxyalkylated polyphenylene ether which exhibits improved compatibility between components (a) and (b) and provides molded articles having characteristics inherent to polyphenylene sulfide and polyphenylene ether, i.e., excellent mechanical strength, excellent rigidity, and good appearance.
摘要:
A thermoplastic resin composition comprising (A) from about 10 to about 90% by weight of a hydroxyalkylated polyphenylene ether represented by formula (I): ##STR1## wherein A represents a residue of a polyphenylene ether from which a hydroxyl group is removed; and n represents an integer of from 1 to 10,and (B) from about 10 to about 90% by weight of a resin selected from a carboxyl-containing olefin resin, an epoxy-containing olefin resin, a hydroxyl-containing olefin resin, a polyamide resin, and a saturated polyester resin, provided that when (B) is the olefin resin, the hydroxyalkylated polyphenylene ether also can be represented by formula (II): ##STR2## werein A is defined as above; X represents an oxygen atom or a nitrogen atom; R.sup.1 represents an alkylene group having from 1 to 12 carbon atoms; R.sup.2 and R.sup.3 each represents a hydrocarbon group having from 1 to 6 carbon atoms; s represents 1 when X is an oxygen atom, or 2 when X is a nitrogen atom; and t represents an integer of from 1 to 3.
摘要:
In a numerically controlled grinding machine of the type which is adapted to perform a machining operation on the basis of the feed amounts specified as relative amounts in various modes of different grinding wheel feed speeds, a feed controller comprising in combination: a contact detector adapted to produce a contact signal upon detection of contact of the grinding wheel with a workpiece; a non-grinding feed remainder detector including a counter for counting feed control distribution pulses to detect the remainder of a preset feed amount at least in a non-grinding mode from a variation in the count value of the counter during a period between a time point of starting the non-grinding mode and a time point of receiving the contact signal from the contact detector; and a feed mode changing means adapted to change the feed mode of the grinding wheel in such a manner as to effect the remainder of the non-grinding feed at a speed lower than that of the non-grinding mode in response to the contact signal from the contact detector.
摘要:
A feed control apparatus wherein a servomotor control device responsive to feed pulses distributed from a numerical controller controls a d.c. servomotor to advance a grinding wheel carriage of a grinding machine through the rotation of a feed screw successsively at a speed-up feed rate, a rapid feed rate, a slow-down feed rate and a grinding feed rate. A detection device is provided, which outputs a velocity checking signal to an abnormality confirmation device when the carriage reaches a velocity checking point defined within a slow-down feed range. When confirming that the feed rate of the carriage has exceeded a reference feed rate lower than the rapid feed rate, the abnormality confirmation device applies a stop signal to an emergency stop control circuit in response to the velocity checking signal, so that the rotation of the servomotor is immediately discontinued.